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1. 发明授权

US07435503B2 Planar membraneless microchannel fuel cell 有权
标题翻译：平面无膜微通道燃料电池
公开(公告)号：US07435503B2
公开(公告)日：2008-10-14
申请号：US11150622
申请日：2005-06-10
申请人： Jamie Lee Cohen , David James Volpe , Daron A. Westly , Alexander Pechenik , Hector D. Abruna
发明人： Jamie Lee Cohen , David James Volpe , Daron A. Westly , Alexander Pechenik , Hector D. Abruna
IPC分类号： H01M8/04
CPC分类号： H01M8/08 , H01M8/006 , H01M8/026 , H01M8/0289 , H01M8/04082 , H01M8/04186 , H01M8/083 , H01M8/086
摘要： A planar microfluidic membraneless flow cell. The design eliminates the need for a mechanical membrane, such as a polyelectrolyte membrane (PEM) in a fuel cell, by providing a flow channel in which laminar flow regimes exist in two fluids flowing in mutual contact to form a “virtual interface” in the flow channel. In the flow cell, diffusion at the interface is the only mode of mass transport between the two fluids. In a fuel cell embodiment, a planar design provides to large contact areas between the two streams, which are fuel and oxidant streams, and between each stream and a respective electrode. In some embodiments, silicon microchannels, of fixed length and variable width and height, have been used to generate power using formic acid as fuel and oxygen as oxidant. Power densities on the order of 180 μW/cm2 have been obtained using this planar design.
摘要翻译：平面微流体无膜流通池。该设计消除了对燃料电池中的机械膜，例如聚电解质膜（PEM）的需要，通过提供流动通道，其中层流状态存在于相互接触的两个流体中以在相互接触中形成“虚拟界面” 流通道。在流动池中，界面处的扩散是两种流体之间唯一的质量传递模式。在燃料电池实施例中，平面设计提供两个流之间的大的接触区域，这两个物流是燃料和氧化剂流，并且在每个流和相应的电极之间。在一些实施例中，具有固定长度和可变宽度和高度的硅微通道已经用于使用甲酸作为燃料和氧气作为氧化剂来产生功率。使用这种平面设计已经获得了大约180μW/ cm 2的功率密度。

2. 发明申请

US20120097832A1 ELECTROSPUN LIGHT-EMITTING FIBERS 有权
标题翻译： ELECTROSPUN发光纤维
公开(公告)号：US20120097832A1
公开(公告)日：2012-04-26
申请号：US13337977
申请日：2011-12-27
申请人： Jose M. Moran-Mirabal , Harold G. Craighead , George G. Malliaras , Hector D. Abruna , Jason D. Slinker
发明人： Jose M. Moran-Mirabal , Harold G. Craighead , George G. Malliaras , Hector D. Abruna , Jason D. Slinker
IPC分类号： G01J1/42 , H01B1/00 , H05B33/14 , D01F9/00 , B82Y30/00
CPC分类号： C09K11/06 , B82Y20/00 , C09K11/02 , C09K2211/1007 , C09K2211/1029 , C09K2211/185 , D01D5/0007 , D01F1/04 , D01F1/06 , G02B6/02033 , G02B6/107
摘要： The invention teaches electrospun light-emitting fibers made from ionic transition metal complexes (‘iTMCs”) such as [Ru(bpy)3]2+(PF6−)2]/PEO mixtures with dimensions in the 10.0 nm to 5.0 micron range and capable of highly localized light emission at low operating voltages such as 3-4 V with turn-on voltages approaching the band-gap limit of the organic semiconductor that may be used as point source light emitters on a chip.
摘要翻译：本发明教导了由离子过渡金属络合物（“iTMC”）例如[Ru（bpy）3] 2+（PF 6 - ）2] / PEO混合物制成的电纺丝发光纤维，其尺寸在10.0nm至5.0微米范围内，能够在诸如3-4V的低工作电压下具有高度局部化的发光，其接通电压接近可用作芯片上的点光源发光体的有机半导体的带隙极限。

