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1. 发明授权

US4536330A 1-Hydroxymethyl-2-acyl cyclopropane derivatives and esters and cyclic condensation products thereof, organoleptic uses of same and processes for preparing same 失效
标题翻译： 1-羟甲基-2-酰基环丙烷衍生物及其酯及其环状缩合产物，其感官用途及其制备方法
公开(公告)号：US4536330A
公开(公告)日：1985-08-20
申请号：US589510
申请日：1984-03-14
申请人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
发明人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , C11D3/50 , C11B9/00
CPC分类号： A23G4/06 , A23L27/203 , C11D3/50 , Y10S514/88 , Y10S514/881
摘要： Described are 1-hydroxymethyl-2-acyl cyclopropane derivatives defined according to the structure: ##STR1## wherein Z represents hydrogen, acyl having the structure: ##STR2## and substituted oxyacyl having the structure: ##STR3## and cyclic condensation products thereof having the structure: ##STR4## wherein R.sub.1, R.sub.2 and R.sub.3 represent C.sub.1 -C.sub.10 alkyl; wherein R.sub.1 ' represents C.sub.1 -C.sub.10 alkylidene and wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or C.sub.1 -C.sub.3 lower alkyl; processes for preparing same by means of a reaction of a halomethyloxirane or substituted halomethyloxirane with a substituted 1,3-propanedione derivative; and organoleptic uses of such 1-hydroxymethyl-2-acyl cyclopropane derivatives in augmenting or enhancing the aroma or taste of perfume compositions, perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, perfumed polymers, hair preparations and shampoos), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos.
摘要翻译：描述的是根据以下结构定义的1-羟甲基-2-酰基环丙烷衍生物：其中Z代表氢，具有以下结构的酰基：具有以下结构的取代的氧酰基：其具有下式的环状缩合产物：结构：其中R 1，R 2和R 3表示C 1 -C 10烷基; 其中R1'表示C1-C10亚烷基，其中R4，R5，R6和R7表示氢或C1-C3低级烷基; 通过卤代环氧丙烷或取代的卤代甲基环氧乙烷与取代的1,3-丙二酮衍生物的反应制备其的方法; 以及这种1-羟甲基-2-酰基环丙烷衍生物在增强或增强香料组合物，香料制品（例如固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品）中的香味或味道的感官用途，加香聚合物，头发制剂和洗发剂），古龙水，食品，口香糖，牙膏，药用产品和咀嚼烟草。

2. 发明授权

US4570008A 2-Alkylidenyl-3-oxabicyclo[3.1.0]hexanes 失效
标题翻译： 2-烷基亚基-3-氧杂二环[3.1.0]己烷
公开(公告)号：US4570008A
公开(公告)日：1986-02-11
申请号：US662680
申请日：1984-10-19
申请人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
发明人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , C11D3/50 , C07D307/93
CPC分类号： A23G4/06 , A23L27/203 , C11D3/50
摘要： Described are 1-hydroxymethyl-2-acyl cyclopropane derivatives defined according to the structure: ##STR1## wherein Z represents hydrogen, acyl having the structure: ##STR2## and substituted oxyacyl having the structure: ##STR3## and cyclic condensation products thereof having the structure: ##STR4## wherein R.sub.1, R.sub.2 and R.sub.3 represent C.sub.1 --C.sub.10 alkyl; wherein R.sub.1 ' represents C.sub.1 --C.sub.10 alkylidene and wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or C.sub.1 --C.sub.3 lower alkyl; processes for preparing same by means of a reaction of a halomethyloxirane or substituted halomethyloxirane with a substituted 1,3-propanedione derivative; and organoleptic uses of such 1-hydroxymethyl-2-acyl cyclopropane derivatives in augmenting or enhancing the aroma or taste of perfume compositions, perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, perfumed polymers, hair preparations and shampoos), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos.
摘要翻译：描述的是根据以下结构定义的1-羟甲基-2-酰基环丙烷衍生物：其中Z代表氢，具有以下结构的酰基：具有以下结构的取代的氧酰基：其具有下式的环状缩合产物：结构：其中R 1，R 2和R 3表示C 1 -C 10烷基; 其中R1'表示C1-C10亚烷基，其中R4，R5，R6和R7表示氢或C1-C3低级烷基; 通过卤代环氧丙烷或取代的卤代甲基环氧乙烷与取代的1,3-丙二酮衍生物的反应制备其的方法; 以及这种1-羟甲基-2-酰基环丙烷衍生物在增强或增强香料组合物，香料制品（例如固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品）中的香味或味道的感官用途，加香聚合物，头发制剂和洗发剂），古龙水，食品，口香糖，牙膏，药用产品和咀嚼烟草。

