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1. 发明申请

WO2014154803A1 PRODUCTION OF MIDDLE DISTILLATE HYDROCARBON COMPOSITION 审中-公开
标题翻译：中间馏分油组合物的生产
公开(公告)号：WO2014154803A1
公开(公告)日：2014-10-02
申请号：PCT/EP2014/056154
申请日：2014-03-27
申请人： BP P.L.C. , LUCY, Andrew Richard
发明人： LUCY, Andrew Richard
IPC分类号： C10G50/00 , C10G69/12
CPC分类号： C10G50/00 , C10G69/126 , C10G2300/1092 , C10G2400/04 , C10G2400/08
摘要： A process for the preparation of a middle distillate hydrocarbon composition from ethylene, wherein said process comprises the following steps: (a) feeding ethylene in to an oligomerisation reaction zone containing a supported nickel oligomerisation catalyst to form an oligomerisation product stream A, wherein the oligomerisation reaction zone is operated at a temperature in the range of from 30 to 300 °C and a pressure of at least 10 bara; (b) separating a light products stream B and a middle distillate product stream C from oligomerisation product stream A, wherein the light product stream B comprises the fraction of oligomerisation product stream A which boils in the C2-C8 mono-olefin boiling range and the middle distillate product stream C consists of a fraction of oligomerisation product stream A which boils above the boiling range of the light product stream B; and (c) recycling at least a portion of the light products stream B to the oligomerisation reaction zone of step (a) of the process; wherein at least a portion of the middle distillate product stream C is recovered as the middle distillate hydrocarbon composition.
摘要翻译：一种用于从乙烯制备中间馏分烃组合物的方法，其中所述方法包括以下步骤：（a）将乙烯进料到含有负载的镍低聚催化剂的低聚反应区以形成低聚产物流A，其中低聚反应区在30-300℃的温度和至少10巴的压力下操作; （b）从低聚产物流A中分离轻质产物流B和中间馏分产物流C，其中轻质产物流B包含在C2-C8单烯烃沸程范围内沸腾的低聚产物流A的馏分和中间馏分产物流C由低级产物流A的一部分组成，其沸点高于轻产物流B的沸程; 和（c）将至少一部分轻质产物流B再循环到该方法的步骤（a）的低聚反应区; 其中中间馏分产物流C的至少一部分作为中间馏分烃组合物回收。

2. 发明申请

WO2014154802A1 PRODUCTION OF A LIQUID HEAVY HYDROCARBON COMPOSITION 审中-公开
标题翻译：液体重质烃组合物的生产
公开(公告)号：WO2014154802A1
公开(公告)日：2014-10-02
申请号：PCT/EP2014/056153
申请日：2014-03-27
申请人： BP P.L.C. , LUCY, Andrew Richard
发明人： LUCY, Andrew Richard
IPC分类号： C10G29/20 , C10G50/02 , C10G69/12
CPC分类号： C10G29/205 , C10G50/02 , C10G69/126 , C10G2300/1092 , C10G2400/10
摘要： A process for the preparation of a liquid heavy hydrocarbon composition from ethylene, wherein said process comprises the following steps: (a) feeding an ethylene composition in to an oligomerisation reaction zone containing a supported nickel oligomerisation catalyst to form an oligomerisation product A, wherein the oligomerisation reaction is operated at a temperature in the range of from 30 to 300 °C and a pressure of at least 10 bara; (b) separating a light products stream B, a middle distillate product stream C and a heavy products stream D from oligomerisation product A, wherein the light product stream B comprises the fraction of oligomerisation product A which boils in the C2-C8 mono-olefm boiling range, the middle distillate product stream C comprises a fraction of oligomerisation product A which boils above the boiling range of the light product stream B and below the boiling range of the heavy products stream D, and wherein the heavy product stream D comprises the fraction of oligomerisation product A which boils above the C22 mono-olefin boiling range; (c) recycling at least a portion of the light products stream B to the oligomerisation reaction zone of step (a) of the process; (d) optionally recycling at least a portion of the middle distillate product stream C to the oligomerisation reaction zone of step (a) of the process; and (e) hydrogenating the heavy products stream C, wherein the at least a portion of the hydrogenated heavy products stream D is recovered as the liquid heavy hydrocarbon composition.
摘要翻译：一种从乙烯制备液体重质烃组合物的方法，其中所述方法包括以下步骤：（a）将乙烯组合物进料至含有负载型镍低聚催化剂的低聚反应区以形成低聚产物A，其中低聚反应在30-300℃的温度和至少10巴的压力下操作; （b）从低聚产物A分离轻质产物流B，中间馏分产物流C和重质产物流D.其中轻质产物流B包含在C2-C8单烯烃中沸腾的低聚产物A馏分中间馏分产物流C包含低聚产物A的一部分，其沸点高于轻产物流B的沸程并低于重产物流D的沸程，并且其中重产物流D包含馏分的低聚产物A，其沸点高于C22单烯烃沸程; （c）将至少一部分轻质产物流B再循环到该方法的步骤（a）的低聚反应区; （d）任选地将中间馏分产物流C的至少一部分再循环到该方法的步骤（a）的低聚反应区; 和（e）氢化重产物流C，其中至少一部分氢化重质产物流D作为液体重烃组合物被回收。

