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1. 发明专利

JPS5740507A Peroxide mixture composition 失效
标题翻译：过氧化物混合物组合物
公开(公告)号：JPS5740507A
公开(公告)日：1982-03-06
申请号：JP11594980
申请日：1980-08-25
申请人： Kayaku Nuurii Kk
发明人： HIRAI YASUO , SAKAGUCHI SHINICHI , OHARA TERUMICHI , YANAGI SHIYOUICHI
IPC分类号： C08F4/00 , C08F4/28 , C08F4/38 , C08F283/01 , C08F299/00 , C08F299/04
摘要： PURPOSE: An alcohol is added to a mixture of a ketone peroxide and benzoyl peroxide as a stabilizer to improve the storage stability of the titled mixture used as a curing agent for unsaturated polyester resins.
CONSTITUTION: An alcohol as a stabilizer, is added to a mixture of a ketone peroxide such as methyl ethyl ketone peroxide and benzoyl peroxide, e.g., at a rate of 99/1W1/99, preferably 10W80wt%. The preferable alcohol is, e.g., ethanol or polyethylene glycol.
EFFECT: The reduction in active oxygen is inhibited and the gas formation is reduced, too.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：向过氧化酮和过氧化苯甲酰的混合物中加入醇作为稳定剂，以提高用作不饱和聚酯树脂的固化剂的标题混合物的储存稳定性。构成：将醇作为稳定剂，例如以99 / 1-1 / 99，优选10-80wt％的速率加入到酮过氧化物如过氧化甲乙酮和过氧化苯甲酰的混合物中。优选的醇是例如乙醇或聚乙二醇。效果：活性氧的还原被抑制，气体形成也减少。

2. 发明专利

JPS61100559A Ketone peroxide composition 失效
标题翻译：酮过氧化物组合物
公开(公告)号：JPS61100559A
公开(公告)日：1986-05-19
申请号：JP22062584
申请日：1984-10-22
申请人： Kayaku Nuurii Kk
发明人： MURATA OSAMU , KURODA SHINICHI , HIRAI YASUO
IPC分类号： C08F4/00 , C07C67/00 , C07C407/00 , C07C409/20 , C08F4/28 , C08F4/34 , C08J3/24 , C08K5/00 , C08K5/14
摘要： PURPOSE: To produce the titled composition capable of curing a gelcoat rapidly, and useful as a curing agent for the cold-forming of a fiber-reinforced plastic composition, by compounding a specific solvent in addition to the plasticizer used for the safety of ketone peroxide.
CONSTITUTION: A ketone peroxide composition compounded with at least one kind of solvent selected from ethyl glycol acetate, butyl glycol acetate, dimethyl glutarate, dimethyl succinate, and dimethyl adipate, and a plasticizer (e.g. dimethyl phthalate). Since the molding operation of an FRP (fiber-reinforced plastic) cannot be carried out before the drying of a gelcoat, a long waiting period is necessary especially in a cold season giving low rate of drying. The waiting period can be shortened by about 30W40% by the addition of said solvent. The ratio of the solvent to the plasticizer is 9/1W3/7, preferably 7/3W5/5.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：为了制备能够快速固化凝胶涂层的标题组合物，并且可用作纤维增强塑料组合物的冷成型用固化剂，除了用于酮过氧化物安全性的增塑剂之外还配合特定溶剂。构成：与至少一种选自乙二醇乙酸酯，丁二醇乙酸酯，戊二酸二甲酯，琥珀酸二甲酯和己二酸二甲酯的溶剂以及增塑剂（例如邻苯二甲酸二甲酯）混合的酮过氧化物组合物。由于在凝胶涂布干燥之前不能进行FRP（纤维增强塑料）的成型操作，因此需要长时间的等待时间，特别是在寒冷季节，干燥速度低。通过加入所述溶剂，等待时间可以缩短约30-40％。溶剂与增塑剂的比例为9 / 1-3 / 7，优选为7 / 3-5 / 5。

