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1. 发明申请

US20070276075A1 Process for Producing Polyorganosiloxane-Containing Resin and Resin Composition Containing the Resin 审中-公开
标题翻译：含有有机硅氧烷的树脂和含有树脂的树脂组合物的制造方法
公开(公告)号：US20070276075A1
公开(公告)日：2007-11-29
申请号：US10592015
申请日：2005-03-11
申请人： Akira Takaki , Takao Michinobu
发明人： Akira Takaki , Takao Michinobu
IPC分类号： C08J3/16 , C08G77/20
CPC分类号： C08G77/34 , C08F6/005 , C08F283/12 , C08J3/16 , C08J2383/04 , C08L51/085 , C08L55/02 , C08L69/00 , C08L83/04 , C08L2666/24 , C08L2666/02 , C08L2666/14
摘要： The present invention provides a polyorganosiloxane-containing resin decreased in volatile siloxane content. A resin which contains 5% or more of volatile silicon compounds immediately after coagulation and dehydration is mixed with an organic solvent, and the resultant mixture is filtered to decrease the content of the volatile silicon compounds in the resin. Therefore, the target polyorganosiloxane-containing resin decreased in volatile siloxane content can be obtained. Mixing the polyorganosiloxane-containing resin and a thermoplastic resin and/or a thermosetting resin gives a resin composition having improved strength.
摘要翻译：本发明提供了含有有机硅氧烷的树脂，其挥发性硅氧烷含量降低。在凝结和脱水后立即含有5％以上挥发性硅化合物的树脂与有机溶剂混合，过滤所得混合物以降低树脂中挥发性硅化合物的含量。因此，可以获得挥发性硅氧烷含量降低的含目标聚有机硅氧烷的树脂。混合含聚有机硅氧烷的树脂和热塑性树脂和/或热固性树脂，得到强度提高的树脂组合物。

2. 发明申请

US20140048489A1 ION-EXCHANGE FIBERS AND METHOD FOR PRODUCING SAME, METHOD FOR REMOVING AND ADSORBING CHEMICAL SUBSTANCE IN WATER, AND DEVICE FOR REMOVING AND ADSORBING CHEMICAL SUBSTANCE IN WATER 有权
标题翻译：离子交换纤维及其制造方法，水中除去和吸附化学物质的方法以及用于除去和吸附化学物质的装置
公开(公告)号：US20140048489A1
公开(公告)日：2014-02-20
申请号：US14113704
申请日：2012-04-27
申请人： Yusuke Hirai , Wataru Mio , Masanobu Tamura , Yoshitomo Matsumoto , Takao Michinobu
发明人： Yusuke Hirai , Wataru Mio , Masanobu Tamura , Yoshitomo Matsumoto , Takao Michinobu
IPC分类号： B01J47/12 , C02F1/42
CPC分类号： B01J47/123 , B01J41/14 , B01J45/00 , B01J47/12 , B01J47/127 , C02F1/42 , C08J5/20 , D01F6/54 , D01F11/06 , D06M13/332 , D06M2101/28 , G21F9/12 , G21F9/125
摘要： Provided is an ion-exchange fiber including a polymer A obtained by introducing an ion-exchangeable substituent to 100 parts by weight of an acrylic polymer that is obtained by polymerization of a monomer composition containing 30% by weight or more of acrylonitrile with respect to 100% by weight of the composition and a polymer B obtained by introducing an ion-exchangeable substituent to 1 part by weight or more and 100 parts by weight or less of an epoxy group-containing polymer. Each ion-exchangeable substituent is introduced by reaction with an amine compound and is an ion-exchangeable substituent derived from the amine compound. A method for producing the ion-exchange fiber is also provided.
摘要翻译：本发明提供一种离子交换纤维，其包含通过将100重量份的丙烯酸类聚合物引入离子交换性取代基而得到的聚合物，所述丙烯酸类聚合物相对于100重量份聚合含有30重量％以上的丙烯腈的单体组合物以及通过将可离子交换的取代基引入1重量份以上而得到的聚合物B和100重量份以下的含环氧基的聚合物。每个可离子交换的取代基通过与胺化合物反应引入，并且是衍生自胺化合物的可离子交换的取代基。还提供了一种生产离子交换纤维的方法。

