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    • 1. 发明授权
    • 1,2,4-triazolo-[1,5a]pyrimidin-2-yl derivatives
    • 1,2,4-三唑并 - [1,5a]嘧啶-2-基衍生物
    • US5175289A
    • 1992-12-29
    • US706838
    • 1991-05-29
    • Hans-Dieter SchneiderDieter Durr
    • Hans-Dieter SchneiderDieter Durr
    • A01N25/32C07D487/04
    • C07D487/04A01N25/32
    • The present invention relates to the novel use of antidotes of formula I ##STR1## wherein R.sup.1 is C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.6 cycloalkyl, and each of R.sup.2 and R.sup.3, independently of the other, is hydrogen, C.sub.1 -C.sub.3 alkyl, trifluoromethyl or cyclopropyl, with the proviso that only one of the symbols R.sup.2 and R.sup.3 may be hydrogen, for protecting cultivated plants from the phytotoxic action of herbicides. The invention relates also to novel compounds and the preparation thereof and to novel intermediates and the preparation thereof. The invention further relates to herbicidal compositions that contain a combination of herbicide and antidote and to corresponding methods of controlling weeds. Finally, the invention relates also to the seeds of cultivated plants protected by the treatment with the antidote.
    • 本发明涉及式Ⅰ的解毒剂(I)的新用途,其中R 1是C 1 -C 6烷基或C 3 -C 6环烷基,R 2和R 3各自独立地是氢,C 1 -C 3烷基,三氟甲基 或环丙基,条件是符号R2和R3中只有一个可以是氢,以保护栽培植物免受除草剂的植物毒性作用。 本发明还涉及新型化合物及其制备方法以及新型中间体及其制备方法。 本发明还涉及含有除草剂和解毒剂组合的除草组合物以及控制杂草的相应方法。 最后,本发明还涉及通过用解毒剂处理而保护的栽培植物的种子。
    • 3. 发明授权
    • Herbicidal sulfonylureas
    • 除草磺酰脲类
    • US4685961A
    • 1987-08-11
    • US699388
    • 1985-02-07
    • Werner TopflWilly MeyerHans-Dieter Schneider
    • Werner TopflWilly MeyerHans-Dieter Schneider
    • A01N47/36C07D239/42C07D239/46C07D239/48C07D239/52C07D249/08C07D251/52C07D403/12C07D521/00C07D239/69A01N43/54A01N43/707
    • C07D239/42A01N47/36C07D231/12C07D233/56C07D239/47C07D239/48C07D239/52C07D249/08C07D251/52C07D403/12C07D521/00
    • Novel substituted N-sulfonyl-N'-pyrimidinylureas or N-sulfonyl-N'-triazinylureas of the formula I ##STR1## have good pre- and postemergence selective herbicidal and growth regulating properties.In this formula E is nitrogen or --CH.dbd., the group ##STR2## is a phenyl, naphthyl, furyl, thiophenyl, pyrrole or pyridinyl radical which is substituted in accordance with the definitions ofR.sup.1 and R.sup.2,R.sup.3 and R.sup.4 are hydrogen, lower alkyl or lower alkoxy, or one of R.sup.3 and R.sup.4 may also be halogen, lower alkenyl, lower haloalkenyl, lower haloalkoxy, amino, lower alkylamino, --CH(OCH.sub.3).sub.2, a cyclised ketal group or a saturated 5- to 7-membered heterocycle which is bound through the nitrogen atom,R.sup.5 is hydrogen, lower alkyl, lower haloalkyl, or an unsubstituted or substituted phenyl, benzyl or naphthyl radical, andR.sup.6 is an alkyl, acyl or acylamido radical which is bound through sulfur or a sulfinyl or sulfonyl group and is as defined in the description, or is a 5- to 7-membered heterocyclic amino radical which is bound through the nitrogen atom.These compounds are particularly suitable for selectively controlling weeds in crops of cereals.