3. 发明授权

US4554095A Organoleptic uses of esters of 1-hydroxymethyl-2-acyl cylopropane 失效
标题翻译：感官使用1-羟甲基-2-酰基环丙烷的酯
公开(公告)号：US4554095A
公开(公告)日：1985-11-19
申请号：US630693
申请日：1984-07-13
申请人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
发明人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , C11D3/50 , A61K7/46
CPC分类号： A23G4/06 , A23L27/203 , C11D3/50
摘要： Described are 1-hydroxymethyl-2-acyl cyclopropane derivatives defined according to the structure: ##STR1## wherein Z represents hydrogen, acyl having the structure: ##STR2## and substituted oxyacyl having the structure: ##STR3## and cyclic condensation products thereof having the structure: ##STR4## wherein R.sub.1, R.sub.2 and R.sub.3 represent C.sub.1 -C.sub.10 alkyl; wherein R.sub.1 ' represents C.sub.1 -C.sub.10 alkylidene and wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or C.sub.1 -C.sub.3 lower alkyl; processes for preparing same by means of a reaction of a halomethyloxirane or substituted halomethyloxirane with a substituted 1,3-propanedione derivative; and organoleptic uses of such 1-hydroxymethyl-2-acyl cyclopropane derivatives in augmenting or enhancing the aroma or taste of perfume compositions, perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, perfumed polymers, hair preparations and shampoos), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos.
摘要翻译：描述的是根据以下结构定义的1-羟甲基-2-酰基环丙烷衍生物：其中Z代表氢，具有以下结构的酰基：具有以下结构的取代的氧酰基：其具有下式的环状缩合产物：结构：其中R 1，R 2和R 3表示C 1 -C 10烷基; 其中R1'表示C1-C10亚烷基，其中R4，R5，R6和R7表示氢或C1-C3低级烷基; 通过卤代环氧丙烷或取代的卤代甲基环氧乙烷与取代的1,3-丙二酮衍生物的反应制备其的方法; 以及这种1-羟甲基-2-酰基环丙烷衍生物在增强或增强香料组合物，香料制品（例如固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品）中的香味或味道的感官用途，加香聚合物，头发制剂和洗发剂），古龙水，食品，口香糖，牙膏，药用产品和咀嚼烟草。

4. 发明授权

US4534891A Branched C.sub.13 -alk-1-en-5-ones and use thereof in perfumery 失效
标题翻译：支链C13-烷-1-烯-5-酮及其在香料中的用途
公开(公告)号：US4534891A
公开(公告)日：1985-08-13
申请号：US574155
申请日：1984-01-26
申请人： Richard M. Boden , Steven D. Temes , Theodore J. Tyszkiewicz , Marie R. Hanna
发明人： Richard M. Boden , Steven D. Temes , Theodore J. Tyszkiewicz , Marie R. Hanna
IPC分类号： C07C2/28 , C07C29/48 , C07C45/28 , C07C45/45 , C07C45/68 , C07C49/203 , C07D303/04 , C11B9/00
CPC分类号： C11B9/0015 , C07C2/28 , C07C29/48 , C07C45/28 , C07C45/455 , C07C45/68 , C07C49/203 , C07D303/04 , C07C2531/06 , C07C2531/10 , Y10S514/844
摘要： Described are compounds defined according to the structure: ##STR1## wherein R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or methyl with the provisos that:(i) the sum total of carbon atoms in R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 is three;(ii) when R.sub.7 is methyl, then R.sub.5 and R.sub.6 are both methyl, and(iii) when either R.sub.3 or R.sub.4 is methyl, then R.sub.7 is hydrogenand wherein R.sub.8 represents hydrogen, acetyl, alkoxyacyl, hydroxyacyl, or alkali metal carboxylate; and R.sub.9 is hydrogen or allyl with the additional proviso that R.sub.8 and R.sub.9 are not both hydrogen.Also described is the use of the subgenus of such compounds defined according to the structure: ##STR2## in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including solid or liquid nonionic, cationic, anionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, cosmetic powders, hair preparations and the like.
摘要翻译：描述了根据以下结构定义的化合物：其中R 3，R 4，R 5，R 6和R 7表示氢或甲基，条件是：（i）R 3，R 4，R 5，R 6和R 7中的碳原子总和是三（ii）当R 7为甲基时，R 5和R 6均为甲基，（iii）当R 3或R 4为甲基时，R 7为氢，R 8为氢，乙酰基，烷氧基酰基，羟基酰基或碱金属羧酸盐; 并且R 9是氢或烯丙基，另外条件是R 8和R 9不都是氢。还描述了根据以下结构定义的这种化合物亚类的用途：在增加或增强香料组合物，古龙水和加香制品的芳香物质中包括固体或液体非离子，阳离子，阴离子或两性离子洗涤剂，织物柔软剂组合物织物柔软剂制品，化妆粉，头发制剂等。

