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1. 发明公开

EP0791384A2 Foam control agents for silicone surfactants in agriculture 失效
标题翻译：农业中用于有机硅表面活性剂的泡沫控制剂
公开(公告)号：EP0791384A2
公开(公告)日：1997-08-27
申请号：EP97102887.3
申请日：1997-02-21
申请人： Policello, George A. , Murphy, Gerald J.
发明人： Policello, George A. , Murphy, Gerald J.
IPC分类号： B01D19/04
CPC分类号： B01D19/0409
摘要： The present invention teaches silicone polyether copolymers with a low degree of polymerization (3 to 4 Si units) provide control for foams generated by organosilicone based surfactants in water without the need for an additional antifoam component. The copolymer foam control agent is a compound of the formula

(CH 3 ) 3 SiO[SiO(CH 3 ) 2 ] X [SiOCH 3 R 1 ] Y Si(CH 3 ) 3

wherein X + Y = 1 to 2, Y ≥ 1, R 1 is an alkyleneoxide group of the formula C a H 2a O(C 3 H 6 O) z R 2 wherein a = 3 to 4, z is 1 to 15, R 2 is hydrogen, a hydrocarbon radical of 1 to 4 carbons or acetyl.
This invention provides compositions for use in agricultural formulations that give improved foam control for foams generated from organosilicone surfactants in aqueous systems. The copolymer foam control agent is soluble in a surfactant matrix comprised of an organosilicone surfactant alone or in mixtures with short chain conventional surfactants. This invention provides clear, homogeneous, low foaming agricultural formulations having of a water insoluble copolymer foam control agent, and a water soluble or dispersible trisiloxane or tetrasiloxane alkoxylates when said formulation is used in an aqueous mixture.
摘要翻译：本发明教导了具有低聚合度（3至4个Si单元）的硅氧烷聚醚共聚物提供了在水中由有机基硅氧烷基表面活性剂产生的泡沫的控制，而不需要额外的消泡剂组分。共聚物泡沫控制剂是式（CH3）3SiO [SiO（CH3）2] X [SiOCH3R1] YSi（CH3）3的化合物，其中X + Y = 1至2，Y≥1，R1是式CaH2aO（C3H6O）zR2其中a = 3至4，z为1至15，R2为氢，1至4个碳的烃基或乙酰基。本发明提供了用于农业制剂的组合物，该组合物给予水性体系中由有机硅氧烷表面活性剂产生的泡沫的改进泡沫控制。共聚物泡沫控制剂可溶于由单独的有机硅氧烷表面活性剂组成或与短链常规表面活性剂混合的表面活性剂基质中。当所述制剂用于含水混合物中时，本发明提供了具有水不溶性共聚物泡沫控制剂和水溶性或水分散性三硅氧烷或四硅氧烷烷氧基化物的透明，均匀，低起泡的农业制剂。

2. 发明授权

EP1117727B1 ORGANOSILOXANE CONTAINING MODIFIED GROUPS IN PESTICIDAL COMPOSTIONS 有权
标题翻译：修饰的基团有机硅氧烷在农药组合物
公开(公告)号：EP1117727B1
公开(公告)日：2004-07-07
申请号：EP99954681.5
申请日：1999-09-28
申请人： General Electric Company , Policello, George A.
发明人： POLICELLO, George, A. , CZECH, Anna , BURGAZLI, Jack
IPC分类号： C08G77/388 , C08G77/46 , C08G65/02
CPC分类号： C08G77/46 , A01N25/30 , C08G77/388

3. 发明公开

EP1117727A1 ORGANOSILOXANE CONTAINING MODIFIED GROUPS IN PESTICIDAL COMPOSTIONS 有权
标题翻译：修饰的基团有机硅氧烷在农药组合物
公开(公告)号：EP1117727A1
公开(公告)日：2001-07-25
申请号：EP99954681.5
申请日：1999-09-28
申请人： Crompton Corporation , Policello, George A.
发明人： POLICELLO, George, A. , CZECH, Anna , BURGAZLI, Jack
IPC分类号： C08G77/388 , C08G77/46 , C08G65/02
CPC分类号： C08G77/46 , A01N25/30 , C08G77/388
摘要： The present invention teaches amino alkoxylate organosilicone an d their use, a preferred of which is as adjuvants for pesticides, as well intermediates for the manufacture of such siloxanes.