    • 式I(I)的新型取代的N-磺酰基-N'-嘧啶基或N-磺酰基-N'-三嗪基脲具有良好的芽前和芽后选择性除草和生长调节性质。 在该式中,E是氮或-CH =,根据R1和R2的定义被取代的苯基,萘基,呋喃基,噻吩基,吡咯基或吡啶基,R3和R4是氢,低级 烷基或低级烷氧基,或者R 3和R 4中的一个也可以是卤素,低级链烯基,低级卤代烯基,低级卤代烷氧基,氨基,低级烷基氨基,-CH(OCH 3)2,环化的缩酮基或饱和的5-至7-元 通过氮原子结合的杂环,R5是氢,低级烷基,低级卤代烷基或未取代或取代的苯基,苄基或萘基,R6是通过硫或亚磺酰基结合的烷基,酰基或酰基酰氨基, 磺酰基,如描述中所定义,或是通过氮原子结合的5-至7-元杂环氨基。 这些化合物特别适用于选择性地控制谷物作物中的杂草。
    • 4. 发明授权
    • Guides for mineral mining machines
    • 矿山机械指南
    • US4391471A
    • 1983-07-05
    • US249315
    • 1981-03-31
    • Alois HauschoppHans-Dieter SchneiderChristoph Rassmann
    • Alois HauschoppHans-Dieter SchneiderChristoph Rassmann
    • E21C27/32B65G19/28E21C35/12E21C35/08
    • E21C35/12B65G19/28
    • A guide for mineral winning machines is composed of assemblies secured to the mineral face side of a conveyor. The assemblies have angle plates secured to the side walls of the conveyor pans and structures, integral or otherwise, which provide spacers at least partly defining elongate upper and lower passages for accomodating a drive chain. Covers are detachably and pivotably mounted to the structures to close off the upper passage. The covers are provided with substantial flat upper surfaces which serves to support and guide a machine. An upper guide rail formed by ribs at the edges of the upper surfaces and a lower guide rail formed by webs or web plates on the structures serve to locate with guide means of a plough supported on the inclined walls of the angle plates and driven by the drive chain. Where the flat support surfaces are not needed, or otherwise in case of need, the covers can be removed or replaced by covers of different design. In the latter case the upper guide rail can still be established by the different covers.
    • 矿山机的指南由固定在输送机的矿物面侧的组件组成。 组件具有固定到输送机平台和结构的侧壁的角板,整体或其它,其提供至少部分地限定用于容纳驱动链的细长的上部和下部通道的间隔件。 盖子可拆卸地且可枢转地安装到结构上以封闭上部通道。 盖具有大致平坦的上表面,其用于支撑和引导机器。 在上表面的边缘处由肋形成的上导轨和在结构上由腹板或腹板形成的下导轨用于定位在支撑在角板的倾斜壁上的犁的引导装置,并由 驱动链。 在不需要扁平支撑表面的情况下,或者在需要的情况下,可以通过不同设计的盖子去除或替换盖子。 在后一种情况下,上导轨仍然可以由不同的盖构成。
    • 5. 发明授权
    • Mining installations
    • 采矿设备
    • US3960265A
    • 1976-06-01
    • US541553
    • 1975-01-16
    • Helmut TemmeWerner HageneierHans-Dieter Schneider
    • Helmut TemmeWerner HageneierHans-Dieter Schneider
    • B65G19/28B65G15/60
    • B65G19/28
    • A mining installation has a scraper-chain conveyor for transferring material and which is constructed in known manner from a series of channel sections joined end-to-end. A shifting apparatus serves to bodily displace the conveyor in a longitudinal direction and the connveyor is reinforced by means of L-shaped stiffening members attached to the exteriors of the side walls of the channel sections. These stiffening members or plates are interconnected by means of coupling plates which permit pivotal movement in a vertical plane as well as some free horizontal movement. The upper sides of the stiffening plates extend over the side walls of the channel sections and are provided or formed with webs or the like for the reception and connection of further barrier plates and their supports for example.
