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    • 53. 发明授权
    • 1-Hydroxymethyl-2-acyl cyclopropane derivatives and esters and cyclic
condensation products thereof, organoleptic uses of same and processes
for preparing same
    • 1-羟甲基-2-酰基环丙烷衍生物及其酯及其环状缩合产物,其感官用途及其制备方法
    • US4536330A
    • 1985-08-20
    • US589510
    • 1984-03-14
    • Richard M. BodenMarie R. HannaTheodore J. Tyszkiewicz
    • Richard M. BodenMarie R. HannaTheodore J. Tyszkiewicz
    • A23G4/00A23G4/06A23L27/20C11D3/50C11B9/00
    • A23G4/06A23L27/203C11D3/50Y10S514/88Y10S514/881
    • Described are 1-hydroxymethyl-2-acyl cyclopropane derivatives defined according to the structure: ##STR1## wherein Z represents hydrogen, acyl having the structure: ##STR2## and substituted oxyacyl having the structure: ##STR3## and cyclic condensation products thereof having the structure: ##STR4## wherein R.sub.1, R.sub.2 and R.sub.3 represent C.sub.1 -C.sub.10 alkyl; wherein R.sub.1 ' represents C.sub.1 -C.sub.10 alkylidene and wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or C.sub.1 -C.sub.3 lower alkyl; processes for preparing same by means of a reaction of a halomethyloxirane or substituted halomethyloxirane with a substituted 1,3-propanedione derivative; and organoleptic uses of such 1-hydroxymethyl-2-acyl cyclopropane derivatives in augmenting or enhancing the aroma or taste of perfume compositions, perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, perfumed polymers, hair preparations and shampoos), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos.
    • 描述的是根据以下结构定义的1-羟甲基-2-酰基环丙烷衍生物:其中Z代表氢,具有以下结构的酰基:具有以下结构的取代的氧酰基:其具有下式的环状缩合产物: 结构:其中R 1,R 2和R 3表示C 1 -C 10烷基; 其中R1'表示C1-C10亚烷基,其中R4,R5,R6和R7表示氢或C1-C3低级烷基; 通过卤代环氧丙烷或取代的卤代甲基环氧乙烷与取代的1,3-丙二酮衍生物的反应制备其的方法; 以及这种1-羟甲基-2-酰基环丙烷衍生物在增强或增强香料组合物,香料制品(例如固体或液体阴离子,阳离子,非离子或两性离子洗涤剂,织物柔软剂组合物,织物柔软剂制品)中的香味或味道的感官用途, 加香聚合物,头发制剂和洗发剂),古龙水,食品,口香糖,牙膏,药用产品和咀嚼烟草。
    • 55. 发明授权
    • Perfume use for oxoalkyl esters
    • 香料用于氧代烷基酯
    • US4368145A
    • 1983-01-11
    • US307366
    • 1981-10-01
    • Michael LicciardelloRichard M. BodenHugh WatkinsMarie R. Hanna
    • Michael LicciardelloRichard M. BodenHugh WatkinsMarie R. Hanna
    • C11B9/00A61K7/46
    • C11B9/0015C11B9/0061
    • Described is a genus of compounds defined according to the structure: ##STR1## wherein Z represents carbinol having the structure: ##STR2## or carboxaldehyde having the structure: ##STR3## and wherein R represents 3-heptanyl or phenyl produced by (i) reacting a carboxylic acid with 2,2-dimethyl-1,3--propanediol to form the compound wherein Z represents carbinol; (ii) and then, if, desired, subsequently reacting the resulting alcohol to form an aldehyde; and organoleptic uses of such compounds in the field of perfumery, colognes and perfumed articles (e.g. perfumed polymers, or solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, hair preparations, hair sprays, bath preparations and the like).
