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1. 发明授权

US4366327A Process for producing ethers by reacting olefins with alcohols 失效
标题翻译：通过烯烃与醇反应制备醚的方法
公开(公告)号：US4366327A
公开(公告)日：1982-12-28
申请号：US258317
申请日：1981-04-28
申请人： Alain Convers , Bernard Torck , Jean-Paul Euzen , Pierre Amigues
发明人： Alain Convers , Bernard Torck , Jean-Paul Euzen , Pierre Amigues
IPC分类号： C07C41/05 , B01J27/00 , B01J31/00 , C07C41/00 , C07C41/06 , C07C67/00
CPC分类号： C07C41/06
摘要： Process for producing ethers by reacting a catalytic cracking C.sub.4 olefinic cut which may contain such impurities as NaOH, an alkanolamine, an alkaline earth metal compound or an iron, copper or lead compound, with an alcohol, in the liquid phase, in the presence of an expanded bed of an etherification solid catalyst of the sulfonic resin type in acid form, in a circuit of two or more successive reaction zones wherethrough the order of passage of the reactants is periodically modified by disconnecting the first zone from the circuit, feeding the reactants to the second zone, replacing the catalyst of the first zone with fresh catalyst and thereafter connecting said first zone at the end of the circuit.
摘要翻译：通过在液相中存在下使可能含有诸如NaOH，链烷醇胺，碱土金属化合物或铁，铜或铅化合物的杂质的催化裂解C4烯烃切割物与醇反应来制备醚的方法在两个或更多个连续反应区的电路中，酸性磺酸树脂的醚化固体催化剂的膨胀床通过使第一区与电路断开而周期性地改变反应物的通过顺序，将反应物到第二区域，用新鲜催化剂代替第一区域的催化剂，然后在回路的末端连接所述第一区域。

2. 发明授权

US5658539A Chambers of a moving bed 失效
标题翻译：移动床的房间
公开(公告)号：US5658539A
公开(公告)日：1997-08-19
申请号：US506038
申请日：1995-07-24
申请人： Jean-Paul Euzen , Maurice Berthelin , Jean De Bonneville , Roland Huin , Daniel Vuillemot
发明人： Jean-Paul Euzen , Maurice Berthelin , Jean De Bonneville , Roland Huin , Daniel Vuillemot
IPC分类号： B65D6/12 , B01J8/12 , C10G35/12 , B01J8/08
CPC分类号： B01J8/12 , C10G35/12 , B01J2219/1925 , B01J2219/1943
摘要： An enclosure in which there circulates a moving bed of solid particles (for example a moving-bed catalytic reactor such as a reforming reactor), is delimited in the enclosure by at least one grill. In the enclosure a fluid passes through the bed in a direction different from that of the flow of the assembly of the particles and issues from the bed by way of at least one grill. Disposed in the thickness of said bed in an intermediate wall (grill) such as to distribute the thrust forces produced by the fluid on the particles in the zones of the bed which are delimited in that way. Jamming of the particles against the grill or grills is greatly reduced and the admissible fluid flow rate is then decreased.
摘要翻译：在其中循环固体颗粒的移动床（例如移动床催化反应器例如重整反应器）的外壳通过至少一个格栅限定在外壳中。在外壳中，流体沿与颗粒组件的流动不同的方向通过床，并通过至少一个格栅从床发出。设置在中间壁（格栅）中的所述床的厚度上，以便将由流体产生的推力分配在以这种方式界定的床的区域中的颗粒上。颗粒对格栅或烤架的干扰大大降低，然后允许的流体流速减小。

