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41. 发明授权

US08664431B2 Preparation method of copolymerizable photoinitiators 失效
标题翻译：可共聚光引发剂的制备方法
公开(公告)号：US08664431B2
公开(公告)日：2014-03-04
申请号：US12744966
申请日：2008-11-27
申请人： Johan Loccufier
发明人： Johan Loccufier
IPC分类号： C07C69/63
CPC分类号： C07C69/63 , C07C67/14 , C07C67/317 , C07C69/54 , C07D335/16 , C07F9/3247 , C07F9/5337
摘要： An intermediate for preparing (meth)acrylated photoinitiators according to Formula (I): wherein: R1 is selected from the group consisting of hydrogen and a methyl group; A represents a group including at least one photoinitiating moiety; L represents a n+o-valent linking group including at least one carbon atom; n and o each independently represent an integer from 1 to 4; p is equal to 0 or 1; X represents a group selected from the group consisting of CI, Br, I, and R2SO3; and R2 represents an optionally substituted group selected from the group consisting of an alkyl group, an alkenyl group, an alkynyl group, an alkaryl group-, an aralkyl group, an aryl group and a heteroaryl group. Also, a method for the preparation of (meth)acrylated photoinitiators by β-elimination of HX from the intermediate according to Formula (I).
摘要翻译：用于制备根据式（I）的（甲基）丙烯酸酯化光引发剂的中间体：其中：R1选自氢和甲基; A表示包含至少一个光引发部分的基团; L表示包含至少一个碳原子的n + O价连接基团; n和o各自独立地表示1至4的整数; p等于0或1; X表示选自由Cl，Br，I和R 2 SO 3组成的组中的基团; 并且R 2表示选自烷基，烯基，炔基，烷芳基 - ，芳烷基，芳基和杂芳基中的任选取代的基团。此外，通过根据式（I）的中间体β-去除HX制备（甲基）丙烯酸酯化光引发剂的方法。

42. 发明申请

US20100227271A1 METHOD FOR MAKING A LITHOGRAPHIC PRINTING PLATE 有权
标题翻译：制作平版印刷版的方法
公开(公告)号：US20100227271A1
公开(公告)日：2010-09-09
申请号：US12670836
申请日：2008-08-13
申请人： Johan Loccufier , Stefaan Lingier , Mark Lens
发明人： Johan Loccufier , Stefaan Lingier , Mark Lens
IPC分类号： G03F7/004 , G03F7/20
CPC分类号： B41C1/1008 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262 , G03F7/322
摘要： A method for making a lithographic printing plate is disclosed which comprises the steps of: (1) providing a heat-sensitive lithographic printing plate precursor comprising on a support having a hydrophilic surface or which is provided with a hydrophilic layer, a heat-sensitive coating, (2) image-wise exposing said precursor with IR-radiation or heat, and (3) developing said image-wise exposed precursor with an alkaline developing solution, characterised in that a sludge inhibiting agent is present in said precursor or in said developing solution or in said precursor and said developing solution, and wherein said sludge inhibiting agent is a triazaindolisine compound. According to the above method, the formation of sludge is inhibited or reduced.
摘要翻译：公开了一种制备平版印刷版的方法，其包括以下步骤：（1）提供热敏平版印刷版前体，其包含在具有亲水性表面的支持体上，或者设置有亲水层，热敏涂层，（2）用IR辐射或加热使所述前体成像曝光，和（3）用碱性显影液显影所述成像曝光的前体，其特征在于在所述前体或所述显影剂中存在污泥抑制剂溶液或所述前体和所述显影溶液中，并且其中所述污泥抑制剂是三嗪二葡萄糖酸化合物。根据上述方法，抑制或减少污泥的形成。