3. 发明申请

WO2003074454A1 ALKENE SEPARATION PROCESS 审中-公开
标题翻译： ALKENE分离过程
公开(公告)号：WO2003074454A1
公开(公告)日：2003-09-12
申请号：PCT/GB2003/000686
申请日：2003-02-12
申请人： BP CHEMICALS LIMITED , LUCY, Andrew, Richard
发明人： LUCY, Andrew, Richard
IPC分类号： C07C7/11
CPC分类号： C07C7/152 , C07C5/48 , C07C7/156 , C07C51/215 , C07C67/055 , C07C2523/20 , C07C2523/22 , C07C2523/28 , Y02P20/125 , Y02P20/582 , C07C11/04 , C07C53/08 , C07C69/15
摘要： A process for the oxidation of a C 2 to C 4 alkane to produce the corresponding alkene and carboxylic acid which process comprises separation of the alkene from a mixture of the alkene, the alkane and oxygen by absorption in a metallic salt solution, and recovery of an alkene-rich stream from the metallic salt solution. Integrated processes for the production of alkyl carboxylate and alkenyl carboxylate, which processes comprise oxidation of a C 2 to C 4 alkane to produce the corresponding alkene and carboxylic acid, separation of the alkene from a mixture of the alkene, the alkane and oxygen by absorption in a metallic salt solution, and recovery of an alkene-rich stream from the metallic salt solution for use in production of alkyl carboxylate or alkenyl carboxylate.
摘要翻译：用于氧化C 2至C 4烷烃以产生相应的烯烃和羧酸的方法，该方法包括通过在金属盐溶液中吸收将烯烃与烯烃和氧气的混合物分离，并回收烯烃来自金属盐溶液的富流。用于生产羧酸烷基酯和链烯基羧酸酯的综合方法，该方法包括将C2至C4烷烃氧化以产生相应的烯烃和羧酸，通过吸收烯烃和烷烃与氧气的混合物将烯烃分离出来金属盐溶液，并从用于生产羧酸烷基酯或羧酸烯基酯的金属盐溶液中回收富含烯烃的物流。

4. 发明申请

WO1995017461A1 ETHER COSOLVENTS FOR RESIN FORMULATIONS 审中-公开
标题翻译：树脂配方的其他成分
公开(公告)号：WO1995017461A1
公开(公告)日：1995-06-29
申请号：PCT/GB1994002722
申请日：1994-12-13
申请人： BP CHEMICALS LIMITED , CHAPMAN, Richard, George , GOODWIN, Stephen, Paul , HAZEL, Nicholas, John , LUCY, Andrew, Richard , STEWART, Nevin, John
发明人： BP CHEMICALS LIMITED
IPC分类号： C08K05/06
CPC分类号： C09D5/024 , C07C43/11 , C08J3/091 , C08J3/095 , C09D7/20
摘要： This invention relates to aqueous resin formulations comprising as cosolvent an alkoxy ethoxyethanol which (i) has 4-8 carbon atoms in the alkoxy group, (ii) has a boiling point at atmospheric pressure within the range from 200 to 350 DEG C and (iii) in mixtures with n-heptane in the ratio of 30:70 by weight respectively has specific miscibility characteristics. The cosolvent acts either as a solvent or coalescing aid in aqueous formulations used as coatings and paints.
摘要翻译：本发明涉及包含作为共溶剂的烷氧基乙氧基乙醇的水性树脂配制剂，其中（i）在烷氧基中具有4-8个碳原子，（ii）在大气压下的沸点在200-350℃范围内，和（iii ）与正庚烷的混合比例分别为30:70（重量比），具有特定的混溶性。共溶剂在用作涂料和涂料的水性配方中用作溶剂或聚结助剂。

