摘要:
Latexes are thicknened by a blend of a urethane compound effective as an associative thickener and a non-urethane compound of the formula: R -(O-A)a-B -R -(B -R )d-(B -(A'-O)b-f-(A'-B )f-R -(B -R )e)n-B -(A"O)c-R , wherein R and R are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group; R and R are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent; R and R are independently selected from hydrogen, lower alkyl and lower aralkyl; B , B , B , B , B and B are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage -O-), a carboxylated group (to form an ester linkage R -C(O)-O- and/or R -C(O)-O-, an amino group to form the amine linkage R -N(R)- and/or R -N(R)-, wherein R is hydrogen, lower alkyl, lower aralky, or lower acyl), and an amido group (to form the amide linkage R -N(R)-C(O)- and or R -N(R)-C(O)-, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl); each of a, b, c, d, e, f and n are integers, wherein each of a and c are independently any integer from greater than 20 to about 200; b is any integer from greater than 20 to about 450; d, e, and f are zero or 1; and n is any integer from 1 to about 5; and each of A, A' and A'' is independently an ethylene, 1,2-propylene, 1,2-butylene unit or combinations thereof.
摘要(中):
通过有效作为缔合增稠剂的氨基甲酸酯化合物和下式的非氨基甲酸酯化合物的混合物使乳胶变稠:R 1 - (OA)a B 1 -R 2 - (B 2 -R <3>)D-(B <3> - (A'-O)BF-(A'-B <4>)FR <4> - (B <5> -R <5>)e)NB的<6 - (A“O)c R 6,其中R 1和R 6是独立地选自脂族基团,取代的脂族基团,芳族基团和取代的芳香族基团的一价疏水基团 基团; R 2和R 4独立地选自脂族,取代的脂族,芳族或取代的芳族基团,每个基团是二价或三价的; R 3和R 5独立地选自 低级烷基和低级芳烷基; B 1,B 2,B 3,B 4,B 5和B 6是独立地选自氧, 原子(形成醚键-O-),羧基(形成酯键R 2 -C(O)-O-和/或R 4 -C(O)-O-, 氨基形成胺l 油墨R 2 -N(R) - 和/或R 4 -N(R) - ,其中R是氢,低级烷基,低级芳基或低级酰基)和酰胺基(形成酰胺 连接R 2 -N(R)-C(O) - 和/或R 4 -N(R)-C(O) - ,其中R是氢,低级烷基,低级芳烷基或低级酰基)。 a,b,c,d,e,f和n中的每一个为整数,其中a和c各自独立地为大于20至约200的任何整数; b是大于20至约450的任何整数; d,e和f为零或1; n为1〜5的整数; A,A'和A“各自独立地为乙烯,1,2-亚丙基,1,2-亚丁基单元或其组合。