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1. 发明授权

US08350245B2 Variable resistance element and nonvolatile semiconductor memory device using the same 有权
标题翻译：可变电阻元件和使用其的非易失性半导体存储器件
公开(公告)号：US08350245B2
公开(公告)日：2013-01-08
申请号：US13133809
申请日：2009-12-08
申请人： Kiyotaka Tsuji
发明人： Kiyotaka Tsuji
IPC分类号： H01L29/02
CPC分类号： H01L27/101 , H01L27/2436 , H01L27/2472 , H01L45/08 , H01L45/1233 , H01L45/146 , H01L45/1625 , H01L45/1675
摘要： To provide a variable resistance element capable of preventing the interface resistance, in a side of the variable resistance element in which resistance change is not allowed, from changing to high resistance due to applied voltage. The variable resistance element is configured by providing a variable resistance film (265) between a first electrode (280) and a second electrode (250), the oxygen concentration within the film of the variable resistance film (265) is high at the side of an interface with the second electrode (250) (high-concentration variable resistance layer (260)) and low at the side of an interface with the first electrode (280) (low-concentration variable resistance layer (270)), and the junction surface area between the low-concentration variable resistance layer (270) and the first electrode (280) is larger than the interface surface area between the high-concentration variable resistance layer (260) and the second electrode (250).
摘要翻译：为了提供一种可变电阻元件，能够防止在不允许电阻变化的可变电阻元件侧的界面电阻由于施加的电压而变为高电阻。可变电阻元件通过在第一电极（280）和第二电极（250）之间设置可变电阻膜（265）而构成，可变电阻膜（265）的膜内的氧浓度在与第二电极（250）（高浓度可变电阻层（260））的界面和与第一电极（280）的界面侧的低（低浓度可变电阻层（270））的界面，低浓度可变电阻层（270）和第一电极（280）之间的表面积大于高浓度可变电阻层（260）和第二电极（250）之间的界面面积。

2. 发明申请

US20110074539A1 VARIABLE RESISTANCE ELEMENT AND MANUFACTURING METHOD OF THE SAME 有权
标题翻译：可变电阻元件及其制造方法
公开(公告)号：US20110074539A1
公开(公告)日：2011-03-31
申请号：US12994916
申请日：2010-04-14
申请人： Kiyotaka Tsuji
发明人： Kiyotaka Tsuji
IPC分类号： H01C7/10 , H01C17/00
CPC分类号： H01L45/1246 , H01L27/101 , H01L45/08 , H01L45/1233 , H01L45/146 , H01L45/1625 , H01L45/1683 , Y10T29/49082
摘要： A variable resistance element capable of increasing stability of a resistance changing operation and reducing a current necessary for changing, to a low resistance state for the first time, the variable resistance element in an initial state immediately after manufacture. The variable resistance element includes: a first electrode (101); a memory cell hole (150) formed above the first electrode (101); a first variable resistance layer (201) covering a bottom of the memory cell hole (150) and an upper surface of the first electrode (101); a second variable resistance layer (202) formed on the first variable resistance layer (201); and a second electrode (102) formed on the memory cell hole (150), in which a thickness of the first variable resistance layer (201) at the bottom of the memory cell hole (150) gradually decreases toward an edge area of the memory cell hole (150) and has a local minimum value around the edge area of the memory cell hole (150). Furthermore, an oxygen concentration in the first variable resistance layer (201) is higher than an oxygen concentration in the second variable resistance layer (202).
摘要翻译：一种可变电阻元件，其能够增加电阻变化操作的稳定性，并且减少在制造后立即将初始状态中的可变电阻元件首次变为低电阻状态所需的电流。可变电阻元件包括：第一电极（101）; 形成在所述第一电极（101）上方的存储单元孔（150）; 覆盖存储单元孔（150）底部的第一可变电阻层（201）和第一电极（101）的上表面; 形成在第一可变电阻层（201）上的第二可变电阻层（202）; 以及形成在存储单元孔（150）上的第二电极（102），其中存储单元孔（150）底部的第一可变电阻层（201）的厚度朝向存储器的边缘区域逐渐减小电池孔（150），并且在存储单元孔（150）的边缘区域周围具有局部最小值。此外，第一可变电阻层（201）中的氧浓度高于第二可变电阻层（202）中的氧浓度。

