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1. 发明申请

WO2012080098A1 FOAMABLE FLUOROPOLYMER COMPOSITIONS 审中-公开
标题翻译：可泡沫氟聚合物组合物
公开(公告)号：WO2012080098A1
公开(公告)日：2012-06-21
申请号：PCT/EP2011/072260
申请日：2011-12-09
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , COLAIANNA, Pasqua , BESANA, Giambattista , DI NICOLO, Emanuele , BRAGANTE, Letanzio , MARCHIONNI, Giuseppe , BRINATI, Giulio
发明人： COLAIANNA, Pasqua , BESANA, Giambattista , DI NICOLO, Emanuele , BRAGANTE, Letanzio , MARCHIONNI, Giuseppe , BRINATI, Giulio
IPC分类号： C08J9/00
CPC分类号： C08K5/42 , C08J9/0019 , C08J2327/12
摘要： The invention pertains to foamable thermoplastic fluoropolymer composition comprising: - at least one fluoropolymer [polymer (A)]; and - at least one perfluoroalkoxysulphonic derivative of either of formulae: (X n+ ) 1/n -O 3 S-CF 2 CF 2 O-R d f -OCF 2 CF 2 -SO 3 -(X n+ ) 1/n and R m f -OCF 2 CF 2 -SO 3 -(X n+ ) 1/n wherein R d f is a divalent C 1 -C 12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom; Rmf is a monovalent C 1 -C 12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom, optionally comprising heteroatoms, generally selected from S, N, P; X = H, a metal cation, or an ammonium group; n is the valence of the cation X, preferably 1 or 2.
摘要翻译：本发明涉及可发泡热塑性含氟聚合物组合物，其包含： - 至少一种含氟聚合物[聚合物（A）]; 和（Xn +）1 / n -O3S-CF2CF2O-Rdf-OCF2CF2-SO3-（Xn +）1 / n和Rmf-OCF2CF2-SO3-（Xn +）1 / n的至少一种全氟代烷氧基磺酸衍生物其中Rd f是可能包含一个或多个醚类氧原子的二价C1-C12全氟化碳基团; Rmf是单价C1-C12全氟化碳基团，可能包含一个或多个醚性氧原子，任选地包含杂原子，通常选自S，N，P; X = H，金属阳离子或铵基; n是阳离子X的化合价，优选1或2。

2. 发明申请

WO2010063745A1 POLYFUNCTIONAL (PER)FLUOROPOLYETHERS 审中-公开
标题翻译：多官能（PER）氟代乙烯醚
公开(公告)号：WO2010063745A1
公开(公告)日：2010-06-10
申请号：PCT/EP2009/066204
申请日：2009-12-02
申请人： SOLVAY SOLEXIS S.p.A. , MARCHIONNI, Giuseppe , PETRICCI, Silvia , GUARDA, Pier, Antonio
发明人： MARCHIONNI, Giuseppe , PETRICCI, Silvia , GUARDA, Pier, Antonio
IPC分类号： C08G65/00
CPC分类号： C08G65/007
摘要： The invention pertains to novel (per)fluoropolyethers comprising at least one (per)fluoropolyoxyalkylene chain (chain R f ) comprising at least one recurring unit (R2) having formula: -CF 2 -CF(CF 2 OSO 2 F)-O- [poly(fluorosulfate) PFPE], to a process for their manufacture, and to their use for providing functional (per)fluoropolyethers.
摘要翻译：本发明涉及包含至少一种（全）氟聚氧亚烷基链（链Rf）的新型（全）氟聚醚，其包含至少一种具有式-CF 2 -CF（CF 2 OSO 2 F）-O- [聚（氟硫酸酯）PFPE的重复单元（R2） ]，其制造方法及其用于提供功能性（全）氟聚醚的用途。