5. 发明授权

US4500448A 1-Hydroxymethyl cyclopropanes organoleptic use of same 失效
标题翻译： 1-羟甲基环丙烷的感官使用相同
公开(公告)号：US4500448A
公开(公告)日：1985-02-19
申请号：US541275
申请日：1983-10-12
申请人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
发明人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , C11D3/50 , A61K7/46
CPC分类号： A23G4/06 , A23L27/203 , C11D3/50
摘要： Described are 1-hydroxymethyl-2-acyl cyclopropane derivatives defined according to the structure: ##STR1## wherein Z represents hydrogen, acyl having the structure: ##STR2## and substituted oxyacyl having the structure: ##STR3## and cyclic condensation products thereof having the structure: ##STR4## wherein R.sub.1, R.sub.2 and R.sub.3 represent C.sub.1 -C.sub.10 alkyl; wherein R.sub.1 ' represents C.sub.1 -C.sub.10 alkylidene and wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or C.sub.1 -C.sub.3 lower alkyl; processes for preparing same by means of a reaction of a halomethyloxirane or substituted halomethyloxirane with a substituted 1,3-propanedione derivative; and organoleptic uses of such 1-hydroxymethyl-2-acyl cyclopropane derivatives in augmenting or enhancing the aroma or taste of perfume compositions, perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, perfumed polymers, hair preparations and shampoos), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos.
摘要翻译：描述的是根据以下结构定义的1-羟甲基-2-酰基环丙烷衍生物：其中Z代表氢，具有以下结构的酰基：具有以下结构的取代的氧酰基：其具有下式的环状缩合产物：结构：其中R 1，R 2和R 3表示C 1 -C 10烷基; 其中R1'表示C1-C10亚烷基，其中R4，R5，R6和R7表示氢或C1-C3低级烷基; 通过卤代环氧丙烷或取代的卤代甲基环氧乙烷与取代的1,3-丙二酮衍生物的反应制备其的方法; 以及这种1-羟甲基-2-酰基环丙烷衍生物在增强或增强香料组合物，香料制品（例如固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品）中的香味或味道的感官用途，加香聚合物，头发制剂和洗发剂），古龙水，食品，口香糖，牙膏，药用产品和咀嚼烟草。

6. 发明授权

US4515987A Process for preparing a methoxybenzaldehyde from the corresponding phenolic benzaldehyde 失效
标题翻译：从相应的酚类苯甲醛制备甲氧基苯甲醛的方法
公开(公告)号：US4515987A
公开(公告)日：1985-05-07
申请号：US624757
申请日：1984-06-26
申请人： Richard M. Boden , Theodore J. Tyszkiewicz , Michael Licciardello , Manfred H. Vock , Joaquin F. Vinals , Patrick Whalen , Marie R. Hanna
发明人： Richard M. Boden , Theodore J. Tyszkiewicz , Michael Licciardello , Manfred H. Vock , Joaquin F. Vinals , Patrick Whalen , Marie R. Hanna
IPC分类号： A23G3/00 , A23G3/36 , A23G4/00 , A23G4/06 , C07C45/67 , C07D317/64 , C11B9/00 , C11D3/50 , C07C45/61
CPC分类号： A23G3/36 , A23G4/06 , C07C45/673 , C07D317/64 , C11B9/0061 , C11B9/0076 , C11D3/50 , Y10S514/835 , Y10S514/974
摘要： Described is a genus of compounds defined according to the structure: ##STR1## (Z) represents one of the moieties ##STR2## as well as the substantially pure compound defined according to the structure: ##STR3## and the use thereof for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, fabric softener articles, perfumed articles, hair preparations and the like.
摘要翻译：描述了根据以下结构定义的化合物属：（Z）代表部分中的一个以及根据以下结构定义的基本上纯的化合物：＆lt; IMAGE＆gt;及其用于增加或增强包括食品，口香糖，药用产品，牙膏，咀嚼烟草，烟草烟草，烟草制品，香水，古龙水和包括固体或液体阴离子，阳离子，非离子或两性离子洗涤剂的香料制品在内的消耗材料的香气或味道，织物柔软剂，织物柔软剂制品，香料制品，头发制剂等。