    • 采矿设备具有用于转移材料的刮板链式输送机,并且以已知的方式从端对端连接的一系列通道部分构造。 换档装置用于沿纵向方向身体移动输送机,并且通过连接到通道部分的侧壁的外部的L形加强构件来加强连接器。 这些加强构件或板通过联接板相互连接,这些连接板允许在垂直平面中枢转运动以及一些自由的水平运动。 加强板的上侧在通道部分的侧壁上延伸,并且设置或形成有腹板等,用于例如接收和连接另外的阻挡板及其支撑件。
    • 7. 发明授权
    • Process for the preparation of O-substituted hydroxylamines
    • US5075504A
    • 1991-12-24
    • US539751
    • 1990-06-18
    • Hans-Dieter Schneider
    • Hans-Dieter Schneider
    • C07C259/06
    • C07C259/06
    • O-substituted hydroxylamines of the formula IH.sub.2 NOR.sub.1 (I)in whichR.sub.1 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, --CH.sub.2 CR.sub.2 .dbd.CR.sub.3 R.sub.4 or --CH.sub.2 C.tbd.CR.sub.5 ;R.sub.2 is hydrogen, halogen or methyl;R.sub.3 is hydrogen, halogen or methyl;lR.sub.4 is hydrogen, halogen or methyl; andR.sub.5 is hydrogen, methyl or ethyl,R.sub.6 --CN (II)in which R.sub.6 is C.sub.1 -C.sub.4 alkyl, phenyl or benzyl, is reacted with an alcohol of the formula IIIR.sub.7 --OH (III)in which R.sub.7 is C.sub.1 -C.sub.5 alkyl, benzyl or C.sub.1 -C.sub.4 alkoxyethyl, in an organic solvent which is only sparingly miscible with water or not at all, in the presence of hydrogen halide HX, the suspension obtained of the iminoester hydrohalide of the formula IV ##STR1## in which R.sub.6 and R.sub.7 are as defined above and X is chlorine, bromine or iodine, is added at a controlled rate to an aqueous suspension of a carbonate or hydrogen carbonate at a temperature of from -3.degree. to +5.degree. C., an aqueous solution of a hydroxylamine salt is added to the mixture obtained at a temperature of from -20.degree. to -5.degree. C., the aqueous phase is separated off after the mixture has been warmed to room temperature, the solution obtained of the hydroximic acid ester of the formula V ##STR2## in which R.sub.6 and R.sub.7 are as defined above, in an organic solvent is first treated with an aqueous solution of a strong base and then with an alkylating agent of the formula VIY--R.sub.1 (VI)in which R.sub.1 is as defined above and Y is chlorine, bromine, iodine or --O--SO.sub.2 R.sub.8, and R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, phenyl or phenyl-substituted C.sub.1 -C.sub.4 alkyl, it being possible for the phenyl ring itself to be monosubstituted, disubstituted or trisubstituted by halogen or C.sub.1 -C.sub.4 alkyl, and Y is alternatively --OSO.sub.2 OR.sub.1 if R.sub.1 is C.sub.1 -C.sub.2 alkyl, at from room temperature to the boiling point of the reaction mixture, the mixture is cooled to room temperature when the O-alkylation is complete, the aqueous phase is separated off, the oxime ether of the formula VII ##STR3## in which R.sub.1, R.sub.6 and R.sub.7 are as defined above, formed is hydrolysed by stirring with an aqueous solution of a strong acid, and the aqueous phase containing the salt of the O-substituted hydroxylamine of the formula I is separated off, and the hydroxylamine of the formula I is isolated, if necessary, by evaporating the water.
    • 9. 发明授权
    • Conveyor and guide assembly
    • 输送机和导轨组装
    • US4286823A
    • 1981-09-01
    • US127716
    • 1980-03-06
    • Gerhard MertenWolfgang PetersHans-Dieter SchneiderWilly Heyer
    • Gerhard MertenWolfgang PetersHans-Dieter SchneiderWilly Heyer
    • E21C27/32E21C35/12
    • E21C35/12
    • A conveyor and guide assembly comprises a conveyor and a plough guide attached to one side of the conveyor. The conveyor comprises a plurality of conveyor sections joined end-to-end, and the guide comprises a plurality of guide sections positioned end-to-end. Each guide section is associated with, and extends substantially along, a corresponding conveyor section. The guide section has a generally L-shaped guide plate and a ramp-like cover plate which define therebetween upper and lower chain ducts for receiving a plough drive chain. Each section of the cover plate is curved over at the top towards the guide plate thereby delimiting the upper portion of the upper chain duct. Each adjacent pair of cover plate sections overlap in a first zone which extends over at least the curved-over portions thereof. Each pair of adjacent sections of the guide plate overlap in a second zone which adjoins said first zone. The gap between each pair of adjacent guide plate sections is longitudinally off-set from the corresponding gap between adjacent conveyor sections in a third zone which is adjacent to said second zone.
    • 输送机和导向组件包括输送机和连接到输送机一侧的犁引导件。 输送机包括端对端连接的多个输送段,并且导向件包括端对端定位的多个引导部分。 每个引导部分与相应的传送部分相关联并且基本上沿其延伸。 引导部分具有大致L形的引导板和斜面状的盖板,其在其间限定用于接收犁式驱动链的上部和下部链条导管。 盖板的每个部分在顶部朝向导板弯曲,从而限定上链管道的上部。 每个相邻的一对盖板部分在至少在其弯曲部分上延伸的第一区域中重叠。 引导板的每对相邻部分在邻接所述第一区域的第二区域中重叠。 每对相邻引导板部分之间的间隙在邻近所述第二区域的第三区域中相邻的传送部分之间的相应间隙纵向偏移。