会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 1. 发明申请
    • POLYMERIC HAIR DYES
    • WO2011006946A9
    • 2011-01-20
    • PCT/EP2010/060175
    • 2010-07-15
    • BASF SECREMER, ChristianBECHERER, OliverFRÖHLING, Beate
    • CREMER, ChristianBECHERER, OliverFRÖHLING, Beate
    • C09B26/04C09B69/10A61Q5/00
    • Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X 1 and X 2 independently from each other are a linkage group selected from -S-, -S-S-, -N-, - N=-, -N(R 5 )-, -S(O)-, -SO 2 -, -(CH 2 CH 2 -O) 1-5 -, -(CH 2 CH 2 CH 2 -O) 1-5 -, -C(O)-, -C(O)O-,-OCO-, (formula II) -CON(R 1 )-, -C(NR 1 R 2 ) 2 -, -(R 1 )NC(O)-, -C(S)R 1 -; which may be interrupted and/or terminated at one or both ends by one or more than one -C 1 C 30 alkylene- or -C 2 -C 12 alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C 1 -C 30 alkyl, C 1 -C 30 alkoxy, C 2 -C 12 alkenyl, C 5 -C 10 aryl, C 5 -C 10 cycloalkyl, C 1 - C 10 alkyl(C 5 -C 10 arylene), hydroxy or halogen; R 1 and R 2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 - C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl- C 1 -C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); Y 1 and Y 2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z 1 , Z 2 and Z 3 , independently from each other are -CR 8 - or -NR 9 +-; and at least one of Z 1 , Z 2 or Z 3 is -NR 9 +-; wherein at least one of Y 1 and Y 2 is a residue of an organic dye; R, R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 independently from each other are hydrogen; hydroxy; C 1 - C 5 alkyl; hydroxy-C 1 C 5 alkyl; C 1 C 5 alkoxy; -NO 2 ; -Cl; -Br; -COOH; -SO 3 H; -CN; NH 2 ; or CH 3 -CO-NH-; An 1 , An 2 and An 3 , independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p ≥ 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    • 4. 发明申请
    • OXAZINE DISULFIDE DYES
    • WO2007039529A3
    • 2007-04-12
    • PCT/EP2006/066784
    • 2006-09-27
    • CIBA SPECIALTY CHEMICALS HOLDING INC.CREMER, ChristianWALLQUIST, Olof
    • CREMER, ChristianWALLQUIST, Olof
    • A61Q5/10A61K8/49C09B17/02C09B19/00C09B49/06
    • Disclosed are oxazine disulfide dyes of formula (1) D 1 ―(Z 1 ) r ―Y 1 ―S―A, wherein A is hydrogen; or a radical of formula (1a) *―S―Y 2 ―(Z 2 ) r ―D 2 ; Y 1 and Y 2 independently from each other are unsubstituted or substituted, straight-chain or branched, interrupted or uninterrupted C- 1 -C- 10 alkylene; C 5 -C 10 cycloalkylene; C 5 -C 10 arylene; or-C 5 -C 10 arylene-(C 1 -C 10 alkylene); Z 1 and Z 2 independently from each other are *-(CH 2 ) p -C(O)-**; *-(CH 2 CH 2 -O) s -**; *-(CH 2 ) p -C(O)O-**; *-(CH 2 ) p -OCO-**; *-(CH 2 ) P -N(R 1 )-**; formula 1(g); -(CH 2 ) P -CON(R 1 )-**; *-(CH 2 ) P -(R 1 )NC(O)-**; . - 0-; -S-; -S(O)-; -S(O) 2 -; or a cationic biradical of a substituted or unsubstituted aromatic or heteroaromatic compound of the formula (1a); (1b); (1c); (1d); or (1e); wherein the asterix * indicates the linkage to D 1 and/or D 2 ; the asterix ** indicates the linkage to Y 1 and/or Y 2 ; W 1 is N or a radical of CR 5 ; R 1 , R 2 , R 3 , R 4 and R 5 independently from each other are hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 5 -C 10 aryl; C 5 -C 10 aryl-(C 1 -C 10 alkyl) ; or -C 1 -C 10 alkyl(C 5 -C 10 aryl); D 1 and D 2 independently from each other ar the residue of an organic dye selected from the radical of formula (1f); R 6 and R 7 independently from each other are hydrogen; C 1 -C 20 alkyl; C 1 -C 20 alkoxy; C 3 -C 6 cycloalkyl; C 5 -C 10 aryl; anellated aromatic groups; carboxylate; or sulfonate groups; R 8 , R 9 and R 10 , R 11 and R 12 each independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 -C 14 alkyl, C 2 -C 14 alkenyl, C 6 -C 10 aryl, C 6 -C 10 aryl-C 1 -C 10 alkyl or C 5 -C 10 alkyl(C 5 -C 10 aryl); or R 8 and R 9 or R 10 and R 11 together with the linking nitrogen atom form a 5 to 7 membered carbocyclic ring which may contain one or more than one hetero atom; or R 8 is linked to C 1 together with N + forming a 5-7 membered carbocyclic ring; or R 9 is linked to C 2 together with N + forming a 5-7 membered carbocyclic ring; X is -O-; or -N(R 9 )-; or -S-; p is a number from 0 to 5; r is 0 or 1; and s is a number from 1 to 5. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
    • 6. 发明申请
    • SULFIDE DYES
    • WO2006136516A2
    • 2006-12-28
    • PCT/EP2006/063179
    • 2006-06-14
    • CIBA SPECIALTY CHEMICALS HOLDING INC.CREMER, ChristianWALLQUIST, Olof
    • CREMER, ChristianWALLQUIST, Olof
    • C09B1/002A61K8/355A61K8/46A61K8/4946A61Q5/065C09B1/207
    • Disclosed are compounds of formula. Method of dyeing keratin-containing fibers comprising treating the fiber with at least one sulfide dye of formula (1), their salts, isomers, hydrates and other solvates, wherein R 1 , R 2 , R 3 and R 4 independently from each other are hydrogen; C 1 -C 20 alkyl; C 1 -C 20 alkoxy; C 3 -C 6 cycloalkyl; halogen; NO 2 ; OH; SH; or a radical of formula (1a) wherein R 5 is hydrogen; or C 1 -C 20 alkyl; R 6 , R 7 and R 8 independently from each other are hydrogen, C 1 -C 20 alkyl, C 4 -C 12 cycloalkyl, C 6 -C 13 aralkyl; phenyl- C 1 -C 5 alkyl; or R 6 and R 7 together with the linking nitrogen atom form a C 4 -C 12 -membered heterocyclic ring which may be interrupted by one or more than one- O- or -NH- goups; Y 1 is C 1 -C 10 alkylene; C 5 -C 10 cycloalkylene; C 5 -C 10 arylene; or C 5 -C 10 arylene-( C 1 -C 10 alkylene); T 1 is a radical of formula (1b); or -O-(X 3 ) s ; Q 1 is a cationic biradical of a saturated, aromatic or heteroaromatic group; or a radical of formula (1c); Z 1 is -C(O)-; -(CH 2 CH 2 -O) 1-5 -; -C(O)O-; -OCO-; CON(R 9 )-; -X 4 -CON(R 9 )-; -(R 9 )NC(O)-; - O-; -S-; -S(O)-; or -S(O) 2 -; R 9 , R 10 and R 11 each independently from each other are hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl- C 1 -C 10 alkyl; or C 1 -C 10 alkyl(C 5 -C 10 aryl); X 1 , X 2 , X 3 and X 4 independently from each other are C 1 -C 18 alkylene; -(CO)- C 1 -C 18 alkylene, C 1 -C 18 arylene; C 6 -C 18 arylene- C 1 -C 12 alkylene; or -(OCH 2 CH 2 ) n -O-; n is a number from 1 to 5; p, r, s, t and u independently from each other are a 0 or 1; m is 1; or 2; U is hydrogen, if m is 1; and U is the direct bond, if m is 2. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair. The dyes are distinguished by deep dying having good fastness properties with respect to washing, light, shampooing and rubbing.