5. 发明申请

WO1985005356A1 CHEMICAL PROCESS 审中-公开
标题翻译：化学工艺
公开(公告)号：WO1985005356A1
公开(公告)日：1985-12-05
申请号：PCT/GB1985000195
申请日：1985-05-09
申请人： THE BRITISH PETROLEUM COMPANY P.L.C. , LUCY, Andrew, Richard , MORRIS, George, Ernest
发明人： THE BRITISH PETROLEUM COMPANY P.L.C.
IPC分类号： C07C67/38
CPC分类号： C07C67/38 , C07C69/34 , C07C69/40
摘要： A process for the preparation of an ester of dicarboxylic acid from an alkene, carbon monoxide. The process is catalysed by a catalyst which comprises a platinum group metal, for example palladium, and a copper compound. To avoid catalyst deactivation the process is carried out in the presence of a dihydrocarbyl peroxide which is reduced to a hydrocarbyl alcohol under the process conditions. The process can be used, for example, to prepapre succinate esters from ethylene, carbon monoxide, an alcohol and a dihydrocarbyl peroxide such as di-tertiary butyl peroxide.

6. 发明申请

WO2014154801A1 PRODUCTION OF MIDDLE DISTILLATE HYDROCARBON COMPOSITION 审中-公开
标题翻译：中间馏分油组合物的生产
公开(公告)号：WO2014154801A1
公开(公告)日：2014-10-02
申请号：PCT/EP2014/056152
申请日：2014-03-27
申请人： BP P.L.C. , LUCY, Andrew, Richard , BOUGH, Matthew
发明人： LUCY, Andrew, Richard , BOUGH, Matthew
IPC分类号： C10G47/00 , C10G50/00 , C10G65/14 , C10G69/00 , C10G69/12
CPC分类号： C10G47/00 , C10G50/00 , C10G65/14 , C10G69/00 , C10G69/12 , C10G69/126 , C10G2400/04 , C10G2400/08
摘要： A process for the preparation of a middle distillate hydrocarbon composition from ethylene, wherein said process comprises the following steps: (a) feeding an ethylene composition in to an oligomerisation reaction zone containing a supported nickel oligomerisation catalyst to form an oligomerisation product A, wherein the oligomerisation reaction is operated at a temperature in the range of from 30 to 300 °C and a pressure of at least 10 bara; (b) separating a light products stream B, a middle distillate product stream C and a heavy products stream D from oligomerisation product A, wherein the light product stream B comprises the fraction of oligomerisation product A which boils in the C2-C8 mono-olefin boiling range and the middle distillate product stream C comprises a fraction of oligomerisation product A which boils above the boiling range of the light product stream B and below the boiling range of the heavy products stream D, and wherein the heavy product stream D comprises the fraction of oligomerisation product A which boils above the C22 mono-olefin boiling range; (c) recycling at least a portion of the light products stream B to the oligomerisation reaction zone of step (a) of the process; (d) cracking the heavy product stream D in a cracking reactor to produce a cracked product stream E; (e) separating a middle distillate product F from the cracked product stream E; and (f) hydrogenating the middle distillate product stream C, wherein the middle distillate hydrocarbon composition comprises at least a portion of the hydrogenated middle distillate product stream C and at least a portion of the middle distillate product F.
摘要翻译：一种用于从乙烯制备中间馏分烃组合物的方法，其中所述方法包括以下步骤：（a）将乙烯组合物进料至含有负载型镍低聚催化剂的低聚反应区以形成低聚产物A，其中低聚反应在30-300℃的温度和至少10巴的压力下操作; （b）从低聚产物A分离轻质产物流B，中间馏分产物流C和重质产物流D.其中轻质产物流B包含在C2-C8单烯烃中沸腾的低聚产物A馏分沸腾范围和中间馏分产物流C包含低聚产物A的一部分，其沸点高于轻产物流B的沸程并且低于重产物流D的沸程，并且其中重产物流D包含馏分的低聚产物A，其沸点高于C22单烯烃沸程; （c）将至少一部分轻质产物流B再循环到该方法的步骤（a）的低聚反应区; （d）在裂解反应器中裂解重质产物流D以产生裂化产物流E; （e）将中间馏分产物F与裂化产物流E分离; 和（f）中间馏出物产物流C的氢化，其中中间馏分烃组合物包含至少一部分氢化中间馏分产物流C和至少部分中间馏分产物F。