43. 发明申请

US20100055610A1 HEAT SENSITIVE POSITIVE-WORKING LITHOGRAPHIC PRINTING PLATE PRECURSOR 有权
标题翻译：热敏正极工作平版印刷机前驱板
公开(公告)号：US20100055610A1
公开(公告)日：2010-03-04
申请号：US12552690
申请日：2009-09-02
申请人： Johan Loccufier , Stefaan Lingier , Heidi Janssens
发明人： Johan Loccufier , Stefaan Lingier , Heidi Janssens
IPC分类号： G03F7/20 , G03F7/004
CPC分类号： B41C1/1016 , B41C2201/04 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262
摘要： A heat-sensitive positive-working lithographic printing plate precursor comprising(1) a support having a hydrophilic surface or which is provided with a hydrophilic layer, (2) a heat-sensitive coating, comprising an underlayer on said support and thereon an upperlayer, an IR absorbing agent in at least one of said underlayer and upperlayer, a phenolic resin in said upperlayer, and a first polymer in said underlayer, characterised in that said first polymer is an alkaline soluble polymer comprising a first sulfonamide containing monomeric unit having a specified structure according to formula I or formula II and a second amide containing monomeric unit having a specified structure according to formula III. The printing plates show an improved chemical resistance of the coating and a reduced undercutting of the image forming parts of the coating.
摘要翻译：一种热敏正性平版印刷版原版，其包含（1）具有亲水性表面的或具有亲水层的载体，（2）热敏涂层，其包含在所述载体上的底层上及其上层，所述底层和上层中的至少一个中的IR吸收剂，所述上层中的酚醛树脂和所述底层中的第一聚合物，其特征在于，所述第一聚合物是包含含有单体单元的第一种磺酰胺的碱溶性聚合物，根据式I或式II的结构和具有根据式III具有特定结构的第二种含酰胺的单体单元。印版显示出涂层的耐化学性改善和涂层成像部分的底切减少。

44. 发明授权

US07582151B2 Pigment dispersion with polymeric dispersants having pending chromophore groups 失效
标题翻译：具有悬浮发色团的聚合物分散剂的颜料分散体
公开(公告)号：US07582151B2
公开(公告)日：2009-09-01
申请号：US11995323
申请日：2006-06-23
申请人： Wojciech Jaunky , Geert Deroover , Johan Loccufier , Lambertus Groenendaal
发明人： Wojciech Jaunky , Geert Deroover , Johan Loccufier , Lambertus Groenendaal
IPC分类号： C09D11/02 , C08K5/23
CPC分类号： C09B69/106 , C09B67/0046 , C09B67/0063 , C09B67/009 , C09B69/10 , C09D11/326
摘要： A pigment dispersion includes a color pigment represented by formula (I): wherein X1 to X4 are independently selected from the group consisting of hydrogen and a halogen atom; R1 to R10 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, and an ethoxy group; and a polymeric dispersant, having via a linking group covalently linked to its polymeric backbone, at least one pending chromophore group which has a molecular weight smaller than 90% of the molecular weight of the color pigment; wherein the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; and the at least one pending chromophore group is represented by formula (II): wherein, one of L1, L2 or L3 is the linking group and is selected from the group consisting of an aliphatic group, a substituted aliphatic group, an unsaturated aliphatic group, and a substituted unsaturated aliphatic group; L1, L2, and/or L3, if not representing the linking group, are independently selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkoxy group, a carboxylic acid group, an ester group, an acyl group, a nitro group, and a halogen; AR1 and AR2-represent an aromatic group; and n represents the integer 0 or 1. The pigment dispersion can be advantageously used in inkjet inks. Also disclosed are methods for preparing the inkjet ink.
摘要翻译：颜料分散体包括由式（I）表示的着色颜料：其中X1至X4独立地选自氢和卤素原子; R 1至R 10独立地选自氢，卤素原子，甲基，乙基，甲氧基和乙氧基; 和通过与其聚合物骨架共价连接的连接基团的聚合物分散剂，至少一种分子量小于彩色颜料分子量的90％的待发色团; 其中所述至少一个未完成的发色团组是作为所述聚合物主链上的侧基而不是所述聚合物主链本身中的基团或仅作为所述聚合物主链的端基发生的发色团。并且所述至少一个未决发色团由式（II）表示：其中，L1，L2或L3中的一个为连接基团，并且选自脂族基团，取代的脂族基团，不饱和脂族基团和取代的不饱和脂族基团; 如果不代表连接基团，则L1，L2和/或L3独立地选自氢，烷基，烯基，烷氧基，羧酸基，酯基，酰基，硝基和卤素; AR1和AR2代表芳族基团; 并且n表示整数0或1.颜料分散体可有利地用于喷墨油墨中。还公开了制备喷墨油墨的方法。

