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71. 发明授权

US6130285A Binder composition and its use for coating metallic and mineral substrates 失效
标题翻译：粘合剂组合物及其用于涂覆金属和矿物基材的用途
公开(公告)号：US6130285A
公开(公告)日：2000-10-10
申请号：US911510
申请日：1997-08-14
申请人： Martin Melchiors , Jurgen Schwindt , Gerhard Ruttmann , Wieland Hovestadt , Joachim Probst , Josef Pedain
发明人： Martin Melchiors , Jurgen Schwindt , Gerhard Ruttmann , Wieland Hovestadt , Joachim Probst , Josef Pedain
IPC分类号： C08G18/62 , C08G18/40 , C08G18/63 , C09D175/04 , C08L75/00
CPC分类号： C08G18/632 , C08G18/4063 , C08G18/638 , C08G2150/90
摘要： The present invention relates to a solvent-free, low viscosity binder composition which contains, in amounts sufficient to provide an NCO:OH equivalent ratio of 0.5:1 to 2.0:1,A) a polyisocyanate component containing one or more organic polyisocyanates andB) a solvent-free polyhydroxy component having a hydroxyl group content of 3.0 to 18 wt. % and a viscosity at 23.degree. C. of 200 to 10,000 mPa.s, which containsB.sub.1) a hydroxy-functional polyacrylate component which is prepared by polymerizing a mixture of olefinically unsaturated monomers in which at least one monomer is hydroxy-functional in the presence ofB.sub.2) a compound containing ether groups and having one or more hydroxy groups.The invention also relates to the use of this binder composition in solvent-free two-component polyurethane coating compositions for coating metallic or mineral substrates.
摘要翻译：本发明涉及无溶剂的低粘度粘合剂组合物，其含量足以提供0.5：1至2.0：1的NCO:OH当量比，A）含有一种或多种有机多异氰酸酯和B ）无羟基含量为3.0-18重量％的无溶剂多羟基组分％，在23℃下的粘度为200至10,000mPa.s，其含有B1）羟基官能的聚丙烯酸酯组分，其通过聚合烯属不饱和单体的混合物而制备，其中至少一种单体在存在B2）含有醚基并具有一个或多个羟基的化合物。本发明还涉及这种粘合剂组合物在无溶剂双组分聚氨酯涂料组合物中用于涂覆金属或矿物基材的用途。

72. 发明授权

US5563208A Aqueous binder mixture and use thereof 失效
标题翻译：水性粘合剂混合物及其用途
公开(公告)号：US5563208A
公开(公告)日：1996-10-08
申请号：US463526
申请日：1995-06-05
申请人： Eberhard K onig , Josef Pedain
发明人： Eberhard K onig , Josef Pedain
IPC分类号： C08G18/10 , C08G18/08 , C08G18/12 , C08G18/32 , C08G18/65 , C09D175/00 , C09D175/04 , C08J3/00 , B05D3/02 , C08K3/20 , C08L75/00
CPC分类号： C08G18/12 , C08G18/0823
摘要： An aqueous binder mixture comprising substantially an aqueous solution and/or dispersion of a combination of a) at least one NCO prepolymer which is soluble and/or dispersible in water in the presence of component b), exhibits urethane groups and has blocked isocyanate groups, and b) a polyamine component comprising at least one (cyclo)aliphatic polyamine having at least 2 primary and/or secondary amino groups, and the use of the aqueous binder mixture for the preparation of coatings on heat-resistant substrates.
摘要翻译：基本上包含a）至少一种在组分b）存在下可溶和/或可分散在水中的NCO预聚物的水溶液和/或分散体的水性粘合剂混合物显示出氨基甲酸酯基并具有封闭的异氰酸酯基团，和b）包含至少一种具有至少2个伯和/或仲氨基的（环状）脂族多胺的多胺组分，以及所述水性粘合剂混合物用于制备耐热基材上的涂层的用途。