3. 发明专利

JPS6187659A Aqueous suspension containing organic peroxide 失效
标题翻译：含有机有机过氧化物的水性悬浮液
公开(公告)号：JPS6187659A
公开(公告)日：1986-05-06
申请号：JP20992084
申请日：1984-10-08
申请人： Kayaku Nuurii Kk
发明人： YANAKA TAKUMI , TAKEMOTO HIDEKI , HIRAI YASUO
IPC分类号： C07C407/00 , C07C67/00 , C07C409/00 , C07C178/00 , C07C179/00
摘要： PURPOSE: To obtain an aqueous suspension containing an organic peroxide, useful as a polymerization initiator of polystyrene, etc., and transport able with a pump without causing clogging, by using tribasic calcium phosphate as an active component.
CONSTITUTION: An aqueous suspension containing an organic peroxide is prepared by compounding tribasic calcium phosphate. The liquid can be prepared e.g. by adding a necessary amount of tribasic calcium phosphate to a definite amount of water, dispersing under stirring, optionally adding and dispersing a dispersion stabilizing assistant in the dispersion, adding a required amount of powder (benzoyl peroxide) moistened with water, and stirring the mixture. Even if a partial phase-separation takes place in the above suspension, the suspension can be homogenized easily by the light shaking or stirring, to enable the approach to the practical adoption of the automatic charging system with a pump. In the conventional process, the charge of the peroxide has to be carried out through a manhole and accordingly the operation of a polymerization plant in closed system has been impossible. The present process clears the way for the operation of the plant in closed system.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过使用磷酸三钙作为活性成分，得到含有有机过氧化物的水性悬浮液，其可用作聚苯乙烯等的聚合引发剂，并可通过泵输送而不引起堵塞。构成：含有有机过氧化物的含水悬浮液通过配合磷酸三钙制备。液体可以例如制备。通过向一定量的水中加入必要量的磷酸三钙，在搅拌下分散，任选地在分散体中加入和分散分散体稳定助剂，加入所需量的用水润湿的粉末（过氧化苯甲酰），并搅拌混合物。即使在上述悬浮液中发生部分相分离，也可以通过轻摇或搅拌容易地使悬浮液均质化，从而能够实现采用泵的自动计费系统。在常规方法中，过氧化物的电荷必须通过人孔进行，因此聚合装置在封闭系统中的操作是不可能的。本程序清除了封闭系统中工厂运行的方式。

4. 发明专利

JPS5918758A Method for crosslinking silicone rubber 失效
标题翻译：交联硅橡胶的方法
公开(公告)号：JPS5918758A
公开(公告)日：1984-01-31
申请号：JP12573782
申请日：1982-07-21
申请人： Kayaku Nuurii Kk
发明人： OHARA HIROMICHI , YANAGI SHIYOUICHI , HIRAI YASUO
IPC分类号： C08L83/00 , C08F4/32 , C08K5/14 , C08L83/04 , C08L83/07 , C08L83/08
摘要： PURPOSE: To obtain a crosslinked composition, crosslinkable with hot air at a low crosslinking temperature and a high crosslinking rate without causing blooming even in the absence of the secondary crosslinking treatment, by using bis(o-methylbenzoyl) peroxide as a crosslinking agent.
CONSTITUTION: A silicone rubber is crosslinked by using bis(o-methylbenzoyl) peroxide as a crosslinking agent therefor at 90W150°C. The above-mentioned peroxide may be formed into a paste with a phthalic acid ester for ensuring the safety and finely dividing into particles. The amount of the peroxide is about 0.5W10mmol, preferably 1W10mmol, based on 100g silicone rubber.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过使用双（邻甲基苯甲酰基）过氧化物作为交联剂，得到交联组合物，可在低交联温度和高交联速率下与热空气交联而不引起起霜，即使不进行二次交联处理。构成：通过在90-150℃下使用双（邻甲基苯甲酰基）过氧化物作为交联剂将硅橡胶交联。上述过氧化物可以与邻苯二甲酸酯形成糊状物，以确保安全性并将其细分成颗粒。基于100g硅橡胶，过氧化物的量为约0.5-10mmol，优选1-10mmol。

5. 发明专利

JPS597458A Peroxide composition for forming casting sand 失效
标题翻译：用于成型铸铁的过氧化物组合物
公开(公告)号：JPS597458A
公开(公告)日：1984-01-14
申请号：JP11612982
申请日：1982-07-06
申请人： Kayaku Nuurii Kk
发明人： YANAGI SHIYOUICHI , OHARA TERUMICHI , HIRAI YASUO
IPC分类号： B22C1/02 , B22C1/20 , B22C1/22
CPC分类号： B22C1/20
摘要： PURPOSE:To provide a peroxide compsn. for forming molding sand having improved curing efficiency, by incorporating a diluent having a specific ester structure in ketone peroxide or hydroperoxide. CONSTITUTION:A peroxide compsn. for forming molding sand is formed by incorporating the ester structure compd. such as octyl oleate, etc. or the like expressed by the formula I (X is an alkyl group, alkenyl group, etc. of 1-20C atoms, R1 is an alkyl group, alkinyl group, etc. of 3-60C atoms), the compd. such as ethylene glycol diacetate or the like expressed by the formula II (Y is an alkylene group, alkenylene group, etc. of 2-20C atoms), and compds. of >=1 kinds from glycerol esters or phsophorus esters expressed by the formula III in a ketone peroxide or hydroperoxide compsn. for forming molding sand. The pot life of the mixture of the molding sand is prolonged by using such compsn. and the compressive strength of the molding of the molding sand is increased.
摘要翻译：目的：提供一种过氧化物。通过在酮过氧化物或氢过氧化物中加入具有特定酯结构的稀释剂来形成具有改善的固化效率的型砂。构成：过氧化物。用于形成型砂通过掺入酯结构体形成。例如由式I表示的油酸辛酯等（X为1-20C原子的烷基，烯基等，R 1为3-60个碳原子的烷基，炔基等），compd。例如由式II表示的乙二醇二乙酸酯等（Y为2-20C原子的亚烷基，亚链烯基等），以及其组合。在酮过氧化物或氢过氧化物组合物中，由式III表示的甘油酯或phophorus酯为> 1种。用于形成型砂。通过使用这种组合来延长型砂混合物的适用期。并且模型砂的压缩强度增加。

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