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    • 62. 发明授权
    • Color-forming aminopyrimidine couplers and silver halide color
photographic light-sensitive materials containing the coupler
    • 含有偶合剂的成色氨基嘧啶成色剂和卤化银彩色照相感光材料
    • US5017466A
    • 1991-05-21
    • US527376
    • 1990-05-23
    • Hidetoshi KobayashiReiichi OhiKei Sakanoue
    • Hidetoshi KobayashiReiichi OhiKei Sakanoue
    • G03C7/32G03C7/38
    • G03C7/3815
    • A color-forming aminopyrimidine coupler represented by formula (I): ##STR1## where R.sub.1, R.sub.2, and R.sub.3 independently represent a hydrogen atom, a halogen atom, an alkoxy group, an aryloxy group, a heterocyclic-oxy group, an alkylthio group, an arylthio group, a heterocyclic-thio group, a substituted or unsubstitued amino group, a heterocyclic group bonding to the pyrimidine ring via a nitrogen atom thereof, an alkyl group or an aryl group; provided that at least one of R.sub.1, R.sub.2 and R.sub.3 is an unsubstituted or substituted amino group, and that when any one of R.sub.1, R.sub.2 or R.sub.3 contains a sulfonic acid group or a salt thereof, R.sub.1 , R.sub.2 or R.sub.3 contains at least one linear or branched alkyl group and that the total carbon atoms in the alkyl group(s) are to be more than 8; and R.sub.4 represents a hydrogen atom, a halogen atom, an alkoxy group, an aryloxy group, a heterocyclic-oxy group, an alkylthio group, an arylthio group, a heterocyclic-thio group, a substituted or unsubstituted amino group, or a heterocyclic group bonding to the pyrimidine ring via a nitrogen atom thereof.At least one coupler of formula (I) is incorporated into the photographic constitutive layer of a color silver halide photographic material, which gives a color image with high heat-fastness.
    • 由式(I)表示的形成颜色的氨基嘧啶成色剂:其中R 1,R 2和R 3独立地表示氢原子,卤素原子,烷氧基,芳氧基,杂环氧基, 烷硫基,芳硫基,杂环硫基,取代或未取代的氨基,通过氮原子与嘧啶环键合的杂环基,烷基或芳基; 条件是R 1,R 2和R 3中的至少一个是未取代或取代的氨基,当R 1,R 2或R 3中的任何一个含有磺酸基或其盐时,R 1,R 2或R 3含有至少一个直链 或支链烷基,并且烷基中的总碳原子数大于8; R 4表示氢原子,卤素原子,烷氧基,芳氧基,杂环氧基,烷硫基,芳硫基,杂环硫基,取代或未取代的氨基或杂环基 通过其氮原子与嘧啶环结合。 将至少一种式(I)的成色剂并入到彩色卤化银照相材料的照相组成层中,其产生具有高耐热性的彩色图像。
    • 65. 发明授权
    • Direct positive photographic materials and a method of forming direct
positive images
    • 直接的正性照相材料和形成直接正像的方法
    • US4948712A
    • 1990-08-14
    • US184552
    • 1988-06-07
    • Noriyuki InoueTatsuo HekiHidetoshi KobayashiNaoyasu DeguchiShigeo Hirano
    • Noriyuki InoueTatsuo HekiHidetoshi KobayashiNaoyasu DeguchiShigeo Hirano
    • G03C7/30
    • G03C7/3022G03C2200/20G03C7/3029Y10S430/156
    • The invention provides (1) direct positive photographic photosensitive materials in which at least one type of FR compound which releases fogging agent or development accelerator or a precursor thereof in accordance with the amount of silver developed when the silver halide is being developed is included in a direct positive photographic material comprising at least one layer of non-pre-fogged internal latent image type silver halide emulsion on a support, and (2) a method of forming direct positive images of which the distinguishing features are that in a method for the formation of direct positive images in which a direct positive photographic photosensitive material comprising at least one layer of non-pre-fogged internal latent image forming silver halide emulsion on a support is processed, after image exposure, in a surface developer, at least one type of FR compound which releases fogging agent or development accelerator or precursors thereof is included in the said photographic mateiral, and that the said photosensitive material is subjected to a fogging process and to a development process during and/or after the said fogging process.It is possible by means of this invention to obtain direct positive photographic materials which have excellent stability with respect to the passage of time and especially good stability with respect to the passage of time under conditions of high temperature and high humidity.Moreover, it is possible to obtain direct positive photographic materials and a method of forming direct positive images which have a high maximum image density and a high resolving power.Moreover, it is possible to obtain direct positive photographic materials and a method of forming direct positive images with which direct positive images which have a satisfactorily high color density can be obtained, even on processing in highly stable developers of low pH.
    • 67. 发明授权
    • Silver halide color photographic material and method for processing the
same
    • 卤化银彩色照相材料及其加工方法
    • US4840877A
    • 1989-06-20
    • US94638
    • 1987-09-09
    • Akira AbeKeiji MihayashiHidetoshi KobayashiHirohiko Kato
    • Akira AbeKeiji MihayashiHidetoshi KobayashiHirohiko Kato
    • G03C7/30
    • G03C7/3012
    • A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide color photographic material contains a magenta dye forming coupler represented by the general formula (I) and a compound represented by the general formula (II) in the same layer ##STR1## wherein R.sub.1 is represents an aromatic group, an aliphatic group or a heterocyclic group; R.sub.2 represents a substituent; Za, Zb, Zc and Zd, which may be the same or different, each represents an unsubstituted methine group, a substituted methine group or --N.dbd.,(R'--COO.sup.-).sub.n M.sup.n+ (II)wherein R' represents a substituent which imparts a diffusion-resistant property to the compound represented by the general formula (II); M.sup.n+ represents a hydrogen ion, a metal ion or an ammonium ion; and n represents an integer from 1 to 4.
    • 一种卤化银彩色照相材料,包括其上具有至少一个卤化银乳剂层的载体,其中所述卤化银彩色照相材料含有由通式(I)表示的品红色染料形成成色剂和由通式(II)表示的化合物 ),其中R1表示芳族基团,脂族基团或杂环基团; R2表示取代基; Za,Zb,Zc和Zd可以相同或不同,各自表示未取代的次甲基,取代的次甲基或-N =,(R'-COO-)nMn +(II)其中R'表示取代基 赋予由通式(II)表示的化合物的扩散阻止性; Mn +表示氢离子,金属离子或铵离子; n表示1〜4的整数。