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1. 发明授权

US07196240B2 Method and equipment for making polychlorobiphenyl nontoxic 失效
标题翻译：制备聚氯联苯无毒的方法和设备
公开(公告)号：US07196240B2
公开(公告)日：2007-03-27
申请号：US10487608
申请日：2003-11-13
申请人： Hirofusa Shirai , Mutsumi Kimura , Kenji Hanabusa , Kunihiro Hamada , Toshihiro Hirai
发明人： Hirofusa Shirai , Mutsumi Kimura , Kenji Hanabusa , Kunihiro Hamada , Toshihiro Hirai
IPC分类号： A62D3/00 , B09B3/00 , F23J15/00
CPC分类号： F23L7/00 , A62D3/38 , A62D2101/22 , A62D2203/02 , B01D53/70 , B01D2257/2064 , F23G5/12 , F23G5/16 , F23G7/065 , F23J15/04 , F23J2215/301 , F23L2900/07004 , F23M9/06 , Y02E20/344 , Y10S588/90
摘要： Methods and equipment are provided for making polybichlorophenyl non-toxic. Methods include a first oxidation step, in which polybichlorophenyl is burned, and a second oxidation step, in which exhaust gas from the first oxidation step is oxidized by contact with metallic phthalocyanines or metallic phthalocyanine derivatives and with an oxygen supply compound. Equipment includes a first furnace for burning a polybichlorophenyl-containing oil with an auxiliary fuel and a second oxidation reaction unit. The second oxidation reaction unit connects to the first furnace under seal, and includes metallic phthalocyanine or metallic phthalocyanine derivative solution supply source and an oxygen supply compound supply source.
摘要翻译：提供了制备聚二氯苯基无毒的方法和设备。方法包括其中燃烧聚二氯苯基的第一氧化步骤和第二氧化步骤，其中来自第一氧化步骤的废气通过与金属酞菁或金属酞菁衍生物和供氧化合物接触而被氧化。设备包括用辅助燃料和第二氧化反应单元燃烧含聚二氯苯基的油的第一炉。第二氧化反应单元在密封下连接到第一炉，并且包括金属酞菁或金属酞菁衍生物溶液供应源和供氧源供应源。

2. 发明授权

US5618930A Phthalocyanine compound and method for making, nitro-substituted phthalocyanine compound, amino-substituted phthalocyanine compound, phthalocyanine-containing polymer and method for making, catalyst, and optical recording medium 失效
标题翻译：酞菁化合物及其制造方法，硝基取代酞菁化合物，氨基取代酞菁化合物，含酞菁聚合物及其制造方法，催化剂和光记录介质
公开(公告)号：US5618930A
公开(公告)日：1997-04-08
申请号：US609548
申请日：1996-03-01
申请人： Mutsumi Kimura , Hirofusa Shirai , Toshiki Koyama , Kenji Hanabusa , Yuichi Kubota
发明人： Mutsumi Kimura , Hirofusa Shirai , Toshiki Koyama , Kenji Hanabusa , Yuichi Kubota
IPC分类号： C09B47/22 , C09B69/10 , G11B7/248 , C09B47/04
CPC分类号： G11B7/248 , C09B47/22 , C09B69/108 , Y10T428/21
摘要： A novel phthalocyanine compound having improved solubility and high purity and containing a polymerizable vinyl group within its molecule is provided. Intermediates to this phthalocyanine compound also have improved solubility and high purity. Further, with the novel phthalocyanine compound used as a starting monomer, a novel polymer is obtained which has a high content of (metal) phthalocyanine and is easy to control the orientation of phthalocyanine rings. The polymer having improved solubility and high purity is expected of use as functional material such as catalysts and recording material.
摘要翻译：提供了一种具有改善的溶解度和高纯度并在其分子内含有可聚合乙烯基的新型酞菁化合物。该酞菁化合物的中间体也具有改善的溶解性和高纯度。另外，作为起始单体使用新型酞菁化合物，可以得到高分子量（金属）酞菁的容易控制酞菁环取向的新型聚合物。具有改善的溶解度和高纯度的聚合物预期用作功能材料如催化剂和记录材料。

