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1. 发明授权

US08511113B2 Process for the separation of CO2 from a gaseous feed stream 失效
标题翻译：从气态进料流中分离CO 2的方法
公开(公告)号：US08511113B2
公开(公告)日：2013-08-20
申请号：US12682673
申请日：2008-10-10
申请人： Gerrit Jan Barend Assink , Gert Jan Kramer , Martin Van Sint Annaland , Martin Jan Tuinier
发明人： Gerrit Jan Barend Assink , Gert Jan Kramer , Martin Van Sint Annaland , Martin Jan Tuinier
IPC分类号： F25J1/00 , F25J3/00 , B01D9/04
CPC分类号： B01D7/02 , B01D53/62 , B01D2256/22 , B01D2257/504 , B01D2259/416 , Y02C10/04 , Y02C10/12 , Y02P70/34
摘要： The invention provides a process for the separation of CO2 from a gaseous feed stream, comprising the subsequent steps of: a) cooling a porous body in the form of a fixed bed (101,102,103) to a temperature below the sublimation temperature of CO2 to obtain a cold body; b) contacting a gaseous feed stream (120) comprising CO2 and one or more other gaseous compounds with the surface of the cold body to obtain a body comprising solid CO2 and a CO2-depleted effluent gas (124); and c) removing the solid CO2 by exposing the porous body comprising solid CO2 to a fluid CO2 stream (130) having a temperature above the sublimation temperature of CO2 whereby fluid CO2 (136) and a warm porous body are obtained.
摘要翻译：本发明提供了一种从气态进料流中分离CO 2的方法，其包括以下步骤：a）将固定床（101,102,103）形式的多孔体冷却至低于CO 2升华温度的温度，以获得冷身 b）将包含CO 2和一种或多种其它气态化合物的气态进料流（120）与冷体的表面接触以获得包含固体CO 2和不含CO 2的废气（124）的主体; 和c）通过将包含固体CO 2的多孔体暴露于温度高于CO 2升华温度的流体CO 2流（130），从而获得流体CO 2（136）和温热多孔体，从而去除固体CO 2。

2. 发明授权

US07823570B2 Process for operating a compression ignition internal combustion engine in combination with a catalytic reformer 有权
标题翻译：用于与催化重整器结合操作压燃式内燃机的方法
公开(公告)号：US07823570B2
公开(公告)日：2010-11-02
申请号：US10580942
申请日：2004-12-01
申请人： Roger Francis Cracknell , Gert Jan Kramer , Eric Johannes Vos
发明人： Roger Francis Cracknell , Gert Jan Kramer , Eric Johannes Vos
IPC分类号： F02M25/07 , F02B47/08 , F01N3/20 , B63B38/00 , C01B3/26
CPC分类号： F01N13/011 , C01B3/386 , C01B2203/0261 , C01B2203/0465 , C01B2203/066 , C10L3/00 , F01N3/0814 , F01N3/0842 , F01N2240/30 , F01N2240/32 , F01N2610/03 , F01N2610/08 , F02B1/12 , F02B3/06 , F02B43/10 , F02D19/0642 , F02D19/0671 , F02D19/081 , F02M25/0224 , F02M25/0228 , F02M25/10 , F02M26/35 , F02M26/36 , F02M27/02 , Y02T10/121 , Y02T10/32 , Y02T10/36
摘要： A process for operating a compression ignition internal combustion engine in combination with a catalytic partial oxidation reformer and, optionally, an exhaust gas aftertreater, wherein: (a) a mixture of a first fuel and air, wherein the first fuel comprises Fischer-Tropsch derived fuel, is introduced in the combustion chamber of the engine; (b) exhaust gas is discharged from the engine and optionally partly recirculated to the combustion chamber of the engine; (c) a second fuel and oxygen and/or steam are supplied to the catalytic partial oxidation reformer to produce synthesis gas, wherein the second fuel comprises Fischer-Tropsch derived fuel; (d) at least part of the synthesis gas is supplied to: (i) the exhaust gas aftertreater; (ii) the combustion chamber of the engine; or to both.
摘要翻译：一种用于与催化部分氧化重整器和任选的废气后处理器结合操作压燃式内燃机的方法，其中：（a）第一燃料和空气的混合物，其中所述第一燃料包括费 - 托衍生的燃料被引入发动机的燃烧室; （b）废气从发动机排出并任选地部分再循环到发动机的燃烧室; （c）将第二燃料和氧气和/或蒸汽供应到催化部分氧化重整器以产生合成气，其中第二燃料包括费 - 托衍生的燃料; （d）至少部分合成气被供给到：（i）废气后处理机; （ii）发动机的燃烧室; 或两者兼而有之。