3. 发明授权

US08063556B2 Cascaded light emitting devices based on mixed conductor electroluminescence 有权
标题翻译：基于混合导体电致发光的级联发光器件
公开(公告)号：US08063556B2
公开(公告)日：2011-11-22
申请号：US12691905
申请日：2010-01-22
申请人： George G. Malliaras , Kiyotaka Mori , Jason D. Slinker , Daniel A. Bernards , Hector D. Abruna
发明人： George G. Malliaras , Kiyotaka Mori , Jason D. Slinker , Daniel A. Bernards , Hector D. Abruna
IPC分类号： H01J63/02
CPC分类号： H01L51/5032 , H01L27/3209 , H01L51/5203 , H01L51/5271 , H01L51/5278 , H01L2251/564
摘要： A cascaded light emitting device. The cascaded light emitting device includes: a base electrode formed of a base electrode material and electrically coupled to a base voltage lead; a top electrode layer formed of a top electrode material and electrically coupled to a top voltage lead; a number of electroluminescent layers arranged between and electrically coupled to the base electrode and top electrode layer; and at least one middle electrode layer formed of a middle electrode material. Each of the middle electrodes is coupled between two juxtaposed electroluminescent layers. The electroluminescent layers include a mixed conductor that luminesces with a peak wavelength.
摘要翻译：级联发光器件。级联发光器件包括：基极，由基极材料形成并电耦合到基极电压引线; 由顶部电极材料形成并电耦合到顶部电压引线的顶部电极层; 布置在基极和顶电极层之间并电耦合的电致发光层; 以及由中间电极材料形成的至少一个中间电极层。每个中间电极耦合在两个并置的电致发光层之间。电致发光层包括以峰值波长发光的混合导体。

4. 发明申请

US20090072728A1 ELECTROSPUN LIGHT-EMITTING FIBERS 有权
标题翻译： ELECTROSPUN发光纤维
公开(公告)号：US20090072728A1
公开(公告)日：2009-03-19
申请号：US12233340
申请日：2008-09-18
申请人： Jose M. Moran-Mirabal , Harold G. Craighead , George G. Malliaras , Hector D. Abruna , Jason D. Slinker
发明人： Jose M. Moran-Mirabal , Harold G. Craighead , George G. Malliaras , Hector D. Abruna , Jason D. Slinker
IPC分类号： H01J1/62 , B29D11/00
CPC分类号： C09K11/06 , B82Y20/00 , C09K11/02 , C09K2211/1007 , C09K2211/1029 , C09K2211/185 , D01D5/0007 , D01F1/04 , D01F1/06 , G02B6/02033 , G02B6/107
摘要： The invention teaches electrospun light-emitting fibers made from ionic transition metal complexes (“iTMCs”) such as [Ru(bpy)3]2+(PF6.)2]/PEO mixtures with dimensions in the 10.0 nm to 5.0 micron range and capable of highly localized light emission at low operating voltages such as 3-4 V with turn-on voltages approaching the band-gap limit of the organic semiconductor that may be used as point source light emitters on a chip.
摘要翻译：本发明教导了由离子过渡金属络合物（“iTMC”）例如[Ru（bpy）3] 2+（PF 6）2] / PEO混合物制成的电纺丝发光纤维，其尺寸在10.0nm至5.0μm的范围内，能够在诸如3-4V的低工作电压下具有高度局部化的发光，其接通电压接近可用作芯片上的点光源发光体的有机半导体的带隙极限。

5. 发明申请

US20100117518A1 CASCADED LIGHT EMITTING DEVICES BASED ON MIXED CONDUCTOR ELECTROLUMINESCENCE 有权
标题翻译：基于混合导体电致发光器件的发光器件
公开(公告)号：US20100117518A1
公开(公告)日：2010-05-13
申请号：US12691905
申请日：2010-01-22
申请人： George M. Malliaras , Kiyotaka Mori , Jason D. Slinker , Daniel A. Bernards , Hector D. Abruna
发明人： George M. Malliaras , Kiyotaka Mori , Jason D. Slinker , Daniel A. Bernards , Hector D. Abruna
IPC分类号： H01J1/62
CPC分类号： H01L51/5032 , H01L27/3209 , H01L51/5203 , H01L51/5271 , H01L51/5278 , H01L2251/564
摘要： A cascaded light emitting device. The cascaded light emitting device includes: a base electrode formed of a base electrode material and electrically coupled to a base voltage lead; a top electrode layer formed of a top electrode material and electrically coupled to a top voltage lead; a number of electroluminescent layers arranged between and electrically coupled to the base electrode and top electrode layer; and at least one middle electrode layer formed of a middle electrode material. Each of the middle electrodes is coupled between two juxtaposed electroluminescent layers. The electroluminescent layers include a mixed conductor that luminesces with a peak wavelength.
摘要翻译：级联发光器件。级联发光器件包括：基极，由基极材料形成并电耦合到基极电压引线; 由顶部电极材料形成并电耦合到顶部电压引线的顶部电极层; 布置在基极和顶电极层之间并电耦合的电致发光层; 以及由中间电极材料形成的至少一个中间电极层。每个中间电极耦合在两个并置的电致发光层之间。电致发光层包括以峰值波长发光的混合导体。