3. 发明申请

US20080108593A1 Allergen Decomposer and Antiallergenic Feathers 审中-公开
标题翻译：过敏原分解剂和抗过敏羽毛
公开(公告)号：US20080108593A1
公开(公告)日：2008-05-08
申请号：US10579059
申请日：2004-03-29
申请人： Hirofusa Shirai , Seigo Higaki , Hisanaga Tsuiki , Yasuji Sugihara
发明人： Hirofusa Shirai , Seigo Higaki , Hisanaga Tsuiki , Yasuji Sugihara
IPC分类号： A61K31/409 , C07D487/22 , C09K3/00
CPC分类号： C07D487/22 , B68G3/08 , D06M13/50 , D06M19/00 , D06M2101/12
摘要： An allergen decomposer which contains as an active ingredient a derivative of metal phthalocyanine represented by the following formula (I) (M is a metal selected among iron, cobalt, manganese, titanium, vanadium, nickel, copper, zinc, molybdenum, tungsten, and osmium).
摘要翻译：作为活性成分含有下述式（I）所示的金属酞菁衍生物的变应原分解剂（M是选自铁，钴，锰，钛，钒，镍，铜，锌，钼，钨和锇）。

4. 发明申请

US20130178508A1 COSMETIC COMPOSITION 审中-公开
标题翻译：化妆品组合物
公开(公告)号：US20130178508A1
公开(公告)日：2013-07-11
申请号：US13822253
申请日：2011-09-29
申请人： Hirofusa Shirai , Tomiko Iwama , Hisanaga Tsuiki
发明人： Hirofusa Shirai , Tomiko Iwama , Hisanaga Tsuiki
IPC分类号： A61K8/58 , A61Q19/08
CPC分类号： A61K8/58 , A61K8/19 , A61K8/494 , A61K2800/58 , A61Q5/02 , A61Q19/00 , A61Q19/007 , A61Q19/08 , A61Q19/10
摘要： A highly moisturizing cosmetic composition having firmness/elasticity-improving effect, wrinkle-improving effect, and texture-improving effect can be provided by blending a metal phthalocyanine derivative or salt thereof in a cosmetic material. For the metal phthalocyanine derivative, iron phthalocyanine tetracarboxylic acid is particularly favorable.
摘要翻译：通过将金属酞菁衍生物或其盐混合在化妆品中可以提供具有坚实/弹性改善效果，皱纹改善效果和质地改善效果的高保湿化妆品组合物。对于金属酞菁衍生物，铁酞菁四羧酸是特别有利的。

5. 发明申请

US20050107652A1 Method and equipment for making polychlorobiphenyl nontoxic 失效
标题翻译：制备聚氯联苯无毒的方法和设备
公开(公告)号：US20050107652A1
公开(公告)日：2005-05-19
申请号：US10487608
申请日：2003-11-13
申请人： Hirofusa Shirai , Mutsumi Kimura , Kenji Hanabusa , Kunihiro Hamada , Toshihiro Hirai
发明人： Hirofusa Shirai , Mutsumi Kimura , Kenji Hanabusa , Kunihiro Hamada , Toshihiro Hirai
IPC分类号： A62D3/38 , A62D101/22 , B01D53/70 , F23G5/12 , F23G5/16 , F23G7/06 , F23J15/04 , F23L7/00 , F23M9/06 , B01J8/04 , A62D3/00 , B01J10/00
CPC分类号： F23L7/00 , A62D3/38 , A62D2101/22 , A62D2203/02 , B01D53/70 , B01D2257/2064 , F23G5/12 , F23G5/16 , F23G7/065 , F23J15/04 , F23J2215/301 , F23L2900/07004 , F23M9/06 , Y02E20/344 , Y10S588/90
摘要： An equipment for making PCB nontoxic comprises: a first burn furnace 10 for burning an oil containing the PCB with auxiliary fuel: a second oxidation reaction unit 12, connecting to the first burn furnace 10 under sealing, comprising a supply source of a solution of metallic phthalocyanine derivatives and a supply source of the solution of the oxygen supply compound.
摘要翻译：一种用于制造PCB无毒的设备包括：用辅助燃料燃烧含有PCB的油的第一燃烧炉10：在密封下连接到第一燃烧炉10的第二氧化反应单元12，包括金属溶液的供应源酞菁衍生物和供氧化合物溶液的供应源。

