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    • 1. 发明授权
    • Methods for n-type doping of graphene, and n-type-doped graphene compositions
    • 石墨烯n型掺杂的方法和n型掺杂石墨烯组合物
    • US08940576B1
    • 2015-01-27
    • US13239673
    • 2011-09-22
    • Steven S. BuiJeong-Sun Moon
    • Steven S. BuiJeong-Sun Moon
    • H01L31/00
    • H01L29/1606B82Y30/00B82Y40/00C01B32/194
    • The present invention provides practical methods for n-type doping of graphene, either during graphene synthesis or following the formation of graphene. Some variations provide a method of n-type doping of graphene, comprising introducing a phosphorus-containing dopant fluid to a surface of graphene, under effective conditions to dope the graphene with phosphorus atoms or with phosphorus-containing molecules or fragments. It has been found that substitutional doping with phosphine can effectively modulate the electrical properties of graphene, such as graphene supported on Si or SiC substrates. Graphene sheet resistances well below 200 ohm/sq, and sheet carrier concentrations above 5×1013 cm−2, have been observed experimentally for n-doped graphene produced by the disclosed methods. This invention provides n-doped graphene for various electronic-device applications.
    • 在石墨烯合成或石墨烯形成之后,本发明提供石墨烯的n型掺杂的实用方法。 一些变型提供了石墨烯的n型掺杂的方法,包括在有效条件下将含磷掺杂剂流体引入到石墨烯的表面,以用磷原子或含磷分子或片段掺杂石墨烯。 已经发现,使用膦的取代掺杂可以有效地调节石墨烯的电性能,例如负载在Si或SiC衬底上的石墨烯。 对于通过所公开的方法制备的n掺杂石墨烯,实验观察到石墨烯片电阻远低于200欧姆/平方英寸,片载体浓度高于5×1013厘米-2。 本发明提供了用于各种电子设备应用的n掺杂石墨烯。
    • 2. 发明授权
    • Carbon-beryllium combinationally doped semiconductor
    • 碳铍组合掺杂半导体
    • US08575659B1
    • 2013-11-05
    • US13209395
    • 2011-08-13
    • Steven S. BuiTahir HussainJames Chingwei Li
    • Steven S. BuiTahir HussainJames Chingwei Li
    • H01L29/66H01L21/8249
    • H01L29/36H01L29/0826H01L29/1004H01L29/207H01L29/66242H01L29/7371
    • A combinationally doped semiconductor layer, a double heterojunction bipolar transistor (DHBT) including a combinationally doped semiconductor layer, and a method of making a combinationally doped semiconductor layer employ a combination of carbon and beryllium doping. The combinationally doped semiconductor layer includes a first sublayer of a semiconductor material doped substantially with beryllium and a second sublayer of the semiconductor material doped substantially with carbon. The DHBT includes a carbon-beryllium combinationally doped semiconductor layer as a base layer. The method of making a combinationally doped semiconductor layer includes growing a first sublayer of the semiconductor layer, the first sublayer being doped substantially with beryllium and growing a second sublayer of the semiconductor layer, the second sublayer being doped substantially with carbon.
    • 组合掺杂半导体层,包括组合掺杂半导体层的双异质结双极晶体管(DHBT)以及制造组合掺杂半导体层的方法采用碳和铍掺杂的组合。 组合掺杂的半导体层包括基本上掺杂有铍的半导体材料的第一子层和基本上掺杂碳的半导体材料的第二子层。 DHBT包括作为基底层的碳 - 铍组合掺杂半导体层。 制造组合掺杂半导体层的方法包括生长半导体层的第一子层,第一子层基本上掺杂有铍并生长半导体层的第二子层,第二子层基本上被碳掺杂。