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51. 发明授权

US4680367A Process for the production of urea group-containing polyisocyanates 失效
标题翻译：制备含脲基的多异氰酸酯的方法
公开(公告)号：US4680367A
公开(公告)日：1987-07-14
申请号：US783590
申请日：1985-10-03
申请人： Richard Kopp , Gerhard Grogler , Heinrich Hess , Klaus Konig
发明人： Richard Kopp , Gerhard Grogler , Heinrich Hess , Klaus Konig
IPC分类号： C08G18/00 , B01J13/00 , C07C273/18 , C08G18/02 , C08G18/08 , C08G18/30 , C08G18/70 , C08G18/72 , C08G18/78 , C08G18/80 , C08G18/83
CPC分类号： C08G18/703 , C07C273/1809 , C08G18/7825 , C08G18/8045
摘要： The present invention is directed to a process for the production of urea group-containing, finely divided solid polyisocyanates by emulsifying or suspending a urea group-free organic polyisoycanate in an excess of water so that said organic polyisocyanate amounts to about 1 to 65% by weight of the reaction mixture, said water containing about 0.01 to 5% by weight, based on the aqueous phase, of a protective colloid and reacting the organic polyisocyanate with water to yeild a urea group-containing polyisocyanate.
摘要翻译：本发明涉及通过在过量的水中乳化或悬浮不含脲基团的有机聚异氰酸酯来制备含尿素基团的细分固体多异氰酸酯的方法，使得所述有机多异氰酸酯的量为约1至65％反应混合物的重量，所述水含有基于水相的约0.01至5重量％的保护胶体，并使有机多异氰酸酯与水反应以产生含脲基的多异氰酸酯。

52. 发明授权

US4663415A Process for the preparation of stabilized polyamines, stabilized polyamines with retarded reactivity and their use for polyurethane production 失效
标题翻译：用于制备稳定的多胺，具有延迟反应性的稳定的多胺及其用于聚氨酯生产的方法
公开(公告)号：US4663415A
公开(公告)日：1987-05-05
申请号：US759818
申请日：1985-07-29
申请人： Gerhard Grogler , Richard Kopp , Heinrich Hess , Werner Rasshofer
发明人： Gerhard Grogler , Richard Kopp , Heinrich Hess , Werner Rasshofer
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/32 , C08G18/65 , C08G18/66 , C09D175/04 , C08G18/79
CPC分类号： C08G18/6618 , C08G18/10 , C08G18/3253
摘要： This invention relates to a process for the production of solid polyamines stabilized by a polyadduct covering and showing retarded reactivity comprising reacting(1) one or more solid organic polyamines in particulate form, said polyamines containing at least two primary and/or secondary amino groups and having melting points above 50.degree. C., and(2) from 0.1 to 25 equivalent % of isocyanate per amine equivalent of a water insoluble, difunctional and/or higher functional polyisocyanate,said reaction being conducted at a temperature below the melting point of said solid polyamine, and being conducted in the presence of(3) a liquid medium selected from the group consisting of(a) organic compounds containing two or more hydroxy groups and having molecular weights of from 62 to 10,000,(b) plasticizers,(c) water, and(d) mixtures thereofto form a suspension of polyadduct-covered stabilized polyamines in the liquid medium.
摘要翻译：本发明涉及用于生产由多加成分稳定的固体多胺的方法，其覆盖并显示延迟反应性，包括使（1）一种或多种颗粒形式的固体有机多胺，所述多胺含有至少两个伯和/或仲氨基和具有高于50℃的熔点，和（2）0.1至25当量异氰酸酯/胺当量的水不溶性，双官能和/或更高官能的多异氰酸酯，所述反应在低于所述固体多胺，并且在（3）选自（a）含有两个或多个羟基并且分子量为62至10,000的有机化合物的组分的存在下进行，（b）增塑剂，（c ）水，和（d）它们的混合物以在液体介质中形成多加合物覆盖的稳定化多胺的悬浮液。

