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1. 发明申请

WO2012154244A3 BARRIER MATERIALS FOR MIRROR ASSEMBLIES 审中-公开
标题翻译：用于镜子组装的障碍物
公开(公告)号：WO2012154244A3
公开(公告)日：2013-03-14
申请号：PCT/US2012025336
申请日：2012-02-16
申请人： HONEYWELL INT INC , MUKHOPADHYAY SUDIP , VARAPRASAD DESARAJU , NALEWAJEK DAVID , KERKAR AWDHOOT VASANT
发明人： MUKHOPADHYAY SUDIP , VARAPRASAD DESARAJU , NALEWAJEK DAVID , KERKAR AWDHOOT VASANT
IPC分类号： B32B15/04 , F24S23/70 , G02B5/12 , H01L31/052
CPC分类号： G02B1/14 , B05D1/02 , B05D3/02 , C09D127/12 , F24J2002/1071 , G02B1/105 , G02B5/0808 , Y10T428/26 , Y10T428/269 , Y10T428/3154
摘要： Provided herein is a reflective optical construction containing a fluoropolymer barrier layer, wherein the fluoropolymer is selected from the group consisting of homopolymers and copolymers of at least one tetrafluoropropene or pentafluoropropene, preferably 2,3,3,3-tetrafluoropropene. Also disclosed is a method of forming a reflective optical construction including (a) applying a barrier layer comprising one or more fluoropolymers selected from the group consisting of homopolymers and copolymers of at least one tetrafluoropropene or pentafluoropropene, and (b) curing.
摘要翻译：本文提供了含有氟聚合物阻挡层的反射光学结构，其中氟聚合物选自由至少一种四氟丙烯或五氟丙烯，优选2,3,3,3-四氟丙烯的均聚物和共聚物组成的组。还公开了一种形成反射光学结构的方法，其包括（a）施加包含一种或多种选自至少一种四氟丙烯或五氟丙烯的均聚物和共聚物的含氟聚合物的阻隔层和（b）固化。

2. 发明申请

WO2007079431A8 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 审中-公开
标题翻译：生产氟化有机化合物的方法
公开(公告)号：WO2007079431A8
公开(公告)日：2008-08-21
申请号：PCT/US2007000056
申请日：2007-01-03
申请人： HONEYWELL INT INC , TUNG HSUEH SUNG , MUKHOPADHYAY SUDIP , VAN DER PUY MICHAEL , MA JING JI , BORTZ CHERYL , LIGHT BARBARA , PHILLIPS STEVEN D , DUBEY RAJESH , MERKEL DANIEL C
发明人： TUNG HSUEH SUNG , MUKHOPADHYAY SUDIP , VAN DER PUY MICHAEL , MA JING JI , BORTZ CHERYL , LIGHT BARBARA , PHILLIPS STEVEN D , DUBEY RAJESH , MERKEL DANIEL C
IPC分类号： C07C17/087 , C07C21/19 , C09K5/00
CPC分类号： C07C19/10 , C07C17/04 , C07C17/06 , C07C17/087 , C07C17/206 , C07C17/21 , C07C17/25 , C07C21/18 , C07C19/01 , C07C21/073
摘要： Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF 3 CF=CH 2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCI 2 =CCICH 2 CI (which may be purchased or synthesized from 1,2,3- trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CFaCCl=CH2, preferably in a 80-96% selectivity. The CF 3 CCl=CH 2 is preferably converted to CF 3 CFClCH 3 (244-isomer) using a SbCl 5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture Of Cr2O3 and FeCl 3 /C is preferably used as the catalyst to achieve high selectivity to CF 3 CCl=CH 2 (96%). In the second step, SbCl 5 /C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF 3 CFClCH 3 . The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.
摘要翻译：公开了用于生产氟化烯烃的方法，优选适于CF 3 CH 2 CH 2（1234yf）的商业化。优选实施方案中可以使用三个步骤，其中诸如CCI 2 = CCICH 2 Cl（其可以从1,2,3-三氯丙烷购买或合成）被氟化（优选在催化剂存在下在气相中用HF）合成化合物如CFaClCl = CH 2，优选为80-96％的选择性。 CF 3 3 CCl = CH 2 2优选使用以下化合物转化为CF 3 CFClCH 3（244-异构体） SbCl 5作为催化剂，然后将其选择性地转化为1234yf，优选在使用活性炭作为催化剂的气相催化反应中进行。对于第一步，优选使用Cr 2 O 3和FeCl 3/3的混合物作为催化剂，以实现对CF 3 CCl = CH 2 / （96％）。在第二步中，优选使用SbCl 5 / C作为将1233xf转化为244-异构体CF 3 CFClCH 3的选择性催化剂。中间体优选通过蒸馏分离和纯化，并且用于下一步骤而不进一步纯化，优选纯度高于约95％。