3. 发明申请

US20100295012A1 NONVOLATILE MEMORY ELEMENT, AND NONVOLATILE MEMORY DEVICE 有权
标题翻译：非易失性存储元件和非易失性存储器件
公开(公告)号：US20100295012A1
公开(公告)日：2010-11-25
申请号：US12863535
申请日：2009-11-18
申请人： Takumi Mikawa , Kiyotaka Tsuji , Takashi Okada
发明人： Takumi Mikawa , Kiyotaka Tsuji , Takashi Okada
IPC分类号： H01L27/10 , H01L45/00
CPC分类号： G11C13/003 , G11C13/0007 , G11C13/0069 , G11C2013/0073 , G11C2213/15 , G11C2213/32 , G11C2213/56 , G11C2213/72 , G11C2213/76 , H01L27/101 , H01L27/2409 , H01L27/2463 , H01L27/2481 , H01L45/08 , H01L45/1233 , H01L45/146 , H01L45/1625 , H01L45/1675 , H01L45/1683
摘要： A nonvolatile memory element comprises a resistance variable element 105 configured to reversibly change between a low-resistance state and a high-resistance state in response to electric signals with different polarities which are applied thereto; and a current controlling element 112 configured such that when a current flowing when a voltage whose absolute value is a first value as a desired value which is larger than 0 and smaller than a predetermined voltage value and whose polarity is a first polarity is applied is a first current and a current flowing when a voltage whose absolute value is the first value and whose polarity is a second polarity different from the first polarity is applied is a second current, the first current is higher than the second current, and the resistance variable element is connected in series with the current controlling element such that a polarity of a voltage applied to the current controlling element when the resistance variable element is changed from the low-resistance state to the high-resistance state is the first polarity.
摘要翻译：非易失性存储元件包括电阻可变元件105，其被配置为响应于施加到其上的具有不同极性的电信号在低电阻状态和高电阻状态之间可逆地变化; 以及电流控制元件112，被配置为当施加绝对值为第一值的电压作为大于0且小于预定电压值且极性为第一极性的期望值的电流流过的电流控制元件112为当施加绝对值为第一值且极性为与第一极性不同的第二极性的电压时的第一电流和电流是第二电流，第一电流高于第二电流，并且电阻可变元件与电流控制元件串联连接，使得当电阻可变元件从低电阻状态改变为高电阻状态时施加到电流控制元件的电压的极性是第一极性。

4. 发明申请

US20060056250A1 Magnetic memory, and its operating method 有权
标题翻译：磁记忆体及其操作方法
公开(公告)号：US20060056250A1
公开(公告)日：2006-03-16
申请号：US10512545
申请日：2003-04-21
申请人： Sadahiko Miura , Tadahiko Sugibayashi , Hideaki Numata , Kiyotaka Tsuji
发明人： Sadahiko Miura , Tadahiko Sugibayashi , Hideaki Numata , Kiyotaka Tsuji
IPC分类号： G11C7/00
CPC分类号： H01L27/228 , B82Y10/00 , G11C11/16
摘要： A technology for eliminating the defects in a tunnel insulation film of magnetic tunnel junction and for suppressing generation of a defective bit in an MRAM using magnetic tunnel junction in a memory. The magnetic memory includes a substrate, an interlayer insulation film covering the upper surface side of the substrate, memory cells, and plugs penetrating the interlayer insulation film. The memory cell includes a first magnetic layer formed on the upper surface side of the interlayer insulation film, a tunnel insulation layer formed on the first magnetic layer, and a second magnetic layer formed on the tunnel insulation layer. The plug is connected electrically with the first magnetic layer. The tunnel current passing part of the tunnel insulation layer located between the first and second magnetic layers is arranged, at least partially, so as not to overlap the plug in the direction perpendicular to the surface of the substrate.
摘要翻译：一种用于消除磁隧道结隧道绝缘膜中的缺陷并用于抑制在存储器中使用磁性隧道结的MRAM中的有缺陷位的产生的技术。磁性存储器包括基板，覆盖基板的上表面侧的层间绝缘膜，存储单元和穿透层间绝缘膜的插塞。存储单元包括形成在层间绝缘膜的上表面侧的第一磁性层，形成在第一磁性层上的隧道绝缘层和形成在隧道绝缘层上的第二磁性层。插头与第一磁性层电连接。位于第一和第二磁性层之间的隧道绝缘层的隧道电流通过部分被布置成至少部分地不与垂直于衬底的表面的方向上的插塞重叠。