3. 发明申请

US20130108827A1 ADHESIVE RESIN COMPOSITION AND MOLDED PRODUCTS 有权
标题翻译：粘合树脂组合物和成型产品
公开(公告)号：US20130108827A1
公开(公告)日：2013-05-02
申请号：US13641182
申请日：2011-04-08
申请人： Yasunori Okada , Takashi Matsumoto , Takao Michinobu
发明人： Yasunori Okada , Takashi Matsumoto , Takao Michinobu
IPC分类号： C09J151/06 , B32B27/08
CPC分类号： C09J151/06 , B32B7/12 , B32B15/08 , B32B27/08 , B32B27/302 , C08F212/08 , C08F255/04 , C08F255/10 , C08L9/00 , C08L51/06 , C08L53/02 , C08L53/025 , Y10T428/2419 , Y10T428/24777 , Y10T428/31507 , Y10T428/31692 , Y10T428/31757 , Y10T428/31797 , Y10T428/31913 , Y10T428/31928 , C08F220/32
摘要： An adhesive resin composition, including: a base resin which comprises (A) 30-90 parts by weight of a modified ethylene-olefin copolymer, and (B) 70-10 parts by weight of a styrene thermoplastic elastomer, provided that (A)+(B) equals 100 parts by weight; and (C) a tackifier in an amount of 30-60 parts by weight per 100 parts by weight of the base resin, the modified ethylene-olefin copolymer being one which has been graft-modified with (a) an unsaturated carboxylic acid or a derivative thereof and (b) an aromatic vinyl monomer, comprises 0.1%-5% by weight of (a) the unsaturated carboxylic acid or the derivative thereof, and has a melting point peak in a range of 100-150° C. with an enthalpy of crystal fusion of 0.5-10 J/g as determined by DSC.
摘要翻译：一种粘合剂树脂组合物，其包含：（A）30-90重量份改性乙烯 - 烯烃共聚物的基础树脂和（B）70-10重量份的苯乙烯热塑性弹性体，条件是（A） +（B）等于100重量份; 和（C）每100重量份基础树脂30-60重量份的增粘剂，改性乙烯 - 烯烃共聚物是用（a）不饱和羧酸或其衍生物和（b）芳族乙烯基单体包含0.1％-5％（重量）的（a）不饱和羧酸或其衍生物，并且具有在100-150℃范围内的熔点峰，通过DSC测定的晶体熔化焓为0.5-10J / g。

4. 发明授权

US09205422B2 Ion-exchange fibers and method for producing and using same 有权
标题翻译：离子交换纤维及其制造和使用方法
公开(公告)号：US09205422B2
公开(公告)日：2015-12-08
申请号：US14113704
申请日：2012-04-27
申请人： Yusuke Hirai , Wataru Mio , Masanobu Tamura , Yoshitomo Matsumoto , Takao Michinobu
发明人： Yusuke Hirai , Wataru Mio , Masanobu Tamura , Yoshitomo Matsumoto , Takao Michinobu
IPC分类号： B01J47/12 , G21F9/12 , C02F1/42 , C08J5/20 , D06M13/332 , D01F6/54 , B01J41/14 , D01F11/06 , B01J45/00 , D06M101/28
CPC分类号： B01J47/123 , B01J41/14 , B01J45/00 , B01J47/12 , B01J47/127 , C02F1/42 , C08J5/20 , D01F6/54 , D01F11/06 , D06M13/332 , D06M2101/28 , G21F9/12 , G21F9/125
摘要： Provided is an ion-exchange fiber including a polymer A obtained by introducing an ion-exchangeable substituent to 100 parts by weight of an acrylic polymer that is obtained by polymerization of a monomer composition containing 30 % by weight or more of acrylonitrile with respect to 100 % by weight of the composition and a polymer B obtained by introducing an ion-exchangeable substituent to 1 part by weight or more and 100 parts by weight or less of an epoxy group-containing polymer. Each ion-exchangeable substituent is introduced by reaction with an amine compound and is an ion-exchangeable substituent derived from the amine compound. A method for producing the ion-exchange fiber is also provided.
摘要翻译：本发明提供一种离子交换纤维，其包含通过将100重量份的丙烯酸类聚合物引入离子交换性取代基而得到的聚合物，所述丙烯酸类聚合物相对于100重量份聚合含有30重量％以上的丙烯腈的单体组合物以及通过将可离子交换的取代基引入1重量份以上而得到的聚合物B和100重量份以下的含环氧基的聚合物。每个可离子交换的取代基通过与胺化合物反应引入，并且是衍生自胺化合物的可离子交换的取代基。还提供了一种生产离子交换纤维的方法。

