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61. 发明授权

US5436033A Method of manufacturing a polymer ultra thin film electret 失效
标题翻译：制造聚合物超薄膜驻极体的方法
公开(公告)号：US5436033A
公开(公告)日：1995-07-25
申请号：US284735
申请日：1994-08-01
申请人： Norihisa Mino , Yoshikazu Yamagata , Kazufumi Ogawa
发明人： Norihisa Mino , Yoshikazu Yamagata , Kazufumi Ogawa
IPC分类号： B29C41/12 , B29L9/00 , B29L31/34 , C08J5/18 , C08J7/00 , H01G7/02 , B05D3/06
CPC分类号： H01G7/023 , B82Y30/00 , B82Y40/00
摘要： The invention concerns an ultra thin polymer film electret comprising a polymer and a substrate having a surface electric charge, wherein a side chain of the polymer and the substrate are physically or chemically bonded. A method of manufacturing an ultra thin polymer film electret comprising: adsorbing a monomolecular film comprising a unsaturated group or a laminated film comprising the monomolecular film on to a substrate surface, irradiating the monomolecular film or the laminated film with an energy beam to polymerize the unsaturated groups and applying a high voltage to the film is also disclosed. Further, a method of manufacturing an ultra thin polymer film electret comprising: physically bonding a side chain of the polymer to a substrate surface to form a thin film and applying a high voltage to the thin film is also disclosed.
摘要翻译：本发明涉及一种包含聚合物和具有表面电荷的基底的超薄聚合物膜驻极体，其中聚合物和基底的侧链物理或化学键合。一种制造超薄聚合物膜驻极体的方法，包括：将包含不饱和基团的单分子膜或包含单分子膜的层压膜吸附到基材表面上，用能量束照射单分子膜或层压膜以聚合不饱和并且还公开了向薄膜施加高电压的组。此外，还公开了一种制造超薄聚合物膜驻极体的方法，其包括：将聚合物的侧链物理结合到基板表面以形成薄膜并向薄膜施加高电压。

62. 发明授权

US5425988A Recording and reproducing device which includes a protective film and a monomolecular fluoro organo silicon film 失效
标题翻译：包括保护膜和单分子氟有机硅膜的记录和再现装置
公开(公告)号：US5425988A
公开(公告)日：1995-06-20
申请号：US127288
申请日：1993-09-27
申请人： Kazufumi Ogawa , Norihisa Mino , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Yasuhisa Tanaka
发明人： Kazufumi Ogawa , Norihisa Mino , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Yasuhisa Tanaka
IPC分类号： B05D1/18 , C10M105/76 , C10M107/50 , C10N40/18 , G11B5/187 , G11B5/255 , G11B5/64 , G11B5/72 , G11B5/725 , G11B5/00
CPC分类号： B82Y30/00 , B05D1/185 , B82Y10/00 , B82Y40/00 , G11B5/255 , G11B5/72 , G11B5/725 , Y10S428/90 , Y10T428/261 , Y10T428/268 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663
摘要： A recording and reproducing device is provided. The device comprises a recording medium, a head giving and receiving recording signals to or from the recording medium, and a mechanism section and a circuit section giving and receiving the recording signals, wherein at least one protective film, and at least one fluorine-containing monomolecular film are formed in this order on the recording layer of the recording medium or on the surface of the head which comes into contact with said recording layer, wherein said protective film is a metal film, oxidized metal film, semi-conductor film, oxidized semi-conductor film, or organic monomolecular film, and wherein said fluorine-containing monomolecular film is formed by the chemical adsorption of a specific-type of silane compound that contains a perfluoroalkyl group at the molecular end on the surface of the protective film.
摘要翻译：提供了一种记录和再现装置。该装置包括记录介质，向记录介质提供和接收记录信号的磁头，以及提供和接收记录信号的机构部分和电路部分，其中至少一个保护膜和至少一个含氟单分子膜依次形成在记录介质的记录层上或与记录层接触的头的表面上，其中所述保护膜是金属膜，氧化金属膜，半导体膜，氧化物半导体膜或有机单分子膜，并且其中所述含氟单分子膜通过在保护膜的表面上的分子末端的含有全氟烷基的特定类型的硅烷化合物的化学吸附而形成。