5. 发明授权

US08900965B2 Nonvolatile memory device manufacturing method 有权
标题翻译：非易失性存储器件制造方法
公开(公告)号：US08900965B2
公开(公告)日：2014-12-02
申请号：US13884630
申请日：2012-03-21
申请人： Haruyuki Sorada , Takumi Mikawa , Kenji Tominaga , Kiyotaka Tsuji
发明人： Haruyuki Sorada , Takumi Mikawa , Kenji Tominaga , Kiyotaka Tsuji
IPC分类号： H01L45/00 , H01L27/24 , H01L27/10
CPC分类号： H01L45/16 , H01L27/101 , H01L27/2409 , H01L27/2418 , H01L27/2463 , H01L45/04 , H01L45/1683
摘要： A method of manufacturing a nonvolatile memory device that is a variable resistance nonvolatile memory device, which has good consistency with a dual damascene process that is suitable for the formation of fine copper lines and which enables large capacity and high integration. This method includes: forming a variable resistance element, a contact hole and a line groove; and forming a current steering layer of a bidirectional diode element above interlayer insulating layers and a variable resistance layer to cover the line groove without covering a bottom surface of the contact hole.
摘要翻译：一种制造非易失性存储器件的方法，其是可变电阻非易失性存储器件，其与适合于形成细铜线的双镶嵌工艺具有良好的一致性，并且能够实现大容量和高集成度。该方法包括：形成可变电阻元件，接触孔和线槽; 并且在层间绝缘层之上形成双向二极管元件的电流转向层和可变电阻层以覆盖线槽而不覆盖接触孔的底表面。

6. 发明申请

US20130148407A1 NONVOLATILE SEMICONDUCTOR MEMORY DEVICE AND READ METHOD FOR THE SAME 有权
标题翻译：非易失性半导体存储器件及其读取方法
公开(公告)号：US20130148407A1
公开(公告)日：2013-06-13
申请号：US13700346
申请日：2012-06-18
申请人： Kiyotaka Tsuji , Kazuhiko Shimakawa
发明人： Kiyotaka Tsuji , Kazuhiko Shimakawa
IPC分类号： G11C13/00
CPC分类号： G11C13/004 , G11C11/1673 , G11C13/0002 , G11C13/0004 , G11C13/0007 , G11C13/0011 , G11C13/003 , G11C2013/0054 , G11C2213/77
摘要： A nonvolatile semiconductor memory device includes: word lines; bit lines formed so as to three-dimensionally cross the word lines; and a cross-point cell array including cells each provided at a corresponding one of three-dimensional cross-points of the word lines and the bit lines. The cells include: a memory cell including a memory element that operates as a memory by reversibly changing in resistance value between at least two states based on an electrical signal; and an offset detection cell having a constant resistance value that is higher than the resistance value of the memory element in a high resistance state which is a state of the memory element when operating as the memory.
摘要翻译：非易失性半导体存储器件包括：字线; 形成为三维地跨越字线的位线; 以及包括各自提供在字线和位线的三维交叉点中的相应一个的单元的交叉点单元阵列。单元包括：存储单元，其包括通过基于电信号在至少两个状态之间可逆地改变电阻值而作为存储器操作的存储元件; 以及偏移检测单元，其具有比作为存储器操作时作为存储元件的状态的高电阻状态下的存储元件的电阻值高的恒定电阻值。

