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    • 1. 发明授权
    • Method of dyeing keratin-containing fibres
    • US07189268B2
    • 2007-03-13
    • US11235912
    • 2005-09-27
    • Peter Möckli
    • Peter Möckli
    • A61K7/13
    • A61Q5/065A61K8/4946C09B44/16
    • A method of dyeing keratin-containing fibres, which comprises using a dye of formula wherein R1 and R2 are each independently of the other hydrogen, C1–C4alkyl, halogen or nitro, R3 and R4 are each independently of the other unsubstituted C1–C4alkyl or C1–C4alkyl substituted by OH, C1–C4alkoxy, halogen, CN or by phenyl, X1 and X2 are each independently of the other hydrogen, C1–C4alkyl, C1–C4alkoxy or halogen, R5 is hydrogen or C1–C4alkyl, R6 is C5–C12alkyl or C5–C8cycloalkyl each unsubstituted or substituted by OH, C1–C4alkoxy, halogen, CN or phenyl, or R6 is C1–C4alkyl substituted by phenyl or by C5–C8cycloalkyl, or wherein R5 and R6 together with the nitrogen atom linking them form a piperazine ring, which is substituted, at the nitrogen atom that is not bonded to the phenyl group, by C1–C8-alkyl or phenyl, or which is quaternised at that nitrogen atom by two such groups, the C1–C8-alkyl radicals and phenyl mentioned as substituents of the nitrogen atom of the piperazine ring being unsubstituted or substituted by OH, C1–C4alkoxy, halogen, CN or phenyl, and wherein X− is an anion.
    • 2. 发明授权
    • Cationic imidazole azo dyes
    • 阳离子咪唑偶氮染料
    • US06762287B2
    • 2004-07-13
    • US10398823
    • 2003-04-10
    • Peter Möckli
    • Peter Möckli
    • C09B4416
    • A61Q5/065A61K8/4946C09B44/16
    • Dyes of formula (1) or (2) wherein R1, R1′, R2 and R2′ are each independently of the others hydrogen, C1-C4alkyl, halogen or nitro, R3, R3′, R4 and R4′ are each independently of the others C1-C4alkyl unsubstituted or substituted by OH, C1-C4alkoxy, halogen, CN or phenyl, R5 is hydrogen or C1-C4alkyl, R6 is unsubstituted or amino-substituted C5-C12alkyl; or unsubstituted or amino-substituted C5-C8cycloalkyl; or phenyl-substituted C1-C4alkyl; or wherein R5 and R6 together with the nitrogen atom linking them from a piperazine ring, which is substituted, at the nitrogen atom that is not bonded to the phenyl group, by C1-C4-alkyl or phenyl, the alkyl and phenyl radicals mentioned as substituents of the nitrogen atom of the piperazine ring being unsubstituted or substituted by amino, X1, X2, X3 and X4 are each independently of the others hydrogen, C1-C4alkyl, C1-C4alkoxy or halogen, Y1 is a bridging member of formula (I) or —NH—(CH2)6—NH—, and X− is an anion, as wels as methods of dyeing or printing textile materials, leather, paper or glass fibres with those dyes, are described.
    • 式(1)或(2)的染料其中R1,R1',R2和R2'各自独立地为氢,C1-C4烷基,卤素或硝基,R3,R3',R4和R4'各自独立地为 另外未被取代或被OH,C1-C4烷氧基,卤素,CN或苯基取代的C1-C4烷基,R5是氢或C1-C4烷基,R6是未取代的或氨基取代的C5-C12烷基; 或未取代的或氨基取代的C 5 -C 8环烷基; 或苯基取代的C 1 -C 4烷基; 或者其中R 5和R 6与氮原子一起连接它们与在不与苯基键合的氮原子上的哌嗪环上被C1-C4烷基或苯基连接,烷基和苯基被提及为 哌嗪环的氮原子的取代基未被取代或被氨基,X 1,X 2,X 3和X 4取代,各自独立地为氢,C 1 -C 4烷基,C 1 -C 4烷氧基或卤素,Y 1为式(I )或-NH-(CH 2)6 -NH-,X - 是阴离子,其作为染色或印刷织物,皮革,纸或玻璃纤维与这些染料的方法一样。