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61. 发明授权

US4812337A Metallic coating method 失效
标题翻译：金属涂层法
公开(公告)号：US4812337A
公开(公告)日：1989-03-14
申请号：US122721
申请日：1987-11-18
申请人： You Sugimura , Nobushige Numa , Tadashi Watanabe , Yutaka Sugiyama , Kazuhiko Ohira , Sachio Yamaguchi
发明人： You Sugimura , Nobushige Numa , Tadashi Watanabe , Yutaka Sugiyama , Kazuhiko Ohira , Sachio Yamaguchi
IPC分类号： B05D5/06 , B05D7/00 , C09D133/16 , B05D1/36
CPC分类号： B05D7/532 , B05D5/068 , C09D133/16
摘要： Disclosed is a coating method for forming a metallic coat, comprising the steps of applying to a substrate a base coating composition containing a metallic pigment and applying a clear top coating composition to the coated surface, the method being characterized in that the clear top coating composition is a curable one comprising as a main component a nonaqueous dispersion of a polymer of a radically polymerizable monomer, said dispersion containing as a dispersion stabilizer a fluorine-containing copolymer comprising a hydroxyl group-containing monomer and a perfluoroalkyl group-containing acrylic or methacrylic monomer represented by the following formula (1) ##STR1## wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 11 and R.sub.f is a straight chain or branched chain perfluoroalkyl group having 1 to 21 carbon atoms.
摘要翻译：公开了一种用于形成金属涂层的涂布方法，包括以下步骤：向基材施加含有金属颜料的基底涂料组合物，并向涂布表面施加透明顶涂层组合物，其特征在于，所述透明顶涂层组合物是含有可自由基聚合的单体的聚合物的非水分散体作为主要成分的固化物，所述分散体含有含羟基单体和含全氟烷基的丙烯酸或甲基丙烯酸单体的含氟共聚物作为分散稳定剂（1）其中R为氢原子或甲基，n为1〜11的整数，Rf为碳原子数1〜21的直链或支链全氟烷基，。

62. 发明授权

US4329266A Water-dispersed coating composition comprising an acrylic graft polymer containing carboxyl groups, hydroxyl and/or amide groups 失效
标题翻译：包含含有羧基，羟基和/或酰胺基团的丙烯酸接枝聚合物的水分散涂料组合物
公开(公告)号：US4329266A
公开(公告)日：1982-05-11
申请号：US186557
申请日：1980-09-12
申请人： Yukio Suzuki , Naozumi Iwasawa , Tadashi Watanabe
发明人： Yukio Suzuki , Naozumi Iwasawa , Tadashi Watanabe
IPC分类号： C08F290/12 , C09D151/00 , C08L61/28
CPC分类号： C08F290/126 , C09D151/003
摘要： A water-dispersed coating composition comprising (1) a dispersion of a water-dispersible form of an acrylic graft polymer containing carboxyl groups and hydroxyl and/or amide groups in an aqueous medium containing 60 to 90% by weight of water, and (2) an amino resin. The water-dispersible form of this polymer is obtained by neutralizing at least 50% of the carboxyl groups of the polymer with a basic substance. Prior to neutralization, the polymer has an acid value of 15 to 40 and a glass transition temperature of -10.degree. C. to 70.degree. C., and is produced by polymerizing (A) an acrylic copolymer and (B) a mixture of an alpha,beta-ethylenically unsaturated carboxylic acid and another copolymerizable unsaturated monomer. The copolymer (A) and the mixture (B) is selected so that either one of them has hydroxyl and/or amide groups and the difference between the acid value of the copolymer (A) and that of the mixture (B) is from 25 to 200. The present invention also provides a water-dispersed coating composition comprising a dispersion of a water-dispersible form of a self-curable acrylic graft polymer without an amino resin.
摘要翻译：一种水分散涂料组合物，其包含（1）含水分散体形式的含羧基和羟基和/或酰胺基的丙烯酸接枝聚合物在含有60-90％重量水的水性介质中的分散体，和（2））氨基树脂。该聚合物的水分散形式通过用碱性物质中和聚合物的至少50％的羧基而获得。在中和之前，聚合物的酸值为15至40，玻璃化转变温度为-10℃至70℃，并通过聚合（A）丙烯酸共聚物和（B）将 α，β-烯属不饱和羧酸和另一种可共聚的不饱和单体。选择共聚物（A）和混合物（B），使得它们中的任一个具有羟基和/或酰胺基，并且共聚物（A）和混合物（B）的酸值之间的差异为25 本发明还提供一种水分散涂料组合物，其包含不具有氨基树脂的可分散自由基的丙烯酸接枝聚合物的分散体。

