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1. 发明授权

US07097961B2 Stabilizers for use in substantially light-insensitive thermographic recording materials 有权
公开(公告)号：US07097961B2
公开(公告)日：2006-08-29
申请号：US11127645
申请日：2005-05-12
申请人： Frank Louwet , Johan Loccufier
发明人： Frank Louwet , Johan Loccufier
IPC分类号： G03C1/494 , G03C1/34
CPC分类号： G03C1/4989 , G03C1/49845 , Y10S430/165 , Y10S430/166
摘要： A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, said thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, at least one binder and at least one stabilizer represented by formula (I): wherein R1, R2, R3 and R4 are independently selected from the group consisting of a hydrogen atom, halogen atoms and aliphatic, alkoxy, nitro, acyl, sulfonyl, nitrile, alkaryl, aryl, amino, thioalkyl, aldehyde, urea, —O—(C═O)-alkyl, —O—(C═O)-aryl, —O—(C═O)—O-alkyl, —O—(C═O)—O-aryl, —NH—(C═O)-alkyl, —NH—(C═O)-aryl, —(C═O)—NH-alkyl, —(C═O)—NH-aryl, —NH—(SO2)-alkyl, —NH—(SO2)-aryl, —(SO2)—NH-alkyl, —(SO2)—NH-aryl groups; X is represented by -A(-M)n or is selected from the group consisting of substituted aliphatic groups, unsubstituted aliphatic groups, substituted cycloaliphatic groups, unsubstituted cycloaliphatic groups, substituted aromatic groups and unsubstituted aromatic groups where in each of said groups one or more of the chain or ring carbon atoms may be substituted by one of more atoms selected from the group consisting of S, O, Si, N and P atoms; n is 2, 3 or 4; A is selected from the group consisting of substituted aliphatic groups, unsubstituted aliphatic groups, substituted cycloaliphatic groups, unsubstituted cycloaliphatic groups, substituted aromatic groups and unsubstituted aromatic groups where in each of said groups one or more of the chain or ring carbon atoms may be substituted by one of more atoms selected from the group consisting of S, O, Si, N and P atoms; each (-M) is independently a substituted or unsubstituted group selected from the group consisting of -(2-S-imidazole) groups and -(2-S-imidazole) groups annelated with an aromatic ring system, the optional substituents for -M being selected from the group consisting of halogen atoms and aliphatic, alkoxy, nitro, acyl, sulfonyl, nitrile, alkaryl and aryl groups.

2. 发明申请

US20060100103A1 Toning agents for use in thermographic recording materials 失效
标题翻译：用于热敏记录材料的调色剂
公开(公告)号：US20060100103A1
公开(公告)日：2006-05-11
申请号：US11257480
申请日：2005-10-24
申请人： Carlo Uyttendaele , Johan Loccufier , Frank Louwet
发明人： Carlo Uyttendaele , Johan Loccufier , Frank Louwet
IPC分类号： B41M5/20
CPC分类号： G03C1/49845 , G03C1/4989
摘要： A thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element comprising at least one substantially light-insensitive organic silver salt, at least one organic reducing agent therefor in thermal working relationship therewith, at least one binder and at least one toning agent represented by formula (I): wherein X represents the optionally substituted atoms necessary to form a 6-membered ring.
摘要翻译：一种包含支持体和热敏元件的热敏记录材料，所述热敏元件包含至少一种基本上不光敏的有机银盐，至少一种与其热处理关系的有机还原剂，至少一种粘合剂和至少一种调色剂由式（I）表示：其中X表示形成6元环所需的任选取代的原子。

3. 发明授权

US06740479B2 Silver halide photographic processing solution 失效
标题翻译：卤化银照相处理液
公开(公告)号：US06740479B2
公开(公告)日：2004-05-25
申请号：US10617647
申请日：2003-07-11
申请人： Johan Loccufier , Frank Louwet , André Roefs
发明人： Johan Loccufier , Frank Louwet , André Roefs
IPC分类号： G03E5305
CPC分类号： G03C5/3056
摘要： A silver halide photographic processing solution comprising at least one polymeric compound inhibiting sludge formation and preventing “pi-line” artefact, more particularly in radiographic non-destructive testing applications, wherein said polymeric compound comprises at least one monomer unit having a silver complexing moiety and at least one monomer unit having a solubilizing group, and wherein both said silver ion complexing moiety and said solubilizing group are comprised in same or different monomer units.
摘要翻译：一种卤化银照相处理溶液，其包含至少一种抑制污泥形成的聚合物，并防止“pi系”人造物，更特别是在射线照相非破坏性测试应用中，其中所述聚合物包含至少一个具有银络合部分的单体单元和至少一个具有增溶基团的单体单元，并且其中所述银离子络合部分和所述增溶基团都包含相同或不同的单体单元。

