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1. 发明授权

US07420078B2 Process for the preparation of intermediates useful in the synthesis of statin derivatives especially 7-amino 3,5-dihydroxy heptanoic acid derivatives, and intermediates thereof 有权
标题翻译：制备可用于合成他汀类衍生物，特别是7-氨基3,5-二羟基庚酸衍生物的中间体的方法及其中间体
公开(公告)号：US07420078B2
公开(公告)日：2008-09-02
申请号：US10482463
申请日：2002-07-02
申请人： Reinhold Öhrlein , Gabriele Baisch , Nicole End , Stephan Burkhardt , Martin Studer
发明人： Reinhold Öhrlein , Gabriele Baisch , Nicole End , Stephan Burkhardt , Martin Studer
IPC分类号： C07C69/66 , C07C259/06 , C07C69/22
CPC分类号： C07C235/74 , C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C12P7/62 , Y02P20/55
摘要： The invention relates to synthesis methods for the preparation of statin derivatives, which methods proceed by way of a key intermediate of formula I wherein X is halogen, acyloxy, activated hydrocarbyloxy, activated hydrocarbylthio or N(CH3)OCH3, Ra is a hydroxy-protecting group, and Rb is a carboxy-protecting group, and, as well as to the compound of formula I, to further intermediates and methods for their preparation by Friedel-Crafts acylation.
摘要翻译：本发明涉及用于制备他汀类衍生物的合成方法，该方法通过式I的关键中间体进行，其中X是卤素，酰氧基，活化的烃氧基，活化的烃基硫基或N（CH 3） OCH 3，R a是羟基保护基，R b是羧基保护基，以及对于式I化合物，其进一步的中间体及其通过Friedel-Crafts酰化制备的方法。

2. 发明授权

US07402675B2 Process for the synthesis of amine ethers from secondary amino oxides 有权
公开(公告)号：US07402675B2
公开(公告)日：2008-07-22
申请号：US10919776
申请日：2004-08-17
申请人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
发明人： Andreas Hafner , Hans Jürg Kirner , Franz Schwarzenbach , Paul Adriaan Van Der Schaaf , Peter Nesvadba
IPC分类号： C07D211/54
CPC分类号： C07D401/14 , C04B35/632 , C07D209/44 , C07D211/94 , C07D217/26 , C07D241/08 , C07D401/12 , C07D405/12 , C08K5/3412
摘要： An amine ether of formula A wherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L; E′ is C1-C36 alkyl; C3-C18 alkenyl; C2-C18 alkinyl; C5-C18 cycloalkyl; C5-C18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C2-C7alkyl or C3-C7alkenyl substituted by halogen; C7-C15 aralkyl or C7-C15 aralkyl substituted by C1-C4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C4-C18alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR21 or C(O)—R22; or T′ is C5-C12cycloalkyl; C5-C12cycloalkyl which is interrupted by at least one O or —NR18—; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR18—; or T′ is —C(G1)(G2)-T″; or C1-C18alkyl or C5-C12cycloalkyl substituted by T″ is hydrogen, halogen, NO2, cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G1 and G2, an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E1-H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

3. 发明授权

US07402639B2 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators 有权
公开(公告)号：US07402639B2
公开(公告)日：2008-07-22
申请号：US11035915
申请日：2005-01-14
申请人： Andreas Kramer , Peter Nesvadba
发明人： Andreas Kramer , Peter Nesvadba
IPC分类号： C08F2/38 , C08F2/50 , C08F4/00
CPC分类号： C07D211/46 , C07D211/74 , C07D211/94 , C08F4/00
摘要： The present invention relates to 1-alkoxy-polyalkyl-peridine derivatives containing a structural element of formula (I) G1, G2, G3, G4 are independently C1-C6alkyl with the proviso that at least one is not methyl or G1 and G2 or G3 and G4, or G1 and G2 and G3 and G4 together form a C5-C12cycloalkyl group; G5, G6 independently are H, C1-C18alkyl, phenyl, naphthyl or a group COOC1-C18alkyl and X represents a group such that the free radical X• derived from X is capable of initiating polymerization of ethylenically unsaturated monomers, with the proviso that compounds A1 and A2 are excluded Further subjects of the invention are a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a 1-alkoxy-polyalkyl-piperidine derivative, a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-polyalkyl-piperidine derivatives for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X•, as well as a process for polymerization are also subjects of the present invention.