3. 发明申请

WO2007079435A2 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 审中-公开
标题翻译：生产氟化有机化合物的方法
公开(公告)号：WO2007079435A2
公开(公告)日：2007-07-12
申请号：PCT/US2007/000064
申请日：2007-01-03
申请人： HONEYWELL INTERNATIONAL INC. , TUNG, Hsueh Sung , MUKHOPADHYAY, Sudip , VAN DER PUY, Michael , MA, Jing Ji , MERKEL, Daniel, C. , BORTZ, Cheryl , LIGHT, Barbara , PHILLIPS, Steven, D. , FLEMING, Kim, M. , FERGUSON, Susan
发明人： TUNG, Hsueh Sung , MUKHOPADHYAY, Sudip , VAN DER PUY, Michael , MA, Jing Ji , MERKEL, Daniel, C. , BORTZ, Cheryl , LIGHT, Barbara , PHILLIPS, Steven, D. , FLEMING, Kim, M. , FERGUSON, Susan
CPC分类号： C07C17/10 , C07C17/00 , C07C17/087 , C07C17/206 , C07C17/25 , C07C17/383 , C07C19/10 , C07C19/01 , C07C19/08 , C07C21/18
摘要： Disclosed is a process for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of Formula (I): C(X)3CF2C(X)3 (I) to at least one compound of Formula (II) CF3CF=CHZ (II) where each X and Z is independently H, F, Cl, I or Br, said process preferably not including any substantial amount of oxygen-containing catalyst in certain embodiments. Preferably Z is H.
摘要翻译：公开了一种制备氟化有机化合物的方法，包括氢氟丙烯，其优选包括将至少一种式（I）化合物：C（X）3CF 2 C（X）3（I）转化为至少一种式（II）化合物CF 3 CF = CHZ（II）其中每个X和Z独立地为H，F，Cl，I或Br，在某些实施方案中，所述方法优选不包括任何显着量的含氧催化剂。 Z优选为

4. 发明申请

WO2007056127A1 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 审中-公开
标题翻译：生产氟化有机化合物的方法
公开(公告)号：WO2007056127A1
公开(公告)日：2007-05-18
申请号：PCT/US2006/042935
申请日：2006-11-03
申请人： HONEYWELL INTERNATIONAL INC. , MUKHOPADHYAY, Sudip , NAIR, Haridasan , TUNG, Hsueh Sung , VAN DER PUY, Michael , JOHNSON, Robert , MERKEL, Daniel, C.
发明人： MUKHOPADHYAY, Sudip , NAIR, Haridasan , TUNG, Hsueh Sung , VAN DER PUY, Michael , JOHNSON, Robert , MERKEL, Daniel, C.
IPC分类号： C07C17/266 , C07C17/269 , C07C21/18
CPC分类号： C07C21/18 , C07C17/266 , C07C17/269
摘要： Disclosed is a process for the preparation of fluorinated C3 olefins comprising contacting a compound of the Formula (I): C(R 1 a R 2 b R 3 c ), with a compound of Formula (II) C(R 1 a R 2 b R 3 c )C n (R 1 a R 2 b R 3 c ): wherein R 1 a , R 2 b, and R 3 c are independently a hydrogen atom or a halogen selected from the group consisting of fluorine; chlorine, bromine and iodine, provided that the compound of formula (I) has at least three halogen substituents and that said at three halogen substituents comprise at least one fluorine; a, b and c are independently= 0, 1, 2 or 3 and (a+b+c) = 2 or 3; and n is 0 or 1, under conditions effective to produce at least one C3 fluoroolefin.
摘要翻译：公开了一种制备氟化C3烯烃的方法，包括使式（I）的化合物：C（R 1）