4. 发明授权

US07147936B2 Layer configuration with improved stability to sunlight exposure 有权
标题翻译：层状结构具有改善的阳光照射的稳定性
公开(公告)号：US07147936B2
公开(公告)日：2006-12-12
申请号：US10642933
申请日：2003-08-18
申请人： Frank Louwet , Geert Van Dyck , Johan Loccufier , Bert Groenendaal , Hieronymus Andriessen
发明人： Frank Louwet , Geert Van Dyck , Johan Loccufier , Bert Groenendaal , Hieronymus Andriessen
IPC分类号： C07D211/021 , H01L51/50
CPC分类号： C08G61/126 , C08L25/08 , C08L2666/06 , C09J165/00 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10S428/917
摘要： A layer configuration on a support, the layer configuration comprising a layer containing a polymer containing optionally substituted 3,4-alkylenedioxythiophene structural units, in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, and a compound selected from the group consisting of polyphosphoric acids, polyphosphoric acid salts, thia-alkanedicarboxylic acids, cyclohexadiene compounds and polyhydroxy-compounds selected from the group consisting of tetronic acid derivatives; ortho-dihydroxybenzene compounds with at least one sulpho group, compounds according to formula (I): HO—CH2—CH(OH)—(CH2)m—S—CH2—C(R1)(R2)—CH2—S—(CH2)n—CH(OH)—CH2—OH (I) wherein R1 and R2 are independently H, —OH or alkyl, and n and m are independently 1, 2 or 3; compounds according to formula (II): HO—(CH2)p—S—CH2—S—(CH2)q—OH (II) wherein p and q are independently 2, 3 or 4; compounds hydrolyzable to tetronic acid derivatives; compounds hydrolyzable to compounds according to formula (I); and sulpho-substituted 2-thia-alkyl-benzimidazole compounds.
摘要翻译：在支撑体上的层构型，该层构型包括含有含有任选取代的3,4-亚烷基二氧噻吩结构单元的聚合物的层，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧基 - 桥，以及选自多磷酸，多磷酸盐，硫杂烷二羧酸，环己二烯化合物和选自由以下组成的组的多羟基化合物的化合物：四氢酸衍生物; 具有至少一个磺酸基的邻二羟基苯化合物，根据式（I）的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> HO-CH 2 -CH（OH） - （CH 2 CH 2）m -S- CH 2 -C（R 1）（R 2） - CH 2 -S-（CH 2）n - （CH 2）n - （CH 2） -CH 2 -O-OH（I）<β在线公式描述=“在线式”末端=“尾”→其中R 1和R 2， SUP> 2独立地是H，-OH或烷基，n和m独立地是1,2或3; 根据式（II）的化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> HO-（CH 2） > -S-CH 2 -S-（CH 2）2 -O-OH（II）<β在线配方说明书=“ 其中p和q独立地为2,3或4; 可水解成四氢酸衍生物的化合物; 可水解成根据式（I）的化合物的化合物的化合物; 和磺基取代的2-硫代 - 烷基 - 苯并咪唑化合物。

5. 发明申请

US20060100102A1 Toning agents for use in thermographic recording materials 审中-公开
标题翻译：用于热敏记录材料的调色剂
公开(公告)号：US20060100102A1
公开(公告)日：2006-05-11
申请号：US11257440
申请日：2005-10-24
申请人： Carlo Uyttendaele , Frank Louwet , Johan Loccufier
发明人： Carlo Uyttendaele , Frank Louwet , Johan Loccufier
IPC分类号： B41M5/24
CPC分类号： G03C1/4989 , C07C309/88 , C07C311/47 , C07C311/49 , G03C1/49845
摘要： A compound represented by formula (I): wherein X is a carbonyl or sulfonyl group; R2 is an alkyl, alkaryl or aryl group; and R1 is an amino group or an N-alkyl-amino group if Y is a halogen atom, an alkyl group or a hydroxy group; and R1 is a halogen atom, an alkyl group or a hydroxy group if Y is an amino group or an N-alkyl-amino group; and a thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element comprising at least one substantially light-insensitive organic silver salt, at least one organic reducing agent therefor in thermal working relationship therewith, at least one binder and at least one compound represented by formula (I).
摘要翻译：由式（I）表示的化合物：其中X是羰基或磺酰基; R 2是烷基，烷芳基或芳基; 如果Y是卤素原子，烷基或羟基，则R 1是氨基或N-烷基 - 氨基; 如果Y是氨基或N-烷基 - 氨基，则R 1是卤素原子，烷基或羟基; 以及包括支持体和热敏元件的热敏记录材料，所述热敏元件包含至少一种基本上不光敏的有机银盐，至少一种与其热加工关系的有机还原剂，至少一种粘合剂和至少一种化合物由式（I）表示。