4. 发明授权

US07374387B2 Method and arrangement for emptying big bags 失效
标题翻译：排空大袋的方法和布置
公开(公告)号：US07374387B2
公开(公告)日：2008-05-20
申请号：US10574765
申请日：2004-10-07
申请人： Rolf Strub , Wan-Chang Chiu
发明人： Rolf Strub , Wan-Chang Chiu
IPC分类号： B65B69/00
CPC分类号： B65B69/0075
摘要： A method and an arrangement are provided for emptying a Big Bag or similar transport container which is filled with pourable, especially pulverized goods which are not to come into contact with their surroundings, wherein the Big Bag is inserted in a sluice means (2) which is closed off from the surroundings, with simultaneous sealing of the sluice means, which communicates with a processing container (3) for receiving the contents of the Big Bag, whereupon the Big Bag is cut open inside the sluice means by a cutting means (6) provided therein.The empty Big Bag is compressed in a removal zone (A) inside the sluice means (2) and removed into a plastic sack (8) attached to the sluice means (2).
摘要翻译：提供了一种用于排空大袋或类似运输容器的方法和装置，该运输容器填充有可倾倒的，特别是不与其周围环境接触的粉碎物品，其中大袋被插入闸门装置（2）中，与周围封闭，同时密封与用于接收大袋内容物的处理容器（3）连通的闸门装置，于是大袋通过切割装置（6）在闸门装置内被切开）。空的大袋在闸门装置（2）内的去除区（A）中被压缩，并被移除到附接到闸门装置（2）的塑料袋（8）中。

5. 发明授权

US07368525B2 Polymeric alkoyamines prepared by atom transfer radical addition (ATRA) 失效
标题翻译：通过原子转移自由基加成（ATRA）制备的聚合烷基胺
公开(公告)号：US07368525B2
公开(公告)日：2008-05-06
申请号：US10526693
申请日：2003-09-16
申请人： Peter Nesvadba , Lucienne Bugnon
发明人： Peter Nesvadba , Lucienne Bugnon
IPC分类号： C08G73/56 , C08K5/34 , C08K15/00 , C08F4/00 , C08F4/40
CPC分类号： C08F4/00 , C08K5/3435
摘要： The instant invention pertains to polymeric alkoxyamines, which are prepared by atom transfer radical addition polymerization (ATRA). Further aspects of the invention are a process for their preparation and their use as light stabilizers, flame retardants and polymerization regulators/initiators in controlled radical polymerization processes. Yet another aspect of the invention are novel monomeric intermediate alkoxyamines, which are also useful as polymerization regulators/initiators.
摘要翻译：本发明涉及通过原子转移自由基加成聚合（ATRA）制备的聚合烷氧基胺。本发明的其它方面是其制备方法及其作为受控自由基聚合方法中的光稳定剂，阻燃剂和聚合调节剂/引发剂的用途。本发明的另一方面是新颖的单体中间体烷氧基胺，其也可用作聚合调节剂/引发剂。

6. 发明授权

US07354572B2 Method of dyeing keratin-containing fibres 失效
标题翻译：染色含角蛋白纤维的方法
公开(公告)号：US07354572B2
公开(公告)日：2008-04-08
申请号：US10491855
申请日：2001-10-10
申请人： Peter Möckli
发明人： Peter Möckli
IPC分类号： A61Q5/12 , A61K8/18 , A61K8/00 , C09B44/10
CPC分类号： A61Q5/065 , A61K8/4946
摘要： A method of dyeing keratin-containing fibers, especially human hair, which comprises using dyes of formula (1), wherein X− is an anion.
摘要翻译：一种染色含角蛋白的纤维，特别是人类头发的方法，其包括使用式（1）的染料，其中X为 - 阴离子。

7. 发明授权

US07344706B2 UV absorber compositions comprising a hydroxyphenyltriazine compound 有权
标题翻译：包含羟基苯基三嗪化合物的紫外线吸收剂组合物
公开(公告)号：US07344706B2
公开(公告)日：2008-03-18
申请号：US10507295
申请日：2003-03-04
申请人： Jürg Haase , Thomas Ehlis , Elek Borsos , Dietmar Hüglin , Bernd Herzog
发明人： Jürg Haase , Thomas Ehlis , Elek Borsos , Dietmar Hüglin , Bernd Herzog
IPC分类号： A61Q17/00 , A61Q17/04 , A61Q19/00 , A61K8/02 , A61K31/53
CPC分类号： A61K8/4966 , A61Q17/04
摘要： UV absorber compositions are described, comprising (a) from 1 to 99% by weight of a hydroxyphenyltriazine compound of formula (I) wherein R1, R2 and R3 are each independently of the others C1-C18alkyl; C2-C10,alkenyl; or phenyl-C1-C4 alkyl; R4 is hydrogen; or C1-C5alkyl; and (b) from 99 to 1% by weight of a further UV absorber selected from the group of (b) hydroxyphenyltriazines that are different from component (a), (b2) benzotriazoles, (b3) dibenzoylmethane derivatives and (b4) camphor derivatives. The compositions are suitable as UV filters in cosmetic compositions
摘要翻译：描述了UV吸收剂组合物，其包含（a）1至99重量％的式（I）的羟基苯基三嗪化合物，其中R 1，R 2和R 2 > 3 各自独立地为C 1 -C 12烷基; C 2 -C 10，烯基; 或苯基-C 1 -C 4烷基; R 4是氢; 或C 1 -C 5烷基; （b）99〜1重量％的另外的紫外线吸收剂，其选自（b）不同于组分（a），（b-2）苯并三唑的（b）羟基苯基三嗪，（b < （3/4）二苯甲酰甲烷衍生物和（b 4 S）樟脑衍生物。该组合物适用于化妆品组合物中的UV过滤器