5. 发明申请

US20080125527A1 Flame-Retardant Resin Composition 审中-公开
标题翻译：阻燃树脂组合物
公开(公告)号：US20080125527A1
公开(公告)日：2008-05-29
申请号：US11547837
申请日：2005-04-04
申请人： Hiroshi Tsuneishi , Takao Michinobu
发明人： Hiroshi Tsuneishi , Takao Michinobu
IPC分类号： C09K21/06
CPC分类号： C08L25/04 , C08K3/34 , C08L69/00 , C08L71/12 , C08L83/04 , C08L2666/14 , C08L2666/02
摘要： There is provided a novel flame-retardant resin composition capable of expressing extremely high flame retardancy without a flame retardant containing a halogen atom, a phosphorus atom, a nitrogen atom, or the like.The present invention provides a composition including a thermoplastic resin mixture of an aromatic polycarbonate or the like (A) and an aromatic vinyl resin or the like (B); a silicone compound (C); and a specific metal silicate compound (D), the silicone compound (C) being represented by average chemical formula (1): R1mR2nSio(4−m−m)/2 (1) (wherein R1 represents a methyl group or the like; R2 represents a phenyl group or the like; and 1.1≦m+n≦1.7 and 0.4≦n/m≦2.5).
摘要翻译：提供了能够在不含有卤素原子，磷原子，氮原子等的阻燃剂的情况下表现出极高阻燃性的新型阻燃性树脂组合物。本发明提供了包含芳族聚碳酸酯等（A）和芳族乙烯基树脂等（B）的热塑性树脂混合物的组合物。硅氧烷化合物（C）; 和特定的金属硅酸盐化合物（D），硅化合物（C）由平均化学式（1）表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> （1）（1）（1）（2）（1） <？in-line-formula description =“In-line formula”end =“tail”？>（其中R 1表示甲基等; R 2 = 表示苯基等;且1.1≤m+ n <= 1.7且0.4≤n/m≤2.5）。

6. 发明申请

US20080073628A1 Flame-Retardant Resin Composition 审中-公开
标题翻译：阻燃树脂组合物
公开(公告)号：US20080073628A1
公开(公告)日：2008-03-27
申请号：US11662760
申请日：2005-09-27
申请人： Takao Michinobu , Hiroshi Tsuneishi
发明人： Takao Michinobu , Hiroshi Tsuneishi
IPC分类号： C09K21/14
CPC分类号： C08L71/12 , C08K5/5419 , C08L25/06 , C08L83/00 , C08L2666/02 , C08L2666/04
摘要： An object of the present invention is to provide a novel flame-retardant resin composition capable of exhibiting high flame retardancy without incorporation of flame retardants containing halogen atoms, phosphorus atoms, nitrogen atoms, and the like. A flame-retardant resin composition of the present invention includes a resin component composed of a polyphenylene ether resin (A) and an aromatic vinyl resin (B); a silicone compound (C) represented by the average compositional formula (1) below; and a metal silicate compound (D) having a pH of 8.0 or more and a volume-average particle size of 1 nm to 100 μm: R1mR2nSiO(4-m-n)/2 (1) (wherein R1 represents an aliphatic hydrocarbon group; R2 represents an aromatic hydrocarbon group; and m and n each represent a number satisfying the relationships: 1.1≦m+n≦1.7 and 0.4≦n/m≦2.5).
摘要翻译：本发明的目的是提供一种能够在不含有卤原子，磷原子，氮原子等的阻燃剂的情况下显示出高阻燃性的新型阻燃性树脂组合物。本发明的阻燃性树脂组合物包含由聚苯醚树脂（A）和芳香族乙烯基树脂（B）构成的树脂成分。由下述平均组成式（1）表示的硅氧烷化合物（C）以及pH为8.0以上，体积平均粒径为1nm〜100μm的金属硅酸盐化合物（D）：R 1，...，（4-mn）/ 2（1）（其中R 1表示脂族烃基; R 1，R 2， SUP> 2代表芳族烃基; m和n各自表示满足以下关系的数：1.1 <= m + n <= 1.7和0.4 <= n / m <= 2.5）。