53. 发明授权

US4623686A Storage stable compositions based on polyvinyl chloride plastisols and stabilized isocyanates 失效
标题翻译：基于聚氯乙烯增塑溶胶和稳定的异氰酸酯的储存稳定组合物
公开(公告)号：US4623686A
公开(公告)日：1986-11-18
申请号：US694562
申请日：1985-01-24
申请人： Helmut Hurnik , Gerhard Grogler , Heinrich Hess , Richard Kopp
发明人： Helmut Hurnik , Gerhard Grogler , Heinrich Hess , Richard Kopp
IPC分类号： C08G18/00 , C08G18/08 , C08G18/62 , C08G18/70 , C08G18/80 , C08K9/04 , C08L1/00 , C08L27/00 , C08L67/00 , C08L75/00 , C09D127/06 , C09D175/00 , D06N3/06 , C08K5/34
CPC分类号： D06N3/06 , C08G18/703 , C08G18/8003 , C08K9/04 , C09D127/06 , C08L75/00
摘要： The invention relates to novel compositions for coating purposes comprising(A) polyvinyl plastisols,(B) surface modified, finely divided, stabilized polyisocyanates with retarded reactivity, in which 0.1 to 25 equivalents-% of the isocyanate groups of the unstabilized polyisocyanate have been deactivated on the surface, preferably by a reaction with polyamines, hydrazine, alkylhydrazines, polyhydrazide compounds and/or selected amidine and/or guanidine compounds; and(C) plasticizers and/or lightly branched, relatively high molecular weight polyhydroxyl compounds having melting points below 60.degree. C. and compatible with PVC plastisol.The invention also relates to the use of these storage stable but heat curable mixtures as primers for PVC coatings on plastics, foils, textile sheet products or filaments and as primer coats for flocking.
摘要翻译：本发明涉及用于涂覆目的的新型组合物，其包含（A）聚乙烯基增塑溶胶，（B）具有延迟反应性的表面改性，细碎，稳定的多异氰酸酯，其中未稳定的多异氰酸酯的异氰酸酯基团的0.1至25当量已被去活化表面上优选通过与多胺，肼，烷基肼，聚酰肼化合物和/或选择的脒和/或胍化合物的反应; 和（C）具有熔点低于60℃并与PVC增塑溶胶相容的增塑剂和/或轻支化的相对高分子量的多羟基化合物。本发明还涉及这些储存稳定但可热固化的混合物作为塑料，箔，纺织品产品或长丝上的PVC涂料的底漆以及用于植绒的底漆涂层的用途。

54. 发明授权

US4587275A Process for the preparation of polyurethane elastomers 失效
标题翻译：制备聚氨酯弹性体的方法
公开(公告)号：US4587275A
公开(公告)日：1986-05-06
申请号：US429707
申请日：1982-09-30
申请人： Richard Kopp , Holger Meyborg , Gerhard Grogler , Jurgen Schwindt
发明人： Richard Kopp , Holger Meyborg , Gerhard Grogler , Jurgen Schwindt
IPC分类号： C08G18/00 , C08G18/10 , C08G18/32 , C08G18/38 , C08G18/65 , C08G18/14
CPC分类号： C08G18/3861 , C08G18/10
摘要： Polyurethane urea elastomers are produced by reacting polyisocyanates with compounds containing at least two isocyanate reactive hydrogen atoms having a molecular weight of 400 to 10,000 and mononuclear or dinuclear aromatic diamines. The aromatic diamines must have at least one sulfonamide group as a substituent on at least one of their aromatic rings. Known chain lengthening agents, activators, blowing agents, auxiliary agents and additives may also be included in the reaction mixture.Polyurethane elastomers produced by this process have excellent mechanical properties. In particular, such elastomers are soft yet have high tear propagation resistance.
摘要翻译：聚氨酯脲弹性体是通过使多异氰酸酯与分子量为400至10,000的至少两个异氰酸酯反应性氢原子和单核或双核芳族二胺的化合物反应来制备的。芳族二胺必须在至少一个它们的芳环上具有至少一个磺酰胺基作为取代基。已知的增链剂，活化剂，发泡剂，辅助剂和添加剂也可以包括在反应混合物中。通过该方法生产的聚氨酯弹性体具有优异的机械性能。特别地，这种弹性体是柔软的但具有高的抗撕裂传播性。