3. 发明申请

US20110177410A1 PROCESS AND REACTOR FOR THE PRODUCTION OF HYDROGEN AND CARBON DIOXIDE AND A FUEL CELL SYSTEM 失效
标题翻译：生产二氧化碳和二氧化碳和燃料电池系统的过程和反应器
公开(公告)号：US20110177410A1
公开(公告)日：2011-07-21
申请号：US12305667
申请日：2007-06-28
申请人： Gerrit Jan Barend Assink , Gert Jan Kramer , Arian Nijmeijer , Martin Van Sint Annaland
发明人： Gerrit Jan Barend Assink , Gert Jan Kramer , Arian Nijmeijer , Martin Van Sint Annaland
IPC分类号： H01M8/06 , C01B31/20 , B01J8/02
CPC分类号： C01B3/501 , B01D63/06 , B01D2315/08 , B01J8/009 , B01J8/18 , C01B3/384 , C01B32/50 , C01B2203/0233 , C01B2203/041 , C01B2203/0475
摘要： The invention relates to a process for the production of hydrogen and carbon dioxide from a hydrocarbonaceous feed-stock, comprising: a) supplying a gaseous hydrocarbonaceous feedstock and steam to a reaction zone comprising a steam reforming catalyst and catalytically reforming the hydrocarbonaceous feedstock to produce a reformed gas comprising hydrogen and carbon dioxide; b) supplying a molecular oxygen-comprising gas to the permeate side of a first hydrogen separation membrane; c) contacting a part of the hydrogen with a first hydrogen separation membrane, allowing the hydrogen to permeate through the first hydrogen separation membrane and combusting the hydrogen with the molecular oxygen at a permeate side of the first hydrogen separation membrane to produce all heat necessary for catalytic reforming the hydrocarbonaceous feedstock; d) contacting the remainder of the hydrogen with a second hydrogen separation membrane, which is separate from the first hydrogen separation membrane, and allowing the hydrogen to permeate through the second hydrogen separation membrane to obtain a first effluent comprising a substantially pure stream of hydrogen; and e) removing a stream rich in carbon dioxide from the reaction zone as a second effluent. The invention further related to a reactor for such process and to a fuel cell system comprising in series such reactor and a fuel cell.
摘要翻译：本发明涉及一种从烃类原料生产氢气和二氧化碳的方法，包括：a）将气态烃类原料和蒸汽供应到包含蒸汽重整催化剂的反应区，并催化重整含烃原料以产生包含氢和二氧化碳的重整气体; b）向第一氢分离膜的渗透侧供应含分子氧的气体; c）使一部分氢与第一氢分离膜接触，允许氢穿过第一氢分离膜并在第一氢分离膜的渗透侧将氢与分子氧一起燃烧以产生所需的全部热量催化重整含烃原料; d）使氢的剩余部分与第二氢分离膜分开，第二氢分离膜与第一氢分离膜分离，并允许氢渗透通过第二氢分离膜以获得包含基本上纯的氢气流的第一流出物; 和e）作为第二流出物从反应区除去富含二氧化碳的物流。本发明还涉及用于这种方法的反应器和一种包括串联的这种反应器和燃料电池的燃料电池系统。