3. 发明授权

US5047217A Reactor with internal heat control by hollow heat exchanger plates 失效
标题翻译：通过中空换热器板进行内部热控制的反应器
公开(公告)号：US5047217A
公开(公告)日：1991-09-10
申请号：US288365
申请日：1988-12-22
申请人： Quang Dang Vu , Roland Huin , Jean-Paul Euzen
发明人： Quang Dang Vu , Roland Huin , Jean-Paul Euzen
IPC分类号： B01J8/00 , B01J8/02 , B01J19/00 , B01J19/24 , F28D9/00 , F28F3/02
CPC分类号： F28F3/025 , B01J8/025 , B01J8/0285 , F28D9/0006 , F28D9/0031 , B01J2208/0015 , B01J2208/022 , B01J2219/00085
摘要： The invention provides an apparatus for carrying out chemical reactions, in the presence of at least one catalyst, in at least one reaction zone equipped with heat exchanger plates which make it possible to control the temperature of the zone. The apparatus mainly comprises a reactor, at least one central distributor manifold, a plurality of distributor manifolds, at least one central receiver manifold, a plurality of receiver manifolds and a plurality of continuous and elongate hollow plates, preferably substantially perpendicular. The hollow plates can contain adjacent channels having one of the following shapes: square, rectangular, triangular, sinusoidal.
摘要翻译：本发明提供了一种用于在至少一个装有热交换器板的反应区中的至少一种催化剂的存在下进行化学反应的装置，该反应区使得可以控制该区域的温度。该装置主要包括反应器，至少一个中央分配器歧管，多个分配器歧管，至少一个中央接收器歧管，多个接收器歧管和多个连续和细长的中空板，优选地基本上垂直。中空板可以包含具有以下形状之一的相邻通道：正方形，矩形，三角形，正弦形。

4. 发明授权

US5869541A Conversion of synthesis gas to hydrocarbons in the presence of a liquid phase 失效
标题翻译：在液相存在下将合成气转化为烃
公开(公告)号：US5869541A
公开(公告)日：1999-02-09
申请号：US815987
申请日：1997-03-10
申请人： Jean-Paul Euzen , Isabelle Harter , Patrick Chaumette
发明人： Jean-Paul Euzen , Isabelle Harter , Patrick Chaumette
IPC分类号： B01J8/04 , C07C1/06 , C10G2/00 , C07C27/00
CPC分类号： C10G2/34 , B01J8/0453 , B01J8/0492 , C07C1/06
摘要： A process for the synthesis of essentially linear saturated C.sub.5.sup.+ hydrocarbons from a gas phase comprising synthesis gas is described. The process comprises circulation of an inert liquid phase and said gas phase in a reaction zone, in which the reaction zone is provided with at least one means for introducing gas and liquid phases, and at least one means for extracting the hydrocarbon phase formed by the Fischer-Tropsch reaction, and characterized in that the reaction zone comprises at least one mixing means. Preferably, at least one mixing means is a static mixer. An apparatus for carrying out the described process is also described.
摘要翻译：描述了从包含合成气的气相合成基本上线性的饱和C 5+烃的方法。该方法包括在反应区中循环惰性液相和所述气相，其中反应区设置有至少一种用于引入气相和液相的装置，以及至少一种用于提取由费 - 托反应，其特征在于反应区包含至少一个混合装置。优选地，至少一个混合装置是静态混合器。还描述了用于执行所描述的过程的装置。

5. 发明授权

US5712213A Rejuvenation process for a solid alkylation catalyst 失效
标题翻译：固体烷基化催化剂的再生过程
公开(公告)号：US5712213A
公开(公告)日：1998-01-27
申请号：US493462
申请日：1995-06-22
申请人： Jean-Fran.cedilla.ois Joly , Eric Benazzi , Christian Marcilly , Jean-Paul Euzen , Alain Forestiere
发明人： Jean-Fran.cedilla.ois Joly , Eric Benazzi , Christian Marcilly , Jean-Paul Euzen , Alain Forestiere
IPC分类号： B01J27/053 , B01J27/30 , B01J37/00 , C07B61/00 , C07C2/58 , C07C9/16 , C10G35/04 , B01J20/34 , B01J38/56
CPC分类号： C07C2/58
摘要： The invention concerns a rejuvenation process for a solid catalyst for the alkylation of at least one isoparaffin by at least one olefin. The process is characterised in that the catalyst is rejuvenated in the reaction zone by circulating an isoparaffin-rich liquid fraction over the bed, said fraction originating from a zone for separating the reaction effluent extracted from the reaction zone.
摘要翻译：本发明涉及用于至少一种烯烃烷基化至少一种异链烷烃的固体催化剂的再生方法。该方法的特征在于，通过在床上循环富含异构烷烃的液体馏分，催化剂在反应区中再生，所述馏分源自用于分离从反应区提取的反应流出物的区域。

