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    • 41. 发明授权
    • Method of purifying glutamic acid by transition recrystallization
    • 通过过渡重结晶纯化谷氨酸的方法
    • US06881861B2
    • 2005-04-19
    • US10761253
    • 2004-01-22
    • Yoshiki SaitouTakayuki KodaHiroshi UedaKazuhiro Sato
    • Yoshiki SaitouTakayuki KodaHiroshi UedaKazuhiro Sato
    • C12P13/14C07C227/42C07C229/24C07C229/00C07C227/00
    • C07C227/42C07C229/24
    • Disclosed herein is a method of purifying L-glutamic acid by transformation recrystallization which method comprises maintaining crude crystals of L-glutamic acid containing α crystals of L-glutamic acid in an aqueous solvent at a temperature of from 50° C. to the boiling point of said aqueous solvent in the coexistence of active carbon until about 30% or more of the crystals of L-glutamic acid have been transformed into β crystals thereof, the amount of said aqueous solvent being an amount not more than the amount sufficient (i.e., an amount insufficient) to form a saturated solution of said crystals of L-glutamic acid, according to which method purified crystals of L-glutamic acid can be obtained extremely rapidly and in high yields, and remarkably conveniently and easily on an industrial scale, as compared with the conventional transformation recrystallization method which is a hitherto common purification method of L-glutamic acid.
    • 本文公开了通过转化重结晶纯化L-谷氨酸的方法,该方法包括将含有L-谷氨酸的α晶体的L-谷氨酸的粗晶体在水溶剂中在50℃至沸点 的所述水性溶剂在活性炭的共存下直至约30%以上的L-谷氨酸晶体转变为β晶体,所述水性溶剂的量不大于足够的量(即, 不足量),形成所述L-谷氨酸晶体的饱和溶液,根据该方法可以非常快速且高产率地获得纯化的L-谷氨酸晶体,并且在工业规模上非常方便和容易地获得,如 与常规的转化重结晶方法相比,该方法是迄今常见的L-谷氨酸纯化方法。
    • 48. 发明授权
    • Sheet for protecting paint films of automobiles
    • 用于保护汽车漆膜的片材
    • US06395390B1
    • 2002-05-28
    • US09406815
    • 1999-09-28
    • Tsuyoshi InoueKenichi ShibataKenji SanoAkira WakabayashiKeiji HayashiShuuji SugimotoKomaharu MatsuiTakeshi EdaHiroshi Ueda
    • Tsuyoshi InoueKenichi ShibataKenji SanoAkira WakabayashiKeiji HayashiShuuji SugimotoKomaharu MatsuiTakeshi EdaHiroshi Ueda
    • C09J704
    • C09J7/04B32B7/12B32B27/12C09J7/21C09J7/29C09J2201/28C09J2203/306C09J2400/263C09J2453/00Y10T428/28Y10T442/2738Y10T442/2746Y10T442/2754
    • A sheet for protecting paint films of automobiles which can prevent the paint film of automobiles from suffering from damages such as discoloration and denaturation even if rainwater or washer penetrates into the gap between the adhesive cover and the paint film while achieving excellent protection function to suspended matters, colliding matters, etc. inherent to protecting sheets and being easily peeled off and removed after completion of the desired protection. The sheet for protecting paint films of automobiles comprises a pressure-sensitive adhesive layer having a roughened surface provided on a substrate made of fiber sheet. Even when rainwater, washer, etc. penetrates into the gap between the pressure-sensitive adhesive layer and the paint film of automobiles from wrinkles formed thereon, the liquid diffuses by capillary action through the gap developed by the roughened pressure-sensitive adhesive layer, making it possible to avoid the residence and concentration of the penetrated dirty water and hence prevent the occurrence of damages such as discoloration and denaturation of the paint film. Further, the arrangement of a pressure-sensitive adhesive layer having a roughened surface reflecting the fiber constituting the protecting sheet, particularly a fibrous continuous roughened surface, makes it possible to further diffuse the contaminating dirty water and hence further avoid the retention and concentration of the penetrated dirty water. Thus, the damages on the paint film can be more securely prevented.
    • 一种用于保护汽车漆膜的片材,即使雨水或垫片渗透到胶粘剂盖和漆膜之间的间隙中也能够防止汽车漆膜遭受损坏,例如变色和变性,同时对悬浮物实现优异的保护功能 ,碰撞物等,以保护片材,并在完成所需保护之后容易地剥离和除去。 用于保护汽车漆膜的片材包括设置在由纤维片制成的基材上的具有粗糙表面的压敏粘合剂层。 即使雨水,洗涤器等渗透到压敏粘合剂层和汽车漆膜之间的间隙中,由于毛孔作用而通过由粗糙化的压敏粘合剂层形成的间隙而扩散, 可以避免渗透的脏水的滞留和浓缩,从而防止出现诸如漆膜的变色和变性的损害。 此外,具有反映构成保护片的纤维的粗糙表面的压敏粘合剂层的布置,特别是纤维连续粗糙化表面,使得可以进一步扩散污染的污水,因此进一步避免了保留和保留 渗透脏水。 因此,可以更可靠地防止漆膜上的损伤。
    • 50. 发明授权
    • Method for producing purified phenylenedioxydiacetic acids
    • 纯化苯二氧基二乙酸生产方法
    • US06316666B1
    • 2001-11-13
    • US09495951
    • 2000-02-02
    • Junji MorimotoTakashi KamikawaHiroshi Ueda
    • Junji MorimotoTakashi KamikawaHiroshi Ueda
    • C07C5948
    • C07C51/367C07C51/43C07C59/70
    • A method for producing phenylenedioxydiacetic acids of high purity at high yield from crude phenylenedioxydiacetic acids which mainly contains phenylenedioxydiacetic acids represented by the following general formula (I): wherein, R represents a hologen, carboxyl group or hydrocarbon group having 1-4 carbon atoms, and n represents an integer from 0 to 3, wherein an alkaline aqueous solution of the crude phenylenedioxydiacetic acids is mixed with a mineral acid to precipitate the phenylenedioxydiacetic acids, wherein at least 10% by weight of the alkaline aqueous solution is mixed with a mineral acid at 0 to 50° C.; and, after completion of the mixing, the temperature of the mixture is kept at 80 to 110° C.
    • 由以下通式(I)表示的主要含有亚苯基二氧二乙酸的粗亚苯基二氧基二乙酸生产高纯度亚苄二氧基二乙酸的方法:其中,R表示氢原子,羧基或具有1-4个碳原子的烃基, n表示0〜3的整数,将亚苯基二氧二乙酸粗碱的碱性水溶液与无机酸混合,使亚苯二氧基二乙酸沉淀,其中将至少10重量%的碱性水溶液与无机酸 在0至50℃。 混合完成后,将混合物的温度保持在80〜110℃。