5. 发明申请

WO2009052064A3 PROCESSES FOR SYNTHESIS OF FLUORINATED OLEFINS 审中-公开
标题翻译：合成氟化烯烃的方法
公开(公告)号：WO2009052064A3
公开(公告)日：2009-06-11
申请号：PCT/US2008079759
申请日：2008-10-14
申请人： HONEYWELL INT INC , BORTZ CHERYL L , MUKHOPADHYAY SUDIP , LIGHT BARBARA A , CANTLON CHERYL L , JOHNSON ROBERT C
发明人： MUKHOPADHYAY SUDIP , LIGHT BARBARA A , CANTLON CHERYL L , JOHNSON ROBERT C
IPC分类号： C07C17/25 , C07C19/08 , C07C21/18
CPC分类号： C07C17/21 , C07C17/23 , C07C17/25 , C07C21/18 , C07C19/08
摘要： Disclosed is a process for the synthesis of fluorinated olefins, and in particularly preferred embodiments tetrafluorinated olefins having F on an unsaturated, non-terminal carbon, such as 2,3,3,3-tetrafluoropropene. The preferred processes of the present invention in accordance with one embodiment generally comprise: (a) reacting a compound of formula (I) X1X2 (I) with a compound of formula (II) CX1X2X3CX1=CX1X2 (II) to produce a reaction product comprising a compound of formula (III) CF3CHX1CH2X2 (III), and (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound of formula (III) to a compound of formula (IV) CF3CZ=CH2 (IV) wherein X1, X2, and X3 are each independently selected from the group consisting of hydrogen, chlorine, bromine, fluorine and iodine, provided that X1 and X2 in formula (I) are not both hydrogen and Z is Cl, I, Br, or F.
摘要翻译：公开了一种合成氟化烯烃的方法，并且在特别优选的实施方案中，在不饱和非端碳上的F为氟的四氟化烯烃如2,3,3,3-四氟丙烯。根据一个实施方案，本发明的优选方法通常包括：（a）使式（I）化合物与式（II）化合物反应，生成包含式（III）的化合物和（b）使所述式（III）的化合物暴露于有效将所述式（III）的化合物转化为式（IV）的化合物的反应条件：CF 3 CZ = CH 2 ）其中X 1，X 2和X 3各自独立地选自氢，氯，溴，氟和碘，条件是式（I）中的X 1和X 2不都为氢且Z为Cl，I，Br，或F.

6. 发明申请

WO2009026526A1 METHOD FOR PRODUCING FLUORINATED OLEFINS 审中-公开
标题翻译：生产氟化油脂的方法
公开(公告)号：WO2009026526A1
公开(公告)日：2009-02-26
申请号：PCT/US2008/074033
申请日：2008-08-22
申请人： HONEYWELL INTERNATIONAL INC. , PHILLIPS, Steven , FLEMING, Kim , DUBEY, Rajesh , BORTZ, Cheryl , MUKHOPADHYAY, Sudip
发明人： PHILLIPS, Steven , FLEMING, Kim , DUBEY, Rajesh , BORTZ, Cheryl , MUKHOPADHYAY, Sudip
IPC分类号： C07C21/18 , C07C17/25 , C07C17/21 , C07C19/08 , C07C17/087 , C07C19/10 , C07C17/04
CPC分类号： C07C17/38 , C07C17/04 , C07C17/206 , C07C17/21 , C07C17/25 , C07C17/389 , C07C21/18 , C07C19/10 , C07C19/08
摘要： A method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): to at least one compound of formula (II): where X 1 is Cl, Br or I, each X 2 is independently selected from the group consisting of H, Cl, F, Br or I, and n is 0, 1, or 2.
摘要翻译：包括氢氟丙烯的氟化有机化合物的制备方法，其优选包括将至少一种式（I）化合物转化为至少一种式（II）化合物：其中X1是Cl，Br或I，每个X2独立地选自由H，Cl，F，Br或I组成的组，n为0,1或2。

