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    • 6. 发明申请
    • UNDERWATER CERAMIC ELECTRODES
    • 水下陶瓷电极
    • WO2005094276A2
    • 2005-10-13
    • PCT/US2005/010089
    • 2005-03-25
    • HI-Z TECHNOLOGY, INC.INFOSTO NEWTECH OYMETCALFE, ArthurELSNER, Norbert, B.MUSTONEN, Sakari
    • METCALFE, ArthurELSNER, Norbert, B.MUSTONEN, Sakari
    • B23K9/00B23K9/013
    • B23K9/0061
    • An underwater torch with a metal infiltrated ceramic electrode for cutting and machining. The electrode has a composition with an empirical formula MB 2-Z +N, wherein 0 2.-Z defines a ceramic structure formed with ceramic and defining a volume with void spaces comprising at least 10 percent of the volume of the matrix structure and the N occupies a portion of the void spaces. A preferred electrode material is ceramic matrix of ZrB 2 slightly enriched in Zr that is infiltrated with copper. Preferred methods of making the composition involves at least two step: First, ZrB 2 (which preferably is slightly enriched in Zr) is formed into a ceramic matrix having a density of up to 96 percent. Second, the ceramic matrix is heated in a pool of copper at a vacuum and at an infiltration temperature of about 1700 degrees C. to permit copper from the pool to infiltrate the ceramic matrix. Preferred processes for making the product are similar to the processes described in the ‘574 patent. Applicants’ tests have shown that conductors made for underwater electric discharge cutting provide good results. However, some significant erosion resulted from the flaking off of ceramic powders at the outer surface of the copper infiltrated electrodes when the surface copper melted during the cutting process. To minimize this problem, Applicants have modified the ceramics in the compositions described in the ‘547 patent. In a preferred embodiment, the metal content in the voids in the ceramic matrix is reduced from at least 70% to between 10% and 30%. In another preferred embodiment ceramic fibers are used in place of ceramic powders. In a third preferred embodiment ceramic wires such as ZrB 2 wires are utilized instead of the ZrB 2 powder. ZrB 2 wires are preferably prepared using a chemical process to convert the Zr wires to ZrB 2 wires. Bundles of the ZrB 2 wires may then be infiltrated with the copper.
    • 具有金属渗透陶瓷电极的水下手电筒用于切割和加工。 电极具有经验式MB2-Z + N的组成,其中0
    • 7. 发明申请
    • THERMOELECTRIC DEVICE WITH SI/SIC SUPERLATTICE N-LEGS
    • 具有SI / SIC超级电容器的热电偶装置
    • WO2003050878A1
    • 2003-06-19
    • PCT/US2002/040109
    • 2002-12-12
    • HI-Z TECHNOLOGY, INC.GHAMATY, SaiedELSNER, Norbert, B.
    • GHAMATY, SaiedELSNER, Norbert, B.
    • H01L29/06
    • H01L35/22H01L29/155H01L35/32Y10S257/93
    • A superlattice thermoelectric device. The device is comprised of p-legs (60B) and n-legs (60A), each leg being comprised of a large number of at least two different very thin alternating layers of elements (62A, 64A, 66A, 62B, 64B, 66B). The n-legs in the device are comprised of alternating layers of silicon (50) and silicon carbide (48). In preferred embodiments p-legs are comprised of a superlatice of B-C layers, with alternating layers of different stoichiometric forms of B-C. This preferred embodiment is designed to produce 20 Watts with a temperature difference of 300 degrees C with a module efficiency of about 30 percent. The module is about 1 cm thick with a cross section area of about 7 cm 2 and has about 10,000 sets of n and p legs each set of legs about 55 microns thick and having about 5,000 very thin layers (each layer about 10 nm thick).
    • 超晶格热电装置。 该装置由p腿(60B)和n腿(60A)构成,每个腿部由大量至少两个不同的非常薄的交替层元件(62A,64A,66A,62B,64B,66B )。 器件中的n支腿由硅(50)和碳化硅(48)的交替层组成。 在优选实施例中,p支腿由B-C层的超层组成,具有不同化学计量形式的B-C的交替层。 该优选实施例被设计为产生20瓦特,温度差为300摄氏度,模块效率约为30%。 该模块约1厘米厚,横截面积约7厘米2,并且具有大约10,000组n和p腿每组腿约55微米厚并且具有约5,000个非常薄的层(每层约10nm 厚)。
    • 9. 发明申请
    • THERMOELECTRIC MODULE WITH GAPLESS EGGCRATE
    • 具有无缝电极的热电模块
    • WO1997044993A1
    • 1997-11-27
    • PCT/US1997004514
    • 1997-03-20
    • HI-Z TECHNOLOGY, INC.LEAVITT, Frederick, A.BASS, John, C.ELSNER, Norbert
    • HI-Z TECHNOLOGY, INC.