63. 发明授权

US5260115A Organic electro-conductive thin films and process for production thereof 失效
标题翻译：有机导电薄膜及其制造方法
公开(公告)号：US5260115A
公开(公告)日：1993-11-09
申请号：US846160
申请日：1992-03-05
申请人： Norihisa Mino , Kazufumi Ogawa
发明人： Norihisa Mino , Kazufumi Ogawa
IPC分类号： G02F1/361 , H01B1/12 , H01L23/532 , H01L51/30 , B32B3/28
CPC分类号： H01L51/0041 , B82Y20/00 , G02F1/3618 , H01B1/125 , H01L23/5328 , H01L51/0075 , H01L2924/0002 , Y10T428/24479 , Y10T428/2457 , Y10T428/24579 , Y10T428/24612
摘要： The present invention relates to electrical and optical materials, and particularly to organic electro-conductive thin films exhibiting electro-conductivity and non-linear optical effect, and to processes for the production thereof. Further, the above properties and effects depend predominatly on the orientation of molecules constituting the films, and therefore the present invention is for control of the orientation.
摘要翻译：本发明涉及电气和光学材料，特别涉及具有导电性和非线性光学效应的有机导电薄膜及其生产方法。此外，上述性质和效果主要取决于构成膜的分子的取向，因此本发明用于控制取向。

64. 发明授权

US5223331A Organic device and method for producing the same 失效
标题翻译：有机装置及其生产方法
公开(公告)号：US5223331A
公开(公告)日：1993-06-29
申请号：US678436
申请日：1991-04-01
申请人： Kazufumi Ogawa , Norihisa Mino
发明人： Kazufumi Ogawa , Norihisa Mino
IPC分类号： H01L51/05 , C08F38/00 , H01L21/368 , H01L51/00 , H01L51/30
CPC分类号： H01L51/0075 , H01L51/0094 , H01L51/0545 , H01L51/0036 , H01L51/0062 , Y10S428/901 , Y10T428/24917
摘要： The present invention provides an organic device comprising a substrate having a polymerized monomolecular or built-up multi-monomolecular film, a first electrode, a second electrode with said film intervening between the electrodes, a third electrode connected directly or indirectly to the monomolecular or built-up multi-monomolecular film, which device is operated by applying a voltage between the third electrode and the second electrode to control an electric current flowing between the first electrode and the second electrode through said polymerized monomolecular or built-up multi-monomolecular film between the electrodes. If the polymerization of the monomolecular film is eliminated, the device can be imparted with learning functions because the polymerization of the film proceeds depending upon an amount of electricity flowing during the use of the device. Since the present invention makes use of electroconductive groups in the monomolecular or built-up multi-monomolecular film, there can be produced such devices with organic materials as being independent of crystallinity even when any fine processing is performed for further increasing the high packing density of the devices.

65. 发明授权

US4996075A Method for producing ultrathin metal film and ultrathin-thin metal pattern 失效
标题翻译：制作超薄金属薄膜和超薄金属图案的方法
公开(公告)号：US4996075A
公开(公告)日：1991-02-26
申请号：US287090
申请日：1988-12-21
申请人： Kazufumi Ogawa , Hideharu Tamura , Norihisa Mino
发明人： Kazufumi Ogawa , Hideharu Tamura , Norihisa Mino
IPC分类号： G03F7/075 , G03F7/26
CPC分类号： B82Y30/00 , G03F7/0757 , G03F7/265
摘要： A responsive film containing a responsible group occuring a chemical reaction by energy beam is formed on an insulated substrate, and energy beam is irradiated in a pattern, and part of the responsive group is selectively deactivated or activated, and only the remaining portion of the responsive group of the responsive film is coupled with a chemical substance containing metal in a later process, and an ultrafine pattern of metal film is formed.