4. 发明公开

EP0791384A3 Foam control agents for silicone surfactants in agriculture 失效
标题翻译：用于农业硅氧烷表面活性剂的泡沫控制剂
公开(公告)号：EP0791384A3
公开(公告)日：1997-12-29
申请号：EP97102887
申请日：1997-02-21
申请人： POLICELLO GEORGE A , MURPHY GERALD J
发明人： POLICELLO GEORGE A , MURPHY GERALD J
IPC分类号： B01D19/04
CPC分类号： B01D19/0409

5. 发明专利

CA2198059C FOAM CONTROL AGENTS FOR SILICONE SURFACTANTS IN AGRICULTURE 未知
公开(公告)号：CA2198059C
公开(公告)日：2003-05-13
申请号：CA2198059
申请日：1997-02-20
申请人： MURPHY GERALD J , POLICELLO GEORGE A
发明人： MURPHY GERALD J , POLICELLO GEORGE A
IPC分类号： B01D19/04 , A01N25/30
摘要： The present invention teaches silicone polyether copolymers with a low degre e of polymerization (3 to 4 Si units) provide control for foams generated by orga nosilicone based surfactants in water without the need for an additional antifoam component. The copolymer foam control agent is a compound of the formula (CH3)3SiO[SiO(CH3)1]x[SiOCH3R1]ySi(CH)3 wherein X + Y = 1 to 2, Y ~ 1, R1 is an alkyleneoxide group of the formula C aH2aO(C3H6O)zR2 wherein a = 3 to 4, z is 1 to 15, R2 is hydrogen, a hydrocarbon radical of 1 to 4 carbons or acetyl. This invention provides compositions for use in agricultural formulations th at give improved foam control for foams generated from organosilicone surfactants in aqueous systems. The copolymer foam control agent is soluble in a surfactant matrix comprised of all organosilicone surfactant alone or in mixtures with short chain conventional surfactants. This invention provides clear, homogeneous. low foaming agricultural formulations having of a water insoluble copolymer foam control agent, and a water soluble or dispersible t risiloxane or tetrasiloxane alkoxylates when said formulation is used in an aqueous mixtur e.

6. 发明申请

WO2012037333A3 AQUEOUS FOAMING COMPOSITIONS WITH HIGH TOLERANCE TO HYDROCARBONS 审中-公开
标题翻译：具有高耐油性的水性泡沫组合物
公开(公告)号：WO2012037333A3
公开(公告)日：2013-07-11
申请号：PCT/US2011051739
申请日：2011-09-15
申请人： MOMENTIVE PERFORMANCE MAT INC , KOCZO KALMAN , TSELNIK OLEG , FALK BENJAMIN , POLICELLO GEORGE A
发明人： KOCZO KALMAN , TSELNIK OLEG , FALK BENJAMIN , POLICELLO GEORGE A
IPC分类号： C09K8/38
CPC分类号： C09K8/703 , C09K8/38
摘要： A composition for providing a stable foam with high tolerance to hydrocarbons includes (a) an aqueous liquid; (b) at least one water soluble or dispersible silicon- containing polyether foamant contained within the aqueous liquid; and (c) a non-aqueous liquid. The aqueous liquid includes water and brine. The non-aqueous liquid includes liquid hydrocarbons.
摘要翻译：用于提供对烃具有高耐受性的稳定泡沫的组合物包括（a）水性液体; （b）水性液体中含有至少一种水溶性或分散性含硅聚醚发泡剂; 和（c）非水性液体。含水液体包括水和盐水。非水性液体包括液体烃。

