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    • 1. 发明申请
    • MATERIALS AND METHODS FOR IMPROVING PROPERTIES OF SPD EMULSIONS AND FILMS
    • 用于改善SPD乳液和膜的性质的材料和方法
    • WO2007008354A2
    • 2007-01-18
    • PCT/US2006024094
    • 2006-06-21
    • RESEARCH FRONTIERS INCCHAKRAPANI SRINIVASANSAXE ROBERT LSLOVAK STEVEN M
    • CHAKRAPANI SRINIVASANSAXE ROBERT LSLOVAK STEVEN M
    • B29C65/00
    • G02F1/172C08F290/068C08F290/148C08F293/005C08F297/02C08L53/00Y10T428/1014C08L2666/02
    • An emulsifier for use in forming a film for a suspended particle device (SPD) wherein the film is comprised of a cross-linked matrix polymer having a plurality of droplets of a liquid light valve suspension distributed therein. The emulsifier is formed of a copolymer material comprising at least first and second segments, the segments differing from one another in at least one of their chemical affinities, their compositions and their polarities. A first one of the segments is soluble in an uncured liquid matrix polymer used in forming the film, but insoluble in a liquid suspension medium of which the droplets are dispersed. A second segment is soluble in the liquid suspending medium in the droplets and insoluble in the uncured liquid matrix polymer. The first and second segments have substantially the same index of refraction and the index of refraction of the segments is within 0.010 of that of each phase of an emulsion formed with the emulsifier. In one embodiment, the first segment is comprised of a material selected from the group consisting of linear organosiloxanes, branched organosiloxanes, linear alkyl groups, branched alkyl groups, linear fluoroalkyl groups and branched fluoroalkyl groups. The second segment, in turn, is comprised of a material selected from the group consisting of linear esters, branched esters, linear (meth)acrylate, branched (meth)acrylate, linear amide, branched amide, linear amine, branched amine, linear epoxy groups, branched epoxy groups, linear groups comprising hydroxyl or acid groups and branched groups comprising hydroxyl or acid groups. The emulsifier is adapted to substantially prevent coalescence of the droplets of the liquid light valve suspension during formation of the film by retarding the growth of the droplets.
    • 一种用于形成用于悬浮颗粒装置(SPD)的膜的乳化剂,其中所述膜由交联的基质聚合物组成,所述交联基质聚合物具有多个分散在其中的液体光阀悬浮液滴。 所述乳化剂由包含至少第一和第二链段的共聚物材料形成,所述片段以它们的化学亲合力,它们的组成和极性中的至少一个彼此不同。 片段中的第一个可溶于用于形成膜的未固化液体基质聚合物,但不溶于其中分散有液滴的液体悬浮介质。 第二段在液滴中溶于液体悬浮介质,不溶于未固化的液体基质聚合物。 第一和第二段具有基本上相同的折射率,并且片段的折射率在与乳化剂形成的乳液的每个相的相差的0.010以内。 在一个实施方案中,第一段由选自直链有机硅氧烷,支链有机硅氧烷,直链烷基,支链烷基,直链氟烷基和支链氟代烷基组成的组中的材料组成。 第二段又由选自直链酯,支链酯,直链(甲基)丙烯酸酯,支链(甲基)丙烯酸酯,直链酰胺,支链酰胺,直链胺,支链胺,直链环氧化物 基团,支链环氧基团,包含羟基或酸基团的直链基团和包含羟基或酸基团的支链基团。 乳化剂适于在通过延迟液滴的生长来形成膜期间基本上防止液体光阀悬浮液的液滴聚结。
    • 4. 发明申请
    • SPD LIGHT VALVES INCORPORATING FILMS COMPRISING IMPROVED MATRIX POLYMERS AND METHODS FOR MAKING SUCH MATRIX POLYMERS
    • 包含改进的基质聚合物的包装膜的SPD光阀和制备这种基质聚合物的方法
    • WO2007097796A3
    • 2009-05-07
    • PCT/US2006045574
    • 2006-11-29
    • RESEARCH FRONTIERS INCSLOVAK STEVEN MCHEN XIAO-PINGSAXE ROBERT L
    • SLOVAK STEVEN MCHEN XIAO-PINGSAXE ROBERT L
    • G02B26/00
    • C08G77/20C09D183/04C09D183/06G02F1/172
