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41. 发明授权

US4380598A Flame retardant polyarylate compositions 失效
标题翻译：阻燃聚芳酯组合物
公开(公告)号：US4380598A
公开(公告)日：1983-04-19
申请号：US233693
申请日：1981-02-12
申请人： Lloyd M. Robeson , Markus Matzner
发明人： Lloyd M. Robeson , Markus Matzner
IPC分类号： C08K5/00 , C08K5/06 , C08K5/41 , C08K5/42 , C08L1/00 , C08L7/00 , C08L21/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L67/02 , C08L67/03 , C08L77/00
CPC分类号： C08K5/42 , C08L67/03
摘要： Described herein are flame retardant molding compositions comprising a blend of a polyarylate derived from a dihydric phenol and an aromatic dicarboxylic acid and a flame retardant additive which is a metal salt of an aromatic sulfonic acid. The composition may additionally contain one or more thermoplastic polymers.
摘要翻译：本文描述的是包含衍生自二元酚和芳族二羧酸的多芳基化合物和作为芳族磺酸的金属盐的阻燃添加剂的共混物的阻燃模塑组合物。该组合物可另外含有一种或多种热塑性聚合物。

42. 发明授权

US4045180A Apparatus for copolymerizing gaseous monomers 失效
标题翻译：用于共聚气态单体的装置
公开(公告)号：US4045180A
公开(公告)日：1977-08-30
申请号：US693131
申请日：1976-06-04
申请人： Robert Hayward Young , Markus Matzner
发明人： Robert Hayward Young , Markus Matzner
IPC分类号： C08F2/00 , C08F2/34 , C08F10/00 , B01J1/00
CPC分类号： C08F2/34 , C08F10/00 , Y10T137/0329 , Y10T137/4673 , Y10T137/4857
摘要： Apparatus for copolymerizing at least two gaseous monomers to form block copolymers or gradient copolymers comprising a closed reactor for receiving the monomers and subjecting them to copolymerizing conditions, at least three feed tanks for containing the monomers under pressure, a first feed manifold connecting one end of each feed tank to the reactor, first valve means in the first manifold for controlling flow therein between the first and second feed tank, between the second and third feed tank and between the feed tanks and the reactor, a second feed manifold connecting the other end of each feed tank to the reactor, and second valve means in the second manifold for controlling flow from each feed tank into the second manifold.
摘要翻译：用于使至少两种气态单体共聚以形成嵌段共聚物或梯度共聚物的装置，其包含用于接收单体的封闭反应器和使它们共聚的条件，至少三个用于在压力下容纳单体的进料罐，连接一个每个进料罐到反应器，第一歧管中的第一阀装置用于控制在第一和第二进料罐之间，第二和第三进料罐之间以及进料罐和反应器之间的流动，第二进料歧管连接另一端以及第二歧管中用于控制从每个进料罐进入第二歧管的流量的第二阀装置。

43. 发明授权

US5147967A High strength polymer of hydroquinone poly(iso-terephthalate) containing residues of p-hydroxybenzoic acid 失效
标题翻译：含有对羟基苯甲酸残基的氢醌聚（对苯二甲酸丙二醇酯）的高强度聚合物
公开(公告)号：US5147967A
公开(公告)日：1992-09-15
申请号：US499483
申请日：1990-06-04
申请人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
发明人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
IPC分类号： C08G63/60 , C08G63/83 , C08K7/02 , C08L67/00
CPC分类号： C08K7/02 , C08G63/605 , C08G63/83 , C08L67/00
摘要： This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention".The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree. C., when measured under a load of 264 psi. The polymers may be blended to tailor properties. These polymers and blends may be used advantageously in producing fibers and in electrical equipment, electronic components and other end uses requiring moderately high temperatures.
摘要翻译： PCT No.PCT / US89 / 04331 Sec。 371日期1990年6月4日第 102（e）1990年6月4日PCT PCT。于1989年10月10日提交。本发明涉及基本上由单元（I），（II），（III）和（IV）组成的新型共聚酯。这些聚合物和由两者制成的制品的混合物。单位（I），（II），（III）和（IV）按照“发明描述”中定义的特定比例存在。立即共聚酯显示熔融状态的取向，良好的纤维等级和高强度。有利地，本发明的聚合物显示出纯聚合物的粘度和可模塑性的显着改善。该聚合物具有优异的机械和表面性能，包括起泡性，强度，韧性和气相焊料的能力，并形成强力纤维，同时仍保持高的热变形温度。它们的熔点在约250℃至约360℃的范围内，并且是可熔融加工的。有利地，填充有约30重量％的玻璃纤维的这些组合物在264psi的载荷下测量时，显示高达240℃的热变形温度。聚合物可以混合以定制特性。这些聚合物和共混物可以有利地用于生产纤维和电气设备，电子部件和需要适度高温的其它最终用途。