55. 植物专利

US20070083961P1 FAST-GROWING WILLOW SHRUB NAMED 'ONEIDA' 有权
标题翻译： FAST-GROWING WILLOW SHRUB NAMED'ONEIDA'
公开(公告)号：US20070083961P1
公开(公告)日：2007-04-12
申请号：US11244975
申请日：2005-10-06
申请人： Lawrence Abrahamson , Richard Kopp , Lawrence Smart , Timothy Volk
发明人： Lawrence Abrahamson , Richard Kopp , Lawrence Smart , Timothy Volk
IPC分类号： A01H5/00
CPC分类号： A01H5/00
摘要： A distinct male cultivar of Salix purpurea×S. miyabeana named ‘Oneida’, characterized by rapid stem growth producing 2.7-times greater woody biomass than one of its parents (‘SX67’) and greater than 36% more biomass than current production cultivars (‘SV1’ and ‘SX64’). ‘Oneida’ can be planted from dormant stem cuttings, produces multiple stems after coppice, and the stem biomass can be harvested when the plant is dormant. In the spring following harvest, the plant will re-sprout very vigorously, producing new stems that can be harvested after two to four years of growth. This harvest cycle can be repeated several times. The stem biomass can be chipped and burned as a source of renewable energy, generating heat and/or electricity. ‘Oneida’ displays a low incidence of rust disease or damage by beetles or sawflies.
摘要翻译：一个独特的男性品种的紫薇。名称为“Oneida”，其特征是茎干生长快，产生的木本生物量高于其父母（“SX67”）的2.7倍，生物量比目前的生产品种（“SV1”和“SX64”）多36％。 'Oneida'可以从休眠茎切割种植，在萌发后产生多个茎，并且当植物休眠时可以收获茎生物量。收获后的春天，植物将非常有力地重新发芽，产生新的茎，可以在两到四年的增长后收获。这个收获周期可以重复几次。茎生物质可以作为可再生能源的来源被切碎和燃烧，产生热和/或电。 “奥尼达”显示，甲虫或锯叶的锈病或损伤发生率低。

56. 植物专利

US20070083959P1 FAST-GROWING WILLOW SHRUB NAMED 'MILLBROOK' 有权
标题翻译： FAST-GROWING WILLOW SHRUB NAMED'MILLBROOK'
公开(公告)号：US20070083959P1
公开(公告)日：2007-04-12
申请号：US11244636
申请日：2005-10-06
申请人： Lawrence Abrahamson , Richard Kopp , Lawrence Smart , Timothy Volk
发明人： Lawrence Abrahamson , Richard Kopp , Lawrence Smart , Timothy Volk
IPC分类号： A01H5/00
CPC分类号： A01H5/00
摘要： A distinct female cultivar of Salix purpurea×Salix miyabeana named ‘Millbrook’, characterized by rapid stem growth producing 9% more woody biomass than one of its parents (‘SX64’) and 2% more biomass than a current production cultivar (‘SV1’). ‘Millbrook’ produced greater than 2-fold more stem biomass than two other current production cultivars, ‘SX67’ and ‘SX61’. ‘Millbrook’ can be planted from dormant stem cuttings, produces multiple stems after coppice, and the stem biomass can be harvested when the plant is dormant. In the spring following harvest, the plant will re-sprout very vigorously, producing new stems that can be harvested after two to four years of growth. This harvest cycle can be repeated several times. The stem biomass can be chipped and burned as a source of renewable energy, generating heat and/or electricity. ‘Millbrook’ displays a low incidence of rust disease.
摘要翻译：一个独特的女性品种Salix purpureaxSalix miyabeana，命名为“Millbrook”，其特征在于快速茎生长比其父母之一（“SX64”）生产木本生物质多9％，生物量比目前的生产栽培品种“SV1”多2％。 “Millbrook”比另外两个当前的生产品种“SX67”和“SX61”产生了超过2倍的茎生物量。 'Millbrook'可以从休眠茎切割种植，在萌发后产生多个茎，当植物休眠时，可以收获茎生物量。收获后的春天，植物将非常有力地重新发芽，产生新的茎，可以在两到四年的增长后收获。这个收获周期可以重复几次。茎生物质可以作为可再生能源的来源被切碎和燃烧，产生热和/或电。 “Millbrook”表现出低发病率的锈病。