45. 发明申请

US20080311524A1 Method For Making Negative-Working Heat-Sensitive Lithographic Printing Plate Precursor 审中-公开
标题翻译：制造负性热敏平版印刷版前体的方法
公开(公告)号：US20080311524A1
公开(公告)日：2008-12-18
申请号：US11571784
申请日：2005-07-01
申请人： Joan Vermeersch , Johan Loccufier , Paul Callant , Jurgen Jung , Marc Van Damme
发明人： Joan Vermeersch , Johan Loccufier , Paul Callant , Jurgen Jung , Marc Van Damme
IPC分类号： G03F7/20 , B41N1/00
CPC分类号： B41C1/1008 , B41C1/1025 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/26
摘要： A method for making a negative-working heat-sensitive lithographic printing plate precursor includes the steps pf: (i) providing a support having a hydrophilic surface or which is provided with a hydrophilic layer; and (ii) applying on the support a coating which includes a product DQ, wherein DQ is obtained by: the step of coating a solution or dispersion including a nucleophilic compound Q and a dye D selected from the list consisting of di- or tri-arylmethane dyes, cyanine dyes, styryl dyes, and merostyryl dyes; or by D and Q interact to form interaction product DQ, having a white light optical density which is lower that the white light optical density of dye D; and the interaction product DQ is capable of at least partially releasing a dye directly after exposure to infrared light or heat, therby forming a visible image in the coating.
摘要翻译：制造负性热敏平版印刷版原版的方法包括步骤pf：（i）提供具有亲水性表面的或具有亲水层的载体; 并且（ii）在载体上涂覆包含产品DQ的涂层，其中DQ通过以下步骤获得：涂覆包含亲核化合物Q和染料D的溶液或分散体的步骤，所述亲核化合物Q和染料D选自二 - 或三 - 芳基甲烷染料，花青染料，苯乙烯基染料和美洛斯坦林染料; 或通过D和Q相互作用形成具有低于染料D的白光光密度的白光光密度的相互作用产物DQ; 并且相互作用产物DQ能够在暴露于红外光或热之后直接至少部分地释放染料，从而在涂层中形成可见图像。

46. 发明申请

US20080242776A1 Pigment Dispersion with Polymeric Dispersants Having Pending Chromophore Groups 失效
标题翻译：具有悬垂发色团的聚合物分散剂的颜料分散体
公开(公告)号：US20080242776A1
公开(公告)日：2008-10-02
申请号：US11995323
申请日：2006-06-23
申请人： Wojciech Jaunky , Geert Deroover , Johan Loccufier , Lambertus Groenendaal
发明人： Wojciech Jaunky , Geert Deroover , Johan Loccufier , Lambertus Groenendaal
IPC分类号： C09B67/00
CPC分类号： C09B69/106 , C09B67/0046 , C09B67/0063 , C09B67/009 , C09B69/10 , C09D11/326
摘要： A pigment dispersion includes a color pigment represented by formula (I): wherein X1 to X4 are independently selected from the group consisting of hydrogen and a halogen atom; R1 to R10 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, and an ethoxy group; and a polymeric dispersant, having via a linking group covalently linked to its polymeric backbone, at least one pending chromophore group which has a molecular weight smaller than 90% of the molecular weight of the color pigment; wherein the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; and the at least one pending chromophore group is represented by formula (II): wherein one of L1, L2, or L3 is the linking group and is selected from the group consisting of an aliphatic group, a substituted aliphatic group, an unsaturated aliphatic group, and a substituted unsaturated aliphatic group; L1, L2, and/or L3, if not representing the linking group, are independently selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkoxy group, a carboxylic acid group, an ester group, an acyl group, a nitro group, and a halogen; AR1 and AR2 represent an aromatic group; and n represents the integer 0 or 1. The pigment dispersion can be advantageously used in inkjet inks. Also disclosed are methods for preparing the inkjet ink.
摘要翻译：颜料分散体包括由式（I）表示的着色颜料：其中X1至X4独立地选自氢和卤素原子; R 1至R 10独立地选自氢，卤素原子，甲基，乙基，甲氧基和乙氧基; 和通过与其聚合物骨架共价连接的连接基团的聚合物分散剂，至少一种分子量小于彩色颜料分子量的90％的待发色团; 其中所述至少一个未完成的发色团组是作为所述聚合物主链上的侧基而不是所述聚合物主链本身中的基团或仅作为所述聚合物主链的端基发生的发色团。并且所述至少一个未决发色团组由式（II）表示：其中，L 1，L 2或L 3中的一个为连接基团，并且选自脂族基团，取代的脂族基团，不饱和脂族基团和取代的不饱和脂族基团; 如果不代表连接基团，则L1，L2和/或L3独立地选自氢，烷基，烯基，烷氧基，羧酸基，酯基，酰基，硝基和卤素; AR1和AR2代表芳族基团; 并且n表示整数0或1.颜料分散体可有利地用于喷墨油墨中。还公开了制备喷墨油墨的方法。