63. 发明授权

US4324708A Metallic painting 失效
公开(公告)号：US4324708A
公开(公告)日：1982-04-13
申请号：US202763
申请日：1980-10-31
申请人： Satoru Ito , Tadashi Watanabe , Shinji Sugiura
发明人： Satoru Ito , Tadashi Watanabe , Shinji Sugiura
IPC分类号： C09D5/38 , C09D101/08 , C09D151/00 , C09D151/02 , C08L1/10 , C08L1/14
CPC分类号： C08F251/02 , C09D151/02 , C09D5/38 , Y10T428/31692 , Y10T428/31696 , Y10T428/31699 , Y10T428/31703 , Y10T428/3179 , Y10T428/31797 , Y10T428/31862 , Y10T428/31949
摘要： A process for forming a metallic paint film comprising(a) coating on a substrate surface a metallic paint containing as a vehicle component a modified vinyl-type copolymer obtained by copolymerizing 5-75 weight % of cellulose acetate butyrate with 95-25 weight % of a monomeric component consisting of one or more vinyl-type monomers,(b) if necessary, coating a thermosetting resin-type clear topcoating while said coated metallic paint film is in the unhardened state and(c) then baking the paint film.

64. 发明授权

US4089910A Thermosetting powder coating compositions 失效
标题翻译：热固性粉末涂料组合物
公开(公告)号：US4089910A
公开(公告)日：1978-05-16
申请号：US588709
申请日：1975-06-20
申请人： Minoru Shibata , Naozumi Iwasawa , Tadashi Watanabe , Ichiro Yoshihara
发明人： Minoru Shibata , Naozumi Iwasawa , Tadashi Watanabe , Ichiro Yoshihara
IPC分类号： B05D7/14 , B05D1/38 , C08F299/04 , C08G59/32 , C08G59/42 , C08L63/00
CPC分类号： C08G59/42 , C08F299/0478 , C08G59/3209 , Y10S524/904 , Y10T428/31529
摘要： A thermosetting powder coating composition comprising:(A) a graft copolymer ofA. 10 to 40 percent of a linear polyester having a number average molecular weight of 600 to 3,000 and containing one ethylenically unsaturated double bond only at one end of the molecule,B. 5 to 30 percent of at least one of glycidyl esters having the formula ##STR1## wherein R.sub.1 is hydrogen or methyl, and C. 10 TO 85 PERCENT OF AT LEAST ONE OF ACRYLIC COMPOUNDS HAVING THE FORMULA OF CH.sub.2 .dbd.C(R.sub.2)COOR.sub.3, wherein R.sub.2 is hydrogen or methyl and R.sub.3 is alkyl having 1 to 14 carbon atoms, cyclohexyl or hydroxyalkyl represented by ##STR2## wherein R.sub.4 is hydrogen, methyl or ethyl, said graft copolymer having a softening point of 70.degree. to 110.degree. C and a number average molecular weight of 2,000 to 30,000; and(B) at least one of polycarboxylic acids and anhydrides thereof in an amount of 0.6 to 1.2 moles in terms of carboxyl group per mole of the glycidyl group contained in the graft copolymer.
摘要翻译：一种热固性粉末涂料组合物，

65. 发明授权

US4033920A Process for producing unsaturated resin emulsion 失效
标题翻译：生产不饱和树脂乳液的方法
公开(公告)号：US4033920A
公开(公告)日：1977-07-05
申请号：US585770
申请日：1975-06-10
申请人： Osamu Isozaki , Tadashi Watanabe , Masahiro Sakamoto
发明人： Osamu Isozaki , Tadashi Watanabe , Masahiro Sakamoto
IPC分类号： C08F8/14 , C08F290/12 , C08L33/02
CPC分类号： C08F290/12 , C08F8/14 , C08F2810/30
摘要： A process for producing an aqueous emulsion of unsaturated resin suitable for radiation curing coating compositions comprises the steps of: synthesizing polyvinyl resin having an acid value of 50 to 230 by solution polymerization, adding a monomer having both epoxy group and reactive unsaturated group to said polyvinyl resin, if necessary further mixing a monomer of above 190.degree. C in boiling point having reactive unsaturated group(s) to the above adduct, removing solvent under reduced pressure, neutralizing residual acid groups with base and dispersing the neutralized product into water.
摘要翻译：适用于辐射固化涂料组合物的不饱和树脂水乳液的制备方法包括以下步骤：通过溶液聚合合成酸值为50至230的聚乙烯基树脂，将具有环氧基和反应性不饱和基团的单体加入到所述聚乙烯树脂，如果需要，将具有反应性不饱和基团的沸点高于190℃的单体与上述加合物进一步混合，减压除去溶剂，用碱中和残留的酸基，并将中和产物分散在水中。