4. 发明授权

US06902717B2 Process for the catalytic partial oxidation of a hydrocarbonaceous feedstock 失效
标题翻译：烃类原料催化部分氧化的方法
公开(公告)号：US06902717B2
公开(公告)日：2005-06-07
申请号：US10149680
申请日：2000-12-19
申请人： Gert Jan Kramer , Jurjen Wietze Van Der Meer , Coen Willem Johannes Pieterse , Ronald Jan Schoonebeek , Hendrik Martinus Wentinck , Eric Sevenhuijsen
发明人： Gert Jan Kramer , Jurjen Wietze Van Der Meer , Coen Willem Johannes Pieterse , Ronald Jan Schoonebeek , Hendrik Martinus Wentinck , Eric Sevenhuijsen
IPC分类号： B01J8/02 , B01J8/04 , C01B3/38 , H01M8/06 , C01B3/26
CPC分类号： C01B3/386 , B01J8/025 , B01J8/0278 , B01J8/0453 , B01J8/0492 , C01B2203/0261 , C01B2203/066 , C01B2203/1005 , C01B2203/1047 , C01B2203/1082 , C01B2203/1094 , C01B2203/1247 , C01B2203/142 , C01B2203/148 , C01B2203/82 , C01B2203/84
摘要： A process for the catalytic partial oxidation of a hydrocarbonaceous feedstock with an oxygen-containing gas, wherein a flow of a feed mixture comprising the hydrocarbonaceous feedstock and the oxygen-containing gas is contacted with a catalyst comprising at least one metal selected from Group VIII of the Periodic Table supported on a catalyst carrier to form a conversion product comprising carbon monoxide and hydrogen, wherein the catalyst is retained in a fixed arrangement in a reactor comprising a feed supply chamber which is in fluid communication with the upstream surface of the fixed arrangement, in which process a part of the conversion product formed flows back to the feed supply chamber. The invention further relates to an electrical-energy generating process, an electrical-energy generating system, and transport means provided with this electrical-energy generating system.
摘要翻译：一种用含氧气体催化部分氧化烃原料的方法，其中包含含烃原料和含氧气体的进料混合物的流动与包含至少一种选自第所述周期表负载在催化剂载体上以形成包含一氧化碳和氢的转化产物，其中所述催化剂以固定的排列保持在包括与固定装置的上游表面流体连通的进料供应室的反应器中，在该过程中，形成的转化产物的一部分流回到供料室。本发明还涉及一种电能产生过程，电能产生系统和具有该电能发电系统的输送装置。

5. 发明申请

US20110023537A1 PROCESS FOR THE SEPARATION OF CO2 FROM A GASEOUS FEED STREAM 失效
标题翻译：从气体进料流中分离二氧化碳的方法
公开(公告)号：US20110023537A1
公开(公告)日：2011-02-03
申请号：US12682673
申请日：2008-10-10
申请人： Gerrit Jan Barend Assink , Gert Jan Kramer , Martin Van Sint Annaland , Martin Jan Tuinier
发明人： Gerrit Jan Barend Assink , Gert Jan Kramer , Martin Van Sint Annaland , Martin Jan Tuinier
IPC分类号： F25J3/08
CPC分类号： B01D7/02 , B01D53/62 , B01D2256/22 , B01D2257/504 , B01D2259/416 , Y02C10/04 , Y02C10/12 , Y02P70/34
摘要： The invention provides a process for the separation of CO2 from a gaseous feed stream, comprising the subsequent steps of: a) cooling a porous body in the form of a fixed bed (101,102,103) to a temperature below the sublimation temperature of CO2 to obtain a cold body; b) contacting a gaseous feed stream (120) comprising CO2 and one or more other gaseous compounds with the surface of the cold body to obtain a body comprising solid CO2 and a CO2-depleted effluent gas (124); and c) removing the solid CO2 by exposing the porous body comprising solid CO2 to a fluid CO2 stream (130) having a temperature above the sublimation temperature of CO2 whereby fluid CO2 (136) and a warm porous body are obtained.
摘要翻译：本发明提供了一种从气态进料流中分离CO 2的方法，其包括以下步骤：a）将固定床（101,102,103）形式的多孔体冷却至低于CO 2升华温度的温度，以获得冷身 b）将包含CO 2和一种或多种其它气态化合物的气态进料流（120）与冷体的表面接触以获得包含固体CO 2和不含CO 2的废气（124）的主体; 和c）通过将包含固体CO 2的多孔体暴露于温度高于CO 2升华温度的流体CO 2流（130），从而获得流体CO 2（136）和温热多孔体，从而去除固体CO 2。