73. 发明授权

US5455297A Water-based coating compositions and their use for the production of flexible coatings 失效
标题翻译：水性涂料组合物及其用于生产柔性涂料的用途
公开(公告)号：US5455297A
公开(公告)日：1995-10-03
申请号：US169943
申请日：1993-12-20
申请人： Josef Pedain , Heino Muller , Dieter Mager , Manfred Schonfelder
发明人： Josef Pedain , Heino Muller , Dieter Mager , Manfred Schonfelder
IPC分类号： C08G18/08 , C08G18/70 , C08G18/80 , C09D5/02 , C09D175/00 , C09D175/04 , C08G18/34
CPC分类号： C08G18/0823 , C08G18/706 , C08G18/8048 , C08G18/8077 , Y10T428/31605
摘要： The present invention relates to a heat-crosslinkable water-based coating composition containing as bindera) a water-soluble or water-dispersible polyol component andb) a water-soluble or water-dispersible blocked polyisocyanate which has an average NCO functionality of 2.0 to 2.6 and is based on the reaction product ofb1) a polyisocyanate mixture having an average NCO functionality of 2.5 to 3.5 and containing (i) at least 15% by weight of an organic diisocyanate,b2) a blocking agent for isocyanate groups in an amount of 50 to 80 equivalent-%, based on the isocyanate groups of component b1) andb3) an aliphatic monohydroxymonocarboxylic acid in a quantity of 20 to 50 equivalent-%, based on the isocyanate groups of component b1) and the hydroxyl groups of component b3), wherein the equivalent ratio, based on the isocyanate-reactive groups of blocking agent b2) and the hydroxyl groups of component b3) to the isocyanate groups of component b1) is at least 0.9:1.
摘要翻译：本发明涉及一种热交联性水性涂料组合物，其包含作为粘合剂的a）水溶性或水分散性多元醇组分和b）具有平均NCO官能度为2.0的水溶性或水分散性封端多异氰酸酯基于b1）具有2.5至3.5的平均NCO官能度并且包含（i）至少15重量％的有机二异氰酸酯的聚异氰酸酯混合物的反应产物，b2）用于异氰酸酯基团的封闭剂基于组分b1）的异氰酸酯基团和基于组分b1）的异氰酸酯基团的b3）相对于基团b1）的异氰酸酯基团的量为20至50当量的脂族单羟基单羧酸的量为50至80当量％组分b3），其中基于组分b1）的异氰酸酯基团的封端剂b2）和组分b3）的羟基的异氰酸酯反应性基团的当量比至少为0.9:1。

74. 发明授权

US5268428A Binder compositions and their use in coating compositions and sealing compositions 失效
标题翻译：粘合剂组合物及其在涂料组合物和密封组合物中的用途
公开(公告)号：US5268428A
公开(公告)日：1993-12-07
申请号：US748297
申请日：1991-08-21
申请人： Christian Wamprecht , Harald Blum , Josef Pedain
发明人： Christian Wamprecht , Harald Blum , Josef Pedain
IPC分类号： C08G59/20 , C08G59/00 , C08G59/32 , C08K5/05 , C08L35/00 , C08L63/00 , C08L75/04 , C09D5/34 , C09D133/14 , C09D163/00 , C09D167/00 , C08F8/14 , C08L33/08
CPC分类号： C09D133/14 , C09D167/00 , C09D5/34 , C08L75/04
摘要： The present invention relates to binder compositions containingA) 10 to 99 parts by weight of a copolymer component containing at least one copolymer prepared from olefinically unsaturated compositions having a weight average molecular weight of 1,500 to 75,000 and having in chemically bound form both(i) 1 to 30% by weight of cyclic carboxylic anhydride groups (calculated as C.sub.4 H.sub.2 O.sub.3) and(ii) 1 to 29% by weight of epoxide groups (calculated as C.sub.2 H.sub.3 O) andB) 1 to 90 parts by weight of a hydroxyl component containing at least one organic polyol having at least two hydroxyl groups per molecule,provided that for every anhydride group of component A) there are 0.1 to 10 hydroxyl groups of component B).The present invention also relates to the use of these binder compositions as binders for heat-curing coating compositions or sealing compositions optionally containing paint auxiliaries and additives or as binders for room-temperature-curing sealing or coating compositions containing catalysts and, optionally, other paint auxiliaries and additives.
摘要翻译：本发明涉及粘合剂组合物，其包含A）10至99重量份的共聚物组分，所述共聚物组分含有至少一种由烯属不饱和组合物制备的共聚物，其重均分子量为1,500至75,000，并具有化学键合形式，（i） 1至30重量％的环状羧酸酐基团（以C 4 H 2 O 3计）和（ii）1至29重量％的环氧基团（以C 2 H 3 O计算）和B）1至90重量份的至少含有至少一个每分子具有至少两个羟基的有机多元醇，条件是对于组分A）的每个酸酐基团，组分B）中都有0.1至10个羟基。本发明还涉及这些粘合剂组合物作为粘合剂用于热固化涂料组合物或任选地含有涂料助剂和添加剂的密封组合物或用作室温固化密封剂的粘合剂或含有催化剂和任选的其它涂料的涂料组合物的粘合剂助剂和助剂。