8. 发明授权

US07323505B2 Aqueous dispersions for antioxidants 有权
标题翻译：水分散体用于抗氧化剂
公开(公告)号：US07323505B2
公开(公告)日：2008-01-29
申请号：US11387358
申请日：2006-03-23
申请人： Daniel Thibaut
发明人： Daniel Thibaut
IPC分类号： C08K5/105 , C08L29/04
CPC分类号： C08J3/21 , C08F8/00 , C08J3/226 , C08J2329/04 , C08J2429/00 , C08K5/1345 , C09D7/48 , C08F16/06 , C08L29/04
摘要： The present invention relates to aqueous dispersions for solid phenolic antioxidants, wherein the antioxidants are dispersed in the aqueous phase with polyvinyl alcohol as dispersing agent. The invention also relates to a process, which comprises stabilising a polymer material against oxidative, thermal or light-induced degradation by adding to the polymer the aqueous dispersion.
摘要翻译：本发明涉及固体酚类抗氧化剂的水性分散体，其中抗氧化剂以聚乙烯醇作为分散剂分散在水相中。本发明还涉及一种方法，其包括通过向聚合物中加入水性分散体来稳定聚合物材料以抵抗氧化，热或光诱导的降解。

9. 发明授权

US07288585B2 Acrylic dispersing agents in nanocomposites 有权
标题翻译：丙烯酸分散剂纳米复合材料
公开(公告)号：US07288585B2
公开(公告)日：2007-10-30
申请号：US10561297
申请日：2004-06-14
申请人： Graeme Moad , George Philip Simon , Katherine Maree Dean , Guoxin Li , Roshan Tyrrel Anton Mayadunne , Ezio Rizzardo , Richard Alexander Evans , Hendrik Wermter , Rudolf Pfaendner
发明人： Graeme Moad , George Philip Simon , Katherine Maree Dean , Guoxin Li , Roshan Tyrrel Anton Mayadunne , Ezio Rizzardo , Richard Alexander Evans , Hendrik Wermter , Rudolf Pfaendner
IPC分类号： C08K5/10 , C08K5/101
CPC分类号： B82Y30/00 , C08K3/34 , C08K3/346 , C08K7/00 , C08K2201/011 , C08L23/02 , C08L23/08 , C08L23/10 , C08L33/06 , C08L83/02 , C08L2666/04
摘要： The instant invention discloses a composition, preferably a nanocomposite material, comprising (a) a synthetic polymer, (b) a filler such as for example a natural or synthetic phyllosilicate or a mixture of such phyllosilicates, preferably in nanoparticles, and (c) as dispersing agent a polymer based on a long chain alkyl meth(acryte).
摘要翻译：本发明公开了一种组合物，优选纳米复合材料，其包含（a）合成聚合物，（b）填料，例如天然或合成页硅酸盐或这种页硅酸盐的混合物，优选在纳米颗粒中，和（c）作为分散剂是基于长链烷基甲基丙烯酸酯（acryte）的聚合物。

10. 发明授权

US07265171B2 Transparent polymer articles of low thickness 有权
标题翻译：透明聚合物制品的低厚度
公开(公告)号：US07265171B2
公开(公告)日：2007-09-04
申请号：US11359228
申请日：2006-02-22
申请人： David George Leppard , François Gugumus , Michela Bonora
发明人： David George Leppard , François Gugumus , Michela Bonora
IPC分类号： C08K5/34 , C08K5/3492 , C08K5/3435
CPC分类号： C08K5/3492 , C07D251/24 , C08J5/18 , C08J2323/06 , C08J2323/12 , C08K5/34 , Y10T428/24 , Y10T428/298 , C08L23/02
摘要： The novel transparent polyolefin, polyester or polyamide article disclosed is stabilized against the effects of light, oxygen, heat and agressive chemicals by addition of 0.005-0.30% by weight the polymeric substrate of a hydroxyphenyl triazine UV absorber, and is characterized by its thickness between 1 and 500 μm. Preferred polyolefin articles thus stabilized are agricultural films containing as further stabilizer a sterically hindered amine. The novel compositions act as selective UV filter especially useful in agriculture.
摘要翻译：所公开的新型透明聚烯烃，聚酯或聚酰胺制品通过加入羟基苯基三嗪紫外线吸收剂的聚合物基质0.005-0.30重量％来抵抗光，氧，热和侵蚀性化学品的影响，其特征在于其厚度在 1和500个妈妈。如此稳定的优选聚烯烃制品是含有空间位阻胺作为其它稳定剂的农业膜。该新型组合物作为选择性UV过滤器特别适用于农业。

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