3. 发明申请

WO2008065163A1 FLUORINATED LUBRICANTS 审中-公开
标题翻译：氟化润滑剂
公开(公告)号：WO2008065163A1
公开(公告)日：2008-06-05
申请号：PCT/EP2007/062998
申请日：2007-11-29
申请人： SOLVAY SOLEXIS S.p.A. , AVATANEO, Marco , GUARDA, Pier Antonio , MARCHIONNI, Giuseppe , MACCONE, Patrizia , BOCCALETTI, Giovanni
发明人： AVATANEO, Marco , GUARDA, Pier Antonio , MARCHIONNI, Giuseppe , MACCONE, Patrizia , BOCCALETTI, Giovanni
IPC分类号： C08F283/06 , C08F293/00
CPC分类号： C08F293/00 , C08F214/182 , C08F283/06 , C08F293/005 , C08L53/00 , C10M107/38 , C10M119/22 , C10M2201/0616 , C10M2201/1026 , C10M2201/1056 , C10M2203/045 , C10M2203/065 , C10M2203/1006 , C10M2203/1025 , C10M2203/1045 , C10M2205/0285 , C10M2207/1206 , C10M2207/2805 , C10M2209/1033 , C10M2213/043 , C10M2213/046 , C10M2213/0606 , C10M2213/0613 , C10M2213/0626 , C10M2215/121 , C10M2217/0456 , C10M2229/025 , C10N2210/01 , C10N2210/02 , C10N2220/021 , C10N2220/022 , C10N2230/06 , C10N2230/74 , C10N2240/06 , C10N2240/202 , C10N2250/10 , C10N2250/121 , C08L2666/02 , C08L2666/04
摘要： Fluorinated lubricants of formula T-O-[A-B] z -[A-B'] z' -A-T' (I) wherein: A = -(X) a -O-A'-(X') b - A' is a perfluoropolyether chain comprising units (CF 2 O), (CF 2 CF 2 O), (CF 2 CF 2 CF 2 O), (CF 2 CF 2 CF 2 CF 2 O); X, X' = -CF 2 -, -CF 2 CF 2 -; a, b = 0 or 1; B derives from olefins, of which at least one homopolymerizable by radical route, of formula: -[(CR 1 R 2 -CR 3 R 4 ) j (CR 5 R 6 -CR 7 R 8 ) j ' ]- (Ia) wherein j = 1-5, j'= 0-4 and 2 1 -R 8 = halogen, H, C 1 -C 6 (per)haloalkyl, C 1 -C 6 alkyl, C 1 -C 6 oxy(per)-fluoroalkyl; z ≥ 2; z' is 0 or an integer; z, z' are such that the number average molecular weight of the polymer of formula (I) is in the range 500-500,000; B'= (Ia) but at least one of R 1 -R 8 has a meaning different than that in B and 2 ≤(j+j') 1 -C 3 perfluoroalkyl, C 1 -C 6 alkyl and compositions thereof.
摘要翻译：式（A）的氟化润滑剂：其中：A = - （X）-S-（A）其中：A = - （X） a'是包含单元（CF 2 O 2）的全氟聚醚链，（CF 2 O 2），（CF 3） 2 CF 2，O 2），（CF 2 CH 2 CF 2 O），（CF _{2 CF _{2 CF _{2 CF _{2 O）; X，X'= -CF 2 - ， - CF 2 2 CF 2 - 。 a，b = 0或1; B衍生自烯烃，其中至少一种可通过自由基路线均聚的式，其具有下式： - [（CR 1 R 2 R 2 -CR 3 R _{4 ）_{Ĵ（CR _{5 - [R _{6 -CR _{7 - [R _{8 “”}}}}}}}}}}