6. 发明授权

US4392943A Process and device for withdrawing solid particles and introducing a liquid charge at the lower portion of a contact zone 失效
标题翻译：用于取出固体颗粒并在接触区的下部引入液体电荷的方法和装置
公开(公告)号：US4392943A
公开(公告)日：1983-07-12
申请号：US373183
申请日：1982-04-29
申请人： Jean-Paul Euzen , Yves Jacquin , Hugo Van Landeghem, deceased
发明人： Jean-Paul Euzen , Yves Jacquin , Hugo Van Landeghem, deceased
IPC分类号： C10G11/18 , B01J4/00 , B01J8/00 , B01J8/12 , C10G35/14 , C10G49/14 , C10G49/16 , C10B31/02 , C10B31/12
CPC分类号： B01J8/003 , B01J8/12 , C10G49/14
摘要： In a process for the catalytic treatment of hydrocarbon charges in the presence of hydrogen in a vertical reactor where the catalyst is introduced at the top and withdrawn at the bottom, countercurrently with the charge which is introduced at the bottom and discharged from the top. There is provided a flared funnel for the catalyst discharge having small perforations for the upward flow of the charge with the perforations of a size sufficiently small to prevent passage of the catalyst therethrough. These perforations are in association with injection tubes having orifices opening in the vicinity of the funnel wall, wherethrough at least a portion of the fluid charge is injected.
摘要翻译：在催化处理在氢气存在下的氢气的方法中，其中催化剂在顶部引入并在底部引入，垂直反应器与底部引入并从顶部排出的电荷逆流反应。提供了一种用于催化剂放电的扩口漏斗，其具有小的穿孔，用于电荷的向上流动，其中穿孔的尺寸足够小以防止催化剂通过其中。这些穿孔与具有在漏斗壁附近开口的孔的注入管相关联，通过其中注入至少一部分流体进料。

7. 发明授权

US4820495A Plate reactors for chemical syntheses under high pressure in gaseous phase and with heterogeneous catalysis 失效
标题翻译：在高压下在气相和异相催化下进行化学合成的板式反应器
公开(公告)号：US4820495A
公开(公告)日：1989-04-11
申请号：US768780
申请日：1985-08-23
申请人： Quang D. Vu , Claude Pradel , Jean-Paul Euzen , Jean-Francois Le Page
发明人： Quang D. Vu , Claude Pradel , Jean-Paul Euzen , Jean-Francois Le Page
IPC分类号： B01J3/04 , B01J3/00 , B01J8/00 , B01J8/02 , B01J8/06 , C01C1/04 , C07C29/15 , C07C29/152 , C07C31/04 , B01J8/04
CPC分类号： C01C1/0417 , B01J8/0005 , B01J8/0242 , B01J8/0285 , C07C29/15 , B01J2208/0015 , B01J2208/022 , Y02P20/52
摘要： The invention relates to a process and to an apparatus for effecting chemical syntheses in gaseous phase, under pressure, in the presence of a solid catalyst, for instance for ammonia synthesis from hydrogen and nitrogen or for the synthesis of methanol or higher homolog alcohols from hydrogen and at least one carbon oxide.The reactor of substantially cylindrical shape contains a plurality of elongate compartments of parallelipiped shape, adjacent to each other, the adjacent walls of the compartments or the common walls of the adjacent compartments being gas-tight walls, said tight walls forming hollow plates wherein are provided channels for the flow of a fluid heat carrier flowing through said walls under a pressure substantially equal to the pressure to which are subjected the reaction gases.
摘要翻译：本发明涉及一种在固体催化剂存在下，在压力下，在气相中进行化学合成的方法和装置，例如用于从氢和氮合成氨或从氢气合成甲醇或更高级的同系醇和至少一种碳氧化物。基本上圆柱形的反应器包含多个相互邻近的平行形状的细长隔间，隔室的相邻壁或相邻隔室的公共壁是气密壁，所述紧密壁形成中空板，其中提供用于在基本上等于受到反应气体的压力的压力下流过所述壁的流体热载体的流动通道。

