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    • 1. 发明授权
    • Insecticides
    • 杀虫剂
    • US5276205A
    • 1994-01-04
    • US350197
    • 1989-05-11
    • Karl J. Fisher
    • Karl J. Fisher
    • A01N31/14C07C43/295C07C45/68C07C49/255C07C43/225C07C43/23
    • C07C49/255A01N31/14C07C43/295C07C45/68C07C2101/02
    • Novel insecticides have the formula ##STR1## in which R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.5 carboalkoxy, C.sub.2 -C.sub.5 alkylcarbonyl, nitro or cyano;R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkylthio, C.sub.3 haloalkenoxy, nitro, cyano, C.sub.2 -C.sub.5 alkylcarbonyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 carboalkoxy;R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.4 haloalkyl or C.sub.1 -C.sub.4 alkoxy;provided that:R.sub.1, R.sub.2 and R.sub.3 are not all hydrogen; orR.sub.1 and R.sub.2 taken together are C.sub.2 -C.sub.4 alkylene, C.sub.2 -C.sub.4 alkyleneoxy, C.sub.1 -C.sub.2 perhaloalkyleneoxy, C.sub.1 -C.sub.4 alkylenedioxy or halo-C.sub.1 -C.sub.3 alkylenedioxy;R.sub.4 is methyl, ethyl, n-propyl, C.sub.3 -C.sub.5 branched alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.2 -C.sub.4 haloalkenyl or cyclopropyl optionally substituted by up to 4 methyl groups or up to 2 halogens;R.sub.5 is hydrogen or halogen; andR.sub.6 is hydrogen or mono- or poly-halogen.
    • 新型杀虫剂具有其中R 1为氢,卤素,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4烷氧基,C 1 -C 4烷硫基,C 1 -C 4卤代烷氧基,C 1 -C 4卤代烷硫基,C 2 -C 5烷氧羰基 ,C 2 -C 5烷基羰基,硝基或氰基; R2是氢,卤素,C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷硫基,C1-C4卤代烷硫基,C3卤代烯氧基,硝基,氰基,C2-C5烷基羰基,C1- C4烷基磺酰基或C2-C5烷氧羰基; R3是氢,卤素,C1-C4卤代烷基或C1-C4烷氧基; 条件是:R1,R2和R3不都是氢; 或R 1和R 2一起是C 2 -C 4亚烷基,C 2 -C 4亚烷基氧基,C 1 -C 2全卤代亚烷基氧基,C 1 -C 4亚烷基二氧基或卤代-C 1 -C 3亚烷基二氧基; R4是甲基,乙基,正丙基,C 3 -C 5支链烷基,C 1 -C 4卤代烷基,C 2 -C 4烯基,C 2 -C 4卤代烯基或任选被至多4个甲基或至多2个卤素取代的环丙基; R5是氢或卤素; 且R6为氢或单 - 或多 - 卤素。
    • 2. 发明授权
    • Certain imidate insecticides
    • 某些亚胺类杀虫剂
    • US5089623A
    • 1992-02-18
    • US480686
    • 1990-02-15
    • Karl J. Fisher
    • Karl J. Fisher
    • A01N37/52A01N43/08A01N43/40A01N53/00C07C255/61C07D317/66
    • A01N53/00A01N37/52A01N43/08A01N43/40C07C255/61C07D317/66
    • A series of novel imidate insecticides distinguished by the general formula ##STR1## in which R.sub.1 is an optionally substituted aryl group in which the substituents are halo, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.3 -C.sub.6 cycloalkyl, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.5 carboalkoxy, C.sub.1 -C.sub.4 alkylthio, cyano, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 haloalkylsulfonyl; C.sub.2 -C.sub.5 alkylcarbonyl, C.sub.2 -C.sub.4 alkyleneoxy, C.sub.1 -C.sub.4 alkylenedioxy, C.sub.1 -C.sub.3 halo-substituted alkylenedioxy, phenyl, mono-substituted phenyl, pyridyloxy, C.sub.2 -C.sub.4 alkylene, C.sub.2 -C.sub.4 alkenyl, and/or amido;R.sub.2 is C.sub.1 -C.sub.7 alkyl, C.sub.1 -C.sub.6 haloalkyl, cyclopropyl, cyclobutyl, mono- or poly- halo- or methyl-substituted cyclopropyl, cyano, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.2 -C.sub.6 haloalkenyl or C.sub.2 -C.sub.6 alkenyl; andR.sub.3 is (a) an optionally substituted 3-phenoxyphenalkyl, 3-phenoxypyridylalkyl, 3-(pyridyloxy)phenalkyl, 3-phenylaminophenalkyl, 3-benzylphenalkyl or benzyloxyphenalkyl moiety; (b) a benzylfuranylmethyl moiety; (c) a 3- or 4-substituted benzyl or tetrafluorobenzyl moiety; (d) 4-phenoxy-2-butyn-2-yl; (e) 2-methyl-3-phenylbenzyl, or (f) 4-(4-trifluoromethyl-2-pyridyloxy)benzyl.