75. 发明授权

US5189176A Bis-oxazolidines, oxazolidine mixtures consisting essentially thereof and their use as hardeners for plastics precursors containing isocyanate groups 失效
标题翻译： BIS-氧杂环丁烷，氧杂环丁烷混合物及其作为含有异氰酸酯基团的塑料前体的硬化剂
公开(公告)号：US5189176A
公开(公告)日：1993-02-23
申请号：US723863
申请日：1991-07-01
申请人： Harald Blum , Josef Pedain , Karl-Heinz Hentschel
发明人： Harald Blum , Josef Pedain , Karl-Heinz Hentschel
IPC分类号： C07D263/04 , C08G18/32 , C08G18/38
CPC分类号： C07D263/04 , C08G18/3296 , C08G18/3844
摘要： The present invention relates to bis-oxazolidines corresponding to formula (II) ##STR1## wherein R represents a branched, saturated, aliphatic hydrocarbon radical containing 5 to 8 carbon atoms.The present invention also relates to oxazolidine mixtures, which are also suitable as hardeners for plastics precursors containing isocyanate groups, consisting essentially ofa) bis-oxazolidines corresponding to formula (II) above andb) 0.03 to 0.3 moles per mole of component (a), of compounds corresponding to formula (III) ##STR2## wherein R represents a saturated, branched, aliphatic hydrocarbon radical containing 5 to 8 carbon atoms.The present invention additionally relates to a process for the production of these oxazolidine mixtures and to their use in combination with polymer precursors containing isocyanate groups for coating or sealing compositions.
摘要翻译：本发明涉及对应于式（II）的二恶唑烷（II）其中R表示含有5-8个碳原子的支链饱和脂族烃基。本发明还涉及恶唑烷混合物，其也适合作为含有异氰酸酯基团的塑料前体的硬化剂，其基本上由a）对应于上述式（II）的双恶唑烷和b）每摩尔组分0.03至0.3摩尔（a ），对应于式（III）的化合物其中R表示含有5至8个碳原子的饱和支链脂族烃基。本发明还涉及制备这些恶唑烷混合物的方法，以及它们与含有用于涂覆或密封组合物的异氰酸酯基团的聚合物前体组合使用的方法。

76. 发明授权

US5128432A Aliphatic polyurethanes containing acryloyl groups and a process for their preparation 失效
标题翻译：含有丙烯酸酯的聚氨酯和其制备方法
公开(公告)号：US5128432A
公开(公告)日：1992-07-07
申请号：US749235
申请日：1991-08-23
申请人： Jurgen Meixner , Wolfgang Fischer , Josef Pedain
发明人： Jurgen Meixner , Wolfgang Fischer , Josef Pedain
IPC分类号： C08F299/06 , C08G18/28 , C08G18/32 , C08G18/48 , C08G18/67 , C08G18/73 , C09D175/14 , C09D175/16
CPC分类号： C08G18/4887 , C08G18/284 , C08G18/3221 , C08G18/672 , C08G18/673 , C08G18/73 , C09D175/16
摘要： The present invention relates to aliphatic polyurethanes which contain acryloyl groups and are based on the reaction product (at an NCO/OH equivalent ratio of 0.5:1 to 1:1) ofa) 1.0 mole of a diisocyanate component containing at least 50 equivalent percent, based on NCO equivalents, of hexamethylene diisocyanate withb) 0.5 to 0.85 moles of at least one monohydric alcohol having a molecular weight of 116 to 144 and containing acryloyl groups.c) 0.15 to 0.5 moles of a monohydric alcohol having a molecular weight of 154 to 2000 and containing ester groups or a mixture of alcohols having an average molecular weight of 154 to 2000 and an average hydroxyl functionality of 0.8 to 1.5 and containing ester groups andd) 0.3 to 0.5 moles of at least one polyhydric alcohol having a molecular weight of 62 to 2000.The present invention also relates to a process for the preparation of these polyurethanes.
摘要翻译：本发明涉及含有丙烯酰基并基于反应产物（以NCO / OH当量比为0.5:1至1:1）的a）1.0摩尔含至少50当量％的二异氰酸酯组分的脂族聚氨酯基于NCO当量，六亚甲基二异氰酸酯与b）0.5至0.85摩尔的至少一种分子量为116至144的一元醇并含有丙烯酰基。 c）0.15至0.5摩尔分子量为154至2000的一元醇，并且含有酯基或平均分子量为154至2000的醇和0.8至1.5的平均羟基官能度的混合物，并且含有酯基和 d）0.3至0.5摩尔的至少一种分子量为62至2000的多元醇。本发明还涉及制备这些聚氨酯的方法。