8. 发明授权

US4738769A Process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions 失效
$Process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions$
标题翻译：将液体或半液体碳氢化合物装料转化为较轻馏分的方法
公开(公告)号：US4738769A
公开(公告)日：1988-04-19
申请号：US478428
申请日：1983-03-24
申请人： Christian Busson , Jacques Alagy , Jean-Paul Euzen , Pierre Galtier
发明人： Christian Busson , Jacques Alagy , Jean-Paul Euzen , Pierre Galtier
IPC分类号： B01J8/12 , C10G9/28 , C10G47/24
CPC分类号： B01J8/12 , C10G2400/20
摘要： A process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions comprises a first step (a) heating droplets jets of the charge introduced into a pyrolysis chamber by surrounding them with parallel jets of hot solid particles, of relatively large size, of a heat carrier material, not substantially in contact with the droplet jets, so as to maintain a temperature of 700.degree.-1600.degree. C., and introducing a gas so as to obtain a pressure from 1 to 150 bars. A second step involves (b) separating the gaseous fraction from the solid particles. Thereafter (c) at least a portion of the solid particles are heated and fed back to step (a). The gaseous fraction is (d) cooled by means of a cold gas so as to recover light hydrocarbons therefrom.
摘要翻译：将液体或半液体碳氢化合物装料转化成轻馏分的方法包括第一步骤（a）通过用相当大尺寸的热固体颗粒的平行射流包围引入到热解室中的电荷的液滴射流，热载体材料，基本上不与液滴射流接触，以保持700〜-1600℃的温度，并引入气体以获得1至150巴的压力。第二步涉及（b）从固体颗粒中分离气态馏分。此后（c）将至少一部分固体颗粒加热并反馈到步骤（a）。气态馏分（d）通过冷气体冷却，以从其中回收轻质烃。

9. 发明授权

US4210015A Device for following the variations in the composition of a flowing heterogeneous liquid mixture 失效
标题翻译：用于跟踪流动的异质液体混合物的组成变化的装置
公开(公告)号：US4210015A
公开(公告)日：1980-07-01
申请号：US970306
申请日：1978-12-18
申请人： Jean-Paul Euzen , Patrick Scemama
发明人： Jean-Paul Euzen , Patrick Scemama
IPC分类号： G01N9/30 , G01N1/10 , G01N1/20 , G01N33/28 , G01N11/00
CPC分类号： G01N1/2035 , G01N33/2823
摘要： The device repeatedly samples a selected amount of liquid mixture and separates at least one liquid phase from the mixture. The amount of the separated liquid phase is plotted versus the corresponding amount of the sampled mixture. At least some of the sample is recycled.
摘要翻译：该装置重复地对选定量的液体混合物进行取样，并从混合物中分离出至少一个液相。将分离的液相的量相对于取样的混合物的相应量作图。至少有一些样品被回收利用。

10. 发明授权

US6090351A Moving bed chamber with a regularized flow 失效
标题翻译：移动床室具有正规流
公开(公告)号：US6090351A
公开(公告)日：2000-07-18
申请号：US148072
申请日：1998-09-04
申请人： Jean-Paul Euzen , Daniel Vuillemot , Roland Huin
发明人： Jean-Paul Euzen , Daniel Vuillemot , Roland Huin
IPC分类号： B01J8/00 , B01J8/02 , B01J8/12 , C01B3/42 , C10G35/12 , B01J8/08
CPC分类号： B01J8/0214 , B01J8/003 , B01J8/12 , C01B3/42 , C10G35/12 , B01J2208/00884 , B01J2219/1925 , B01J2219/1943 , C01B2203/0227
摘要： A chamber comprising a moving bed of solid particles, delimited by at least one screen with thickness e, circulating in a downward direction substantially parallel to the screen, the bed being traversed by at least one fluid flowing in the bed in a principal direction which is different to that of the ensemble of particles and leaving the bed by an outlet screen. In accordance with the invention, the chamber comprises at least one opening for introducing solid particles located above the bed and comprising at least one orifice for the flow of the particles, located at a distance of at least 0.6 e from the outlet screen. The chamber advantageously comprises at least two extraction openings, one extraction opening being located at a distance not more than 0.5 e from the outlet screen, and the other at a distance of at least 0.5 e from the outlet screen. The invention is applicable to catalytic reactors, in particular to catalytic reforming reactors.
摘要翻译：一个室，包括固体颗粒的移动床，由至少一个具有厚度e的筛网限定，沿着基本上平行于筛网的向下方向循环，该床被沿着主要方向流过床的至少一种流体横穿，不同于粒子的组合，并通过出口屏幕离开床。根据本发明，腔室包括用于引入位于床上方的固体颗粒的至少一个开口，并且包括用于颗粒流动的至少一个孔口，该孔口与出口筛网距离至少0.6e。所述室有利地包括至少两个提取开口，一个提取开口位于离出口屏幕不超过0.5埃的距离处，另一个距出口屏幕至少0.5埃的距离。本发明适用于催化反应器，特别是催化重整反应器。

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