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    • 1. 发明授权
    • Color-forming aminopyrimidine couplers and silver halide color
photographic light-sensitive materials containing the coupler
    • 含有偶合剂的成色氨基嘧啶成色剂和卤化银彩色照相感光材料
    • US5017466A
    • 1991-05-21
    • US527376
    • 1990-05-23
    • Hidetoshi KobayashiReiichi OhiKei Sakanoue
    • Hidetoshi KobayashiReiichi OhiKei Sakanoue
    • G03C7/32G03C7/38
    • G03C7/3815
    • A color-forming aminopyrimidine coupler represented by formula (I): ##STR1## where R.sub.1, R.sub.2, and R.sub.3 independently represent a hydrogen atom, a halogen atom, an alkoxy group, an aryloxy group, a heterocyclic-oxy group, an alkylthio group, an arylthio group, a heterocyclic-thio group, a substituted or unsubstitued amino group, a heterocyclic group bonding to the pyrimidine ring via a nitrogen atom thereof, an alkyl group or an aryl group; provided that at least one of R.sub.1, R.sub.2 and R.sub.3 is an unsubstituted or substituted amino group, and that when any one of R.sub.1, R.sub.2 or R.sub.3 contains a sulfonic acid group or a salt thereof, R.sub.1 , R.sub.2 or R.sub.3 contains at least one linear or branched alkyl group and that the total carbon atoms in the alkyl group(s) are to be more than 8; and R.sub.4 represents a hydrogen atom, a halogen atom, an alkoxy group, an aryloxy group, a heterocyclic-oxy group, an alkylthio group, an arylthio group, a heterocyclic-thio group, a substituted or unsubstituted amino group, or a heterocyclic group bonding to the pyrimidine ring via a nitrogen atom thereof.At least one coupler of formula (I) is incorporated into the photographic constitutive layer of a color silver halide photographic material, which gives a color image with high heat-fastness.
    • 由式(I)表示的形成颜色的氨基嘧啶成色剂:其中R 1,R 2和R 3独立地表示氢原子,卤素原子,烷氧基,芳氧基,杂环氧基, 烷硫基,芳硫基,杂环硫基,取代或未取代的氨基,通过氮原子与嘧啶环键合的杂环基,烷基或芳基; 条件是R 1,R 2和R 3中的至少一个是未取代或取代的氨基,当R 1,R 2或R 3中的任何一个含有磺酸基或其盐时,R 1,R 2或R 3含有至少一个直链 或支链烷基,并且烷基中的总碳原子数大于8; R 4表示氢原子,卤素原子,烷氧基,芳氧基,杂环氧基,烷硫基,芳硫基,杂环硫基,取代或未取代的氨基或杂环基 通过其氮原子与嘧啶环结合。 将至少一种式(I)的成色剂并入到彩色卤化银照相材料的照相组成层中,其产生具有高耐热性的彩色图像。
    • 8. 发明授权
    • Gelatino silver halide photosensitive material
    • 明胶卤化银感光材料
    • US4054458A
    • 1977-10-18
    • US612986
    • 1975-09-12
    • Katsuhiko OhtaniYosuke NakajimaReiichi OhiTokiharu Kondo, deceasedby Yoshiharu Kondo, legal representative
    • Katsuhiko OhtaniYosuke NakajimaReiichi OhiTokiharu Kondo, deceasedby Yoshiharu Kondo, legal representative
    • G03C1/10G03C1/28G03C1/30
    • G03C1/305G03C1/10G03C1/28
    • A practical, useful gelatino silver halide photo-sensitive material having incorporated therein a compound represented by the following formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent a hydroxyl group, a hydroxylamino group, an amino group, an alkylamino group of from 1-6 carbon atoms, said alkyl group of said alkylamino group capable of being substituted by a member selected from the group consisting of a hydroxy group, a dialkylamino group of from 2 to 8 carbon atoms and an alkoxy group of from 1 to 4 carbon atoms, an arylamino group, said arylamino group capable of being substituted with a member selected from the group consisting of an alkyl group of from 1 to 4 carbon atoms, an alkoxy group of from 1 to 4 carbon atoms, a hydroxy group and a halogen atom, an alkoxyl group of from 1 to 6 carbon atoms, an aryloxy group, said aryloxy group capable of being substituted with a member selected from the group consisting of an alkyl group of from 1 to 4 carbon atoms, an alkoxy group of from 1 to 4 carbon atoms, a hydroxy group, and a halogen atom, an alkyl group of from 1 to 6 carbon atoms, an aryl group, said aryl group capable of being substituted with a member selected from the group consisting of an alkyl group of from 1 to 4 carbon atoms, an alkoxy group of from 1 to 4 carbon atoms, a hydroxy group, and a halogen atom, or a halogen atom, said compound represented by the above described formula containing no more than one group which is active to gelatin, with the proviso that if R.sub.1, R.sub.2 or R.sub.3 is a halogen atom, no more than one of said R.sub.1, R.sub.2 and R.sub.3 can be a halogen atom.
    • 一种实用的,有用的明胶卤化银感光材料,其中掺入了由下式表示的化合物:其中R1,R2和R3各自表示羟基,羟基氨基,氨基,烷基氨基, 1-6个碳原子,所述烷基氨基的所述烷基能够被选自羟基,2至8个碳原子的二烷基氨基和1至4个碳原子的烷氧基所选择的基团取代 原子,芳基氨基,所述芳基氨基能够被选自1至4个碳原子的烷基,1至4个碳原子的烷氧基,羟基和卤素 原子,1〜6个碳原子的烷氧基,芳氧基,所述芳氧基能够被选自1〜4个碳原子的烷基,烷氧基 1至4个碳原子,羟基和卤素原子,1至6个碳原子的烷基,芳基,所述芳基能够被选自以下的成员取代:烷基 1〜4个碳原子的烷基,1〜4个碳原子的烷氧基,羟基,卤素原子或卤素原子,上述式中所含的不超过1个 对于明胶是活性的,条件是如果R 1,R 2或R 3是卤素原子,则不超过一个所述R 1,R 2和R 3可以是卤素原子。