7. 发明申请

WO2008073396A1 HYDROLYSIS RESISTANT ORGANOMODIFIED SILYLATED IONIC SURFACTANTS 审中-公开
标题翻译：耐水解有机硅烷化离子表面活性剂
公开(公告)号：WO2008073396A1
公开(公告)日：2008-06-19
申请号：PCT/US2007/025272
申请日：2007-12-11
申请人： MOMENTIVE PERFORMANCE MATERIALS INC. , LEATHERMAN, Mark, D. , POLICELLO, George, A. , PENG, Wenqing, N. , ZHENG, Liping , WAGNER, Roland , XIA, Zijun , RAJARAMAN, Suresh, K.
发明人： LEATHERMAN, Mark, D. , POLICELLO, George, A. , PENG, Wenqing, N. , ZHENG, Liping , WAGNER, Roland , XIA, Zijun , RAJARAMAN, Suresh, K.
IPC分类号： A01N25/30 , A61K8/58 , C02F1/54 , C07F7/08 , C10G33/04 , C11D1/02 , C11D1/38 , C11D1/88 , D21C3/00
CPC分类号： A61K8/585 , A01N25/30 , A61Q19/00 , C10G33/04 , C11D3/162 , D21C9/002 , D21H17/59
摘要： The present invention provides for a composition comprising a silane having the formula: (R 1 )(R 2 )(R 3 )Si -R 4 - Si(R 5 )(R 6 )(R 7 ) wherein R 1 , R 2 , R 3 , R 5 , and R 6 are each independently selected from the group consisting of 1 to 6 monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 7 to 10 carbons containing an aryl group; R 4 is a hydrocarbon group of 1 to 3 carbons; R 7 comprises an anionic, cationic or zwitterionic substituent. The silanes of the present invention exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：本发明提供了一种组合物，其包含具有下式的硅烷：（R 1）（R 2）（R 3）（R 3） Si（R 5）（R 6）（R 7）其中R 1，R 2，R 4， R 2，R 3，R 5，R 5和R 6各自独立地选自由1至6个一价烃基，芳基和含有芳基的7至10个碳的烃基组成的基团; R 4是1至3个碳的烃基; R 7包括阴离子，阳离子或两性离子取代基。本发明的硅烷在宽的pH范围内表现出抗水解性。

8. 发明申请

WO2008048593A2 FLUORINE-FREE TRISILOXANE SURFACTANT COMPOSITIONS FOR USE IN COATINGS AND PRINTING INK COMPOSITIONS 审中-公开
标题翻译：用于涂料和印刷油墨组合物的无氟三硅氧烷表面活性剂组合物
公开(公告)号：WO2008048593A2
公开(公告)日：2008-04-24
申请号：PCT/US2007/022064
申请日：2007-10-16
申请人： MOMENTIVE PERFORMANCE MATERIALS INC. , RAJARAMAN, Suresh, K. , LEJEUNE, Alain , BOROVIK, Alexander , POLICELLO, George, A. , LEATHERMAN, Mark, D. , PENG, Wenqing , XIA, Zijun
发明人： RAJARAMAN, Suresh, K. , LEJEUNE, Alain , BOROVIK, Alexander , POLICELLO, George, A. , LEATHERMAN, Mark, D. , PENG, Wenqing , XIA, Zijun
IPC分类号： C09D183/12
CPC分类号： C09D183/12 , C08G77/46 , C09D11/03 , C08L2666/14 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to coating and printing ink compositions possessing silicone surfactants compositions comprising fluorine-free organomodified trisiloxanes which are resistant to hydrolysis between a pH of about 3 to a pH of about 12. The coatings and printing ink composition of the present invention exhibit enhanced wetting, flow and leveling properties.
摘要翻译：本发明涉及具有有机硅表面活性剂组合物的涂料和印刷油墨组合物，所述有机硅表面活性剂组合物包含在约3至约12的pH下耐水解的无氟有机改性的三硅氧烷。本发明的油墨组合物表现出增强的润湿性，流动性和流平性。