6. 发明授权

US5922743A Pyridine derivative 失效
标题翻译：吡啶衍生物
公开(公告)号：US5922743A
公开(公告)日：1999-07-13
申请号：US849148
申请日：1997-08-07
申请人： Hirofusa Shirai , Kenji Hanabusa , Yuki Takahashi , Fumio Mizobe , Kazunori Hanada
发明人： Hirofusa Shirai , Kenji Hanabusa , Yuki Takahashi , Fumio Mizobe , Kazunori Hanada
IPC分类号： C07D213/38 , C07D213/40 , C07D213/55 , C07D213/56 , C07D213/02 , A61K31/44
CPC分类号： C07D213/40 , C07D213/38 , C07D213/55 , C07D213/56
摘要： A pyridine derivative represented by the following formula: ##STR1## where R.sup.1 and R.sup.2 are as defined in the specification, or a salt thereof. These compounds directly or indirectly act on neuronal cells in vivo and are effective in the amelioration and curing of nerve disorders due to neuronal degeneration, such as, for example, traumatic symptoms and maladies, disorders induced by drugs such as alcohol and antineoplastic agents, inflammatory disorders, metabolic disorders observed in diabetes, and disorders due to idiopathic degeneration of peripheral nerves. These compounds are also effective for ameliorating and curing symptoms and maladies due to degeneration of central nerves, for example, Alzheimer's disease and cerebrovascular ischemia, Down's syndrome, Parkinson's disease, Huntington's chorea, diseases secondary to cerebral ischemia, cerebral infarction, intracerebral bleeding, head injuries, amnesia, and spinal neuropathy.
摘要翻译： PCT No.PCT / JP95 / 02399 Sec。 371日期1997年8月7日 102（e）日期1997年8月7日PCT 1995年11月27日PCT公布。第WO96 / 16942号公报日期：1996年6月6日由下式表示的吡啶衍生物：其中R1和R2如说明书中所定义，或其盐。这些化合物在体内直接或间接作用于神经元细胞，并且由于神经元变性（例如创伤性症状和疾病），药物如酒精和抗肿瘤剂引起的疾病，炎性反应，有助于改善和治疗神经障碍疾病，糖尿病中观察到的代谢紊乱以及由于周围神经特发性退化引起的疾病。这些化合物对于改善和治疗由于中枢神经变性引起的症状和疾病也是有效的，例如阿尔茨海默病和脑血管缺血，唐氏综合征，帕金森病，亨廷顿舞蹈病，脑缺血继发性疾病，脑梗死，脑内出血，头部损伤，遗忘和脊髓神经病变。

7. 发明授权

US5516900A Phthalocyanine compounds containing either a polymerizable vinyl group, a nitro group, or an amino group 失效
标题翻译：含有可聚合乙烯基，硝基或氨基的酞菁化合物
公开(公告)号：US5516900A
公开(公告)日：1996-05-14
申请号：US305881
申请日：1994-09-14
申请人： Mutsumi Kimura , Hirofusa Shirai , Toshiki Koyama , Kenji Hanabusa , Yuichi Kubota
发明人： Mutsumi Kimura , Hirofusa Shirai , Toshiki Koyama , Kenji Hanabusa , Yuichi Kubota
IPC分类号： C09B47/22 , C09B69/10 , G11B7/248 , C09B47/04
CPC分类号： G11B7/248 , C09B47/22 , C09B69/108 , Y10T428/21
摘要： A novel phthalocyanine compound having improved solubility and high purity and containing a polymerizable vinyl group within its molecule is provided. Intermediates to this phthalocyanine compound also have improved solubility and high purity. Further, with the novel phthalocyanine compound used as a starting monomer, a novel polymer is obtained which has a high content of (metal) phthalocyanine and is easy to control the orientation of phthalocyanine rings. The polymer having improved solubility and high purity is expected of use as functional material such as catalysts and recording material.
摘要翻译：提供了一种具有改善的溶解度和高纯度并在其分子内含有可聚合乙烯基的新型酞菁化合物。该酞菁化合物的中间体也具有改善的溶解性和高纯度。另外，作为起始单体使用新型酞菁化合物，可以得到高分子量（金属）酞菁的容易控制酞菁环取向的新型聚合物。具有改善的溶解度和高纯度的聚合物预期用作功能材料如催化剂和记录材料。