    • A film suitable for use as the light-modulating element of an SPD light valve. The film comprises a cross-linked polymer matrix and has droplets of a liquid light valve suspension distributed in the cross-linked polymer matrix. The liquid light valve suspension comprises particles suspended in a liquid suspending medium, wherein the polymer matrix includes at least one siloxane co-polymer comprised of one or more of each of the following units, (a) at least one selected from the group consisting of a silicon-containing, non cross-linkable monomer, a silicon-containing non cross-linkable oligomer and a combination of both the monomer and the oligomer; (b) at least one silicon-containing cross-linkable monomer; and (c) at least one silicon-containing monomer including a non-cross-linking pendent moiety comprising one or more unhindered polar groups capable of bonding to a substrate, wherein the polar groups do not prevent the matrix polymer as a whole from being cross-linked, The film exhibits a greater degree of adhesion to substrates it contacts than films which do not include a unit as recited in (c) above. Additional embodiments include a suspended particle device incorporating the film as a light modulating element, as well as a method of preparing the film according to the invention.
    • 适用于SPD光阀的光调制元件的膜。 膜包含交联聚合物基质并且具有分布在交联聚合物基质中的液体轻阀悬浮液的液滴。 所述液体光阀悬浮液包含悬浮在液体悬浮介质中的颗粒,其中所述聚合物基质包括由以下各单元中的一种或多种组成的至少一种硅氧烷共聚物,(a)选自以下的至少一种: 含硅不可交联单体,含硅不可交联低聚物和单体和低聚物的组合; (b)至少一种含硅交联单体; 和(c)至少一种包含非交联侧链部分的含硅单体,其包含一个或多个能够与基底结合的不受阻碍的极性基团,其中极性基团不会阻止整个基质聚合物交叉 连接的,与上述(c)所述的不包含单元的膜相比,该膜对其接触的基材具有更大程度的粘合性。 另外的实施方案包括将该膜作为光调节元件并入的悬浮颗粒装置,以及制备根据本发明的膜的方法。
    • 8. 发明申请
    • MATERIALS AND METHODS FOR IMPROVING PROPERTIES OF SPD EMULSIONS AND FILMS
    • 提高SPD乳剂和薄膜性能的材料和方法
    • WO2007008354A9
    • 2008-12-04
    • PCT/US2006024094
    • 2006-06-21
    • RESEARCH FRONTIERS INCCHAKRAPANI SRINIVASANSAXE ROBERT LSLOVAK STEVEN M
    • CHAKRAPANI SRINIVASANSAXE ROBERT LSLOVAK STEVEN M
    • C08F30/08
    • G02F1/172C08F290/068C08F290/148C08F293/005C08F297/02C08L53/00Y10T428/1014C08L2666/02
    • An emulsifier for use in forming a film for a suspended particle device (SPD) wherein the film is comprised of a cross-linked matrix polymer having a plurality of droplets of a liquid light valve suspension distributed therein. The emulsifier is formed of a copolymer material comprising at least first and second segments, the segments differing from one another in at least one of their chemical affinities, their compositions and their polarities. A first one of the segments is soluble in an uncured liquid matrix polymer used in forming the film, but insoluble in a liquid suspension medium of which the droplets are dispersed. A second segment is soluble in the liquid suspending medium in the droplets and insoluble in the uncured liquid matrix polymer. The first and second segments have substantially the same index of refraction and the index of refraction of the segments is within 0.010 of that of each phase of an emulsion formed with the emulsifier. In one embodiment, the first segment is comprised of a material selected from the group consisting of linear organosiloxanes, branched organosiloxanes, linear alkyl groups, branched alkyl groups, linear fluoroalkyl groups and branched fluoroalkyl groups. The second segment, in turn, is comprised of a material selected from the group consisting of linear esters, branched esters, linear (meth)acrylate, branched (meth)acrylate, linear amide, branched amide, linear amine, branched amine, linear epoxy groups, branched epoxy groups, linear groups comprising hydroxyl or acid groups and branched groups comprising hydroxyl or acid groups. The emulsifier is adapted to substantially prevent coalescence of the droplets of the liquid light valve suspension during formation of the film by retarding the growth of the droplets.
