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1. 发明申请

WO2009115399A1 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE共聚物
公开(公告)号：WO2009115399A1
公开(公告)日：2009-09-24
申请号：PCT/EP2009/052207
申请日：2009-02-25
申请人： Basell Poliolefine Italia s.r.l. , Resconi, Luigi , Balboni, Davide , Esposito, Simona
发明人： Resconi, Luigi , Balboni, Davide , Esposito, Simona
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F4/65912 , C08F2420/05 , C08F4/65927 , C08F210/14 , C08F2500/17 , C08F2500/15 , C08F2500/11 , C08F2500/20
摘要： A copolymer of 1 -butene and at least a C 8 -C 12 alpha-olefin derived units, having a content of C 8 - C 12 alpha-olefin derived units equal to or higher than 7.2% and lower than 20.0% by mole; endowed with the following features: a) no detectable melting point TmII as the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetraline at 135°C comprised between 0.8 and 5.0 dL/g; c) isotactic pentad mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable at 13 C NMR; d) the tensile modulus (TM) measured with DMTA in MPa and the comonomer content fulfill the following relationship: TM 8 -C 12 alpha-olefin derived units; e) the tension set at 100% of deformation is lower than 55 %; and f) the melting point measured by DSC (TmI) and the C 8 -C 12 alpha-olefin content fulfill the following relationship: TmI 8 -C 12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition; otherwise the melting point TmI is not detectable by DSC.
摘要翻译：具有等于或高于7.2％且低于20.0摩尔％的C 8 -C 12α-烯烃衍生单元的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元的共聚物; 具有以下特征：a）没有可检测的熔点TmII作为第二熔融转变中最高的熔融峰; b）在135℃下在四氢化萘中测得的特性粘度（Ⅳ）为0.8至5.0dL / g; c）全同立构五价mmmm高于或等于90％; 低于4的五元组（mmrr + mrrm）和在13 C NMR下不能检测到的五元组; d）用DMTA测得的拉伸弹性模量（MPa）和共聚单体含量满足下列关系：TM8-C12α-烯烃衍生单元; e）100％变形时的张力设定值低于55％; 和f）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI 8-C12α-烯烃衍生单元，TmI是第一熔融转变中最高的熔融峰; 否则熔点Tm1不能通过DSC检测。

2. 发明申请

WO2009115395A1 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE共聚物
公开(公告)号：WO2009115395A1
公开(公告)日：2009-09-24
申请号：PCT/EP2009/052116
申请日：2009-02-23
申请人： Basell Polyolefine Italia s.r.l. , Resconi, Luigi , Balboni, Davide , Esposito, Simona
发明人： Resconi, Luigi , Balboni, Davide , Esposito, Simona
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F210/14 , C08F210/06 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A copolymer of 1-butene and at least a C 8 -C 12 alpha-olefin derived units, preferably at least 1- octene derived units, containing from 0% to 2% by mole of propylene or pentene, having a content of C 8 -C 12 alpha-olefin derived units higher than 0.2% and lower than 7.2% by mole; endowed with the following features: a) the melting point measured by DSC (TmII) and the C 8 -C 12 alpha-olefin molar content fulfil the following relationship: 0 8 -C 12 alpha-olefin derived units and TmII is the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5 dL/g; and c) isotactic pentads mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentads rmmr not detectable at 13 C NMR.
摘要翻译：含有C-C 12α-烯烃的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元，优选至少1-辛烯衍生单元的共聚物，其含有0％-2％（摩尔）丙烯或戊烯，高于0.2％且低于7.2摩尔％的α-烯烃衍生单元; 具有以下特征：a）通过DSC（TmII）和C8-C12α-烯烃摩尔含量测量的熔点满足以下关系：0 8-C12α-烯烃衍生单元和TmII是在第二次熔融转变; b）在135℃四氢萘中测得的特性粘度（Ⅳ）在0.8和5dL / g之间; 和c）高于或等于90％的全同立构五单元组mmmm; 低于4的五单元组（mmrr + mrrm），在13 C NMR下不能检测到五单元组。

3. 发明公开

EP2254917A1 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-丁烯共聚物
公开(公告)号：EP2254917A1
公开(公告)日：2010-12-01
申请号：EP09721950.5
申请日：2009-02-23
申请人： Basell Poliolefine Italia S.R.L.
发明人： Resconi, Luigi , Balboni, Davide , Esposito, Simona
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F210/14 , C08F210/06 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A copolymer of 1-butene and at least a C
8 -C
12 alpha-olefin derived units, preferably at least 1- octene derived units, containing from 0% to 2% by mole of propylene or pentene, having a content of C
8 -C
12 alpha-olefin derived units higher than 0.2% and lower than 7.2% by mole; endowed with the following features: a) the melting point measured by DSC (TmII) and the C
8 -C
12 alpha-olefin molar content fulfil the following relationship: 0 8 -C
12 alpha-olefin derived units and TmII is the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5 dL/g; and c) isotactic pentads mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentads rmmr not detectable at
13 C NMR.
摘要翻译： 1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元的共聚物，优选至少含有1-辛烯衍生单元，含有0-2％（摩尔）丙烯或戊烯，其含量为C 8 -C 12α-烯烃衍生单元的摩尔比大于0.2％且小于7.2摩尔％; 其具有以下特征：a）通过DSC测量的熔点（TmII）和C 8 -C 12α-烯烃摩尔含量满足以下关系：0

4. 发明公开

EP2254919A1 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-丁烯共聚物
公开(公告)号：EP2254919A1
公开(公告)日：2010-12-01
申请号：EP09722932.2
申请日：2009-02-25
申请人： Basell Poliolefine Italia S.R.L.
发明人： Resconi, Luigi , Balboni, Davide , Esposito, Simona
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F4/65912 , C08F2420/05 , C08F4/65927 , C08F210/14 , C08F2500/17 , C08F2500/15 , C08F2500/11 , C08F2500/20
摘要： A copolymer of 1 -butene and at least a C
8 -C
12 alpha-olefin derived units, having a content of C
8 - C
12 alpha-olefin derived units equal to or higher than 7.2% and lower than 20.0% by mole; endowed with the following features: a) no detectable melting point TmII as the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetraline at 135°C comprised between 0.8 and 5.0 dL/g; c) isotactic pentad mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable at
13 C NMR; d) the tensile modulus (TM) measured with DMTA in MPa and the comonomer content fulfill the following relationship: TM 8 -C
12 alpha-olefin derived units; e) the tension set at 100% of deformation is lower than 55 %; and f) the melting point measured by DSC (TmI) and the C
8 -C
12 alpha-olefin content fulfill the following relationship: TmI 8 -C
12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition; otherwise the melting point TmI is not detectable by DSC.

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