6. 发明授权

US06333145B1 Method for preparing a conductive polythiophene layer at low temperature 有权
标题翻译：在低温下制备导电聚噻吩层的方法
公开(公告)号：US06333145B1
公开(公告)日：2001-12-25
申请号：US09433971
申请日：1999-11-04
申请人： Tom Cloots , Johan Loccufier , Frank Louwet , Hieronymus Andriessen
发明人： Tom Cloots , Johan Loccufier , Frank Louwet , Hieronymus Andriessen
IPC分类号： G03C185
CPC分类号： H01B1/127 , H01G9/028 , H01G11/48 , H01G11/56 , H01L51/5203 , Y02E60/13
摘要： A method for producing a polymeric conductive layer on an object comprising the steps of: providing an aqueous composition containing a polythiophene, a polyanion compound and an aprotic compound with a dielectric constant, &egr;, ≧15, applying said composition to said object forming a layer and drying said layer to form a conductive polymeric layer on said object, characterised in that during said production said object and said layer are kept at a temperature below 100° C. and said conductive polymeric layer has a resistivity of at most 2 k&OHgr;/square.
摘要翻译：一种用于在物体上制备聚合物导电层的方法，包括以下步骤：提供含有聚噻吩，聚阴离子化合物和介质常数εi= 15的非质子化合物的水性组合物，将所述组合物施加到所述物体上形成层和干燥所述层以在所述物体上形成导电聚合物层，其特征在于，在所述生产期间，所述物体和所述层保持在低于100℃的温度，并且所述导电聚合物层具有至多2kOMEGA /平方的电阻率。

7. 发明授权

US07179768B2 Toning agents for use in thermographic recording materials 失效
标题翻译：用于热敏记录材料的调色剂
公开(公告)号：US07179768B2
公开(公告)日：2007-02-20
申请号：US11257480
申请日：2005-10-24
申请人： Carlo Uyttendaele , Johan Loccufier , Frank Louwet
发明人： Carlo Uyttendaele , Johan Loccufier , Frank Louwet
IPC分类号： B41M5/30
CPC分类号： G03C1/49845 , G03C1/4989
摘要： A thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element comprising at least one substantially light-insensitive organic silver salt, at least one organic reducing agent therefor in thermal working relationship therewith, at least one binder and at least one toning agent represented by formula (I): wherein X represents the optionally substituted atoms necessary to form a 6-membered ring.
摘要翻译：一种包含支持体和热敏元件的热敏记录材料，所述热敏元件包含至少一种基本上不光敏的有机银盐，至少一种与其热处理关系的有机还原剂，至少一种粘合剂和至少一种调色剂由式（I）表示：其中X表示形成6元环所需的任选取代的原子。

8. 发明申请

US20050255415A1 Stabilizers for use in substantially light-insensitive thermographic recording materials 有权
公开(公告)号：US20050255415A1
公开(公告)日：2005-11-17
申请号：US11127645
申请日：2005-05-12
申请人： Frank Louwet , Johan Loccufier
发明人： Frank Louwet , Johan Loccufier
IPC分类号： G03C1/00 , G03C1/498
CPC分类号： G03C1/4989 , G03C1/49845 , Y10S430/165 , Y10S430/166
摘要： A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, said thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, at least one binder and at least one stabilizer represented by formula (I): wherein R1, R2, R3 and R4 are independently selected from the group consisting of a hydrogen atom, halogen atoms and aliphatic, alkoxy, nitro, acyl, sulfonyl, nitrile, alkaryl, aryl, amino, thioalkyl, aldehyde, urea, —O—(C═O)-alkyl, —O—(C═O)-aryl, —O—(C═O)—O-alkyl, —O—(C═O)—O-aryl, —NH—(C═O)-alkyl, —NH—(C═O)-aryl, —(C═O)—NH-alkyl, —(C═O)—NH-aryl, —NH—(SO2)-alkyl, —NH—(SO2)-aryl, —(SO2)—NH-alkyl, —(SO2)—NH-aryl groups; X is represented by -A(-M)n or is selected from the group consisting of substituted aliphatic groups, unsubstituted aliphatic groups, substituted cycloaliphatic groups, unsubstituted cycloaliphatic groups, substituted aromatic groups and unsubstituted aromatic groups where in each of said groups one or more of the chain or ring carbon atoms may be substituted by one of more atoms selected from the group consisting of S, O, Si, N and P atoms; n is 2, 3 or 4; A is selected from the group consisting of substituted aliphatic groups, unsubstituted aliphatic groups, substituted cycloaliphatic groups, unsubstituted cycloaliphatic groups, substituted aromatic groups and unsubstituted aromatic groups where in each of said groups one or more of the chain or ring carbon atoms may be substituted by one of more atoms selected from the group consisting of S, O, Si, N and P atoms; each (-M) is independently a substituted or unsubstituted group selected from the group consisting of -(2-S-imidazole) groups and -(2-S-imidazole) groups annelated with an aromatic ring system, the optional substituents for -M being selected from the group consisting of halogen atoms and aliphatic, alkoxy, nitro, acyl, sulfonyl, nitrile, alkaryl and aryl groups.