4. 发明申请

WO2012104365A3 METHOD FOR MANUFACTURING PERFLUOROVINYLETHERS 审中-公开
标题翻译：制备全氟尿嘧啶的方法
公开(公告)号：WO2012104365A3
公开(公告)日：2012-10-04
申请号：PCT/EP2012051730
申请日：2012-02-02
申请人： SOLVAY SPECIALTY POLYMERS IT , MILLEFANTI STEFANO , TORTELLI VITO , MARCHIONNI GIUSEPPE , ALBONETTI STEFANIA , GREGORI MANUEL , FORNASARI GIUSEPPE
发明人： MILLEFANTI STEFANO , TORTELLI VITO , MARCHIONNI GIUSEPPE , ALBONETTI STEFANIA , GREGORI MANUEL , FORNASARI GIUSEPPE
IPC分类号： C07C41/24 , C07C43/17
CPC分类号： C07C41/24 , C07C43/17
摘要： The invention pertains to a process for the manufacture of a perfluorovinylether by hydrodehalogenation of a halofluoroether (HFE) having general formula (l-A) or (l-B): RfO-CRf'X-CRf"Rf"'X' (l-A) wherein Rf represents a C1-C6 perfluoro(oxy)alkyl group; Rf', Rf" and Rf'", equal or different from each other, independently represent fluorine atoms or C1-C5 perfluoro(oxy)alkyl groups; X and X', equal or different from each other, are independently chosen among CI, Br or I; formula (I-B) wherein Rf* and Rf*', equal or different from each other, independently represent fluorine atoms or C1-C3 perfluoro(oxy)alkyl groups; Y1 and Y2, equal or different from each other, independently represent fluorine atoms or C1-C3 perfluoroalkyl groups; X and X' are as above defined; said process comprising contacting said halofluoroether (HFE) with hydrogen in the presence of a catalyst comprising palladium and at least one transition metal (M) selected from the group consisting of the metals of group VIIIB, other than palladium, and of group IB.
摘要翻译：本发明涉及通过具有通式（1A）或（1B）的卤代氟醚（HFE）的加氢脱卤制备全氟乙烯基醚的方法：RfO-CRf'X-CRf“Rf”'X'（1A）其中Rf代表 C1-C6全氟（氧）烷基; Rf'，Rf“和Rf”“彼此相同或不同，独立地表示氟原子或C1-C5全氟（氧）烷基; X和X'彼此相同或不同，独立地选自CI，Br或I; 式（I-B）其中Rf *和Rf *'彼此相同或不同，独立地表示氟原子或C1-C3全氟（氧）烷基; Y1和Y2彼此相同或不同，独立地表示氟原子或C1-C3全氟烷基; X和X'如上所定义; 所述方法包括在催化剂存在下使所述卤代氟醚（HFE）与氢气接触，所述催化剂包含钯和至少一种选自除钯以外的第VIIIB族金属和IB族的过渡金属（M）。

5. 发明申请

WO2012084749A1 THERMOPROCESSABLE PER(HALO)FLUOROPOLYMER COMPOSITION 审中-公开
标题翻译：（HALO）氟聚合物组合物
公开(公告)号：WO2012084749A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073146
申请日：2011-12-16
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A. , COLAIANNA, Pasqua , AVATANEO, Marco , DI NICOLO, Emanuele , BESANA, Giambattista , MARCHIONNI, Giuseppe
发明人： COLAIANNA, Pasqua , AVATANEO, Marco , DI NICOLO, Emanuele , BESANA, Giambattista , MARCHIONNI, Giuseppe
IPC分类号： C08L71/02 , C08G65/00 , C08L27/00
CPC分类号： C08L53/00 , C08G65/007 , C08G2650/48 , C08K3/04 , C08K2003/3045 , C08L27/00 , C08L27/18 , C08L71/02 , C08L2666/04
摘要： The invention pertains to a thermoprocessable composition comprising: - at least one thermoprocessable per(halo)fluoropolymer [polymer (A)]; - at least one inorganic filler [filler (I)]; and - at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain R f ), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain R a ) comprising recurring units of formula: -(CR 1 R 2 -CR 3 R 4 )- wherein R 1 , R 2 , R 3 , R 4 , equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, CI); C 1 -C 6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyi or (per)fluorooxyalkyl.
摘要翻译：本发明涉及一种热可加工组合物，其包含： - 至少一种热可加工的每（卤）含氟聚合物[聚合物（A）]; - 至少一种无机填料[填料（I）]; 和 - 至少一种全氟聚醚嵌段共聚物[聚合物（E）]，其包含：A）一个或多个（全）氟聚氧亚烷基链段（链Rf），也就是说包含具有至少一个链中键的重复单元的链段和至少一个碳氟化合物部分，和B）包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的一个或多个聚亚烷基链段（链Ra） - 其中R 1，R 2，R 3，R 4彼此相同或不同，选自由H，卤素（优选F，Cl）组成的组; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团，优选全氟烷基或（全）氟氧烷基。