7. 发明申请

WO2007086972A3 DIRECT CONVERSION OF HCFC 225CA/CB MIXTURE TO HFC 245CB AND HFC 1234YF 审中-公开
标题翻译： HCFC 225CA / CB混合物直接转化为HFC 245CB和HFC 1234YF
公开(公告)号：WO2007086972A3
公开(公告)日：2007-10-04
申请号：PCT/US2006042704
申请日：2006-10-31
申请人： HONEYWELL INT INC , NAIR HARIDASAN , MUKHOPADHYAY SUDIP , MICHAEL VAN DER PUY
发明人： NAIR HARIDASAN , MUKHOPADHYAY SUDIP , MICHAEL VAN DER PUY
IPC分类号： C07C17/00 , C07C17/21 , C07C17/23
CPC分类号： C07C17/23 , C07C17/00 , C07C17/21 , C07C21/18 , C07C19/08 , C07C19/10
摘要： Provided are methods for producing hydrofluorocarbons via the selective reduction of a halocarbon blend comprising l,3-dichloro-l,l,2,2,3-pentafluoropropane.
摘要翻译：提供了通过选择性还原包含1,3-二氯-1,2,2,3-五氟丙烷的卤代烃共混物制备氢氟烃的方法。

8. 发明申请

WO2007056148A1 METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUNDS 审中-公开
标题翻译：生产氟化有机化合物的方法
公开(公告)号：WO2007056148A1
公开(公告)日：2007-05-18
申请号：PCT/US2006/042972
申请日：2006-11-03
申请人： HONEYWELL INTERNATIONAL INC. , MUKHOPADHYAY, Sudip , NAIR, Haridasan , VAN DER PUY, Michael , TUNG, Hsueh Sung , MERKEL, Daniel, C. , DUBEY, Rajesh , MA, Jing Ji , LIGHT, Barbara , FLEMING, Kim , BORTZ, Cheryl , UDY, Richard
发明人： MUKHOPADHYAY, Sudip , NAIR, Haridasan , VAN DER PUY, Michael , TUNG, Hsueh Sung , MERKEL, Daniel, C. , DUBEY, Rajesh , MA, Jing Ji , LIGHT, Barbara , FLEMING, Kim , BORTZ, Cheryl , UDY, Richard
IPC分类号： C07C17/20 , C07C17/25 , C07C17/10 , C07C17/02 , C07C21/18 , C07C19/08 , C07C19/10
CPC分类号： C07C17/02 , C07C17/10 , C07C17/206 , C07C17/25 , C07C21/18 , C07C19/08 , C07C19/01 , C07C19/10
摘要： A method for preparing fluorinated organic compounds comprising contacting hydrogen fluoride with at least one compound of formula (I): CX 3 CXYCH 3 where each X is independently Cl, I or Br, and each Y is independently H or F, said contacting step being carried out under conditions effective to produce a compound of formula (II) CF 3 CZCH 2 where Z is Cl, I, Br, or F.
摘要翻译：一种制备含氟有机化合物的方法，包括使氟化氢与至少一种式（I）的化合物：其中每个X独立地是Cl，I或Br 并且每个Y独立地为H或F，所述接触步骤在有效产生式（II）的化合物的条件下进行，其中Z为Cl ，I，Br或F.

