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    • 53. 发明申请
    • INCREASING FRACTURE COMPLEXITY IN ULTRA-LOW PERMEABLE SUBTERRANEAN FORMATION USING DEGRADABLE PARTICULATE
    • 使用可降解颗粒物在超低渗透率下层形成中增加裂缝复杂度
    • WO2012104582A1
    • 2012-08-09
    • PCT/GB2012/000097
    • 2012-01-30
    • HALLIBURTON ENERGY SERVICES INC.TODD, Bradley LeonWELTON, Thomas DTURNER, Craig Robert
    • TODD, Bradley LeonWELTON, Thomas D
    • C09K8/70C09K8/80C09K8/88
    • C09K8/70C09K8/80C09K8/86C09K8/885C09K2208/18E21B43/261
    • A method of increasing the fracture complexity in a treatment zone of a subterranean formation is provided. The subterranean formation is characterized by having a matrix permeability less than 1.0 microDarcy (9.869233 x 10 -19 m 2 ). The method includes the step of pumping one or more fracturing fluids into a far-field region of a treatment zone of the subterranean formation at a rate and pressure above the fracture pressure of the treatment zone. A first fracturing fluid of the one or more fracturing fluids includes a first solid particulate, wherein: (a) the first solid particulate includes a particle size distribution for bridging the pore throats of a proppant pack previously formed or to be formed in the treatment zone; and (b) the first solid particulate comprises a degradable material. In an embodiment, the first solid particulate is in an insufficient amount in the first fracturing fluid to increase the packed volume fraction of any region of the proppant pack to greater than 73%. Similar methods using stepwise fracturing fluids and remedial fracturing treatments are provided.
    • 提供了一种增加地下地层处理区的断裂复杂性的方法。 地层的特征在于具有小于1.0微加仑(9.869233×10-19m2)的基质渗透性。 该方法包括以高于处理区的断裂压力的速率和压力将一个或多个压裂流体泵送到地层的处理区的远场区域的步骤。 一个或多个压裂流体的第一压裂流体包括第一固体颗粒,其中:(a)第一固体颗粒包括用于桥接预先形成或将要在处理区中形成的支撑剂组的孔喉的粒度分布 ; 和(b)第一固体颗粒包含可降解材料。 在一个实施方案中,第一固体颗粒在第一压裂流体中的量不足以将支撑剂组的任何区域的填充体积分数增加至大于73%。 提供了使用逐步压裂流体和补救压裂处理的类似方法。
    • 58. 发明申请
    • MODIFICATION OF SOLID POLYSACCHARIDE WITH TRANSESTERIFICATION AGENT
    • 固体多糖与改性剂的改性
    • WO2012052716A1
    • 2012-04-26
    • PCT/GB2011/001502
    • 2011-10-19
    • HALLIBURTON ENERGY SERVICES, INC.REDDY, Raghava, B.TURNER, Craig, Robert
    • REDDY, Raghava, B.
    • C09K8/08C09K8/40C09K8/514C09K8/90
    • C09K8/08C09K8/40C09K8/514C09K8/90
    • Polysaccharides, for example xanthan, diutan, scleroglucan, gums, celluloses, and starches, and derivatives of the foregoing, are reacted with organic carbonates forming products that: (1) have increased viscosifying efficiency, i.e., higher viscosities at reduced concentrations compared to the unmodified polysaccharide; or (2) are insolubilized at temperature ranges for which the unmodified polysaccharide would hydrate fully; or (3) both properties. In some cases, the insolubilized polysaccharides can be activated to dissolve and viscosify at specific temperature ranges by using pH modifiers. A method of treating a well is provided, including the steps of: (a) obtaining a modified polysaccharide characterized by having been made by the process of combining: (i) a water-soluble polysaccharide, wherein the polysaccharide is in a solid form during the combining step; and (ii) a transesterification agent, wherein the transesterification agent is in liquid form; wherein the step of combining is in the presence of less than 10% by weight water relative to the water-soluble polysaccharide and wherein any water present is at a pH of 8 or less; (b) forming a treatment fluid comprising the modified polysaccharide and water; and (c) introducing the treatment fluid into the well.
    • 将多糖,例如黄原胶,二硬脂酸,硬葡聚糖,树胶,纤维素和淀粉以及前述衍生物与有机碳酸酯反应,形成产物:(1)具有增加的增粘效率,即与浓度相比降低的浓度下的较高粘度 未改性多糖; 或(2)在未改性多糖将完全水合的温度范围内不溶; 或(3)两种性质。 在一些情况下,不溶性多糖可以通过使用pH调节剂被活化以在特定温度范围溶解和粘稠。 提供了一种处理井的方法,包括以下步骤:(a)获得改性多糖,其特征在于通过以下方法制备的:(i)水溶性多糖,其中多糖在固体形式期间 组合步骤 和(ii)酯交换剂,其中所述酯交换剂为液体形式; 其中组合步骤相对于水溶性多糖存在小于10重量%的水,并且其中存在的任何水的pH为8以下; (b)形成包含改性多糖和水的处理流体; 和(c)将处理​​流体引入井中。
    • 60. 发明申请
    • METHOD FOR DISPERSING AQUEOUS BASED DRILLING FLUID FOR DRILLING SUBTERRANEAN BOREHOLES
    • 用于钻井水下钻孔的基于水性钻井液的方法
    • WO2012028844A1
    • 2012-03-08
    • PCT/GB2011/001279
    • 2011-08-26
    • HALLIBURTON ENERGY SERVICES, INC.NZEADIBE, Kingsley, IhuezePEREZ, Gregory, PaulTURNER, Craig, Robert
    • NZEADIBE, Kingsley, IhuezePEREZ, Gregory, Paul
    • C09K8/035C09K8/20C09K8/24
    • C09K8/08C09K8/12C09K8/24
    • An inhibitive water-based polymer mud system and method for using the system in drilling and in stabilizing wellbores is disclosed for use in water sensitive formations as an alternative to oil-based muds or water-based muds comprising ferro-chrome lignosulfonates. The system comprises a fresh water or salt water base thinned or dispersed with a sulfonated acrylic copolymer having a hybrid/graft lignosulfonate multipolymer structure containing carboxylate and sulfonate functional groups with synthetic polymer side chains covalently linked to a base lignosulfonate material, having a molecular weight in the range of about 1,000 to about 15,000, and having a high anionic charge density. This system is effective and has stable rheology over a broad pH range, even at a near neutral pH of 8.0. The drilling fluids do not contain heavy metals and are Theologically tolerant to contaminants such as cement, anhydrite and sodium and temperatures as high as about 400°F.
    • 公开了一种用于钻井和稳定井筒的抑制性水基聚合物泥浆系统和方法,用于水敏性地层中,作为包含铁 - 铬木质素磺酸盐的油基泥浆或水基泥浆的替代物。 该系统包含用磺化丙烯酸共聚物稀释或分散的淡水或盐水基质,其具有含羧酸盐和磺酸盐官能团的杂化/接枝木素磺酸盐多聚体结构,其中共聚合物侧链共价连接到碱性木质素磺酸盐材料上,分子量为 约1,000至约15,000的范围,并且具有高的阴离子电荷密度。 该系统是有效的,并且在宽pH范围内具有稳定的流变性,甚至在8.0的接近中性pH下。 钻井液不含重金属,并且具有对水泥,无水石膏和钠等污染物的理论耐受性,温度高达约400°F。