7. 发明申请

WO2014018837A1 BUTANOL PURIFICATION 审中-公开
标题翻译：丁醇净化
公开(公告)号：WO2014018837A1
公开(公告)日：2014-01-30
申请号：PCT/US2013/052213
申请日：2013-07-26
申请人： CHENG, Cecilia , DOBSON, Ian, David , HOGBEN, Andrew, John , LUCY, Andrew, Richard , SUNLEY, John, Glenn , BOLTON, Leslie, William
发明人： CHENG, Cecilia , DOBSON, Ian, David , HOGBEN, Andrew, John , LUCY, Andrew, Richard , SUNLEY, John, Glenn , BOLTON, Leslie, William
IPC分类号： C07C29/76 , C07C29/80 , C07C29/88 , C10L1/02 , C10L1/14 , C10L1/18 , C10L1/182 , C10L1/185 , C10L1/188
CPC分类号： C07C29/88 , C07C29/76 , C07C29/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/02 , C10L1/023 , C10L1/026 , C10L1/14 , C10L1/18 , C10L1/1824 , C10L1/1857 , C10L1/1881 , C10L2200/0423 , C10L2200/043 , C10L2200/0446 , C10L2200/0469 , C10L2270/023 , C10L2270/026 , C10L2270/04 , C10L2290/26 , C10L2290/54 , C10L2290/543 , C07C31/12
摘要： Provided are methods for removing one or more components from a butanol based composition. The methods comprise providing a butanol based composition comprising one or more components, targeting at least one component or a combination thereof for reduction, and processing said butanol based composition such that the at least one targeted component is substantially removed. The butanol based composition can, for example, be bio-produced.
摘要翻译：提供从基于丁醇的组合物中除去一种或多种组分的方法。所述方法包括提供包含一种或多种组分的基于丁醇的组合物，靶向至少一种组分或其组合用于还原，以及处理所述基于丁醇的组合物，使得至少一种目标组分基本上被除去。例如，基于丁醇的组合物可以生物生产。

8. 发明申请

WO2006014834A1 PROCESS FOR OXIDATION OF METHANE TO ACETIC ACID 审中-公开
标题翻译：将甲烷氧化成乙酸的方法
公开(公告)号：WO2006014834A1
公开(公告)日：2006-02-09
申请号：PCT/US2005/026172
申请日：2005-07-21
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , BP CHEMICALS LIMITED , ZERELLA, Mark , MUKHOPADHYAY, Sudip , BELL, Alexis, T. , SUNLEY, John Glenn , GAEMERS, Sander , HOWARD, Philip , ELLIS, Brian , LUCY, Andrew Richard
发明人： ZERELLA, Mark , MUKHOPADHYAY, Sudip , BELL, Alexis, T. , SUNLEY, John Glenn , GAEMERS, Sander , HOWARD, Philip , ELLIS, Brian , LUCY, Andrew Richard
IPC分类号： C07C51/14
CPC分类号： C07C51/305 , C07C53/08
摘要： Acetic acid is produced by oxidation of methane with an oxygen-containing gas in the presence of an acid selected from an acid selected from concentrated sulfuric acid and fuming sulfuric acid, a palladium-containing catalyst and a promoter, preferably a copper or iron salt. The addition of a promoter and O 2 to a system that includes a palladium-containing catalyst such as PdCl 2 increases the rate of acetic acid formation from methane by more than an order of magnitude as compared with prior art and, in addition, inhibits the precipitation of Pd black.
摘要翻译：在选自浓硫酸和发烟硫酸的酸，含钯催化剂和助催化剂的酸存在下，通过用含氧气体氧化甲烷来生产乙酸，优选铜盐或铁盐。向包括含钯催化剂例如PdCl 2的体系添加助催化剂和O 2 2使甲烷的乙酸形成速率增加多于一个数量级与现有技术相比，并且此外还抑制Pd黑的沉淀。