44. 发明授权

US4975470A Blends comprising poly(aryl ether ketone co-carbonates) 失效
标题翻译：包含聚（芳醚酮共碳酸酯）
公开(公告)号：US4975470A
公开(公告)日：1990-12-04
申请号：US362051
申请日：1989-06-06
申请人： Markus Matzner , Barry D. Dean , Donald M. Papuga
发明人： Markus Matzner , Barry D. Dean , Donald M. Papuga
IPC分类号： C08L65/00 , C08L69/00 , C08L71/00 , C08L79/08 , C08L81/02
CPC分类号： C08L79/08 , C08L69/00 , C08L71/00 , C08L81/02 , C08L65/00
摘要： Blends comprising from about 1 to about 99 percent by weight of a poly(aryl ether ketone co-carbonate) and from about 99 to about 1 percent by weight of a thermoplastic polymer selected from the group of a poly(aryl ether ketone), a poly(arylene sulfide), a poly(ether imide) or a poly(aryl ether).
摘要翻译：包含约1-约99重量％的聚（芳基醚酮碳酸酯）和约99至约1重量％的热塑性聚合物的共混物，所述热塑性聚合物选自聚（芳基醚酮），聚（亚芳基硫醚），聚（醚酰亚胺）或聚（芳基醚）。

45. 发明授权

US4746709A Copolymers of polyphenylene oxides and polyarylates 失效
标题翻译：聚苯醚和多芳基化合物的共聚物
公开(公告)号：US4746709A
公开(公告)日：1988-05-24
申请号：US889305
申请日：1986-07-28
申请人： Markus Matzner , Donald M. Papuga
发明人： Markus Matzner , Donald M. Papuga
IPC分类号： C08G63/672 , C08G81/00 , C08L55/02 , C08L67/03 , C08G63/18
CPC分类号： C08L55/02 , C08G63/672 , C08G81/00 , C08L67/03
摘要： Described are novel copolymers of polyphenylene oxides and polyarylates. These copolymers are readily compatible with styrene polymers and copolymers and give tough binary, ternary and quaternary blends.
摘要翻译：描述了聚苯醚和多芳基化合物的新型共聚物。这些共聚物容易与苯乙烯聚合物和共聚物相容，并提供坚硬的二元，三元和四元共混物。

46. 发明授权

US4619975A Novel poly(aryl ether)- polyester block copolymers 失效
标题翻译：新型聚（芳基醚） - 聚酯嵌段共聚物
公开(公告)号：US4619975A
公开(公告)日：1986-10-28
申请号：US772881
申请日：1985-09-05
申请人： Markus Matzner , Donald M. Papuga
发明人： Markus Matzner , Donald M. Papuga
IPC分类号： C08G65/40 , C08G63/19 , C08G63/66 , C08G63/672 , C08G63/688 , C09K19/38 , C08G81/00
CPC分类号： C08G63/6886 , C08G63/672 , C09K19/3814
摘要： Described herein are novel block copolymers wherein one block is a poly(aryl ether) oligomer and the other block is a liquid crystalline polyester oligomer. Processes for the preparation of the subject copolymers are also described. The novel block copolymers display excellent mechanical properties, good high temperature stability and excellent solvent and chemical resistance.
摘要翻译：本文描述的是新的嵌段共聚物，其中一个嵌段是聚（芳基醚）低聚物，另一个嵌段是液晶聚酯低聚物。还描述了制备目标共聚物的方法。新型嵌段共聚物显示出优异的机械性能，良好的高温稳定性和优异的溶剂和耐化学性。

47. 发明授权

US4321355A Process for preparing polyarylates 失效
标题翻译：多芳基化合物的制备方法
公开(公告)号：US4321355A
公开(公告)日：1982-03-23
申请号：US189561
申请日：1980-09-23
申请人： Louis M. Maresca , Markus Matzner , Benito See
发明人： Louis M. Maresca , Markus Matzner , Benito See
IPC分类号： C08L101/00 , C08G63/00 , C08G63/18 , C08G63/19 , C08G63/81 , C08L33/00 , C08L33/02 , C08L67/00 , C08L67/03 , C08L77/00
CPC分类号： C08G63/81 , C08G63/19 , C08L67/03
摘要： Described herein is an improved process for preparing a polyarylate having a reduced viscosity of from about 0.5 to greater than 1.0 dl/gm which process comprises the following steps:(a) reacting an acid anhydride derived from an acid containing from 2 to 8 carbon atoms with at least one dihydric phenol to form the corresponding diester; and(b) reacting said diester with at least one aromatic dicarboxylic acid at a temperature sufficient to form the polyarylate, wherein the improvement comprises removing residual acid anhydride, after formation of the dihydric phenol diester, so that its concentration is less than about 1500 parts per million. The novel polyarylates produced by the improved process of this invention are melt stable and low in color.
摘要翻译：本文描述的是制备具有约0.5至大于1.0dl / gm的比浓粘度的多芳基化合物的改进方法，该方法包括以下步骤：（a）使来自含有2至8个碳原子的酸的酸酐与至少一种二元酚形成相应的二酯; 和（b）在足以形成多芳基化合物的温度下使所述二酯与至少一种芳族二羧酸反应，其中所述改进包括在形成二元酚二酯后除去残余的酸酐，使得其浓度小于约1500份百万。通过本发明改进方法生产的新型聚芳酯熔融稳定，颜色低。