66. 发明授权

US07259389B2 Organic electronic device and method for manufacturing the same 有权
标题翻译：有机电子器件及其制造方法
公开(公告)号：US07259389B2
公开(公告)日：2007-08-21
申请号：US10503829
申请日：2003-02-07
申请人： Shinichi Yamamoto , Norihisa Mino , Kazufumi Ogawa
发明人： Shinichi Yamamoto , Norihisa Mino , Kazufumi Ogawa
IPC分类号： H01L35/24
CPC分类号： G02F1/13439 , C08G61/122 , G02F1/1343 , G02F2001/136295 , G02F2202/022 , H01L51/0021 , H01L51/0035
摘要： An organic electronic device of the present invention includes a substrate, at least two electrodes formed on the substrate, a conductive organic thin film that is formed on the substrate and electrically connects the electrodes, and a coating film for coating at least a portion of the electrodes. The conductive organic thin film is a polymer of organic molecules containing a conjugated-bondable group, and one end of each of the organic molecules is chemically bonded to the surface of the substrate and the conjugated-bondable groups in the organic molecules are polymerized with other conjugated-bondable groups to form a conjugated bond chain. The coating film electrically connects the electrodes to the conductive organic thin film and achieves a smaller connection resistance than that in the case where the electrodes and the conductive organic thin film are connected directly. As the coating film, a film made of metal selected from gold, platinum, and silver, a conductive polymeric film, or a monomolecular film that is chemically bonded to the electrodes can be used.
摘要翻译：本发明的有机电子器件包括基板，形成在基板上的至少两个电极，形成在基板上并电连接电极的导电有机薄膜，以及用于涂覆至少一部分电极。导电有机薄膜是含有共轭键合基团的有机分子的聚合物，并且每个有机分子的一端化学键合到基底表面，并且有机分子中的共轭键基团与其它分子聚合共轭键合基团以形成共轭键链。涂膜将电极与导电性有机薄膜电连接，与直接连接电极和导电性有机薄膜的情况相比，能够实现较小的连接电阻。作为涂膜，可以使用由金，铂，银等金属制成的膜，导电性聚合物膜，或与电极化学键合的单分子膜。

67. 发明授权

US5868827A Chemically bonding material and method for manufacturing the same 失效
标题翻译：化学结合材料及其制造方法
公开(公告)号：US5868827A
公开(公告)日：1999-02-09
申请号：US988645
申请日：1997-12-11
申请人： Norihisa Mino , Kazufumi Ogawa , Yasuo Takebe , Tadashi Otake
发明人： Norihisa Mino , Kazufumi Ogawa , Yasuo Takebe , Tadashi Otake
IPC分类号： C07F7/10 , C07F7/12 , C07F7/18 , C09D183/04 , C09D183/06 , C09D183/07
CPC分类号： C07F7/12 , C07F7/10 , C07F7/1836 , C07F7/184
摘要： A method for manufacturing a chemically bonding material comprising the steps of: mixing a compound expressed by a general formula ABX.sub.n (Formula 1), wherein A shows a group including carbon, B indicates Si, Ge, Sn, Ti or Zr, X is a hydrolyzable group and n indicates 1, 2 or 3, and at least one kind of compound not including active hydrogen groups in a dry atmosphere having a water vapor density of 0.0076 kg/m.sup.3 or less; and storing the same in a dry atmosphere having a water vapor density of 0.0076 kg/m.sup.3 or less. A coating solution including compounds that are easily hydrolyzed is stored in a dry state so that the material is not deactivated before reacting with a substrate.
摘要翻译：一种化学键合材料的制造方法，包括以下步骤：将由通式ABXn（式1）表示的化合物混合，其中A表示包含碳的基团，B表示Si，Ge，Sn，Ti或Zr，X为水解性基团，n表示1,2或3，并且在水蒸汽密度为0.0076kg / m 3以下的干燥气氛中含有至少一种不包括活性氢基团的化合物; 并将其储存在水蒸汽密度为0.0076kg / m 3以下的干燥气氛中。包含容易水解的化合物的涂布溶液以干燥状态储存，使得材料在与基材反应之前不失活。