6. 发明申请

WO2012000853A1 PROCESS FOR THE SYNTHESIS OF TRIFLUOROETHYLENE 审中-公开
标题翻译：三氟乙烯合成方法
公开(公告)号：WO2012000853A1
公开(公告)日：2012-01-05
申请号：PCT/EP2011/060400
申请日：2011-06-22
申请人： SOLVAY SOLEXIS S.p.A. , MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe
发明人： MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe
IPC分类号： C07C17/23 , C07C21/18
CPC分类号： B01J23/44 , B01J21/18 , B01J23/42 , B01J35/023 , B01J35/1023 , B01J35/1028 , B01J37/0009 , B01J37/18 , C07C17/23 , C07C21/18
摘要： A catalytic process for the synthesis of trifluoroethylene from chlorotrifluoroethylene which comprises contacting chlorotrifluoroethylene with hydrogen in the presence of a catalyst consisting of palladium or platinum supported on extruded activated carbon.
摘要翻译：用于从三氟氯乙烯合成三氟乙烯的催化方法，其包括在负载在挤出的活性炭上的由钯或铂组成的催化剂存在下使氯三氟乙烯与氢接触。

7. 发明申请

WO2010057691A3 HYDROFLUOROALCOHOLS WITH IMPROVED THERMAL AND CHEMICAL STABILITY 审中-公开
公开(公告)号：WO2010057691A3
公开(公告)日：2010-05-27
申请号：PCT/EP2009/060302
申请日：2009-08-07
申请人： SOLVAY SOLEXIS S.P.A. , MARCHIONNI, Giuseppe , DE PATTO, Ugo , AVATANEO, Marco
发明人： MARCHIONNI, Giuseppe , DE PATTO, Ugo , AVATANEO, Marco
IPC分类号： C07C43/13
摘要： Hydrofluoro alcohols of formula : A-(R f ) a -CFX-O-R h O-(CFX-(R f ) a* -CFX-O-R h O-) n H (I) in which : R h is a hydrocarbon-based chain; X is F or a C 1 -C 6 (per)fluoroalkyl; a or a* is 0 or 1; R f is a (per)fluoro(poly)oxyalkylene chain or a (per)fluoroalkyl chain; A is chosen from -F, -C1 and -H (possible only when a = 1) or is HO- R h -O-CFX-; n is an integer from 0 to 200, with the condition that n = 0 when A is chosen from -F, -C1 and -H.