77. 发明授权

US5126393A Water-dispersible binder composition, a process for the production of a stoving filler and a coating prepared therefrom 失效
标题翻译：水分散性组合物，生产填充填料的方法及其制备的涂料
公开(公告)号：US5126393A
公开(公告)日：1992-06-30
申请号：US602595
申请日：1990-10-24
申请人： Harald Blum , Jurgen Meixner , Josef Pedain , Hans-Heribert Burgdorfer
发明人： Harald Blum , Jurgen Meixner , Josef Pedain , Hans-Heribert Burgdorfer
IPC分类号： C08G18/00 , B01F17/42 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/42 , C08G18/66 , C08G18/75 , C09D161/20 , C09D175/06
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/423 , C08G18/4288 , C08G18/6659 , C08G18/75 , C09D175/06
摘要： The present invention relates to a water-dispersible binder composition which is suitable for the production of a stoving filler to be processed from the aqueous phase and which containsa) 65 to 95% by weight of a urethane-modified polyester resin containing carboxyl groups,b) 5 to 35% by weight of a crosslinker resin andc) 0 to 2% by weight of an emulsifier,wherein the percentages are based on the total weight of components a) to c), characterized in that component a) has an acid value of 15 to 36, a hydroxyl value of at least 40 and a molecular weight (M.sub.w) of 5,000 to 50,000 and has been obtained by reactinga1) 72 to 80% by weight of a polyester polyol having a hydroxyl value of 130 to 200 and an acid value of 1 to 5 anda2) 4 to 7% by weight of a 2,2-bis-(hydroxymethyl)-alkane carboxylic acid or a quantity corresponding to this quantity of acid of a tertiary amine salt of such an acid witha3) 15 to 24% by weight of at least one cycloaliphatic diisocyanate having a molecular weight of 166 to 294,wherein the percentages are based on the total weight of components a1) to a3).The present invention also relates to a process for the production of an aqueous stoving filler which is suitable for the production of chip resistant coatings and to the chip resistant coatings produced therefrom.
摘要翻译：本发明涉及一种水分散性粘合剂组合物，其适用于从水相制备待加工的烘干填料，其含有a）65至95重量％的含有羧基的氨基甲酸酯改性的聚酯树脂， b）5〜35重量％的交联剂树脂和c）0〜2重量％的乳化剂，其中所述百分比基于组分a）至c）的总重量，其特征在于组分a）具有酸值为15〜36，羟基值为40以上，分子量（Mw）为5,000〜50,000，通过使a1〜72〜80重量％的羟基值为130的聚酯多元醇与 200，酸值1〜5，a2）4〜7重量％的2,2-双 - （羟甲基） - 烷烃羧酸，或相当于该量的这种叔胺盐的酸量酸与a3）15至24重量％的至少一种具有分子的脂环族二异氰酸酯 166至294的百分比，其中百分比基于组分a1）至a3）的总重量。本发明还涉及一种用于生产水性烘干填料的方法，该方法适用于生产耐屑涂层和由其制备的耐芯片涂层。

78. 发明授权

US5095066A Hydrophilic polyurethanes containing (meth)acryloyl groups, their use as reactive emulsifiers for radically curable synthetic resins, water-dispersible mixture of radically curable synthetic resins and an aqueous coating composition based on this mixture 失效
标题翻译：含有（甲基）丙烯酸基团的亲水性聚氨酯，它们作为无机可固化合成树脂的反应性乳化剂，可溶性合成树脂的水分散混合物和基于该混合物的水性涂料组合物
公开(公告)号：US5095066A
公开(公告)日：1992-03-10
申请号：US456539
申请日：1989-12-26
申请人： Jurgen Meixner , Josef Pedain , Wolfgang Fischer
发明人： Jurgen Meixner , Josef Pedain , Wolfgang Fischer
IPC分类号： C08F299/06 , B01F17/52 , C08F290/00 , C08G18/48 , C08G18/67 , C08G18/81 , C09D175/00 , C09D175/14 , C09D175/16
CPC分类号： C08G18/8175 , C08G18/4833 , C09D175/16
摘要： A polyurethane is disclosed having improved properties as a reactive emulsifier for radically-curable synthetic resins. The polyurethane is obtained by the reaction of a) a polyisocyanate component; b) an alcohol component; and c) a polyethylene glycol component. The reactive emulsifiers are useful in aqueous coating compositions.
摘要翻译：公开了具有改进的性质的聚氨酯作为用于可自由基固化的合成树脂的反应性乳化剂。聚氨酯通过a）多异氰酸酯组分的反应获得; b）醇组分; 和c）聚乙二醇组分。反应性乳化剂可用于水性涂料组合物。