6. 发明授权

US08106580B2 Electrospun light-emitting fibers 有权
标题翻译： Electrospun发光纤维
公开(公告)号：US08106580B2
公开(公告)日：2012-01-31
申请号：US12233340
申请日：2008-09-18
申请人： Jose M. Moran-Mirabal , Harold G. Craighead , George G. Malliaras , Hector D. Abruna , Jason D. Slinker
发明人： Jose M. Moran-Mirabal , Harold G. Craighead , George G. Malliaras , Hector D. Abruna , Jason D. Slinker
IPC分类号： H05B33/00 , H05B33/04 , H05B33/22
CPC分类号： C09K11/06 , B82Y20/00 , C09K11/02 , C09K2211/1007 , C09K2211/1029 , C09K2211/185 , D01D5/0007 , D01F1/04 , D01F1/06 , G02B6/02033 , G02B6/107
摘要： The invention teaches electrospun light-emitting fibers made from ionic transition metal complexes (“iTMCs”) such as [Ru(bpy)3]2+(PF6.)2]/PEO mixtures with dimensions in the 10.0 nm to 5.0 micron range and capable of highly localized light emission at low operating voltages such as 3-4 V with turn-on voltages approaching the band-gap limit of the organic semiconductor that may be used as point source light emitters on a chip.
摘要翻译：本发明教导了由离子过渡金属络合物（“iTMC”）例如[Ru（bpy）3] 2+（PF 6）2] / PEO混合物制成的电纺丝发光纤维，其尺寸在10.0nm至5.0μm的范围内，能够在诸如3-4V的低工作电压下具有高度局部化的发光，其接通电压接近可用作芯片上的点光源发光体的有机半导体的带隙极限。

7. 发明授权

US07455927B2 Intermetallic compounds for use as catalysts and catalytic systems 失效
标题翻译：用作催化剂和催化体系的金属间化合物
公开(公告)号：US07455927B2
公开(公告)日：2008-11-25
申请号：US10630237
申请日：2003-07-29
申请人： Francis J. DiSalvo, Jr. , Hector D. Abruna
发明人： Francis J. DiSalvo, Jr. , Hector D. Abruna
IPC分类号： H01M4/00
CPC分类号： B01J23/56 , B01J23/60 , B01J23/62 , B01J23/644 , H01M4/8605 , H01M4/921 , H01M8/1004
摘要： The invention is directed to intermetallic compounds for use as catalysts for chemical reactions and catalytic systems. The structure of ordered intermetallic compounds enables such compounds to function as highly efficient catalysts. The ordered intermetallic compounds may be used to catalyze reactions in fuel cells (e.g., hydrogen fuel cells), amongst numerous other applications.
摘要翻译：本发明涉及用作化学反应和催化体系的催化剂的金属间化合物。有序金属间化合物的结构使得这些化合物起到高效催化剂的作用。在许多其它应用中，有序金属间化合物可用于催化燃料电池（例如，氢燃料电池）中的反应。

8. 发明授权

US07755275B2 Cascaded light emitting devices based on mixed conductor electroluminescence 有权
标题翻译：基于混合导体电致发光的级联发光器件
公开(公告)号：US07755275B2
公开(公告)日：2010-07-13
申请号：US11091088
申请日：2005-03-28
申请人： George G. Malliaras , Kiyotaka Mori , Jason D Slinker , Daniel A. Bernards , Hector D. Abruna
发明人： George G. Malliaras , Kiyotaka Mori , Jason D Slinker , Daniel A. Bernards , Hector D. Abruna
IPC分类号： H01J1/63
CPC分类号： H01L51/5032 , H01L27/3209 , H01L51/5203 , H01L51/5271 , H01L51/5278 , H01L2251/564
摘要： A cascaded light emitting device. The cascaded light emitting device includes: a base electrode formed of a base electrode material and electrically coupled to a base voltage lead; a top electrode layer formed of a top electrode material and electrically coupled to a top voltage lead; a number of electroluminescent layers arranged between and electrically coupled to the base electrode and top electrode layer; and at least one middle electrode layer formed of a middle electrode material. Each of the middle electrodes is coupled between two juxtaposed electroluminescent layers. The electroluminescent layers include a mixed conductor that luminesces with a peak wavelength.
摘要翻译：级联发光器件。级联发光器件包括：基极，由基极材料形成，并电耦合到基极电压引线; 由顶部电极材料形成并电耦合到顶部电压引线的顶部电极层; 布置在基极和顶电极层之间并电耦合的电致发光层; 以及由中间电极材料形成的至少一个中间电极层。每个中间电极耦合在两个并置的电致发光层之间。电致发光层包括以峰值波长发光的混合导体。