9. 发明申请

US20090148722A1 LAYER CONFIGURATION WITH IMPROVED STABILITY TO SUNLIGHT EXPOSURE 有权
标题翻译：具有改进的阳光照射稳定性的层配置
公开(公告)号：US20090148722A1
公开(公告)日：2009-06-11
申请号：US12107898
申请日：2008-04-23
申请人： Frank Louwet
发明人： Frank Louwet
IPC分类号： B32B9/00 , C08G75/00
CPC分类号： C08L65/00 , C08K5/13 , C08K5/134 , C08K5/20 , C08K5/34 , C08K5/41 , C08L25/18 , H01G11/48 , Y02E60/13 , Y10S428/922 , C08L2666/06
摘要： Disclosed are a light-emitting diode, a photovoltaic device, a transistor, and an electroluminescent device, each comprising a layer disposed on a support, the layer comprising a [A] composition exclusive of hydroquinone comprising at least one polymer comprising (3,4-dialkoxythiophene) monomer units, a polyanion, at least one polyhydroxy group-containing aromatic compound exclusive of sulfo groups, at least one amino-compound or heterocyclic compound with at least one ring nitrogen atom, and at least one compound selected from the group consisting of polyhydroxy- and/or carboxy group or amide or lactam group containing aliphatic compounds and aprotic compounds with a dielectric constant ≧15.
摘要翻译：公开了一种发光二极管，光电器件，晶体管和电致发光器件，每个包括设置在支撑体上的层，该层包含不含氢醌的[A]组合物，其包含至少一种包含（3,4 二烷氧基噻吩）单体单元，聚阴离子，不包括磺基的至少一种含多羟基的芳族化合物，至少一种具有至少一个环氮原子的氨基化合物或杂环化合物，和至少一种选自以下的化合物：的含多羟基和/或羧基或酰胺或含内酰胺基团的脂肪族化合物和介质常数> 15的非质子化合物。

10. 发明申请

US20080017833A1 Process for Preparing Electroconductive Coatings 有权
公开(公告)号：US20080017833A1
公开(公告)日：2008-01-24
申请号：US11749617
申请日：2007-05-16
申请人： Frank Louwet , Bert Groenendaal
发明人： Frank Louwet , Bert Groenendaal
IPC分类号： C08K3/00
CPC分类号： H01B1/127 , C08G61/126 , C09D5/24 , H01G9/028 , H01G11/48 , H01G11/56 , H01L51/0037 , Y02E60/13
摘要： An aqueous dispersion of latex particles, said latex particles containing a polymer containing monomer units according to formula (I): in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue and at least one polyanion compound, said latex having a primary particle size of less than 40 nm and said dispersion contains an organic compound containing a di- or polyhydroxy- and/or carboxy groups or amide or lactam group or an aprotic compound with a dielectric constant, ε, ≧15, wherein said latex particles contain said at least one polyanion compound and said polymer in a weight ratio of at least 4; a process for preparing an electroconductive coating comprising the steps of: preparing an aqueous solution or dispersion of the above-mentioned polymer by polymerization with an initiator in a reaction medium in the presence of at least one polyanion compound under oxidizing or reducing conditions, wherein the weight ratio of the at least one polyanion compound to said structural units during the reaction is in the range of 4:1 to 20:1; preparing a first coating composition containing said polymer associated with said at least one polyanion compound and an organic compound containing a di- or polyhydroxy- and/or carboxy groups or amide or lactam group in a aqueous or non-aqueous medium; coating said first coating composition on an object thereby producing a first layer; and heating said first layer at a temperature of at least 100° C.; and a process for preparing an electroconductive coating comprising the steps of: preparing an aqueous solution or dispersion of the above-mentioned polymer by polymerization with an initiator in a reaction medium in the presence of at least one polyanion compound under oxidizing or reducing conditions, wherein the weight ratio of said at least one polyanion compound to said structural units during the reaction is in the range of 4:1 to 20:1; preparing a second coating composition containing said polymer associated with said at least one polyanion compound and an aprotic compound with a dielectric constant, ε, ≧15 in an aqueous or non-aqueous medium; coating said second coating composition on an object thereby producing a second layer; and heating said second layer at a temperature of at least 50° C.

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