66. 发明授权

US3993612A Aqueous coating composition 失效
标题翻译：水性涂料组合物
公开(公告)号：US3993612A
公开(公告)日：1976-11-23
申请号：US559770
申请日：1975-03-19
申请人： Tetsuo Aihara , Tadashi Watanabe , Yasuharu Nakayama , Yoshio Yamashita , Isao Toyomoto
发明人： Tetsuo Aihara , Tadashi Watanabe , Yasuharu Nakayama , Yoshio Yamashita , Isao Toyomoto
IPC分类号： C08J3/02 , C08F220/28 , C08L13/00 , C08L33/06 , C09D4/00 , C09D121/00 , C09D133/14 , C09D157/00 , C09D201/00 , C09D201/02 , C09D201/08 , C08L91/00
CPC分类号： C09D133/14 , C08F220/28 , C09D157/00 , C08L13/00 , C08L33/06
摘要： In an aqueous coating composition comprising a vinyl polymer emulsion prepared by subjecting a vinyl monomer to emulsion polymerization in an aqueous medium in the presence of maleinized polybutadiene used as a dispersion stabilizer, an improvement which is characterized in that at least one copolymer is further incorporated, said copolymer being composed of (A) at least one monomer prepared by reacting one glycidyl ester of acrylic acid and methacrylic acid with at least one fatty acid of drying oil fatty acid and semi-drying oil fatty acid, (B) at least one .alpha.,.beta.-ethylenically unsaturated acid and (C) at least one unsaturated monomer containing substantially no carboxyl group and having a Q value of at least 0.1 as determined by Q-e theory.
摘要翻译：在包含乙烯基聚合物乳液的水性涂料组合物中，其改进在于进一步引入至少一种共聚物，该乙烯基聚合物乳液是通过使乙烯基单体在含水介质中进行乳液聚合而制备的，所述聚合物乳液在用作分散稳定剂的马来化聚丁二烯存在下，所述共聚物由（A）至少一种通过丙烯酸缩水甘油酯和甲基丙烯酸与干性油脂肪酸和半干性油脂肪酸的至少一种脂肪酸反应制备的单体，（B）至少一种α ，β-烯键式不饱和酸和（C）至少一种不含羧基的不饱和单体，并通过Qe理论确定Q值至少为0.1。

67. 发明授权

US3974303A Method for forming coating films 失效
标题翻译：涂膜形成方法
公开(公告)号：US3974303A
公开(公告)日：1976-08-10
申请号：US490753
申请日：1974-07-22
申请人： Seigo Iwase , Osamu Isozaki , Naozumi Iwasawa , Tadashi Watanabe
发明人： Seigo Iwase , Osamu Isozaki , Naozumi Iwasawa , Tadashi Watanabe
IPC分类号： C09D5/00 , B05D3/06 , C08G18/32 , C08G18/67 , C08J3/28 , C09D4/00 , C09D5/03 , C09D175/16 , B05B5/02
CPC分类号： C08G18/3206 , B05D3/067 , B05D3/068 , C08G18/672 , C08J3/28 , C09D175/16 , B05D2401/32 , C08G2150/20
摘要： A method for forming coating films which can provide coating films having good surface appearance and being excellent in such properties as impact resistance, adhesion to the substrate article, flexibility and chemical resistance, said method comprising coating a powdery composition of a thermoplastic resin having 0.5 to 3.5 polymerizable unsaturated bonds per 1000 of the molecular weight on an article to be coated, heat-melting the powdery resinous composition, and curing the molten film under application of ionizing radiation or ultraviolet radiation.
摘要翻译：一种形成涂膜的方法，其可以提供具有良好的表面外观并且具有优异的耐冲击性，对基材制品的粘附性，柔韧性和耐化学性的性能的涂膜，所述方法包括将具有0.5的热塑性树脂的粉末组合物涂覆至 3.5可聚合的不饱和键，每1000个待涂覆的物品上的分子量，对粉末状树脂组合物进行加热熔融，并在施加电离辐射或紫外线辐射下固化熔融膜。