7. 发明授权

US4435428A Use in augmenting or enhancing the aroma or taste of foodstuff or chewing gum with the methyl carbonate of 1-hydroxymethyl-2-heptanoyl cyclopropane 失效
标题翻译：用于增加或增强食品或口香糖的芳香或味道与1-羟甲基-2-庚酰基环丙烷的碳酸甲酯
公开(公告)号：US4435428A
公开(公告)日：1984-03-06
申请号：US422486
申请日：1982-09-23
申请人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
发明人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , C11D3/50 , A23L1/226 , A23L1/235
CPC分类号： A23G4/06 , A23L27/203 , C11D3/50
摘要： Described is the use of the compound having the structure: ##STR1## in augmenting or enhancing the aroma or taste of foodstuffs and chewing gums.
摘要翻译：描述了具有以下结构的化合物在增加或增强食品和口香糖的香味或味道中的用途：。

8. 发明授权

US4430354A Flavoring with heliotropyl methyl carbonate 失效
标题翻译：用碳酸氢丙基甲酯调味
公开(公告)号：US4430354A
公开(公告)日：1984-02-07
申请号：US496648
申请日：1983-05-20
申请人： Richard M. Boden , Theodore J. Tyszkiewicz , Michael Licciardello , Manfred H. Vock , Joaquin F. Vinals , Patrick Whalen , Marie R. Hanna
发明人： Richard M. Boden , Theodore J. Tyszkiewicz , Michael Licciardello , Manfred H. Vock , Joaquin F. Vinals , Patrick Whalen , Marie R. Hanna
IPC分类号： A23G3/00 , A23G3/36 , A23G4/00 , A23G4/06 , C07C45/67 , C07D317/64 , C11B9/00 , C11D3/50 , A23L1/226
CPC分类号： A23G3/36 , A23G4/06 , C07C45/673 , C07D317/64 , C11B9/0061 , C11B9/0076 , C11D3/50
摘要： Described is a genus of compounds defined according to the structure: ##STR1## (Z) represents one of the moieties ##STR2## as well as the substantially pure compound defined according to the structure: ##STR3## and the use thereof for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, fabric softener articles, perfumed articles, hair preparations and the like.
摘要翻译：描述了根据以下结构定义的化合物属：（Z）代表部分中的一个以及根据以下结构定义的基本上纯的化合物：＆lt; IMAGE＆gt;及其用于增加或增强包括食品，口香糖，药用产品，牙膏，咀嚼烟草，烟草烟草，烟草制品，香水，古龙水和包括固体或液体阴离子，阳离子，非离子或两性离子洗涤剂的香料制品在内的消耗材料的香气或味道，织物柔软剂，织物柔软剂制品，香料制品，头发制剂等。

9. 发明授权

US4528142A 1-Hydroxymethyl-2-acyl cyclopropane derivatives and esters thereof 失效
标题翻译： 1-羟甲基-2-酰基环丙烷衍生物及其酯
公开(公告)号：US4528142A
公开(公告)日：1985-07-09
申请号：US541031
申请日：1983-10-12
申请人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
发明人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , C11D3/50 , C07C69/96 , C07C49/172 , C07C69/14
CPC分类号： A23G4/06 , A23L27/203 , C11D3/50
摘要： Described are 1-hydroxymethyl-2-acyl cyclopropane derivatives having one of the structures: ##STR1## and utilities thereof for their organoleptic properties.
摘要翻译：描述了具有以下结构之一的1-羟甲基-2-酰基环丙烷衍生物及其用于其感官特性的其用途。

10. 发明授权

US4481225A Flavoring with a 1-hydroxymethyl-2-acyl cyclopropane derivative 失效
标题翻译：用1-羟甲基-2-酰基环丙烷衍生物调味
公开(公告)号：US4481225A
公开(公告)日：1984-11-06
申请号：US556694
申请日：1983-11-30
申请人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
发明人： Richard M. Boden , Marie R. Hanna , Theodore J. Tyszkiewicz
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , C11D3/50 , A23L1/226 , A23L1/235
CPC分类号： A23G4/06 , A23L27/203 , C11D3/50
摘要： Described is the use of the compound having the structure: ##STR1## in augmenting or enhancing the aroma or taste of foodstuffs.
摘要翻译：描述了具有以下结构的化合物在增加或增强食物的香气或味道中的用途：。

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