    • 一种用于形成用于悬浮颗粒装置(SPD)的薄膜的乳化剂,其中所述薄膜由交联基质聚合物构成,所述交联基质聚合物具有分布在其中的液态光阀悬浮液的多个液滴。 乳化剂由包含至少第一和第二链段的共聚物材料形成,链段在它们的化学亲和力,组成和极性中的至少一种方面彼此不同。 第一个区段可溶于用于形成膜的未固化的液体基质聚合物中,但不溶于液滴分散于其中的液体悬浮介质中。 第二段可溶于液滴中的液体悬浮介质并且不溶于未固化的液体基质聚合物中。 第一段和第二段具有基本相同的折射率,并且段的折射率在用乳化剂形成的乳液的各相的折射率的0.010以内。 在一个实施方案中,第一部分由选自线性有机硅氧烷,支化有机硅氧烷,直链烷基,支链烷基,线性氟代烷基和支链氟代烷基的材料组成。 第二链段又由选自直链酯,支链酯,线性(甲基)丙烯酸酯,支链(甲基)丙烯酸酯,直链酰胺,支链酰胺,线性胺,支链胺,线性环氧树脂 基团,支链环氧基团,包含羟基或酸基团的直链基团和包含羟基或酸基团的支链基团。 乳化剂适用于通过延迟液滴的生长来基本上防止在形成膜期间液态光阀悬浮液的液滴聚结。
    • 9. 发明申请
    • MATERIALS AND METHODS FOR IMPROVING PROPERTIES OF SPD EMULSIONS AND FILMS
    • WO2007008354A3
    • 2007-01-18
    • PCT/US2006/024094
    • 2006-06-21
    • RESEARCH FRONTIERS INCORPORATEDCHAKRAPANI, SrinivasanSAXE, Robert, L.SLOVAK, Steven, M.
    • CHAKRAPANI, SrinivasanSAXE, Robert, L.SLOVAK, Steven, M.
    • C08F30/08
    • An emulsifier for use in forming a film for a suspended particle device (SPD) wherein the film is comprised of a cross-linked matrix polymer having a plurality of droplets of a liquid light valve suspension distributed therein. The emulsifier is formed of a copolymer material comprising at least first and second segments, the segments differing from one another in at least one of their chemical affinities, their compositions and their polarities. A first one of the segments is soluble in an uncured liquid matrix polymer used in forming the film, but insoluble in a liquid suspension medium of which the droplets are dispersed. A second segment is soluble in the liquid suspending medium in the droplets and insoluble in the uncured liquid matrix polymer. The first and second segments have substantially the same index of refraction and the index of refraction of the segments is within 0.010 of that of each phase of an emulsion formed with the emulsifier. In one embodiment, the first segment is comprised of a material selected from the group consisting of linear organosiloxanes, branched organosiloxanes, linear alkyl groups, branched alkyl groups, linear fluoroalkyl groups and branched fluoroalkyl groups. The second segment, in turn, is comprised of a material selected from the group consisting of linear esters, branched esters, linear (meth)acrylate, branched (meth)acrylate, linear amide, branched amide, linear amine, branched amine, linear epoxy groups, branched epoxy groups, linear groups comprising hydroxyl or acid groups and branched groups comprising hydroxyl or acid groups. The emulsifier is adapted to substantially prevent coalescence of the droplets of the liquid light valve suspension during formation of the film by retarding the growth of the droplets.