    • 一系列新颖的酰亚胺类杀虫剂,其特征在于通式(I)其中R 1是任选取代的芳基,其中取代基是卤素,C 1 -C 4烷基,C 1 -C 4卤代烷氧基,C 1 -C 4烷氧基, C4卤代烷硫基,C3-C6环烷基,硝基,C1-C4卤代烷基,C2-C5烷氧羰基,C1-C4烷硫基,氰基,C1-C4烷基磺酰基,C1-C4卤代烷基磺酰基; C 2 -C 5烷基羰基,C 2 -C 4亚烷基氧基,C 1 -C 4亚烷基二氧基,C 1 -C 3卤素取代的亚烷基二氧基,苯基,单取代的苯基,吡啶氧基,C 2 -C 4亚烷基,C 2 -C 4烯基和/或酰胺基。 R 2是C 1 -C 7烷基,C 1 -C 6卤代烷基,环丙基,环丁基,单 - 或多 - 卤代或甲基取代的环丙基,氰基,C 2 -C 4烷氧基烷基,C 2 -C 6卤代链烯基或C 2 -C 6烯基; 并且R 3是(a)任选取代的3-苯氧基苯基烷基,3-苯氧基吡啶基烷基,3-(吡啶基氧基)苯基烷基,3-苯基氨基苯基烷基,3-苄基苯基烷基或苄氧基苯基烷基部分; (b)苄基呋喃甲基部分; (c)3-或4-取代的苄基或四氟苄基部分; (d)4-苯氧基-2-丁炔-2-基; (e)2-甲基-3-苯基苄基或(f)4-(4-三氟甲基-2-吡啶氧基)苄基。
    • 3. 发明授权
    • Novel ketenimines as intermediates for insecticides
    • 新型烯酮亚胺作为杀虫剂的中间体
    • US5070210A
    • 1991-12-03
    • US520292
    • 1990-05-07
    • Michael D. BroadhurstThomas H. CormartieKarl J. FisherWilliam G. HaagDavid B. KanneMichael R. Leadbetter
    • Michael D. BroadhurstThomas H. CormartieKarl J. FisherWilliam G. HaagDavid B. KanneMichael R. Leadbetter
    • A01N37/52A01N43/08A01N43/40A01N53/00C07C255/61C07D317/66
    • C07D317/66A01N37/52A01N43/08A01N43/40A01N53/00C07C255/61
    • A series of novel imidate insecticides distinguished by the general formula ##STR1## in which R.sub.1 is an optionally substituted aryl group in which the substituents are halo, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.3 -C.sub.6 cycloalkyl, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.5 carboalkoxy, C.sub.1 -C.sub.4 alkylthio, cyano, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 haloalkylsulfonyl; C.sub.2 -C.sub.5 alkylcarbonyl, C.sub.2 -C.sub.4 alkyleneoxy, C.sub.1 -C.sub.4 alkylenedioxy, C.sub.1 -C.sub.3 halo-substituted alkylenedioxy, phenyl, mono-substituted phenyl, pyridyloxy, C.sub.2 -C.sub.4 alkylene, C.sub.2 -C.sub.4 alkenyl, and/or amido;R.sub.2 is C.sub.1 -C.sub.7 alkyl, C.sub.1 -C.sub.6 haloalkyl, cyclopropyl, cyclobutyl, mono- or poly- halo- or methyl-substituted cyclopropyl, cyano, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.2 -C.sub.6 haloalkenyl or C.sub.2 -C.sub.6 alkenyl; andR.sub.3 is (a) an optionally substituted 3-phenoxyphenalkyl, 3-phenoxypyridylalkyl, 3-(pyridyloxy)phenalkyl, 3-phenylaminophenalkyl, 3-benzylphenalkyl or benzyloxyphenalkyl moiety; (b) a benzylfuranylmethyl moiety; (c) a 3- or 4-substituted benzyl or tetrafluorobenzyl moiety; (d) 4-phenoxy-2-butyn-2-yl; (e) 2-methyl-3-phenylbenzyl, or (f) 4-(4-trifluoromethyl-2-pyridyloxy)benzyl.