6. 发明授权

US08563185B2 Process and reactor for the production of hydrogen and carbon dioxide and a fuel cell system 失效
标题翻译：用于生产氢和二氧化碳和燃料电池系统的工艺和反应器
公开(公告)号：US08563185B2
公开(公告)日：2013-10-22
申请号：US12305667
申请日：2007-06-28
申请人： Gerrit Jan Barend Assink , Gert Jan Kramer , Arian Nijmeijer , Martin Van Sint Annaland
发明人： Gerrit Jan Barend Assink , Gert Jan Kramer , Arian Nijmeijer , Martin Van Sint Annaland
IPC分类号： H01M8/06 , C01B3/30 , C01B3/44 , C01B3/50
CPC分类号： C01B3/501 , B01D63/06 , B01D2315/08 , B01J8/009 , B01J8/18 , C01B3/384 , C01B32/50 , C01B2203/0233 , C01B2203/041 , C01B2203/0475
摘要： The invention relates to a process for the production of hydrogen and carbon dioxide from a hydrocarbonaceous feedstock, comprising: a) supplying a gaseous hydrocarbonaceous feedstock and steam to a reaction zone comprising a steam reforming catalyst and catalytically reforming the hydrocarbonaceous feedstock to produce a reformed gas comprising hydrogen and carbon dioxide; b) supplying a molecular oxygen-comprising gas to the permeate side of a first hydrogen separation membrane; c) contacting a part of the hydrogen with a first hydrogen separation membrane, allowing the hydrogen to permeate through the first hydrogen separation membrane and combusting the hydrogen with the molecular oxygen at a permeate side of the first hydrogen separation membrane to produce all heat necessary for catalytic reforming the hydrocarbonaceous feedstock; d) contacting the remainder of the hydrogen with a second hydrogen separation membrane, which is separate from the first hydrogen separation membrane, and allowing the hydrogen to permeate through the second hydrogen separation membrane to obtain a first effluent comprising a substantially pure stream of hydrogen; and e) removing a stream rich in carbon dioxide from the reaction zone as a second effluent. The invention further related to a reactor for such process and to a fuel cell system comprising in series such reactor and a fuel cell.
摘要翻译：本发明涉及一种用于从烃原料生产氢气和二氧化碳的方法，包括：a）将气态含烃原料和蒸汽供应到包含蒸汽重整催化剂的反应区，并催化重整含烃原料以产生重整气体包括氢和二氧化碳; b）向第一氢分离膜的渗透侧供应含分子氧的气体; c）使一部分氢与第一氢分离膜接触，允许氢穿过第一氢分离膜并在第一氢分离膜的渗透侧将氢与分子氧一起燃烧以产生所需的全部热量催化重整含烃原料; d）使氢的剩余部分与第二氢分离膜分开，第二氢分离膜与第一氢分离膜分离，并允许氢渗透通过第二氢分离膜以获得包含基本上纯的氢气流的第一流出物; 和e）作为第二流出物从反应区除去富含二氧化碳的物流。本发明还涉及用于这种方法的反应器和一种包括串联的这种反应器和燃料电池的燃料电池系统。