    • 公开了式的化合物。 染色含有角蛋白的纤维的方法,包括用至少一种式(1)的硫化染料,其盐,异构体,水合物和其它溶剂化物处理纤维,其中R 1,R 2, R 3,R 3和R 4彼此独立地是氢; ç 1 -C 20 烷基; ç 1 -C 20 烷氧基; ç 3 -C 6 环烷基; 卤素; NO 2 ; 哦; SH; 或其中R 5为氢的式(1a)基团; 或C 1 -C 20烷基; R 6,R 7和R 8彼此独立地是氢,C 1 -C 3 - 20个C 1 -C 12烷基,C 4 -C 12环烷基,C 6 -C 13芳烷基, 苯基-C 1 -C 5烷基; 或R 6和R 7与连接氮原子一起形成C 4-14碳 - 12个杂环基 环可能被一个或多于一个O-或-NH-羟基中断; Y 1是C 1 -C 10亚烷基; ç 5 -C 10 亚环烷基; ç 5 -C 10 亚芳基; 或C 5 -C 10亚芳基 - (C 1 -C 10亚烷基); T 1是式(1b)的基团; 或-O-(X 3 N 3)3。 Q 1是饱和,芳族或杂芳族基团的阳离子双基; 或式(1c)的基团; Z 1是-C(O) - ; - (CH 2 CH 2 -O) 1-5 - ; -C(O)O-; -OCO-; CON(R 9 ) - ; -X 4 -CON(R 9 ) - ; - (R 9 )NC(O) - ; - O- -S-; -所以)-; 或-S(O)2 - ; R 9,R 10和R 11各自独立地为氢; ç 1 -C 14 烷基; ç 2 -C 14 烯基; ç 6 -C 10 芳基; C 6 -C 10芳基-C 1 -C 10烷基; C 1 -C 6烷基; 或C 1 -C 10烷基(C 5 -C 10芳基);或C 1 -C 10烷基。 X 1,X 2,X 3和X 4彼此独立地为C 1, / SUB> -C 18 亚烷基; - (CO)-C 1 -C 18亚烷基,C 1 -C 18亚芳基; C 6 -C 18亚芳基-C 1 -C 12亚烷基; 或 - (OCH 2 CH 2 CH 2)n -O-; n是从1到5的数字; p,r,s,t和u彼此独立地为0或1; m为1; 或2; U是氢,如果m是1; 如果m为2,则U是直接键合。该化合物可用于染色有机材料,例如角蛋白纤维,优选人发。 这些染料的特征在于具有相对于洗涤,光,洗发和摩擦的良好牢度性质的深度染色。
    • 9. 发明申请
    • POLYMERIC HAIR DYES
    • 聚合物染发剂
    • WO2011006946A2
    • 2011-01-20
    • PCT/EP2010060175
    • 2010-07-15
    • BASF SECREMER CHRISTIANBECHERER OLIVERFROEHLING BEATE
    • CREMER CHRISTIANBECHERER OLIVERFROEHLING BEATE
    • C09B26/04A61Q5/00C09B69/10
    • C09B26/04A61K8/84A61K2800/4324A61Q5/10C09B69/109
    • Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from -S-, -S-S-, -N-, - N=-, -N(R5)-, -S(O)-, -SO2-, -(CH2CH2-O)1-5-, -(CH2CH2CH2-O)1-5-, -C(O)-, -C(O)O-,-OCO-, (formula II) -CON(R1)-, -C(NR1R2)2-, -(R1)NC(O)-, -C(S)R1-; which may be interrupted and/or terminated at one or both ends by one or more than one -C1C30alkylene- or -C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1- C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1- C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl- C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z1, Z2 and Z3, independently from each other are -CR8- or -NR9+-; and at least one of Z1, Z2 or Z3 is -NR9+-; wherein at least one of Y1 and Y2 is a residue of an organic dye; R, R3, R4, R5, R6, R7, R8 and R9 independently from each other are hydrogen; hydroxy; C1- C5alkyl; hydroxy-C1C5alkyl; C1C5alkoxy; -NO2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; or CH3-CO-NH-; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p = 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    • 公开了式(1a),(1b)或(1c)的聚合物染料; 其中A和B彼此独立地表示聚合物骨架; X1和X2彼此独立地为选自-S - , - SS - , - N - , - N = - , - N(R5) - , - S(O) - , - SO2 - , - (O) - , - C(O)O - , - OCO-,(式II)-CON(R 1) - , -C(NR 1 R 2)2 - , - (R 1)NC(O) - , - C(S)R 1 - 其可以在一个或两个末端被一个或多个-C 1 -C 30亚烷基 - 或-C 2 -C 12亚烯基中断和/或终止; 或任选地包含至少一个杂原子的任选取代的饱和或不饱和的稠合或非稠合的芳族或非芳族(杂环)二价基团; 包含至少一个任选被C 1 -C 30烷基,C 1 -C 30烷氧基,C 2 -C 12烯基,C 5 -C 10芳基,C 5 -C 10环烷基,C 1 -C 10烷基(C 1 -C 10)烷基, C5-C10亚芳基),羟基或卤素; R1和R2彼此独立地为氢; 未取代或取代的直链或支链,单环或多环,间断或不间断的C 1 -C 14烷基; C2-C14alkenyl; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基(C 5 -C 10芳基); 其中Z 1,Z 2和Z 3彼此独立地是-CR 8 - 或-NR 9 - ; - 并且Z 1,Z 2或Z 3中的至少一个是-NR 9 + - ; 其中Y 1和Y 2中的至少一个是有机染料的残基; R,R 3,R 4,R 5,R 6,R 7,R 8和R 9彼此独立地为氢; 羟基; C1-C5烷基; 羟基C1C5alkyl; C1C5alkoxy; NO 2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; 或CH 3 -CO-NH-; An1,An2和An3彼此独立地是阴离子; a和b彼此独立地是1至3的数字; m是从0到5000的数字; n是从0到5000的数字; p是1至5000的数字; 其中m + n + p = 3的总和。染料的特征在于它们的色调深度和它们对洗涤的良好牢度性质,例如耐光性,洗发和摩擦。
    • 10. 发明申请
    • POLYMERIC DYES
    • 聚合染料
    • WO2008138726A2
    • 2008-11-20
    • PCT/EP2008/055038
    • 2008-04-25
    • CIBA HOLDING INC.CREMER, ChristianRIGGS, Richard LewisFRÖHLING, BeateMÜLLER, Martin
    • CREMER, ChristianRIGGS, Richard LewisFRÖHLING, BeateMÜLLER, Martin
    • C08G77/22C09B69/10
    • C08G77/26A61K8/11A61K8/26A61K8/898A61K2800/413A61K2800/43A61K2800/434A61Q5/065B82Y5/00C07F7/1836C08G77/22C08L83/08C09B69/008C09B69/101C09B69/103C09B69/106C09B69/107C09B69/109D06P1/0052D06P3/145Y10T428/29
    • A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C 1 -C 18 alkylene, C 2 -C 12 alkenylene, C 5 -C 10 cycloalkylene, C 5 -C 10 arylene, -C 5 -C 10 arylene-(C 1 -C 10 alkylene)-, each of which may be end-capped towards the linkage to Dye by CO, COO, NR 1 , CONR 1 , NR 1 CONR 1 , CS, CSS, CSNR 1 , NR 1 CSNR 1 , O, S, SO, SO 2 , C 5 -C 10 cycloalkylene, C 5 -C 10 arylene; or T is C 3 -C 18 alkylene interrupted, and optionally end- capped towards the linkage to Dye, by CO, COO, NR 1 , CONR 1 , NR 1 CONR 1 , CS, CSS, CSNR 1 , NR 1 CSNR 1 , O, S, SO, -SO 2 -, C 5 -C 10 cycloalkylene, C 5 -C 10 arylene; or is CO; (CH 2 CH 2 -O) 1-5 ; COO; N(R 1 ); CON(R 1 ); O; S; SO; SO 2 ; R 1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl-C 1 - C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); and Dye is a residue of an organic dye, is useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides.
    • 包含至少10个Si原子的高度交联的聚硅氧烷染料,包括至少一个式(I)的部分,其开放的Si键各自连接到氧原子和开放的O形键,其余部分与硅原子连接 聚硅氧烷,其中T是直接键或有机间隔基团,例如C 1 -C 18亚烷基,C 2 -C 3烷基, 亚烷基亚烷基,C 5 -C 10亚环烷基,C 5 -C 10亚芳基 ,-C 5 -C 10亚芳基 - (C 1 -C 10亚烷基) - ,其各自为 可以通过CO,COO,NR 1,CONR 1,NR 1和CON 1连接到染料上, / SUP>,CS,CSS,CSNR ,NR 1,CSNR 1,O,S,SO,SO 2, C 1 -C 5亚烷基,C 5 -C 10亚芳基,C 5 -C 10亚环烷基,C 5 -C 10亚芳基, 或T是C 3 -C 18亚烷基中断,并且任选地通过CO,COO,NR 1至H 2连接到Dye的连接上。 ,CONR 1,NR 1,...,CS,CSS,CSNR 1,NR 1, O,S,SO,-SO 2 - ,C 5 -C 10 - , - C 1 -C 6烷基, 亚环烷基,C 5 -C 10亚芳基; 或是CO; (CH 2 CH 2 -O) 1-5 ; COO; N(R 1 ); CON(R 1 ); O; S; 所以; SO 2 ; R 1是氢; 未取代或取代的直链或支链单环或多环,间断或不间断的C 1 -C 14烷基; ç 2 -C 14 烯基; ç 6 -C 10 芳基; C 6 -C 10芳基-C 1 -C 10烷基; C 1 -C 6烷基; 或C 5 -C 10烷基(C 5 -C 10芳基); 染料是有机染料的残留物,可用于染色有机材料,如含角蛋白的纤维,羊毛,皮革,丝绸,纤维素或聚酰胺。