    • 一系列新颖的酰亚胺类杀虫剂,其特征在于通式(I)其中R 1是任选取代的芳基,其中取代基是卤素,C 1 -C 4烷基,C 1 -C 4卤代烷氧基,C 1 -C 4烷氧基, C4卤代烷硫基,C3-C6环烷基,硝基,C1-C4卤代烷基,C2-C5烷氧羰基,C1-C4烷硫基,氰基,C1-C4烷基磺酰基,C1-C4卤代烷基磺酰基; C 2 -C 5烷基羰基,C 2 -C 4亚烷基氧基,C 1 -C 4亚烷基二氧基,C 1 -C 3卤素取代的亚烷基二氧基,苯基,单取代的苯基,吡啶氧基,C 2 -C 4亚烷基,C 2 -C 4烯基和/或酰胺基。 R 2是C 1 -C 7烷基,C 1 -C 6卤代烷基,环丙基,环丁基,单 - 或多 - 卤代或甲基取代的环丙基,氰基,C 2 -C 4烷氧基烷基,C 2 -C 6卤代链烯基或C 2 -C 6烯基; 并且R 3是(a)任选取代的3-苯氧基苯基烷基,3-苯氧基吡啶基烷基,3-(吡啶基氧基)苯基烷基,3-苯基氨基苯基烷基,3-苄基苯基烷基或苄氧基苯基烷基部分; (b)苄基呋喃甲基部分; (c)3-或4-取代的苄基或四氟苄基部分; (d)4-苯氧基-2-丁炔-2-基; (e)2-甲基-3-苯基苄基或(f)4-(4-三氟甲基-2-吡啶氧基)苄基。
    • 8. 发明授权
    • Novel imidate insecticides
    • 新型酰亚胺类杀虫剂
    • US4994488A
    • 1991-02-19
    • US343550
    • 1989-04-27
    • Michael D. BroadhurstKarl J. FisherWilliam G. HaagMichael R. Leadbetter
    • Michael D. BroadhurstKarl J. FisherWilliam G. HaagMichael R. Leadbetter
    • A01N37/52A01N43/08A01N43/40A01N53/00A01N53/02C07C255/61C07D317/66
    • A01N43/08A01N37/52A01N43/40A01N53/00C07C255/61C07D317/66
    • A series of novel imidate insecticides distinguished by the general formula ##STR1## in which R.sub.1 is an optionally substituted aryl group in which the substituents are halo, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.3 -C.sub.6 cycloalkyl, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.5 carboalkoxy, C.sub.1 -C.sub.4 alkylthio, cyano, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 haloalkylsulfonyl, C.sub.2 -C.sub.5 alkylcarbonyl, C.sub.2 -C.sub.4 alkyleneoxy, C.sub.1 -C.sub.2 perhaloalkyleneoxy, C.sub.1 -C.sub.4 alkylenedioxy, C.sub.1 -C.sub.3 halo-substituted alkylenedioxy, phenyl, mono-substituted phenyl, pyridyloxy, C.sub.2 -C.sub.4 alkylene, C.sub.2 -C.sub.4 alkenyl, C.sub.3 -haloalkenoxy, and/or amido;R.sub.2 is cyclopropyl or mono- or poly- halo- or methyl-substituted cyclopropyl; andR.sub.3 is (a) an optionally substituted 3-phenoxyphenalkyl, 3-phenoxypyridylalkyl, 3-(pyridyloxy)phenalkyl moiety; 3-phenylaminophenalkyl, 3-benzylphenalkyl or benzyloxyphenalkyl moiety; (b) a benzylfuranylmethyl moiety; (c) a 3- or 4-substituted benzyl or tetrafluorobenzyl moiety; (d) 4-phenoxy-2-butyn-2-yl; (e) 2-methyl-3-phenylbenzyl, or (f) 4-(4-trifluoromethyl-2-pyridyloxy)benzyl.
    • 一系列新颖的酰亚胺类杀虫剂,其特征在于通式(I)其中R 1是任选取代的芳基,其中取代基是卤素,C 1 -C 4烷基,C 1 -C 4卤代烷氧基,C 1 -C 4烷氧基, C4卤代烷硫基,C3-C6环烷基,硝基,C1-C4卤代烷基,C2-C5烷氧羰基,C1-C4烷硫基,氰基,C1-C4烷基磺酰基,C1-C4卤代烷基磺酰基,C2-C5烷基羰基,C2-C4亚烷基氧基,C1-C2 全卤代亚烷基氧基,C 1 -C 4亚烷基二氧基,C 1 -C 3卤代取代的亚烷基二氧基,苯基,单取代的苯基,吡啶氧基,C 2 -C 4亚烷基,C 2 -C 4烯基,C 3-卤代烯氧基和/或酰氨基; R 2是环丙基或单 - 或多 - 卤代或甲基取代的环丙基; 并且R 3是(a)任选取代的3-苯氧基苯基烷基,3-苯氧基吡啶基烷基,3-(吡啶氧基)苯烷基部分; 3-苯基氨基苯基烷基,3-苄基苯基烷基或苄氧基苯基烷基部分; (b)苄基呋喃甲基部分; (c)3-或4-取代的苄基或四氟苄基部分; (d)4-苯氧基-2-丁炔-2-基; (e)2-甲基-3-苯基苄基或(f)4-(4-三氟甲基-2-吡啶氧基)苄基。