    • 描述了根据以下结构定义的化合物属:其中Z表示具有以下结构的甲醇:具有以下结构的羧甲基,其中R表示3-庚基或苯基,其通过以下步骤制备:(i) 与2,2-二甲基-1,3-丙二醇的羧酸形成其中Z代表甲醇的化合物; (ii)然后如果需要,随后使所得醇反应形成醛; 以及这些化合物在香料,古龙水和香料制品领域(如加香聚合物,固体或液体阴离子,阳离子,非离子或两性离子洗涤剂,织物柔软剂组合物,干燥剂添加织物柔软剂制品,头发制剂,喷发剂)中的感官用途 ,浴液等)。
    • 57. 发明授权
    • Bicyclic lactones, perfumery uses thereof, processes for preparing same and intermediates therefor
    • 双环内酯,其香料用途,其制备方法及其中间体
    • US06608010B2
    • 2003-08-19
    • US10210386
    • 2002-08-01
    • Richard A. WeissMark A. SpreckerMarie R. HannaCharles E. J. BeckHarold W. Jackson
    • Richard A. WeissMark A. SpreckerMarie R. HannaCharles E. J. BeckHarold W. Jackson
    • C11D350
    • A61K8/498A61L9/01A61L9/012A61Q13/00C07D311/02C07D311/74C11B9/008C11D3/2096C11D3/50
    • Described are bicyclic lactones, both fused ring lactones defined according to the generic structure: and spiro lactones defined according to the generic structure: uses thereof in augmenting, enhancing or imparting aromas in or to perfume compositions, perfumed articles, colognes and perfumed polymers; processes for preparing such bicyclic lactones and intermediates therefor. In the structure: Z is one of the moieties: one of R1 or R3 is methyl and the other is hydrogen; and R4, R5, R6, R7, R8 and R9 are hydrogen or nonadjacent C1-C3 alkyl. In the structure: Y represents C2-C12 substituted or unsubstituted alkylidenyl, alkenylidenyl or alkadienylidenyl having the structure: and completes a C5-C15 cycloalkyl, cycloalkadienyl or cycloalkenyl ring moiety; and wherein R12, R13, R14, R16, R17, R28, R29, R30 and R31 represent hydrogen or C1-C3 nonadjacent alkyl; wherein s is an integer of from 0 up to 10; t is an integer of from 0 up to 10; and v is an integer of 1 or 2; with the proviso that the sum of s and t is between 0 and 10 according to the inequalities: 0≦s+t≦10; 0≦s≦10; and 0≦t≦10.
    • 描述的是双环内酯,根据通用结构定义的稠环内酯和根据通用结构定义的螺内酯:用于增强,增强或赋予香料组合物,香料制品,古龙水和加香聚合物中的香气; 制备这种双环内酯的方法及其中间体。在结构中:Z是部分之一:R 1或R 3中的一个是甲基,另一个是氢; 且R 4,R 5,R 6,R 7,R 8和R 9为氢或不相邻的C 1 -C 3烷基。 在结构中:Y表示具有以下结构的C 2 -C 12取代或未取代的亚烷基,亚烯基或链二烯基;并且完成C 5 -C 15环烷基,环链二烯基或环烯基环部分; 并且其中R12,R13,R14,R16,R17,R28,R29,R30和R31表示氢或C1-C3不相邻的烷基; 其中s为0至10的整数; t是0到10的整数; v为1或2的整数; 条件是根据不等式,s和t之和在0和10之间:0 <= s + t <= 10; 0 <= s <= 10; 0 <= t <= 10。
    • 60. 发明授权
    • Para-c5 alky-substituted ethoxycyclohexanes, organoleptic uses thereof
and processes for preparing same
    • 对-C5烷基取代的乙氧基环己烷,其感官用途及其制备方法
    • US5583264A
    • 1996-12-10
    • US605446
    • 1996-02-26
    • Michael G. MonteleoneRichard A. WeissMarc D. EvansMarie R. Hanna
    • Michael G. MonteleoneRichard A. WeissMarc D. EvansMarie R. Hanna
    • C07C43/184C11B9/00C07C41/20
    • C11B9/0061C07C43/184C11B9/0034C07C2101/14
    • Described are compounds defined according to the structure: ##STR1## wherein Z represents para cyclohexylene or para phenylene and wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different methyl or hydrogen; and wherein R.sub.4 represents hydrogen, methyl or ethyl with the proviso that the sum of the carbon atoms in R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is 2. Also described are para-C.sub.5 alkyl-substituted ethoxycyclohexanes defined according to the structure: ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 represent the same or different methyl or hydrogen; and wherein R.sub.4 represents hydrogen, methyl or ethyl with the proviso that the sum of the carbon atoms in R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is 2 and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including but not limited to solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles and hair preparations; as well as processes for preparing said para-C.sub.5 alkyl-substituted ethoxycyclohexanes.
    • 描述的是根据以下结构定义的化合物:其中Z代表对亚环己基或对亚苯基,其中R 1,R 2和R 3是相同或不同的甲基或氢; 并且其中R 4表示氢,甲基或乙基,条件是R 1,R 2,R 3和R 4中的碳原子之和为2.还描述了根据以下结构定义的对C5烷基取代的乙氧基环己烷:其中 R1,R2和R3表示相同或不同的甲基或氢; 并且其中R 4表示氢,甲基或乙基,条件是R 1,R 2,R 3和R 4中的碳原子之和为2,并且其用于增强或增强香料组合物,古龙水和香料制品的香气,包括但不限于 固体或液体阴离子,阳离子,非离子或两性离子洗涤剂,织物柔软剂组合物,织物柔软剂制品和头发制剂; 以及制备所述对C5烷基取代的乙氧基环己烷的方法。