8. 发明授权

US4663084A Electroconductive compositions 失效
标题翻译：导电组合物
公开(公告)号：US4663084A
公开(公告)日：1987-05-05
申请号：US667346
申请日：1984-11-01
申请人： Hirofusa Shirai , Kenji Hanabusa , Mitsutoshi Kitamura , Nobumasa Hojo , Okikazu Hirabaru
发明人： Hirofusa Shirai , Kenji Hanabusa , Mitsutoshi Kitamura , Nobumasa Hojo , Okikazu Hirabaru
IPC分类号： C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3467 , C08L1/00 , C08L27/00 , C08L101/00 , H01B1/12 , H01B1/20 , H01M4/60 , G02B5/20
CPC分类号： C08K5/3467 , C08K5/0091 , H01B1/12 , H01M4/60
摘要： A novel metalo-phthalocyanine or an alkyl ester thereof in which each of two benzene nuclei of the four benzene nuclei condensed in the phthalocyanine ring has a carboxyl or alkoxy carbonyl radical attached thereto is well compatible with an organic polymer and thus provides an electroconductive polymer composition which may be formed into films or suitable articles.
摘要翻译：一种新型金属酞菁或其烷基酯，其中在酞菁环中缩合的四个苯核的两个苯核中的每一个具有与其连接的羧基或烷氧基羰基，与有机聚合物很好地相容，因此提供导电聚合物组合物其可以形成为膜或合适的制品。

9. 发明申请

US20170105920A1 COSMETIC METHOD USING METAL PHTHALOCYANINE DERIVATIVE 审中-公开
公开(公告)号：US20170105920A1
公开(公告)日：2017-04-20
申请号：US15391737
申请日：2016-12-27
申请人： Hirofusa SHIRAI , I'FORET CO., LTD. , DAIWABO NEU CO., LTD. , DAIWABO HOLDINGS CO., LTD.
发明人： Hirofusa SHIRAI , Tomiko IWAMA , Hisanaga TSUIKI
IPC分类号： A61K8/58 , A61Q19/08 , A61Q19/00
CPC分类号： A61K8/58 , A61K8/19 , A61K8/494 , A61K2800/58 , A61Q5/02 , A61Q19/00 , A61Q19/007 , A61Q19/08 , A61Q19/10
摘要： A cosmetic method for providing a moisturizing effect and anti-aging effect to the skin of a subject, includes applying to the skin a cosmetic composition containing a metal phthalocyanine derivative expressed by General Formula [I] below:

10. 发明授权

US5633370A Naphthalocyanine compounds, naphthalocyanine polymers and method for making 失效
标题翻译：萘酞菁化合物，萘酞菁聚合物及其制备方法
公开(公告)号：US5633370A
公开(公告)日：1997-05-27
申请号：US326918
申请日：1994-10-21
申请人： Hirofusa Shirai , Mutsumi Kimura , Yuichi Kubota
发明人： Hirofusa Shirai , Mutsumi Kimura , Yuichi Kubota
IPC分类号： B41M5/26 , C07D487/22 , C08F20/52 , C08F20/60 , C08F220/60 , C09B47/067 , C09B47/22 , C09B47/30 , C09B69/10 , G11B7/244
CPC分类号： C07D487/22 , C08F20/60 , C09B47/0676 , C09B47/22 , C09B47/30 , C09B69/108
摘要： Novel naphthalocyanine compounds are provided including nitro- and amino-substituted naphthalocyanine compounds, and vinyl-containing naphthalocyanine compounds. The compounds have improved solubility and high purity and are expected to find use as photo-functional materials such as dyes. Polymers are obtained using the vinyl-containing naphthalocyanine compounds- The polymers also have improved solubility, high purity, a high naphthalocyanine content and ease of control of the orientation of naphthalocyanine rings and are expected of use as various functional materials.
摘要翻译：提供新的萘酞菁化合物，包括硝基和氨基取代的萘酞菁化合物和含乙烯基萘酞菁化合物。化合物具有改善的溶解度和高纯度，并且预期可用作光功能材料如染料。使用含乙烯基的萘酞菁化合物获得聚合物 - 聚合物还具有改善的溶解度，高纯度，高萘酞菁含量和易于控制萘酞菁环取向的作用，并且预期用作各种功能材料。

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