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    • 1. 发明申请
    • NONIONIC SURFACTANT COMPOSITIONS
    • 非离子表面活性剂组合物
    • WO2004106297A2
    • 2004-12-09
    • PCT/US2004/017221
    • 2004-05-28
    • COGNIS CORPORATIONBROWN, David, W.BREINDEL, KennethBROADBENT, Ronald, W.WIGGINS, Michael, S.
    • BROWN, David, W.BREINDEL, KennethBROADBENT, Ronald, W.WIGGINS, Michael, S.
    • C07D
    • A61K31/40C11D1/662C11D1/72C11D1/825
    • Surfactant concentrates containing the following components: I) at least one base-catalyzed reaction product of reactants comprising: A) at least one compound of formula I R 1 (X) 3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R 1 group to form an epoxy group, and R 1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R 2 X(AO) n Y (II) wherein R 2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is -0-, -S-, or -NR 3 - where R 3 is hydrogen or a C1-C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-buyleneoxy group, n is a number of from 0 to 200, preferably from 1 to 100, more preferably from 2 to 20; and Y is hydrogen, or Y can be a mercapto group or an amino group (amino or C i-C6 alkylamino group) in place of the terminal -OH group, provided that when Y is mercapto, amino, or a C1-C6 alkylamino group, n is at least 1; and II) at least one nonionic surfactant other than nonionic surfactants of component I).
    • 含有以下组分的表面活性剂浓缩物:I)反应物的至少一种碱催化反应产物,其包含:A)至少一种式IR 1(X)3(I)的化合物,其中每个X基团是卤素原子或一个 X基是卤素原子,两个X基团表示环氧氧原子,其与R 1基团中的两个相邻的碳原子连接以形成环氧基,R 1是含有3〜 10个碳原子; 和B)至少一种具有式II R 2 X(AO)n Y(II)的化合物,其中R 2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O - , - S-或-NR 3 - ,其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基,1,2-亚丙氧基或1,2-二烃基氧基,n为0至200,优选1至100,更优选2至20的数; Y是氢,Y可以是巯基或氨基(氨基或C 1 -C 6烷基氨基)代替末端-OH基团,条件是当Y是巯基,氨基或C 1 -C 6烷基氨基 组,n至少为1; 和II)除了组分I)的非离子表面活性剂之外的至少一种非离子表面活性剂。
    • 3. 发明申请
    • POLYFLUORINATED COMPOUNDS USEFUL AS SURFACTANTS, FOAM CONTROL AGENTS AND/OR RHEOLOGY MODIFIERS
    • 多氟化合物作为表面活性剂,泡沫控制剂和/或流变性改性剂有用
    • WO2005033075A2
    • 2005-04-14
    • PCT/US2004/005899
    • 2004-02-27
    • COGNIS CORPORATIONBROWN, David, W.BREINDEL, KennethBROADBENT, Ronald, W.WIGGINS, Michael, S.
    • BROWN, David, W.BREINDEL, KennethBROADBENT, Ronald, W.WIGGINS, Michael, S.
    • C07D
    • C07C41/03C07C43/11C08G65/2639C08G65/337C08L71/03C09D5/024C09D7/65Y10T428/25C07C43/23
    • Reaction products prepared by processes which comprise reacting: a) at least one compounds having the general formula (I): R 1 (X) 3 wherein each X group independently represents a halogen atom or one X group represents a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R 1 group to form an epoxy group, and R 1 is an alkanetriyl group having from 3 to 10 carbon atoms; and B) at least one compound having the general formula (II): R 2 X(AO) n Y wherein R 2 represents a polyfluorinated organic group having from 1 to 36 carbon atoms and at least two fluorine atoms; X represents -O-, -S-, or NR 3 - where R 3 is hydrogen or a C 1 -C 18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y represents hydrogen, a mercapto group, an amino group or a C 1 -C 6 alkylamino group in place of a terminal -OH group, with the proviso that when Y is a mercapto, amino, or a C 1 -C 6 alkylamino group, n is at least 1; are described.