68. 发明授权

US5716674A Information recording medium and methods of manufacturing and using the same 失效
公开(公告)号：US5716674A
公开(公告)日：1998-02-10
申请号：US718129
申请日：1996-09-18
申请人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
发明人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
IPC分类号： B05D1/18 , C08F8/42 , G11B7/0045 , G11B7/245 , G11B7/249 , G11B7/2492 , G11B7/253 , G11B7/2531 , G11B9/00 , G11B11/00 , G11B11/12 , B05D3/00
CPC分类号： G11B7/2492 , B05D1/185 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C08F8/42 , G11B11/002 , G11B11/007 , G11B11/12 , G11B7/00455 , G11B7/245 , G11B7/249 , G11B9/14 , G11B9/149 , G11B7/2531 , Y10S428/913 , Y10S430/146 , Y10T428/24802 , Y10T428/24909 , Y10T428/31504 , Y10T428/31678
摘要： An information recording layer on a substrate provides a method of recording information by selectively opening the rings of dicyclopentadiene skeletons, thus recording information by forming cyclopentadiene skeletons. The information recorded by the method can be erased by the cycloaddition of cyclopentadiene skeletons. Information can also be recorded or erased by incorporating or eliminating a metal ion from a selectively opened section of a ring of a dicyclopentadiene skeleton after forming an organic thin film comprising the dicyclopentadiene skeleton. Alternatively, after the formation of an organic thin film comprising a cyclopentadiene skeleton, a heterocycle or a benzene ring, a metal ion is incorporated or eliminated from a section between at least two rings of the cyclopentadiene skeleton, the heterocycle or the benzene ring. Thereafter, a metallocene skeleton or a skeleton analogous to the metallocene skeleton is formed or eliminated, thus recording or erasing information. The selective opening of a section of a dicyclopentadiene skeleton ring is carried out by heat or light. The readout of the information is performed by recognizing the cyclopentadiene skeleton, the metallocene skeleton, the skeleton analogous to the metallocene skeleton or the metal atom. The information recording layer of the invention is a chemically adsorbed monomolecular film with a thickness at the angstrom level.

69. 发明授权

US5461166A Chemically adsorbed ultrathin film and its material, and method of manufacturing the same 失效
标题翻译：化学吸附超薄膜及其材料及其制造方法
公开(公告)号：US5461166A
公开(公告)日：1995-10-24
申请号：US384594
申请日：1995-02-03
申请人： Norihisa Mino , Kazufumi Ogawa , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Kazuyuki Asakura
发明人： Norihisa Mino , Kazufumi Ogawa , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Kazuyuki Asakura
IPC分类号： C07B61/00 , B01J23/42 , B05D1/18 , C07F7/08 , C07F7/12 , C07F7/18 , C09K3/00 , G03F7/075 , C07D333/02 , C08G77/08 , C08F28/06
CPC分类号： B82Y30/00 , B05D1/185 , B82Y10/00 , B82Y40/00 , C07F7/12 , C07F7/182 , C07F7/1836 , C07F7/1868
摘要： Disclosed are a conductive thienyl derivative monomolecular film covalently bonded to a substrate surface and method of manufacturing the same, and a silicon compound comprising 3-thienyl groups (thiophene derivative) used for forming the conductive monomolecular film and a method of manufacturing the same. A monomolecular ultrathin film comprising 3-thienyl groups and silicon groups is formed in the invention. The silicon compound used for forming the film is provided by reacting .omega.-(3-thienyl)-1-alkene compound to a monosilane derivative compound, in which three out of four hydrogen atoms of monosilane are replaced with halogen or alkoxy groups, in the presence of a transition metal catalyst. A substrate is dipped and held in a nonaqueous solution of the above-noted compound, thus chemically bonding the monomolecular film to the substrate surface. Furthermore, a thienyl derivative ultrathin film is formed by the electrolytic or catalytic polymerization of the monomolecular film.
摘要翻译：公开了共价结合到基板表面的导电噻吩基衍生物单分子膜及其制造方法，以及包含用于形成导电性单分子膜的3-噻吩基（噻吩衍生物）的硅化合物及其制造方法。在本发明中形成包含3-噻吩基和硅基团的单分子超薄膜。用于形成膜的硅化合物是通过使ω-（3-噻吩基）-1-烯烃化合物与甲硅烷衍生物化合物反应而得到的，其中甲硅烷中四分之三的氢原子被卤素或烷氧基取代，过渡金属催化剂的存在。将基材浸渍并保持在上述化合物的非水溶液中，从而将单分子膜化学键合到基材表面。此外，通过单分子膜的电解或催化聚合形成噻吩衍生物超薄膜。