48. 发明授权

US5296542A Heat resistant polymers and blends of hydroquinone poly (isoterephthalates) containing residues of p-hydroxybenzoic acid 失效
标题翻译：含有对羟基苯甲酸残基的氢醌聚（对苯二甲酸丙二醇酯）的耐热聚合物和共混物
公开(公告)号：US5296542A
公开(公告)日：1994-03-22
申请号：US790663
申请日：1991-11-08
申请人： Richard Layton , James W. Cleary , Paul J. Huspeni , Paul D. Frayer , Markus Matzner
发明人： Richard Layton , James W. Cleary , Paul J. Huspeni , Paul D. Frayer , Markus Matzner
IPC分类号： C08G63/60 , C08G63/83 , C08K7/02 , C08L67/00 , C08F20/00 , C08G63/00 , C08G63/02
CPC分类号： C08K7/02 , C08G63/605 , C08G63/83 , C08L67/00
摘要： This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention."The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340.degree. to about 400.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240.degree. C. up to about 280.degree. C. and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.
摘要翻译：本发明涉及基本上由单元（I），（II），（III）和（IV）组成的新型共聚酯。（*化学结构*）（I）（*化学结构*）（II）（*化学结构*）（III）（*化学结构*）（IV）和由两者制成的这些聚合物和制品的共混物。单位（I），（II），（III）和（IV）按照“发明描述”中定义的指定比例存在。立即共聚酯在熔融态显示取向，良好的纤维等级和高强度; 它们的熔点在约340℃至约400℃的范围内，并且是可熔融加工的。有利地，填充有约30重量百分比的玻璃纤维的这些组合物在264psi的负载下测量时显示高于240摄氏度至高达约280摄氏度的热变形温度。当混合时，某些性能得到改善，特别是它们更容易熔化制造，具有降低的起泡倾向和增加的强度。这些聚合物和共混物可以有利地用于需要高温的烤箱，电子部件，电气设备和其它最终用途。

49. 发明授权

US5204417A High strength polymers and blends of hydroquinone poly(iso-terephthalates) containing residues of p-hydroxybenzoic acid 失效
标题翻译：含有对羟基苯甲酸残基的氢醌聚（异对苯二甲酸酯）的高强度聚合物和共混物
公开(公告)号：US5204417A
公开(公告)日：1993-04-20
申请号：US929667
申请日：1992-08-13
申请人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
发明人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
IPC分类号： C08G63/60 , C08G63/83 , C08K7/02 , C08L67/00
CPC分类号： C08K7/02 , C08G63/605 , C08G63/83 , C08L67/00 , Y10T428/31786 , Y10T428/3179
摘要： This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1##and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention."The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree. C., when measured under a load of 264 psi. The polymers may be blended to tailor properties. These polymers and blends may be used advantageously in producing fibers and in electrical equipment, electronic components and other end uses requiring moderately high temperatures.
摘要翻译：本发明涉及基本上由单元（I），（II），（III）和（IV）组成的新型共聚酯。（IV）和（II）这两种聚合物和制品的共混物。单位（I），（II），（III）和（IV）按照“发明描述”中定义的指定比例存在。立即共聚酯显示熔融状态的取向，良好的纤维等级和高强度。有利地，本发明的聚合物显示出纯聚合物的粘度和可模塑性的显着改善。该聚合物具有优异的机械和表面性能，包括起泡性，强度，韧性和气相焊料的能力，并形成强力纤维，同时仍保持高的热变形温度。它们的熔点在约250℃至约360℃的范围内，并且是可熔融加工的。有利地，填充有约30重量％的玻璃纤维的这些组合物在264psi的载荷下测量时，显示高达240℃的热变形温度。聚合物可以混合以定制特性。这些聚合物和共混物可以有利地用于生产纤维和电气设备，电子部件和需要适度高温的其它最终用途。

50. 发明授权

US5079309A Miscible blends of a poly(aryl ether ketone) and an imide containing polymer 失效
公开(公告)号：US5079309A
公开(公告)日：1992-01-07
申请号：US378784
申请日：1989-07-12
申请人： James E. Harris , Lloyd M. Robeson , Michael D. Cliffton , Bernard H. Eckstein , Markus Matzner
发明人： James E. Harris , Lloyd M. Robeson , Michael D. Cliffton , Bernard H. Eckstein , Markus Matzner
IPC分类号： C08L65/00 , C08L71/00 , C08L79/08
CPC分类号： C08L71/00 , C08L65/00 , C08L79/08
摘要： Described herein are miscible blends of a poly(aryl ether ketone) and an imide-containing polymer which are useful in the manufacture of extruded film, continuous fiber composites and injection molded articles.

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