9. 发明申请

WO2006063069A3 CATALYTIC CONVERSION OF HYDROFLUOROALKANOL TO HYDROFLUOROALKENE 审中-公开
标题翻译：氢氟烷醇对氢氟酸的催化转化
公开(公告)号：WO2006063069A3
公开(公告)日：2006-08-17
申请号：PCT/US2005044298
申请日：2005-12-09
申请人： HONEYWELL INT INC , MUKHOPADHYAY SUDIP , NAIR HARIDASAN K , TUNG HSUEHSUNG
发明人： MUKHOPADHYAY SUDIP , NAIR HARIDASAN K , TUNG HSUEHSUNG
IPC分类号： C07C17/00 , C07C21/18
CPC分类号： C07C17/00 , C07C17/25 , C07C21/18
摘要： Methane is used as the selective dehydrating agent for the production of 2,3,3,3-tetrafluoro-l-propene (R1234yf) from 2,2,3,3,3-pentafluoro-l-propanol. Supported transition metal catalysts are prepared and used for this reaction with high activity. Almost 58% selectivity to R1234yf is obtained at an alcohol conversion level of 60% using unsupported Ni-mesh as the catalyst. Pd and Pt show almost similar level of conversion; however, the selectivity to the desired product is low. The activity of the metal catalyst was found to be a function of the type of support material, activated carbon showing better activity than alumina. Different important process parameters such as temperature, pressure, and contact time are studied to optimize the process. High pressure and temperature are deleterious to the rate of 1234yf formation; yet, the highest yield to 1234yf is obtained while performing a reaction at 494°C with a contact time of 23 sec.
摘要翻译：甲烷被用作从2,2,3,3,3-五氟-1-丙醇制备2,3,3,3-四氟-1-丙烯（R1234yf）的选择性脱水剂。制备负载型过渡金属催化剂，并以高活性用于该反应。使用未负载的Ni-网作为催化剂，在60％的醇转化率下获得对R1234yf几乎58％的选择性。 Pd和Pt显示几乎相似的转化水平; 然而，对所需产物的选择性低。发现金属催化剂的活性是支撑材料的类型的函数，活性炭表现出比氧化铝更好的活性。研究了不同的重要工艺参数，如温度，压力和接触时间，以优化工艺。高压和高温对于1234yf的形成是有害的; 而在494℃下以23秒的接触时间进行反应，得到最高的1234yf产率。

10. 发明申请

WO2005009927A2 PROCESS FOR PRODUCTION OF ACETYL ANHYDRIDES AND OPTIONALLY ACETIC ACID FROM METHANE AND CARBON DIOXIDE 审中-公开
标题翻译：从甲烷和二氧化碳生产乙酰丙酸和乙酸的方法
公开(公告)号：WO2005009927A2
公开(公告)日：2005-02-03
申请号：PCT/US2004/023681
申请日：2004-07-23
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , BP CHEMICALS LIMITED , BELL, Alexis T. , MUKHOPADHYAY, Sudip , ZERELLA, Mark , SUNLEY, John Glenn , GAEMERS, Sander , MUSKETT, Michael James
发明人： BELL, Alexis T. , MUKHOPADHYAY, Sudip , ZERELLA, Mark , SUNLEY, John Glenn , GAEMERS, Sander , MUSKETT, Michael James
IPC分类号： C07C
CPC分类号： C07C309/00 , C07C51/56 , C07C67/08 , C07C381/00 , C07C53/18 , C07C69/14
摘要： Acetyl anhydrides such as acetyl sulfate are produced by a process for comprising contacting methane and carbon dioxide in an anhydrous environment in the presence of effective amounts of a transition metal catalyst and a reaction promoter, and an acid anhydride compound, and optionally an acid. The acetyl anhydride can be contacted with water to produce acetic acid or with an alcohol to produce a product comprising an acetate ester and that may also comprise acetic acid. Optionally, water in stoichiometric amounts or less, with respect to the acetic anhydride, may be fed to a continuous process of this type to produce some acetic acid in situ.
摘要翻译：通过包括在有效量的过渡金属催化剂和反应促进剂以及酸酐化合物和任选的酸的存在下，在无水环境中使甲烷和二氧化碳接触的方法制备乙酰基酸酐。乙酸酐可以与水接触以产生乙酸或与醇反应生成包含乙酸酯的产物，并且还可以包含乙酸。任选地，相对于乙酸酐的化学计量或更少的水可以进料到这种类型的连续方法中以原位产生一些乙酸。

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