9. 发明授权

US06224935B1 Ordered arrays via metal-initiated self-assembly of ligand containing dendrimers and bridging ligands 失效
标题翻译：通过金属引发的含有配体的树枝状大分子和桥连配体的自组装的有序阵列
公开(公告)号：US06224935B1
公开(公告)日：2001-05-01
申请号：US09488927
申请日：2000-01-21
申请人： Diego Diaz , Gregory D. Storrier , Kazutake Takada , Stefan Bernhard , Hector D. Abruna
发明人： Diego Diaz , Gregory D. Storrier , Kazutake Takada , Stefan Bernhard , Hector D. Abruna
IPC分类号： B05D512
CPC分类号： B82Y30/00 , B05D1/185 , B05D1/202 , B82Y40/00 , C30B7/00 , C30B29/54
摘要： An ordered film is formed on a surface by reacting (a) dendrimer or bridging ligand functionalized for reaction with transition metal ions (e.g., terpyridyl-pendant poly-amido amine starburst dendrimers or 1,4-bis[4,4″-bis(1,1-dimethylethyl)-2,2′:6′2″ terpyridine-4′-yl]benzene), dissolved in water immiscible solvent, with (b) transition metal ions dissolved in water, on said surface. This method allows formation of films useful, for example, as electron transfer mediators, other electronic devices, catalysts, sensors, and electrochromic devices.
摘要翻译：通过使（a）与过渡金属离子官能化反应的树枝状聚合物或桥接配体（例如，三联吡啶基 - 侧酰胺酰胺胺星爆树枝状聚合物或1,4-双[4,4“ - 双（1,1-二甲基乙基）-2,2'：6'2“三联吡啶-4'-基]苯），溶解在与水不混溶的溶剂中，（b）过渡金属离子溶解在水中。该方法允许形成可用于例如电子转移介质，其它电子器件，催化剂，传感器和电致变色器件的膜。

10. 发明授权

US5185922A Method of making submicrometer microelectrodes 失效
标题翻译：制备亚微米微电极的方法
公开(公告)号：US5185922A
公开(公告)日：1993-02-16
申请号：US568852
申请日：1990-08-17
申请人： Bradford D. Pendley , Hector D. Abruna
发明人： Bradford D. Pendley , Hector D. Abruna
IPC分类号： C03B23/047 , G01N27/30
CPC分类号： C03B23/0473 , G01N27/30 , Y10S65/06 , Y10T29/49117 , Y10T29/49204
摘要： Microelectrodes and methods for making the same are disclosed which have electrode tip diameter of less than 10 .mu.m. The microelectrodes include a tapered electrode wire sealed in, and surrounded by, a tapered insulator tube. In one preferred embodiment, an annealed platinum wire approximately 75 .mu.m in diameter is inserted in an insulator tube, such as a borosilicate pipette, having an inner diameter of approximatley 600 .mu.m. The pipette is heated to the softening temperature of borosilicate and drawn using a conventional pulling technique. As the inner diameter of the pipette draws down, it engages the annealed platinum wire and causes the wire to also draw down in diameter. Careful selection of the relative diameters of the pipette and the platinum wire ensure that the two will break at essentially the same time thereby forming a microelectrode having a platinum disk electrode of less than 10 .mu.m diameter. Other metals, including gold, copper, silver, rhodium, iridium, tungsten and molybdenum can be used for the electrode wire.
摘要翻译：公开了电极尖端直径小于10微米的微电极及其制造方法。微电极包括密封在锥形绝缘管中并被锥形绝缘管包围的锥形电极线。在一个优选实施例中，将直径约75μm的退火铂丝插入绝缘管中，例如硼硅酸盐移液管，内径约为600μm。将移液管加热至硼硅酸盐的软化温度并使用常规的拉伸技术进行拉伸。当吸管的内径下降时，它与退火的铂丝接合并使线也直径下降。仔细选择移液管和铂丝的相对直径确保两者基本上同时断裂，从而形成具有小于10μm直径的铂盘电极的微电极。其他金属，包括金，铜，银，铑，铱，钨和钼可用于电极线。

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