9. 发明申请

WO2008024308A2 FILM FORMING COMPOSITION WITH SPREADING PROPERTIES 审中-公开
标题翻译：成膜组合物具有膨胀特性
公开(公告)号：WO2008024308A2
公开(公告)日：2008-02-28
申请号：PCT/US2007018399
申请日：2007-08-20
申请人： MOMENTIVE PERFORMANCE MAT INC , CZECH ANNA M , FALK BENJAMIN , NICHOLSON JOHN , POLICELLO GEORGE A , TULLY JO ANNE
发明人： CZECH ANNA M , FALK BENJAMIN , NICHOLSON JOHN , POLICELLO GEORGE A , TULLY JO ANNE
CPC分类号： A61K8/585 , A01N25/04 , A01N25/24 , A01N25/30 , A61K8/0241 , A61K8/25 , A61K8/463 , A61K8/466 , A61K8/894 , A61K2800/412 , A61K2800/624 , A61K2800/652 , A61Q5/06 , A61Q19/00 , C11D1/143 , C11D1/146 , C11D1/22 , C11D1/29 , C11D1/342 , C11D1/345 , C11D1/37 , C11D3/124 , C11D3/373 , C11D3/3738 , C11D17/0013 , C11D17/0039 , Y10T428/2995
摘要： A film forming composition with spreading properties derived from an aqueous emulsion comprising (I) colloidal silica core/silicone shell particles consisting of (a) 90 wt % to 10 wt % cores of colloidal silica and (b) 10 wt % to 90 wt % shells of polyorganosiloxane; (II) a polyalkyleneoxide modified trisiloxane; (III) an emulsifier package consisting of at least one anionic surfactant, and (TV) the salt of an acidic polymerization catalyst. The composition may include optional ingredients useful in Personal Care, Hair Care, Skin Care, Agricultural, and Home Care applications.
摘要翻译：一种具有源自水乳液的铺展性的成膜组合物，其包含（I）由（a）90重量％至10重量％的胶体二氧化硅芯和（b）10重量％至90重量％聚有机硅氧烷壳; （II）聚氧化亚烷基改性的三硅氧烷; （III）由至少一种阴离子表面活性剂和（TV）酸性聚合催化剂的盐组成的乳化剂包。组合物可以包括用于个人护理，护发，护肤，农业和家庭护理应用中的任选成分。

10. 发明申请

WO2007044691A1 HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE SURFACTANTS 审中-公开
标题翻译：水解抗坏血酸有机反应性表面活性剂
公开(公告)号：WO2007044691A1
公开(公告)日：2007-04-19
申请号：PCT/US2006/039445
申请日：2006-10-10
申请人： GENERAL ELECTRIC COMPANY , LEATHERMAN, Mark, D. , POLICELLO, George, A. , RAJARAMAN, Suresh, K.
发明人： LEATHERMAN, Mark, D. , POLICELLO, George, A. , RAJARAMAN, Suresh, K.
IPC分类号： C07F7/08 , A61K8/58 , A61K8/898
CPC分类号： C07F7/0849 , A61K8/891 , A61Q15/00 , A61Q19/00
摘要： Disiloxane surfactant compositions comprising a silicone composition comprising a silicone having the formula: MM' where M = R 1 R 2 R 3 SiO 1/2 ; M' = R 4 R 5 R 6 SiO 1/2 ; with R selected from the group consisting of branched monovalent hydrocarbon radical of from 3 to 6 carbon atoms and R 7 , where R 7 has the formula: R 8 R 9 R 10 SiR 12 with R 8 , R 9 , and R 10 each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and monovalent aryl or alkaryl hydrocarbon radicals having from 6 to 13 carbon atoms and R 12 is a divalent hydrocarbon radical having from 1 to 3 carbon atoms, R 2 and R 3 are each independently selected from the group of from 1 to 6 carbon atom monovalent hydrocarbon radicals or R 1 , with R 4 an alkylpolyalkyleneoxide of the general formula: R 13 (C 2 H 4 O) a (C 3 H 6 O) b (C 4 H 8 O) c R 14 where R 13 is a divalent linear or branched hydrocarbon radical having the structure: -CH 2 -CH(R 15 )(R 16 ) d O- where R 15 is H or methyl; R 16 is a divalent alkyl radical of 1 to 6 carbons where the subscript d may be O or 1 ; R 14 is selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl where the subscripts a, b and c are zero or positive and satisfy the following relationships: 2 2, and R 5 and R 6 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms or R 4 that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译：包含硅氧烷组合物的二硅氧烷表面活性剂组合物，其包含具有下式的MM的硅氧烷：其中M = R 1，R 2，R 3， 1/2 ; M'= R S S 5 其中R选自3至6个碳原子的支化单价烃基和R 7，其中R 7具有下式：R 8，其中R 1，R 2，R 3，R 9，R 12，

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