7. 发明申请

US20120193600A1 VARIABLE RESISTANCE NONVOLATILE MEMORY ELEMENT, METHOD OF MANUFACTURING THE SAME, AND VARIABLE RESISTANCE NONVOLATILE MEMORY DEVICE 审中-公开
标题翻译：可变电阻非易失性存储器元件，其制造方法和可变电阻非易失性存储器件
公开(公告)号：US20120193600A1
公开(公告)日：2012-08-02
申请号：US13499961
申请日：2011-07-01
申请人： Atsushi Himeno , Kiyotaka Tsuji
发明人： Atsushi Himeno , Kiyotaka Tsuji
IPC分类号： H01L47/00 , H01L21/02
CPC分类号： H01L27/2463 , H01L27/2409 , H01L45/08 , H01L45/1233 , H01L45/145 , H01L45/1625 , H01L45/1683
摘要： A variable resistance nonvolatile memory element (10) is formed from a first electrode (101) comprising a material including a metal as a main component, a variable resistance layer (102) having a reversibly changing resistance value in response to applied predetermined electric pulses having different polarities, a semiconductor layer (103) comprising a material including a nitrogen-deficient silicon nitride as a main component, and a second electrode (104). The variable resistance layer (102) includes a first variable resistance layer (102a) adjacent to the first electrode (101) and a second variable resistance layer (102b), both comprising a material including an oxygen-deficient transition metal oxide as a main component. The first variable resistance layer (102a) has a higher oxygen content atomic percentage than the second variable resistance layer (102b). A stacked structure of the variable resistance layer (102), the semiconductor layer (103), and the second electrode (104) functions as a bidirectional diode element (106).
摘要翻译：可变电阻非易失性存储元件（10）由包括以金属为主要成分的材料的第一电极（101）形成，可变电阻层（102）响应于所施加的预定电脉冲具有可逆变化的电阻值，不同极性的半导体层（103）和第二电极（104），包括氮缺乏氮化物作为主要成分的材料。可变电阻层（102）包括与第一电极（101）相邻的第一可变电阻层（102a）和第二可变电阻层（102b），二者包括以氧缺乏的过渡金属氧化物为主要成分的材料。第一可变电阻层（102a）具有比第二可变电阻层（102b）更高的氧含量原子百分比。可变电阻层（102），半导体层（103）和第二电极（104）的堆叠结构用作双向二极管元件（106）。

8. 发明申请

US20110240942A1 VARIABLE RESISTANCE ELEMENT AND NONVOLATILE SEMICONDUCTOR MEMORY DEVICE USING THE SAME 有权
标题翻译：可变电阻元件和非易失性半导体存储器件
公开(公告)号：US20110240942A1
公开(公告)日：2011-10-06
申请号：US13133809
申请日：2009-12-08
申请人： Kiyotaka Tsuji
发明人： Kiyotaka Tsuji
IPC分类号： H01L45/00
CPC分类号： H01L27/101 , H01L27/2436 , H01L27/2472 , H01L45/08 , H01L45/1233 , H01L45/146 , H01L45/1625 , H01L45/1675
摘要： To provide a variable resistance element capable of preventing the interface resistance, in a side of the variable resistance element in which resistance change is not allowed, from changing to high resistance due to applied voltage. The variable resistance element is configured by providing a variable resistance film (265) between a first electrode (280) and a second electrode (250), the oxygen concentration within the film of the variable resistance film (265) is high at the side of an interface with the second electrode (250) (high-concentration variable resistance layer (260)) and low at the side of an interface with the first electrode (280) (low-concentration variable resistance layer (270)), and the junction surface area between the low-concentration variable resistance layer (270) and the first electrode (280) is larger than the interface surface area between the high-concentration variable resistance layer (260) and the second electrode (250).
摘要翻译：为了提供一种可变电阻元件，能够防止在不允许电阻变化的可变电阻元件侧的界面电阻由于施加的电压而变为高电阻。可变电阻元件通过在第一电极（280）和第二电极（250）之间设置可变电阻膜（265）而构成，可变电阻膜（265）的膜内的氧浓度在与第二电极（250）（高浓度可变电阻层（260））的界面和与第一电极（280）的界面侧的低（低浓度可变电阻层（270））的界面，低浓度可变电阻层（270）和第一电极（280）之间的表面积大于高浓度可变电阻层（260）和第二电极（250）之间的界面面积。