9. 发明申请

WO2004108649A3 OXIDATION PROCESS FOR THE PRODUCTION OF CARBOXYLIC ACIDS AND ALKENES 审中-公开
标题翻译：用于生产羧酸和碱的氧化过程
公开(公告)号：WO2004108649A3
公开(公告)日：2005-03-17
申请号：PCT/GB2004002069
申请日：2004-05-13
申请人： BP CHEM INT LTD , FERGUSON EWEN JAMES , LUCY ANDREW RICHARD , ROBERTS MARK STEPHEN , TAYLOR DIANA RACHEL , WILLIAMS BRUCE LEO
发明人： FERGUSON EWEN JAMES , LUCY ANDREW RICHARD , ROBERTS MARK STEPHEN , TAYLOR DIANA RACHEL , WILLIAMS BRUCE LEO
IPC分类号： C07C51/215 , C07C51/25 , C07C67/04 , C07C67/05 , C07C53/08 , C07C67/035 , C07C69/01 , C07C69/14
CPC分类号： C07C67/04 , C07C51/215 , C07C51/25 , C07C67/05 , Y02P20/582 , C07C53/08 , C07C69/14 , C07C69/01 , C07C69/15
摘要： An oxidation process for the production of alkenes and carboxylic acids from a feed comprising alkene and/or alkane, carbon monoxide, a molecular oxygen containing gas and optionally water in the presence of an oxidation catalyst in which the level of carbon monoxide is maintained between 1% and 20% by volume of the total feed to the reactor.
摘要翻译：一种用于在包含烯烃和/或烷烃，一氧化碳，含分子氧气体和任选的水的进料中在存在氧化催化剂的情况下生产烯烃和羧酸的氧化方法，其中一氧化碳水平保持在1 ％和20体积％的反应器的总进料量。

10. 发明申请

WO2003074465A1 PROCESS FOR THE PRODUCTION OF AN ALKENYL CARBOXYLATE OR AN ALKYL CARBOXYLATE 审中-公开
标题翻译：制备羧酸亚烷基酯或羧酸烷基酯的方法
公开(公告)号：WO2003074465A1
公开(公告)日：2003-09-12
申请号：PCT/GB2003/000619
申请日：2003-02-12
申请人： BP CHEMICALS LIMITED , CLARKE, Robert, William , CROLL, Robert , LUCY, Andrew, Richard , WILLIAMS, Bruce, Leo
发明人： CLARKE, Robert, William , CROLL, Robert , LUCY, Andrew, Richard , WILLIAMS, Bruce, Leo
IPC分类号： C07C67/04
CPC分类号： C07C67/04 , C07C67/055 , Y02P20/125 , Y02P20/582 , C07C69/14 , C07C69/01 , C07C69/15
摘要： Integrated processes for the production of alkenyl carboxylate and alkyl carboxylate comprising oxidation of a C 2 to C 4 alkane to produce the corresponding alkene and carboxylic acid, separation of the product stream to give a gaseous stream comprising the alkene and unreacted alkane, subsequent separation of the alkene and the alkane into respective streams rich in alkene and alkane, and use of the alkene rich stream in the production of either alkenyl carboxylate or alkyl carboxylate.
摘要翻译：用于生产烯基羧酸酯和羧酸烷基酯的整合方法包括将C2至C4烷烃氧化以产生相应的烯烃和羧酸，分离产物流以产生包含烯烃和未反应的烷烃的气流，随后分离烯烃并将烷烃分离成富含烯烃和烷烃的相应物流，以及使用富链烯烃生产链烯基羧酸酯或羧酸烷基酯。

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