68. 发明授权

US3936368A Method for curing a coating film 失效
标题翻译：固化涂膜的方法
公开(公告)号：US3936368A
公开(公告)日：1976-02-03
申请号：US93466
申请日：1970-11-27
申请人： Tadashi Watanabe , Tsutomu Maruyama
发明人： Tadashi Watanabe , Tsutomu Maruyama
IPC分类号： C09D5/00 , B05D3/06 , C09D5/44 , C09D167/08 , C25D13/00 , C25D13/08 , G21H5/00 , C25D13/06
CPC分类号： C09D167/08 , C09D5/4423
摘要： A method for curing a coating film wherein a filmforming, polymerizable, organic coating material is electrodeposited upon an electroconductive object as an anode immersed in an aqueous dispersion of an acidic alkyd resin modified with conjugated unsaturated fatty acid and/or oil, wherein the acidic alkyd resin has an oil length in the range of 10 to 60 wt % and a resin acid value in the range of 30 to 100, being neutralized with water soluble bases, and then the curing coating film thus obtained by applying ionizing radiation.
摘要翻译：一种用于固化涂膜的方法，其中成膜可聚合的有机涂层材料电沉积在浸渍在用共轭不饱和脂肪酸和/或油改性的酸性醇酸树脂的水性分散体中的作为阳极的导电物体上，其中酸性醇酸树脂树脂的油长度在10〜60重量％的范围内，树脂酸值在30〜100的范围内，用水溶性碱中和，然后通过施加电离辐射得到固化涂膜。

69. 发明授权

US08188520B2 Field effect transistor and method for fabricating the same 有权
标题翻译：场效应晶体管及其制造方法
公开(公告)号：US08188520B2
公开(公告)日：2012-05-29
申请号：US13104537
申请日：2011-05-10
申请人： Tadashi Watanabe , Hajime Matsuda
发明人： Tadashi Watanabe , Hajime Matsuda
IPC分类号： H01L29/66
CPC分类号： H01L29/7787 , H01L21/28581 , H01L21/28587 , H01L29/205 , H01L29/42316 , H01L29/475 , H01L29/8128
摘要： A method for fabricating a field effect transistor includes: forming an insulating film provided on a semiconductor layer, the insulating film having an opening via which a surface of the semiconductor layer is exposed and including silicon oxide; forming a Schottky electrode on the insulating film and in the opening, the Schottky electrode having an overhang portion and having a first contact layer that is provided in a region contacting the insulating film and contains oxygen, and a second contact layer that is provided on the first contact layer and contains a smaller content of oxygen than that of the first contact layer; and removing the insulating film by a solution including hydrofluoric acid.
摘要翻译：一种用于制造场效应晶体管的方法，包括：形成设置在半导体层上的绝缘膜，所述绝缘膜具有暴露所述半导体层的表面并且包括氧化硅的开口; 在所述绝缘膜上和所述开口中形成肖特基电极，所述肖特基电极具有突出部分，并且具有设置在与所述绝缘膜接触并包含氧的区域中的第一接触层，以及设置在所述绝缘膜上的第二接触层第一接触层并且含有比第一接触层的氧更小的氧含量; 并通过包含氢氟酸的溶液除去绝缘膜。

70. 发明申请

US20080111025A1 Latch device of cockpit door of an aircraft 有权
标题翻译：飞机驾驶舱门的锁定装置
公开(公告)号：US20080111025A1
公开(公告)日：2008-05-15
申请号：US11905519
申请日：2007-10-02
申请人： Fumiaki Saku , Tadashi Watanabe , Yasuo Sekikawa
发明人： Fumiaki Saku , Tadashi Watanabe , Yasuo Sekikawa
IPC分类号： B64C1/14
CPC分类号： B64C1/1469 , B64C2001/009 , B64D45/0015 , E05B51/023
摘要： A latch device for detecting pressure reduction of a cockpit in an aircraft and releasing a bolt and a stopper device are provided so as to prevent a cockpit door from unexpectedly opening by an impact. A main latch device 100 of the cockpit door has a frame 112 fixed to a door panel, and a latch base 120 is mounted to the frame 112 capable of pivotal rotation with a pin 122 as a fulcrum. A bolt 132 is inserted into a catch in conjunction with a door handle 130. A holding/releasing portion 150 holds the latch base 120. When a pressure difference occurs between a cockpit 4 and a cabin 5, a pressure-sensing piston 160 is pushed in, a trigger 170 and a flapper 180 are rotated and the latch base 120 is released. A stopper device 190 regulates movement of the trigger 170 by movement of an inertial piston 192 when an impact force is applied from the cabin 5 side.
摘要翻译：用于检测飞行器中的驾驶舱的减压并释放螺栓和止动装置的闩锁装置被设置成防止驾驶舱门被冲击意外地打开。驾驶舱门的主闩锁装置100具有固定到门板的框架112，并且闩锁基座120安装到能够以销122作为支点枢转旋转的框架112。螺栓132与门把手130一起插入到卡扣中。保持/释放部分150保持闩锁基座120。当驾驶舱4和驾驶舱5之间发生压力差时，压力传感活塞160被推入，触发器170和挡板180旋转并且闩锁底座120被释放。止动装置190通过惯性活塞192的移动来调节触发器170的运动，当从机舱5侧施加冲击力时。

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