7. 发明申请

US20070112157A1 Polyorganiosiloxane-containing graft copolymer, resin compositions containing the same and process for produciton of polyorganosiloxane emulsions 有权
公开(公告)号：US20070112157A1
公开(公告)日：2007-05-17
申请号：US10551944
申请日：2004-04-09
申请人： Tomomichi Hashimoto , Akira Takai , Kazunori Saegusa , Takao Manabe , Takao Michinobu
发明人： Tomomichi Hashimoto , Akira Takai , Kazunori Saegusa , Takao Manabe , Takao Michinobu
IPC分类号： C08F230/08
CPC分类号： C08G77/442 , C08F283/12 , C08F285/00 , C08K5/0066 , C08L51/085 , C08L83/10 , C08L2666/02
摘要： According to the present invention, a flame retardant can be obtained, which provides a thermoplastic resin composition excellent in flame retardancy and impact resistance, and by compounding this flame retardant in thermoplastic resin, a flame retardant resin composition excellent in flame retardancy and impact resistance can be obtained. The present invention relates to a graft copolymer containing polyorganosiloxane obtained by polymerizing 0 to 10 parts by weight of a vinyl monomer (B) comprising 100 to 20% by weight of a multi-functional monomer containing at least two polymerizable unsaturated bonds in a molecule (b-1) and 0 to 80% by weight of another copolymerizable monomer (b-2) and 5 to 70 parts by weight of a vinyl monomer (C), in the presence of 30 to 95 parts by weight of polyorganosiloxane in a latex state (A), so that the total amount of polyorganosiloxane (A), vinyl monomer (B) and vinyl monomer (C) becomes 100 parts by weight. Also, according to the present invention, in a process for preparing an emulsion of polyorganosiloxane, polymerization conversion ratio can be improved. The present invention relates to a process for preparing an emulsion of polyorganosiloxane, which comprises obtaining polyorganosiloxane (H) by emulsion polymerizing cyclic organosiloxane under acidic conditions of pH of at most 5 and adding condensation reactive organosilane represented by formula (I): R1nSi(OR2)(4-n) (1) (wherein R1 represents an organic group, R2 represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, n represents an integer of 0 to 3) or a partially hydrolyzed condensate thereof (I).

8. 发明申请

US20130264741A1 LAMINATED ADHESIVE FILM FOR USE IN INSERT MOLDING 审中-公开
标题翻译：用于嵌入式模具的层压粘合膜
公开(公告)号：US20130264741A1
公开(公告)日：2013-10-10
申请号：US13882888
申请日：2011-10-31
申请人： Tetsuo Ookura , Takao Michinobu
发明人： Tetsuo Ookura , Takao Michinobu
IPC分类号： C09J7/02 , B29C45/16
CPC分类号： B29C45/1679 , B29C45/14811 , B29K2715/006 , B32B27/08 , B32B27/32 , B32B27/34 , B32B2250/02 , B32B2405/00 , C09J7/29 , Y10T428/2826
摘要： The present invention relates to a laminated adhesive film for insert molding, which includes a laminate of a tacky adhesive film containing a modified polyolefin resin and a non-tacky thermoplastic resin film. The present invention aims to provide a highly heat-resistant laminated adhesive film which can form on a metal component an adhesive layer that shows favorable adhesion to a resin to be injection-molded, by a VOC-free high-productivity method. The laminated adhesive film for insert molding of the present invention includes a laminate of a tacky adhesive film containing a modified polyolefin resin obtained through graft-modification with a monomer that contains an ethylenic double bond and a polar group in the same molecule, and a non-tacky thermoplastic resin film.
摘要翻译：本发明涉及用于嵌入成型的层压粘合膜，其包括含有改性聚烯烃树脂的粘性粘合剂膜和非粘性热塑性树脂膜的层压体。本发明的目的是提供一种高耐热层压粘合剂膜，其可以通过无VOC的高生产率方法在金属部件上形成对待注塑的树脂显示良好的粘合性的粘合剂层。本发明的嵌入成型用层压粘合膜包括通过接枝改性而得到的含有改性聚烯烃树脂的粘合剂膜与在同一分子中含有烯属双键和极性基团的单体的粘合膜，热塑性树脂薄膜。