7. 发明申请

US20090031968A1 PROCESS FOR OPERATING A COMPRESSION IGNITION INTERNAL COMBUSTION ENGINE IN COMBINATION WITH A CATALYTIC REFORMER 有权
标题翻译：压缩点火内燃机与催化转化器组合的工艺
公开(公告)号：US20090031968A1
公开(公告)日：2009-02-05
申请号：US10580942
申请日：2004-12-01
申请人： Roger Francis Cracknell , Gert Jan Kramer , Eric Johannes Vos
发明人： Roger Francis Cracknell , Gert Jan Kramer , Eric Johannes Vos
IPC分类号： F02B43/10 , F02M25/07 , F01N3/20 , F02M27/02 , F02D19/08
CPC分类号： F01N13/011 , C01B3/386 , C01B2203/0261 , C01B2203/0465 , C01B2203/066 , C10L3/00 , F01N3/0814 , F01N3/0842 , F01N2240/30 , F01N2240/32 , F01N2610/03 , F01N2610/08 , F02B1/12 , F02B3/06 , F02B43/10 , F02D19/0642 , F02D19/0671 , F02D19/081 , F02M25/0224 , F02M25/0228 , F02M25/10 , F02M26/35 , F02M26/36 , F02M27/02 , Y02T10/121 , Y02T10/32 , Y02T10/36
摘要： A process for operating a compression ignition internal combustion engine (1) in combination with a catalytic partial oxidation reformer (2) and, optionally, an exhaust gas aftertreater (3), wherein: (a) a mixture of a first fuel and air, wherein the first fuel comprises Fischer-Tropsch derived fuel, is introduced in the combustion chamber of the engine (1); (b) exhaust gas is discharged from the engine and optionally partly recirculated to the combustion chamber of the engine (1); (c) a second fuel and oxygen and/or steam are supplied to the catalytic partial oxidation reformer (2) to produce synthesis gas, wherein the second fuel comprises Fischer-Tropsch derived fuel; (d) at least part of the synthesis gas is supplied to: (i) the exhaust gas aftertreater (3); (ii) the combustion chamber of the engine (1); or to both.
摘要翻译：一种与催化部分氧化重整器（2）和任选的废气后处理器（3）组合操作压缩点火内燃机（1）的方法，其中：（a）第一燃料和空气的混合物，其中所述第一燃料包括费 - 托衍生的燃料，被引入所述发动机（1）的燃烧室中; （b）废气从发动机排出并且任选地部分再循环到发动机（1）的燃烧室; （c）第二燃料和氧气和/或蒸汽供应到催化部分氧化重整器（2）以产生合成气，其中第二燃料包括费 - 托衍生的燃料; （d）至少部分合成气被供给到：（i）废气后处理器（3）; （ii）发动机（1）的燃烧室; 或两者兼而有之。