70. 发明授权

US5447778A Information recording medium and methods of manufacturing and using the same 失效
标题翻译：信息记录介质及其制造和使用方法
公开(公告)号：US5447778A
公开(公告)日：1995-09-05
申请号：US107308
申请日：1993-08-17
申请人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
发明人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
IPC分类号： B05D1/18 , C08F8/42 , G11B7/0045 , G11B7/245 , G11B7/249 , G11B7/2492 , G11B7/253 , G11B7/2531 , G11B9/00 , G11B11/00 , G11B11/12 , B32B3/00
CPC分类号： G11B7/2492 , B05D1/185 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C08F8/42 , G11B11/002 , G11B11/007 , G11B11/12 , G11B7/00455 , G11B7/245 , G11B7/249 , G11B9/14 , G11B9/149 , G11B7/2531 , Y10S428/913 , Y10S430/146 , Y10T428/24802 , Y10T428/24909 , Y10T428/31504 , Y10T428/31678
摘要： An information recording layer on a substrate provides a method of recording information by selectively opening the rings of dicyclopentadiene skeletons, thus recording information by forming cyclopentadiene skeletons. The information recorded by the method can be erased by the cycloaddition of cyclopentadiene skeletons. Information can also be recorded or erased by incorporating or eliminating a metal ion from a selectively opened section of a ring of a dicyclopentadiene skeleton after forming an organic thin film comprising the dicyclopentadiene skeleton. Alternatively, after the formation of an organic thin film comprising a cyclopentadiene skeleton, a heterocycle or a benzene ring, a metal ion is incorporated or eliminated from a section between at least two rings of the cyclopentadiene skeleton, the heterocycle or the benzene ring. Thereafter, a metallocene skeleton or a skeleton analogous to the metallocene skeleton is formed or eliminated, thus recording or erasing information. The selective opening of a section of a dicyclopentadiene skeleton ring is carried out by heat or light. The readout of the information is performed by recognizing the cyclopentadiene skeleton, the metallocene skeleton, the skeleton analogous to the metallocene skeleton or the metal atom. The information recording layer of the invention is a chemically adsorbed monomolecular film with a thickness at the angstrom level.
摘要翻译：基板上的信息记录层提供了通过选择性地打开双环戊二烯骨架环以记录信息的方法，从而通过形成环戊二烯骨架来记录信息。通过该方法记录的信息可以通过环戊二烯骨架的环加成来消除。在形成包含二环戊二烯骨架的有机薄膜之后，也可以通过在二环戊二烯骨架的环的选择性开放部分中并入或除去金属离子来记录或消除信息。或者，在形成包含环戊二烯骨架，杂环或苯环的有机薄膜之后，从环戊二烯骨架，杂环或苯环的至少两个环之间的部分引入或除去金属离子。此后，形成或消除类似于茂金属骨架的茂金属骨架或骨架，从而记录或擦除信息。二环戊二烯骨架环的一部分的选择性打开通过热或光进行。通过识别环戊二烯骨架，金属茂骨架，类似于茂金属骨架或金属原子的骨架来进行信息的读出。本发明的信息记录层是厚度为埃埃的化学吸附单分子膜。

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