57. 植物专利

US20070083958P1 FAST-GROWING SHRUB WILLOW NAMED 'TULLY CHAMPION' 有权
标题翻译： FAST-GROWING SHRUB WILLOW NAMED'TULLY CHAMPION'
公开(公告)号：US20070083958P1
公开(公告)日：2007-04-12
申请号：US11244635
申请日：2005-10-06
申请人： Lawrence Abrahamson , Richard Kopp , Lawrence Smart , Timothy Volk
发明人： Lawrence Abrahamson , Richard Kopp , Lawrence Smart , Timothy Volk
IPC分类号： A01H5/00
CPC分类号： A01H5/04
摘要： A distinct female cultivar of Salix viminalis×S. miyabeana named ‘Tully Champion’, characterized by rapid stem growth producing greater than 25% more woody biomass than two current production clones (Salix dasyclados ‘SV1’ and Salix miyabeana ‘SX64’), more than 2.5-fold greater biomass than one of its parents (Salix miyabeana ‘SX67’), and nearly 3-fold more biomass than another production clone (Salix sacchalinensis, ‘SX61’) when grown in the same field for the same length of time (two growing seasons after coppice) in Tully, N.Y. ‘Tully Champion’ can be planted from dormant stem cuttings, produces multiple stems after coppice, and the stem biomass can be harvested when the plant is dormant. In the spring following harvest, the plant will re-sprout very vigorously, producing new stems that can be harvested repeatedly after two to four years of growth. ‘Tully Champion’ displays a low incidence of rust disease and is not damaged by potato leafhoppers.
摘要翻译：一个独特的女性品种Salix viminalisxS。 miyabeana命名为“Tully Champion”，其特征在于快速的茎生长比两个当前生产的克隆（Salix dasyclados'SV1'和Salix miyabeana'SX64'）产生的木本生物质多出25％以上，其生物量比其中之一高2.5倍父母（Salix miyabeana'SX67'），并且在同一领域在相同时间段（两次生殖季节之后）在Tully中生长时，比另一种生产克隆（Salix sacchalinensis，“SX61”）的生物量高近三倍， NY'Tully Champion'可以从休眠茎切割种植，在萌发后产生多个茎，当植物休眠时可以收获茎生物量。收获后的春天，植物将非常旺盛地重新发芽，产生新的茎，可以在两到四年的发育后多次收获。 “Tully Champion”显示锈病发病率低，不会被马铃薯叶蝉破坏。