8. 发明授权

US07232532B2 Catalytic partial oxidation process using a catalyst system having an upstream and a downstream part 失效
标题翻译：使用具有上游和下游部分的催化剂体系的催化部分氧化方法
公开(公告)号：US07232532B2
公开(公告)日：2007-06-19
申请号：US10450602
申请日：2001-12-13
申请人： Gert Jan Kramer , Willem Pieter Leenhouts , Ronald Jan Schoonebeek , Johannes Wijnbelt
发明人： Gert Jan Kramer , Willem Pieter Leenhouts , Ronald Jan Schoonebeek , Johannes Wijnbelt
IPC分类号： C01B3/26
CPC分类号： B01J35/06 , B01J8/0446 , B01J12/007 , B01J23/40 , B01J35/0006 , B01J37/0225 , B01J37/0242 , C01B3/386 , C01B3/48 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/085 , C01B2203/1011 , C01B2203/1023 , C01B2203/1029 , C01B2203/1047 , C01B2203/1064 , C01B2203/1082 , C01B2203/1094 , C01B2203/1205 , C01B2203/1217 , C01B2203/1235 , C01B2203/1276 , C01B2203/1604 , C01B2203/1619 , C01B2203/169 , C01B2203/82 , Y02P20/52
摘要： The invention relates to a process for the catalytic partial oxidation of a hydrocarbonaceous feedstock, wherein a feed mixture having the hydrocarbonaceous feedstock and a molecular-oxygen containing gas is contacted with a catalyst system having an upstream part and a downstream part, the downstream part being in the form of a porous catalyst bed, wherein the catalyst system is retained in a reactor, the reactor having an upstream part that contains the upstream part of the catalyst system and a downstream part that contains the downstream part of the catalyst system, wherein the upstream part of the catalyst system only partly fills the cross-sectional area of the fluid flow path of the upstream part of the reactor and the downstream part of the catalyst system completely fills the cross-sectional area of the fluid flow path of the downstream part of the reactor. The invention further relates to a reactor having such a catalyst system and a catalytic reaction zone for the water-gas shift conversion of the effluent of the catalyst system, to a fuel cell system having such a reactor and a fuel cell, and to a vehicle provided with such a fuel cell system.
摘要翻译：本发明涉及一种用于烃类原料的催化部分氧化的方法，其中具有含烃原料和含分子氧的气体的进料混合物与具有上游部分和下游部分的催化剂体系接触，下游部分为以多孔催化剂床的形式，其中催化剂体系保留在反应器中，反应器具有包含催化剂体系的上游部分的上游部分和包含催化剂体系下游部分的下游部分，其中，催化剂体系的上游部分仅部分地填充反应器上游部分的流体流动路径的横截面积，并且催化剂系统的下游部分完全填充下游部分的流体流动路径的横截面积的反应器。本发明还涉及一种具有这样的催化剂体系和催化剂体系的流出物的水煤气变换转化为具有这种反应器和燃料电池的燃料电池系统的催化剂体系的反应器，以及车辆设置有这样的燃料电池系统。

9. 发明授权

US5712313A Process for carrying out chemical equilibrium reactions 失效
标题翻译：进行化学平衡反应的方法
公开(公告)号：US5712313A
公开(公告)日：1998-01-27
申请号：US550135
申请日：1996-02-26
申请人： Gert Jan Kramer , Jean Paul Lange
发明人： Gert Jan Kramer , Jean Paul Lange
IPC分类号： B01J8/04 , C07C29/152 , C07C29/151
CPC分类号： B01J8/0453 , C07C29/152 , B01J2208/00283 , Y02P20/582
摘要： A process for carrying out a chemical equilibrium reaction is disclosed in which, in a first stage, one or more reactants are contacted with a fixed arrangement of a catalyst under conditions such that the reactants and the products of the reaction are gaseous, the unconverted reactants and products of the first stage being passed to a second stage, in which they are contacted with a fixed arrangement of a catalyst and the reaction allowed to proceed in the presence of an absorbent capable of absorbing a product of the reaction. There is specifically disclosed a process for the synthesis of methanol from carbon monoxide and hydrogen, in which, in a first stage, carbon monoxide and hydrogen are contacted with a fixed arrangement of a catalyst active in catalyzing the synthesis of methanol under conditions such that the methanol formed is present as a gas under the prevailing reaction conditions, the unconverted carbon monoxide and hydrogen and methanol produced in the first stage being passed to a second stage, in which they are contacted with a fixed arrangement of a catalyst active in catalyzing the synthesis of methanol and the reaction allowed to proceed in the presence of an absorbent capable of absorbing methanol.
摘要翻译：公开了一种用于进行化学平衡反应的方法，其中在第一阶段中，一种或多种反应物在反应物和反应产物是气态的条件下与固定排列的催化剂接触，未转化的反应物并且将第一阶段的产物送至第二阶段，在第二阶段中它们与固定的催化剂排列物接触，并且使反应在能够吸收反应产物的吸收剂存在下进行。具体公开了一种从一氧化碳和氢气合成甲醇的方法，其中在第一阶段中，将一氧化碳和氢气与催化甲醇合成的催化剂的固定排列物接触，在主要反应条件下，形成的甲醇作为气体存在，将未转化的一氧化碳和在第一阶段中产生的氢气和甲醇转移到第二阶段，在第二阶段中，它们与催化活性的催化剂的固定排列物接触的甲醇，使反应在能够吸收甲醇的吸收剂存在下进行。

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