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    • 65. 发明授权
    • Resistance-switching memory cell with heavily doped metal oxide layer
    • 具有重掺杂金属氧化物层的电阻切换存储单元
    • US08487292B2
    • 2013-07-16
    • US12842798
    • 2010-07-23
    • Deepak C. SekarFranz Kreupl
    • Deepak C. SekarFranz Kreupl
    • H01L47/00
    • H01L45/146G11C13/0007G11C2213/35G11C2213/71H01L27/1021H01L27/2409H01L27/2463H01L27/2481H01L45/08H01L45/1233H01L45/145H01L45/1641H01L45/1675
    • A non-volatile resistance-switching memory element includes a resistance-switching element formed from a metal oxide layer having a dopant which is provided at a relatively high concentration such as 10% or greater. Further, the dopant is a cation having a relatively large ionic radius such as 70 picometers or greater, such as Magnesium, Chromium, Calcium, Scandium or Yttrium. A cubic fluorite phase lattice may be formed in the metal oxide even at room temperature so that switching power may be reduced. The memory element may be pillar-shaped, extending between first and second electrodes and being in series with a steering element such as a diode. The metal oxide layer may be deposited at the same time as the dopant. Or, using atomic layer deposition, an oxide of a first metal can be deposited, followed by an oxide of a second metal, followed by annealing to cause intermixing, in repeated cycles.
    • 非易失性电阻切换存储元件包括由具有以比较高的浓度(例如10%以上)设置的掺杂剂的金属氧化物层形成的电阻切换元件。 此外,掺杂剂是诸如镁,铬,钙,钪或钇之类的诸如70皮度或更大的离子半径相对较大的阳离子。 即使在室温下也可以在金属氧化物中形成立方萤石相晶格,从而可以降低开关功率。 存储元件可以是柱形的,在第一和第二电极之间延伸并且与诸如二极管的转向元件串联。 金属氧化物层可以与掺杂剂同时沉积。 或者,使用原子层沉积,可沉积第一金属的氧化物,然后沉积第二金属的氧化物,然后在重复循环中进行退火以引起混合。