    • 通过以下方法制备的反应产物:a)至少一种具有通式(I)的化合物:R 1(X)3,其中每个X基团独立地表示卤素原子或一个X基团表示卤素原子,两个 X基团表示环氧氧原子,其与R 1基团中的两个相邻的碳原子连接以形成环氧基,R 1是具有3至10个碳原子的烷三基; 和B)至少一种具有通式(II)的化合物:R 2 X(AO)n Y其中R 2表示具有1至36个碳原子和至少两个氟原子的多氟化有机基团; X表示-O - , - S-或NR 3 - ,其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基,1,2-亚丙氧基或1,2-亚丁氧基,n为0至200的数; 并且Y表示氢,巯基,氨基或C1-C6烷基氨基代替末端-OH基团,条件是当Y为巯基,氨基或C 1 -C 6烷基氨基时,n为 至少1; 被描述。
    • 4. 发明申请
    • POLYMERIC THICKENERS FOR AQUEOUS COMPOSITIONS
    • 聚合物增稠剂用于水性组合物
    • WO1997021743A1
    • 1997-06-19
    • PCT/US1996019136
    • 1996-12-04
    • HENKEL CORPORATIONBROADBENT, Ronald, W.BREINDEL, Kenneth
    • HENKEL CORPORATION
    • C08F20/00
    • C08L71/02C08G65/329C09D7/44C08L75/04
    • Latexes are thicknened by a blend of a urethane compound effective as an associative thickener and a non-urethane compound of the formula: R -(O-A)a-B -R -(B -R )d-(B -(A'-O)b-f-(A'-B )f-R -(B -R )e)n-B -(A"O)c-R , wherein R and R are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group; R and R are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent; R and R are independently selected from hydrogen, lower alkyl and lower aralkyl; B , B , B , B , B and B are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage -O-), a carboxylated group (to form an ester linkage R -C(O)-O- and/or R -C(O)-O-, an amino group to form the amine linkage R -N(R)- and/or R -N(R)-, wherein R is hydrogen, lower alkyl, lower aralky, or lower acyl), and an amido group (to form the amide linkage R -N(R)-C(O)- and or R -N(R)-C(O)-, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl); each of a, b, c, d, e, f and n are integers, wherein each of a and c are independently any integer from greater than 20 to about 200; b is any integer from greater than 20 to about 450; d, e, and f are zero or 1; and n is any integer from 1 to about 5; and each of A, A' and A'' is independently an ethylene, 1,2-propylene, 1,2-butylene unit or combinations thereof.
    • 通过有效作为缔合增稠剂的氨基甲酸酯化合物和下式的非氨基甲酸酯化合物的混合物使乳胶变稠:R 1 - (OA)a B 1 -R 2 - (B 2 -R <3>)D-(B <3> - (A'-O)BF-(A'-B <4>)FR <4> - (B <5> -R <5>)e)NB的<6 - (A“O)c R 6,其中R 1和R 6是独立地选自脂族基团,取代的脂族基团,芳族基团和取代的芳香族基团的一价疏水基团 基团; R 2和R 4独立地选自脂族,取代的脂族,芳族或取代的芳族基团,每个基团是二价或三价的; R 3和R 5独立地选自 低级烷基和低级芳烷基; B 1,B 2,B 3,B 4,B 5和B 6是独立地选自氧, 原子(形成醚键-O-),羧基(形成酯键R 2 -C(O)-O-和/或R 4 -C(O)-O-, 氨基形成胺l 油墨R 2 -N(R) - 和/或R 4 -N(R) - ,其中R是氢,低级烷基,低级芳基或低级酰基)和酰胺基(形成酰胺 连接R 2 -N(R)-C(O) - 和/或R 4 -N(R)-C(O) - ,其中R是氢,低级烷基,低级芳烷基或低级酰基)。 a,b,c,d,e,f和n中的每一个为整数,其中a和c各自独立地为大于20至约200的任何整数; b是大于20至约450的任何整数; d,e和f为零或1; n为1〜5的整数; A,A'和A“各自独立地为乙烯,1,2-亚丙基,1,2-亚丁基单元或其组合。
    • 5. 发明申请
    • NONIONIC SURFACTANT COMPOSITIONS
    • 非离子表面活性剂组合物
    • WO2004106297A3
    • 2005-05-12
    • PCT/US2004017221
    • 2004-05-28
    • COGNIS CORPBROWN DAVID WBREINDEL KENNETHBROADBENT RONALD WWIGGINS MICHAEL S
    • BROWN DAVID WBREINDEL KENNETHBROADBENT RONALD WWIGGINS MICHAEL S
    • A61K31/40C07D20060101
    • A61K31/40C11D1/662C11D1/72C11D1/825
    • Surfactant concentrates containing the following components: I) at least one base-catalyzed reaction product of reactants comprising: A) at least one compound of formula I R (X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R group to form an epoxy group, and R is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R X(AO)nY (II) wherein R is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is -0-, -S-, or -NR - where R is hydrogen or a C1-C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-buyleneoxy group, n is a number of from 0 to 200, preferably from 1 to 100, more preferably from 2 to 20; and Y is hydrogen, or Y can be a mercapto group or an amino group (amino or C i-C6 alkylamino group) in place of the terminal -OH group, provided that when Y is mercapto, amino, or a C1-C6 alkylamino group, n is at least 1; and II) at least one nonionic surfactant other than nonionic surfactants of component I).
    • 含有以下组分的表面活性剂浓缩物:I)反应物的至少一种碱催化反应产物,其包含:A)至少一种式IR 1(X)3(I)的化合物,其中每个X基团是卤素原子或一个 X基是卤素原子,两个X基团表示环氧氧原子,其与R 1基团中的两个相邻的碳原子连接以形成环氧基,R 1是含有3〜 10个碳原子; 和B)至少一种具有式II R 2 X(AO)n Y(II)的化合物,其中R 2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O - , - S-或-NR 3 - ,其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基,1,2-亚丙氧基或1,2-二烃基氧基,n为0至200,优选1至100,更优选2至20的数; Y是氢,Y可以是巯基或氨基(氨基或C 1 -C 6烷基氨基)代替末端-OH基团,条件是当Y是巯基,氨基或C 1 -C 6烷基氨基 组,n至少为1; 和II)除了组分I)的非离子表面活性剂之外的至少一种非离子表面活性剂。