79. 发明授权

US5068402A Stabilized polyisocyanates 失效
标题翻译：稳定的聚异氰酸酯
公开(公告)号：US5068402A
公开(公告)日：1991-11-26
申请号：US555872
申请日：1990-07-20
申请人： Josef Pedain , Lothar Kahl , Karl-Arnold Weber
发明人： Josef Pedain , Lothar Kahl , Karl-Arnold Weber
IPC分类号： C07C263/18 , C08G18/08 , C08G18/70
CPC分类号： C08G18/089 , C07C263/18 , C08G18/4238 , C08G18/724 , C08G18/73 , C08G18/755 , C08G18/7621
摘要： The present invention is directed to polyisocyanates containing a stabilizing amount of a carboxylic acid corresponding to the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 represent hydrogen or C.sub.1 -C.sub.5 -alkyl andX and Y represent hydrogen, chlorine or methyl, with the proviso that when X=Cl, Y=H or CH.sub.3 and when Y=Cl, X=H or CH.sub.3.The present invention is also directed to the use of the stabilized polyisocyanates as binders for coating compositions, sealing compounds and adhesives.
摘要翻译：本发明涉及含有稳定量的对应于下式的羧酸的多异氰酸酯，其中R1，R2和R3代表氢或C1-C5-烷基，X和Y代表氢，氯或甲基，条件是当X = Cl，Y = H或CH 3，当Y = Cl时，X = H或CH 3。本发明还涉及使用稳定化的多异氰酸酯作为涂料组合物，密封化合物和粘合剂的粘合剂。

80. 发明授权

US4980500A Process for the preparation of biuret polyisocyanates, the compounds obtained by this process and their use 失效
标题翻译：制备缩二脲多异氰酸酯的方法，通过该方法获得的化合物及其用途
公开(公告)号：US4980500A
公开(公告)日：1990-12-25
申请号：US281159
申请日：1988-12-07
申请人： Josef Pedain , Manfred Schonfelder , Manfred Schmidt
发明人： Josef Pedain , Manfred Schonfelder , Manfred Schmidt
IPC分类号： C07C273/18 , C07C275/62 , C08G18/10 , C08G18/42 , C08G18/77 , C08G18/78 , C08G18/79 , C08G18/80
CPC分类号： C08G18/8045 , C08G18/10 , C08G18/42 , C08G18/7831 , C08G18/8016 , C08G18/8038
摘要： The present invention is directed to a process for the preparation of urethane-modified biuret polyisocyanates by the reaction of(a) 1,6-diisocyanatohexane with subequivalent quantities of(b) biuretizing agents based on water and/or organic compounds which react with isocyanate groups to form biuret groups,to form biurets followed by removal of the unreacted, excess 1,6-diisocyanatohexane and any volatile components present, characterized in that at any stage before removal of the excess 1,6-diisocyanate,(c) at least one diol containing ester groups and having an average molecular weight of about 350 to 950 is added to the reaction mixture in a quantity of about 1 to 50% by weight, based on the weight of the 1,6-diisocyanatohexane, the diol reacting with part of the isocyanate groups present to form urethane groups.The invention is also directed to the urethane-modified biuret polyisocyanates obtained by this process and their use as polyisocyanate components in two-component polyurethane lacquers.
摘要翻译：本发明涉及通过（a）1,6-二异氰酸根合己烷与基于与异氰酸酯反应的水和/或有机化合物的（b）缩二脲化合物的反应制备氨基甲酸酯改性的缩二脲多异氰酸酯的方法组合形成缩二脲基团，形成缩二脲，然后除去未反应的过量1,6-二异氰酸根合己烷和存在的任何挥发性组分，其特征在于在去除过量的1,6-二异氰酸酯之前的任何阶段，（c）至少一元醇含有酯基并且平均分子量为约350至950的反应混合物中加入约1至50重量％，基于1,6-二异氰酸根合己烷的重量，二醇与存在的部分异氰酸酯基团形成氨基甲酸酯基团。本发明还涉及通过该方法获得的氨基甲酸酯改性的缩二脲多异氰酸酯及其在双组分聚氨酯漆中作为多异氰酸酯组分的用途。

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