47. 发明申请

US20080177016A1 Phenylazo-Acetoacetanilide Derivatives with a Polymerizable Functional Group and Related Compounds as Monomers for Preparing Polymeric Pigment Dispersants for Inkjet Inks 有权
标题翻译：具有可聚合官能团的苯偶氮 - 乙酰乙酰苯胺衍生物和相关化合物作为用于制备喷墨油墨的聚合物颜料分散剂的单体
公开(公告)号：US20080177016A1
公开(公告)日：2008-07-24
申请号：US11995329
申请日：2006-07-04
申请人： Geert Deroover , Wojciech Jaunky , Lambertus Groenendaal , Johan Loccufier
发明人： Geert Deroover , Wojciech Jaunky , Lambertus Groenendaal , Johan Loccufier
IPC分类号： C08F126/06 , C07C243/22 , C07D235/26 , C08F126/02 , C07D207/448
CPC分类号： C07D207/452 , C07C251/76 , C07D207/456 , C07D233/70 , C07D235/26 , C09B29/337 , C09B31/11 , C09B69/106 , C09D11/101 , C09D11/326
摘要： A monomer with a chromophore group represented by Formula (I): wherein AR1 represents a substituted or unsubstituted aromatic group; AR2 represents a substituted or unsubstituted aromatic group or a substituted or unsubstituted alkyl group; and R represents a substituted or unsubstituted alkyl group, with the proviso that one of R, AR1, and AR2 has a substituent with a polymerizable functional group. The monomer can be advantageously used to prepare polymeric dispersants for pigment dispersion, especially inkjet inks.
摘要翻译：具有由式（I）表示的发色团的单体：其中AR 1表示取代或未取代的芳族基团; AR 2表示取代或未取代的芳基或取代或未取代的烷基; 并且R表示取代或未取代的烷基，条件是R 1，AR 1和AR 2 2中的一个具有可聚合官能团的取代基。该单体可有利地用于制备用于颜料分散的聚合物分散剂，特别是喷墨油墨。

48. 发明授权

US07294605B2 Thermographic recording materials containing a mesionic, 1,2,4-triazolium-3-thiolate compound 失效
标题翻译：含有中间体1,2,4-三唑鎓-3-硫醇盐化合物的热成像记录材料
公开(公告)号：US07294605B2
公开(公告)日：2007-11-13
申请号：US11007487
申请日：2004-12-08
申请人： Johan Loccufier , Ingrid Geuens
发明人： Johan Loccufier , Ingrid Geuens
IPC分类号： B41M5/30
CPC分类号： G03C1/49845 , G03C1/49881 , G03C1/4989
摘要： A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one mesionic 1,2,4-triazolium-3-thiolate compound.
摘要翻译：一种基本上不透光的黑色和白色单片热成像记录材料，包括支撑体和热敏元件，该热敏元件含有基本上不光敏的有机银盐，与其热加工关系的有机还原剂，粘合剂和至少一种中间体1,2,4-三唑鎓-3-硫醇化合物。