8. 发明申请

WO2009150091A1 METHOD FOR MANUFACTURING PERFLUOROVINYLETHERS 审中-公开
标题翻译：制备全氟尿嘧啶的方法
公开(公告)号：WO2009150091A1
公开(公告)日：2009-12-17
申请号：PCT/EP2009/056858
申请日：2009-06-04
申请人： SOLVAY SOLEXIS S.P.A. , MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe
发明人： MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe
IPC分类号： C07C17/35 , C07C17/00 , C07C19/08
CPC分类号： C07C41/24 , C07D317/34 , C07C43/17
摘要： The invention pertains to a process for the manufacture of a perfluorovinylether by hydrodehalogenation of a halofluoroether (HFE) having general formula (I-A) or (I-B): R f O-CR f 'X-CR f ''R f '''X' (I-A) wherein R f represents a C 1 -C 6 perfluoro(oxy)alkyl group; R f ', R f " and R f "' equal or different from each other, independently represent fluorine atoms or C 1 -C 5 perfluoro(oxy)alkyl groups; X and X', equal or different from each other, are independently chosen among Cl, Br or I; formula (I-B); wherein R f * and R f *', equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoro(oxy)alkyl groups; Y 1 and Y 2 , equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoroalkyl groups; X and X' are as above defined; said process comprising contacting said halofluoroether (HFE) with hydrogen in the presence of a catalyst comprising at least one transition metal of group VIII B at a temperature of at most 340°C.
摘要翻译：本发明涉及通过具有通式（IA）或（IB）的卤代氟醚（HFE）的加氢脱卤制备全氟乙烯基醚的方法：RfO-CRf'X-CRf''Rf“'X'（IA），其中 Rf表示C1-C6全氟（氧）烷基; Rf'，Rf“和Rf”'彼此相同或不同，独立地表示氟原子或C1-C5全氟（氧）烷基; X和X'彼此相同或不同，独立地选自Cl，Br或I; 式（I-B）; 其中Rf *和Rf *'彼此相同或不同，独立地表示氟原子或C1-C3全氟（氧）烷基; Y1和Y2彼此相同或不同，独立地表示氟原子或C1-C3全氟烷基; X和X'如上所定义; 所述方法包括在包含至少一种第ⅧB族过渡金属的催化剂存在下，在至多340℃的温度下使所述卤代氟醚（HFE）与氢气接触。

9. 发明申请

WO2008065165A1 FLUORINATED LUBRICANTS 审中-公开
标题翻译：氟化润滑剂
公开(公告)号：WO2008065165A1
公开(公告)日：2008-06-05
申请号：PCT/EP2007/063000
申请日：2007-11-29
申请人： SOLVAY SOLEXIS S.p.A. , MARCHIONNI, Giuseppe , GUARDA, Pier Antonio , AVATANEO, Marco
发明人： MARCHIONNI, Giuseppe , GUARDA, Pier Antonio , AVATANEO, Marco
IPC分类号： C08G65/00
CPC分类号： C08G65/007 , C08L27/12 , C08L71/02 , C08L2205/05 , C10M107/38 , C10M2213/043 , C10M2213/0606 , C10N2230/06 , C10N2230/74 , C10N2250/10 , C08L2666/04
摘要： Polymers of formula (I) Q-O-[A-B] z -[A-B'] z' -A-Q' (I) wherein: - A = -(X) a -O-A'-(X') b - with A'= perfluoropolyether chain and X, X'= -CF 2- , -CF 2 CF 2- ; a, b = 0.1 with the proviso that a = 1 if A is linked to Q-O-; b = 0 when A is linked to Q'; - B derives from homopolymerizable olefins by radical route, of formula: -[(CR 1 R 2- CR 3 R 4 ) j (CR 5 R 6 -CR 7 R 8 ) j' ]- (Ia) wherein j is an integer from 1 to 30, j' is an integer from 0 to 29 with the proviso that (j+j') is higher than 2 and lower than 30; R 1 -R 8 are halogen; H; C 1 -C 6 (per)haloalkyl; C 1 -C 6 alkyl; C 1 -C 6 oxy(per)fluoroalkyl; B'= B but at least one among R 1 -R 8 has a meaning different from that in B; - z, z' are such that the number average molecular weight of the polymer of formula (I) is between 500 and 150,000; - Q, Q'= C 1 -C 3 (per)fluoroalkyl or functional end group -(CFW)-D q -T k ; W = F, CF 3 ; k and q are integers, k ranges from 1 to 4, preferably 1 or 2, q is an integer and is equal to 0 or 1; with the proviso that at least one of Q, Q' is functional end group.
摘要翻译：式（I）的聚合物QO- [AB] z - [A-B'] Z'-AQ'（I）其中：-A = - （X） A'=全氟聚醚链和X，X'= -CF 2 - - - - （X'）b - ，-CF 2 CF 2 - ， - a，b = 0.1，条件是如果A连接到Q-O-，则a = 1; 当A连接到Q'时，b = 0; -B通过自由基途径衍生自均聚烯烃，式为： - [（CR 1 R 2 - NR 3 R 4） / SUB>）_{Ĵ（CR _{5 - [R _{6 -CR _{7 - [R _{8 （Ia）其中j为1至30的整数，j'为0至29的整数，条件是（j + j'）高于2且低于超过30 R 1 -R 8是卤素; H; C 1 -C 6 -C 6（全）卤代烷基; C 1 -C 6烷基; C 1 -C 6烷基; C 1 -C 6 -C 6氧基（全）氟代烷基; B'= B，但R 1至R 8中的至少一个具有与B中不同的含义; -z，z'使得式（I）的聚合物的数均分子量在500和150,000之间; - Q，Q'= C 1 -C 3（全）氟烷基或官能端基 - （CFW）-DQ q - SUB>ķ; W = F，CF 3 3; k和q是整数，k的范围是1至4，优选1或2，q是整数并且等于0或1; 条件是Q，Q'中的至少一个是官能端基。}}}}}