    • H05K07/20
    • H01L35/00H01L35/32H01L35/34Y10S257/93Y10T29/49352
    • A thermoelectric module (45) contains thermoelectric elements installed in a gapless eggcrate. An eggcrate having walls without gaps is formed using a technique such as injection molding. This gapless eggcrate provides insulated spaces for a large number of p-type and n-type thermoelectric elements. The absence of gaps in the walls of the spaces virtually eliminates the possibility of interwall shorts between the elements even when electrical connections are made by metal spray techniques. Fabrication of the gapless eggcrate can be automated using several available techniques such as molding and casting to greatly reduce the labor cost of fabricating thermoelectric eggcrates as compared to prior art techniques of fabricating eggcrates. Thermoelectric elements (45), both p-type and n-type, are fabricated and are inserted into the insulated spaces in the gapless eggcrate in a predetermined manner to provide the desired thermoelectric effects for a predetermined type of application. Electrical connections are established on both the hot and cold sides of the module to connect the thermoelectric elements in series or parallel as desired.
    • 热电模块(45)包含安装在无缝隙的蛋鸡中的热电元件。 使用诸如注射成型的技术形成具有没有间隙的壁的鸡蛋。 这种无缝隙的蛋鸡为大量的p型和n型热电元件提供绝缘空间。 空间墙壁上没有间隙实际上消除了元件之间的内部短路的可能性,即使通过金属喷涂技术进行电连接时也是如此。 与现有技术制造蛋鸡相比,无缝隙蛋鸡的制造可以使用几种可用的技术如模制和铸造自动化,以大大降低制造热电蛋鸡的劳动力成本。 制造p型和n型两者的热电元件(45),并以预定的方式插入到无间隙的卵切割器的绝缘空间中,以提供预定类型的应用所需的热电效应。 在模块的热侧和冷端两端都建立电气连接,以根据需要串联或并联连接热电元件。
    • 10. 发明申请
    • UNDERWATER CERAMIC ELECTRODES
    • 水下陶瓷电极
    • WO2005094276A3
    • 2006-08-17
    • PCT/US2005010089
    • 2005-03-25
    • HI Z TECHNOLOGY INCINFOSTO NEWTECH OYMETCALFE ARTHURELSNER NORBERT BMUSTONEN SAKARI
    • METCALFE ARTHURELSNER NORBERT BMUSTONEN SAKARI
    • B23K9/00B23K9/013
    • B23K9/0061
    • An underwater torch with a metal infiltrated ceramic electrode for cutting and machining. The electrode has a composition with an empirical formula MB 2-Z +N, wherein 0 2.-Z defines a ceramic structure formed with ceramic and defining a volume with void spaces comprising at least 10 percent of the volume of the matrix structure and the N occupies a portion of the void spaces. A preferred electrode material is ceramic matrix of ZrB 2 slightly enriched in Zr that is infiltrated with copper. Preferred methods of making the composition involves at least two step: First, ZrB 2 (which preferably is slightly enriched in Zr) is formed into a ceramic matrix having a density of up to 96 percent. Second, the ceramic matrix is heated in a pool of copper at a vacuum and at an infiltration temperature of about 1700 degrees C. to permit copper from the pool to infiltrate the ceramic matrix. Preferred processes for making the product are similar to the processes described in the '574 patent. Applicants' tests have shown that conductors made for underwater electric discharge cutting provide good results. However, some significant erosion resulted from the flaking off of ceramic powders at the outer surface of the copper infiltrated electrodes when the surface copper melted during the cutting process. To minimize this problem, Applicants have modified the ceramics in the compositions described in the '547 patent. In a preferred embodiment, the metal content in the voids in the ceramic matrix is reduced from at least 70% to between 10% and 30%. In another preferred embodiment ceramic fibers are used in place of ceramic powders. In a third preferred embodiment ceramic wires such as ZrB 2 wires are utilized instead of the ZrB 2 powder. ZrB 2 wires are preferably prepared using a chemical process to convert the Zr wires to ZrB 2 wires. Bundles of the ZrB 2 wires may then be infiltrated with the copper.
    • 具有金属渗透陶瓷电极的水下手电筒用于切割和加工。 电极具有经验式MB 2 -Z + N的组成,其中0 的陶瓷基体,其被铜渗透。 制备组合物的优选方法包括至少两个步骤:首先,将ZrB 2 N(其优选地稍微富集于Zr中)形成为密度高达96%的陶瓷基质。 其次,将陶瓷基体在真空中并在大约1700℃的浸入温度下在铜池中加热,以允许来自池的铜渗入陶瓷基体。 制造该产品的优选方法类似于'574专利中描述的方法。 申请人的测试表明,用于水下放电切割的导体提供了良好的效果。 然而,当在切割过程中表面铜熔化时,在铜浸渗电极的外表面剥离陶瓷粉末导致了一些显着的侵蚀。 为了最小化这个问题,申请人已经对'547专利中描述的组合物中的陶瓷进行了改性。 在优选的实施方式中,陶瓷基体中空隙中的金属含量从至少70%降低到10%至30%之间。 在另一个优选实施例中,使用陶瓷纤维代替陶瓷粉末。 在第三优选实施例中,使用诸如ZrB 2-Wire的陶瓷丝来代替ZrB 2 N 2粉末。 优选使用化学工艺制备ZrB 2线,以将Zr线转化为ZrB 2线。 然后可以用铜渗透ZrB 2线的束。