58. 发明授权

US5183876A Urea group-containing polyisocyanates modified with long chain compounds and a process for their preparation 失效
标题翻译：用长链化合物改性的含脲基的多异氰酸酯及其制备方法
公开(公告)号：US5183876A
公开(公告)日：1993-02-02
申请号：US651693
申请日：1991-02-06
申请人： Richard Kopp , Gerhard Grogler , Heinrich Hess
发明人： Richard Kopp , Gerhard Grogler , Heinrich Hess
IPC分类号： C08G18/10 , C08G18/78
CPC分类号： C08G18/7825 , C08G18/10
摘要： The present invention is directed to novel urea group-containing polyisocyanates modified with long chain compounds having molecular weights of 400 to about 10,000. The present invention is also directed to a process for the preparation of modified urea group-containing polyisocyanates by reacting starting polyisocyanates which are free from urea groups with water to form urea groups in an inert reaction medium or in an aqueous mixture containing a dispersion stabilizer, wherein the starting polyisocyanates are mixed or reacted with long chain compounds having molecular weights of 400 to about 10,000 before the reacting the starting polyisocyanates with water and/or the long chain compounds are added to the inert reaction medium and/or to the water.
摘要翻译：本发明涉及用分子量为400至10,000的长链化合物改性的新型含脲基的多异氰酸酯。本发明还涉及通过在惰性反应介质中或含有分散稳定剂的含水混合物中将不含脲基的起始多异氰酸酯与水反应以形成脲基的方法制备含改性脲基的多异氰酸酯的方法，其中起始多异氰酸酯与分子量为400至约10,000的长链化合物混合或反应，然后将起始多异氰酸酯与水和/或长链化合物反应加入到惰性反应介质和/或水中。

59. 发明授权

US5104959A Polyurethane-based reactive adhesives in which the isocyanate is stabilized by a polyether amine 失效
标题翻译：基于聚氨酯的反应性粘合剂，其中异氰酸酯由聚酯胺稳定
公开(公告)号：US5104959A
公开(公告)日：1992-04-14
申请号：US536140
申请日：1990-06-11
申请人： Heinrich Hess , Richard Kopp , Gerhard Groglerl , Horst Stepanski , Rudolf Hombach , Walter Schafer
发明人： Heinrich Hess , Richard Kopp , Gerhard Groglerl , Horst Stepanski , Rudolf Hombach , Walter Schafer
IPC分类号： C09J175/08 , C08G18/32 , C08G18/50 , C08G18/66 , C08G18/70 , C09J20060101 , C09J171/10 , C09J175/00 , C09J175/12
CPC分类号： C08G18/3243 , C08G18/5024 , C08G18/6685 , C08G18/707 , C09J175/12 , Y10S528/902 , Y10S528/905
摘要： The present invention is directed to a polyurethane-based reactive adhesive comprising A) at least one polyisocyanate, B) at least one polyol, and C) at least one polyamine C which is a polyether amine containing at least two amino groups, at least one phenyl group and recurring polyoxyalkylene units.
摘要翻译：本发明涉及一种基于聚氨酯的反应性粘合剂，其包含A）至少一种多异氰酸酯，B）至少一种多元醇，和C）至少一种聚胺C，其是含有至少两个氨基的聚醚胺，至少一种苯基和重复的聚氧化烯单元。

60. 发明授权

US5064875A Process for the preparation of heat-stable polyurethane urea elastomers 失效
标题翻译：制备耐热聚氨酯脲弹性体的方法
公开(公告)号：US5064875A
公开(公告)日：1991-11-12
申请号：US620986
申请日：1990-11-30
申请人： Gerhard Grogler , Urs Thiery , Andreas Ruckes , Richard Kopp , Heinrich Hess
发明人： Gerhard Grogler , Urs Thiery , Andreas Ruckes , Richard Kopp , Heinrich Hess
IPC分类号： C08G18/10 , C08G18/32 , C08G18/65
CPC分类号： C08G18/6529 , C08G18/10 , C08G18/3243 , C08G2101/0008 , C08G2101/0016 , C08G2101/0033 , C08G2120/00
摘要： This invention relates to a process for preparing polyurethane urea elastomers by reacting (a) compounds containing at least two isocyanate-reactive groups and having a molecular weight in the range from about 400 to about 10,000; (b) polyisocyanates; and (c) aromatic diamines corresponding to the formula ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen or alkyl.
摘要翻译：本发明涉及通过使（a）含有至少两个异氰酸酯反应性基团并且分子量在约400至约10,000范围内的化合物反应来制备聚氨酯脲弹性体的方法; （b）多异氰酸酯; 和（c）对应于式 + TR 的芳族二胺，其中R 1和R 2独立地是氢或烷基。

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