10. 发明申请

WO2012104365A2 METHOD FOR MANUFACTURING PERFLUOROVINYLETHERS 审中-公开
标题翻译：制备全氟尿嘧啶的方法
公开(公告)号：WO2012104365A2
公开(公告)日：2012-08-09
申请号：PCT/EP2012/051730
申请日：2012-02-02
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.p.A. , MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe , ALBONETTI, Stefania , GREGORI, Manuel , FORNASARI, Giuseppe
发明人： MILLEFANTI, Stefano , TORTELLI, Vito , MARCHIONNI, Giuseppe , ALBONETTI, Stefania , GREGORI, Manuel , FORNASARI, Giuseppe
IPC分类号： C07C41/42
CPC分类号： C07C41/24 , C07C43/17
摘要： The invention pertains to a process for the manufacture of a perfluorovinylether by hydrodehalogenation of a halofluoroether (HFE) having general formula (l-A) or (l-B): R f O-CR f 'X-CR f "R f "'X' (l-A) wherein Rf represents a C 1 -C 6 perfluoro(oxy)alkyl group; R f ', R f " and R f '", equal or different from each other, independently represent fluorine atoms or C 1 -C 5 perfluoro(oxy)alkyl groups; X and X', equal or different from each other, are independently chosen among CI, Br or I; wherein R f * and R f *', equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoro(oxy)alkyl groups; Y 1 and Y 2 , equal or different from each other, independently represent fluorine atoms or C 1 -C 3 perfluoroalkyl groups; X and X' are as above defined; said process comprising contacting said halofluoroether (HFE) with hydrogen in the presence of a catalyst comprising palladium and at least one transition metal (M) selected from the group consisting of the metals of group VIIIB, other than palladium, and of group IB.
摘要翻译：本发明涉及通过具有通式（1A）或（1B）的卤代氟醚（HFE）的加氢脱卤制备全氟乙烯基醚的方法：RfO-CRf'X-CRf“Rf”'X'（1A）其中Rf代表 C1-C6全氟（氧）烷基; Rf'，Rf“和Rf”“彼此相同或不同，独立地表示氟原子或C1-C5全氟（氧）烷基; X和X'彼此相同或不同，独立地选自CI，Br或I; 其中Rf *和Rf *'彼此相同或不同，独立地表示氟原子或C1-C3全氟（氧）烷基; Y1和Y2彼此相同或不同，独立地表示氟原子或C1-C3全氟烷基; X和X'如上所定义; 所述方法包括在催化剂存在下使所述卤代氟醚（HFE）与氢气接触，所述催化剂包含钯和至少一种选自除钯以外的第VIIIB族金属和IB族的过渡金属（M）。

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