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    • 7. 发明授权
    • Ethylenic random copolymer, process for preparing the same, and rubber
composition
    • 乙烯无规共聚物,其制备方法和橡胶组合物
    • US6140441A
    • 2000-10-31
    • US983636
    • 1998-03-30
    • Takashi HakutaMikio HosoyaTetsuo TojoMasaaki Kawasaki
    • Takashi HakutaMikio HosoyaTetsuo TojoMasaaki Kawasaki
    • C08F4/68C08F210/18
    • C08F210/18
    • A process for preparing an ethylene/.alpha.-olefin/norbornene nonconjugated polyene random copolymer, comprising preparing an ethylene random copolymer simultaneously meeting the following requirements (1) to (5):(1) the molar ratio of ethylene (a) to an .alpha.-olefin (b) having 3 to 20 carbon atoms ranges from 40:60 to 95:5;(2) a given amount of non conjugated polyene (c) has a norbornene skeleton;(3) the available network chain density .nu. is not less than 1.5.times.10.sup.20 /cm.sup.3 after press cross-linking of the copolymer using a dicumyl peroxyde;(4) the ratio of the rate .gamma.1 of shear showing a shearing stress of 0.4.times.10.sup.6 dyn/cm.sup.2 as determined from the melt flow curve at 100.degree. C. and the rate .gamma.2 of shear showing a shearing stress of 2.4.times.10.sup.6 dyn/cm.sup.2, that is .gamma.2/.gamma.1 and the available network chain density .nu. has a relationship represented by the following general formula: 0.04.times.10.sup.-19 .ltoreq.Log(.gamma.2/.gamma.1)/.nu..ltoreq.0.20.times.10.sup.-19 ; and(5) the intrinsic viscosity [.eta.] ranges from 0.5 to 10 dl/g as measured in decalin at 135.degree. C. The copolymer has excellent cross-linkability, can be cross-linked with a small amount of a peroxide or the like, and a cross-linked rubber composition prepared using this copolymer has excellent heat aging resistance, mechanical strength, weather resistance, and oxone resistance.
    • PCT No.PCT / JP97 / 01815 Sec。 371日期1998年3月30日 102(e)1998年3月30日PCT PCT 1997年5月28日PCT公布。 公开号WO97 / 45466 日期1997年12月4日制备乙烯/α-烯烃/降冰片烯非共轭多烯无规共聚物的方法,包括同时制备满足以下要求(1)至(5)的乙烯无规共聚物:(1)乙烯 a)具有3至20个碳原子的α-烯烃(b)的范围为40:60至95:5; (2)给定量的非共轭多烯(c)具有降冰片烯骨架; (3)使用二枯基过氧化物压制交联共聚物后,可用的网络链密度nu不小于1.5×10 20 / cm 3; (4)从100℃的熔体流动曲线确定的剪切应力为剪切应力为0.4×10 6 dyn / cm 2的剪切速率γ1与剪切应​​力为2.4×10 6 dyn / cm 2,即γ2 /γ1,可用的网络链密度nu具有由以下通式表示的关系:0.04×10-19
    • 8. 发明授权
    • Process for preparing propylene polymer composition and propylene
polymer composition
    • 制备丙烯聚合物组合物和丙烯聚合物组合物的方法
    • US5969049A
    • 1999-10-19
    • US816042
    • 1997-03-11
    • Takashi UedaMikio HashimotoMasaaki KawasakiDaisuke FukuokaJunichi Imuta
    • Takashi UedaMikio HashimotoMasaaki KawasakiDaisuke FukuokaJunichi Imuta
    • C08F2/00C08F2/20C08F4/60C08F10/06C08F210/06C08F210/16C08F297/08C08F297/06C08L23/14
    • C08F297/086C08F10/06C08F210/06C08F210/16C08F4/65912
    • A process for preparing a propylene polymer composition having excellent rigidity, heat resistance and impact resistance, the process comprising conducting multistage polymerization including a step (a) for preparing a propylene (co)polymer (a), a step (b) for preparing a propylene-olefin copolymer (b) and a step (c) for preparing an ethylene-olefin copolymer (c) in the presence of (A) a transition metal compound and (B) a compound activating the transition metal compound (A), in which the steps (a), (b) and (c) may be carried out in any order, each of the second and subsequent stage polymerizations is carried out in the presence of a polymer or polymers obtained by the preceding stage or stages, respectively, and the resulting propylene polymer composition contains the propylene (co)polymer (a) in an amount of 20 to 90% by weight, the propylene-olefin copolymer (b) in an amount of 5 to 75% by weight and the ethylene-olefin copolymer (c) in an amount of 5 to 75% by weight, and has MFR, as measured at 230.degree. C. under a load of 2.16 kg, of 0.01 to 500 g/10 min.
    • 一种制备具有优异的刚性,耐热性和耐冲击性的丙烯聚合物组合物的方法,该方法包括进行包括步骤(a)的制备丙烯(共)聚合物(a)的步骤(a)的多段聚合,制备 丙烯 - 烯烃共聚物(b)和用于在(A)过渡金属化合物和(B)活化过渡金属化合物(A)的化合物存在下制备乙烯 - 烯烃共聚物(c)的步骤(c) 步骤(a),(b)和(c)可以以任何顺序进行,第二阶段和后续阶段聚合中的每一个分别在分别由先前阶段或阶段获得的聚合物或聚合物的存在下进行 ,得到的丙烯聚合物组合物含有20〜90重量%的丙烯(共)聚合物(a),丙烯 - 烯烃共聚物(b)的含量为5〜75重量%,乙烯 - 烯烃共聚物(c)的量为5〜75重量%,MFR为MFR, 在230℃,2.16kg的载荷下测量为0.01〜500g / 10分钟。