9. 发明授权

US07628903B1 Silver and silver alloy plating bath 有权
标题翻译：银和银合金电镀浴
公开(公告)号：US07628903B1
公开(公告)日：2009-12-08
申请号：US09563479
申请日：2000-05-02
申请人： Kiyotaka Tsuji , Tetsuji Nishikawa , Takao Takeuchi , Keigo Obata , Hidemi Nawafune
发明人： Kiyotaka Tsuji , Tetsuji Nishikawa , Takao Takeuchi , Keigo Obata , Hidemi Nawafune
IPC分类号： C25D3/46 , C23C18/31
CPC分类号： C25D3/46 , C25D3/64
摘要： A silver and silver alloy plating bath, includes (A) a soluble salt, having a silver salt or a mixture of a silver salt and a salt of a metal such as tin, bismuth, indium, lead, and the like; and (B) a particular aliphatic sulfide compound, such as thiobis(diethyleneglycol), dithiobis(triglycerol), 3,3′-thiodipropanol, thiodiglycerin, 3,6-dithiooctane-1,8-diol, and the like, which contain at least one or more of an ether oxygen atom, a 1-hydroxypropyl group, a hydroxypropylene group, or two or more of a sulfide bond in the molecule, and not containing a basic nitrogen atom. Compared to baths containing aliphatic monosulfide compounds, such as thiodiglycol or beta-thiodiglycol, which do not contain an ether oxygen atom, 1-hydroxypropyl group, a hydroxypropylene group, or two or more of a sulfide bond in the molecule, by having these particular compounds, the plating bath of the present invention has excellent stability over extended time, excellent co-deposition of silver and various metals, and excellent appearance of the electrodeposition coating.
摘要翻译：银和银合金电镀浴包括（A）可溶性盐，其具有银盐或银盐和金属如锡，铋，铟，铅等的盐的混合物; 和（B）特定的脂族硫醚化合物，例如硫代双（二甘醇），二硫代双（三甘油），3,3'-硫代二丙醇，硫二甘油，3,6-二硫辛烷-1,8-二醇等，至少一个或多个醚氧原子，1-羟丙基，羟基亚丙基，或分子中的硫原子键中的两个或多个，并且不含碱性氮原子。与分子中含有不含醚氧原子，1-羟丙基，羟基亚丙基或两个或多个硫键的脂族单硫醚化合物如硫二甘醇或β-硫二甘醇相比，具有这些特定化合物，本发明的电镀浴在延长的时间内具有优异的稳定性，优异的银和各种金属的共沉积，以及优异的电沉积外观。

10. 发明申请

US20090238127A1 MOBILE COMMUNICATION SYSTEM 有权
标题翻译：移动通信系统
公开(公告)号：US20090238127A1
公开(公告)日：2009-09-24
申请号：US12365782
申请日：2009-02-04
申请人： Kiyotaka TSUJI
发明人： Kiyotaka TSUJI
IPC分类号： H04W4/00
CPC分类号： H04L41/00 , H04L41/22 , H04W24/00
摘要： According to an aspect of the present invention, there is provided a mobile communication system which comprises a plurality of base stations each accommodating mobile terminals via radio channels, and base station control devices connecting the base stations to an Internet Protocol (IP) network via cable channels, and achieves voice communication through Voice over IP (VoIP) via the IP network. And the mobile communication system comprises a system management device which is connected to the base station control devices via the IP network and acquires operation information of the plurality of base stations through the base station control devices.
摘要翻译：根据本发明的一个方面，提供了一种移动通信系统，其包括多个基站，每个基站经由无线电信道容纳移动终端，以及基站控制设备，经由电缆将基站连接到因特网协议（IP）网络通过IP网络实现通过IP语音（VoIP）的语音通信。并且移动通信系统包括经由IP网络连接到基站控制装置的系统管理装置，并通过基站控制装置获取多个基站的操作信息。

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