49. 发明授权

US07097961B2 Stabilizers for use in substantially light-insensitive thermographic recording materials 有权
公开(公告)号：US07097961B2
公开(公告)日：2006-08-29
申请号：US11127645
申请日：2005-05-12
申请人： Frank Louwet , Johan Loccufier
发明人： Frank Louwet , Johan Loccufier
IPC分类号： G03C1/494 , G03C1/34
CPC分类号： G03C1/4989 , G03C1/49845 , Y10S430/165 , Y10S430/166
摘要： A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, said thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, at least one binder and at least one stabilizer represented by formula (I): wherein R1, R2, R3 and R4 are independently selected from the group consisting of a hydrogen atom, halogen atoms and aliphatic, alkoxy, nitro, acyl, sulfonyl, nitrile, alkaryl, aryl, amino, thioalkyl, aldehyde, urea, —O—(C═O)-alkyl, —O—(C═O)-aryl, —O—(C═O)—O-alkyl, —O—(C═O)—O-aryl, —NH—(C═O)-alkyl, —NH—(C═O)-aryl, —(C═O)—NH-alkyl, —(C═O)—NH-aryl, —NH—(SO2)-alkyl, —NH—(SO2)-aryl, —(SO2)—NH-alkyl, —(SO2)—NH-aryl groups; X is represented by -A(-M)n or is selected from the group consisting of substituted aliphatic groups, unsubstituted aliphatic groups, substituted cycloaliphatic groups, unsubstituted cycloaliphatic groups, substituted aromatic groups and unsubstituted aromatic groups where in each of said groups one or more of the chain or ring carbon atoms may be substituted by one of more atoms selected from the group consisting of S, O, Si, N and P atoms; n is 2, 3 or 4; A is selected from the group consisting of substituted aliphatic groups, unsubstituted aliphatic groups, substituted cycloaliphatic groups, unsubstituted cycloaliphatic groups, substituted aromatic groups and unsubstituted aromatic groups where in each of said groups one or more of the chain or ring carbon atoms may be substituted by one of more atoms selected from the group consisting of S, O, Si, N and P atoms; each (-M) is independently a substituted or unsubstituted group selected from the group consisting of -(2-S-imidazole) groups and -(2-S-imidazole) groups annelated with an aromatic ring system, the optional substituents for -M being selected from the group consisting of halogen atoms and aliphatic, alkoxy, nitro, acyl, sulfonyl, nitrile, alkaryl and aryl groups.

50. 发明授权

US07018786B2 Toning agents for use in thermographic recording materials 失效
标题翻译：用于热敏记录材料的调色剂
公开(公告)号：US07018786B2
公开(公告)日：2006-03-28
申请号：US10737495
申请日：2003-12-16
申请人： Ingrid Geuens , Johan Loccufier , Vera Drieghe
发明人： Ingrid Geuens , Johan Loccufier , Vera Drieghe
IPC分类号： C03C1/35 , C03C1/494 , C03C1/498 , C03C5/29
CPC分类号： G03C1/4989 , G03C1/49845 , Y10S430/165 , Y10S430/166
摘要： A black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one toning agent, wherein the at least one toning agent is represented by formula (I): wherein R1 is a hydrogen atom or an alkyl, an alkenyl, an alkynyl, a cycloalkyl, an alkaryl, an aryl, a heterocyclic or a heteroaryl group all of which may be optionally substituted; with the proviso that R1 may not be a hydrogen atom if both R2 and R3 are both hydrogen atoms; R2 and R3 are independently a hydrogen or a halogen atom or an amino, amide, ester, carboxy, carbonate, alkyl, alkenyl, alkynyl, cycloalkyl, alkaryl, aryl, heterocyclic or heteroaryl group all of which may be optionally substituted; R2 and R3 may together represent the atoms necessary to complete a heteroaromatic ring with no more than one nitrogen atom, an alicyclic or a heterocyclic group which all may be optionally substituted; and X is a carbonyl group, or is —N—R4, where R4 is an alkyl group.
摘要翻译：一种包含支持体和热敏元件的黑色和白色单片热成像记录材料，所述热敏元件含有基本上不光敏的有机银盐，与其热加工关系的有机还原剂，粘合剂和至少一种调色剂，其中所述至少一种调色剂由式（I）表示：其中R 1是氢原子或烷基，烯基，炔基，环烷基，烷芳基，芳基，杂环或全部可以任选被取代的杂芳基; 条件是如果R 2和R 3两个都是氢原子，R 1可以不是氢原子; R 2和R 3独立地是氢或卤素原子或氨基，酰胺，酯，羧基，碳酸酯，烷基，烯基，炔基，环烷基，烷芳基，芳基，杂环或杂芳基，其全部可以任选被取代; R 2和R 3可以一起表示完成具有不超过一个氮原子的杂芳环所必需的原子，所有可以任选取代的脂环族或杂环基 ; 并且X是羰基，或者是-N-R 4，其中R 4是烷基。

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