9. 发明授权

US09328271B2 Adhesive resin composition and molded products 有权
标题翻译：粘合剂树脂组合物和成型品
公开(公告)号：US09328271B2
公开(公告)日：2016-05-03
申请号：US13641182
申请日：2011-04-08
申请人： Yasunori Okada , Takashi Matsumoto , Takao Michinobu
发明人： Yasunori Okada , Takashi Matsumoto , Takao Michinobu
IPC分类号： C08F212/00 , C09J151/06 , C08F212/08 , C08L51/06 , C08L53/02 , B32B7/12 , B32B15/08 , B32B27/08 , B32B27/30 , C08F255/04 , C08F255/10 , C08L9/00
CPC分类号： C09J151/06 , B32B7/12 , B32B15/08 , B32B27/08 , B32B27/302 , C08F212/08 , C08F255/04 , C08F255/10 , C08L9/00 , C08L51/06 , C08L53/02 , C08L53/025 , Y10T428/2419 , Y10T428/24777 , Y10T428/31507 , Y10T428/31692 , Y10T428/31757 , Y10T428/31797 , Y10T428/31913 , Y10T428/31928 , C08F220/32
摘要： An adhesive resin composition, including: a base resin which comprises (A) 30-90 parts by weight of a modified ethylene-olefin copolymer, and (B) 70-10 parts by weight of a styrene thermoplastic elastomer, provided that (A)+(B) equals 100 parts by weight; and (C) a tackifier in an amount of 30-60 parts by weight per 100 parts by weight of the base resin, the modified ethylene-olefin copolymer being one which has been graft-modified with (a) an unsaturated carboxylic acid or a derivative thereof and (b) an aromatic vinyl monomer, comprises 0.1%-5% by weight of (a) the unsaturated carboxylic acid or the derivative thereof, and has a melting point peak in a range of 100-150° C. with an enthalpy of crystal fusion of 0.5-10 J/g as determined by DSC.
摘要翻译：一种粘合剂树脂组合物，其包含：（A）30-90重量份改性乙烯 - 烯烃共聚物的基础树脂和（B）70-10重量份的苯乙烯热塑性弹性体，条件是（A） +（B）等于100重量份; 和（C）每100重量份基础树脂30-60重量份的增粘剂，改性乙烯 - 烯烃共聚物是用（a）不饱和羧酸或其衍生物和（b）芳族乙烯基单体包含0.1％-5％（重量）的（a）不饱和羧酸或其衍生物，并且具有在100-150℃范围内的熔点峰，通过DSC测定的晶体熔化焓为0.5-10J / g。

10. 发明授权

US07994255B2 Polyorganiosiloxane-containing graft copolymer, resin compositions containing the same and process for produciton of polyorganosiloxane emulsions 有权
标题翻译：含有有机基硅氧烷的接枝共聚物，含有该聚有机硅氧烷的接枝共聚物的树脂组合物和聚有机硅氧烷乳液的制造方法
公开(公告)号：US07994255B2
公开(公告)日：2011-08-09
申请号：US10551944
申请日：2004-04-09
申请人： Tomomichi Hashimoto , Akira Takaki , Kazunori Saegusa , Takao Manabe , Takao Michinobu
发明人： Tomomichi Hashimoto , Akira Takaki , Kazunori Saegusa , Takao Manabe , Takao Michinobu
IPC分类号： C08F283/12
CPC分类号： C08G77/442 , C08F283/12 , C08F285/00 , C08K5/0066 , C08L51/085 , C08L83/10 , C08L2666/02
摘要： The present invention relates to a flame retardant which is a graft copolymer. The graft copolymer is obtained by polymerizing a vinyl monomer containing at least two polymerizable groups, and at least one other vinyl monomer, in the presence of polyorganosiloxane particles in a latex state. The polyorganosiloxane particles contain grafting agents that are unevenly distributed on the surface thereof. The present invention also relates to thermoplastic resins containing this flame retardant.
摘要翻译：本发明涉及作为接枝共聚物的阻燃剂。接枝共聚物通过在胶乳状态的聚有机硅氧烷颗粒的存在下聚合含有至少两个可聚合基团的乙烯基单体和至少一种其它乙烯基单体而获得。聚有机硅氧烷颗粒含有在其表面上不均匀分布的接枝剂。本发明还涉及含有该阻燃剂的热塑性树脂。

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