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1. 发明授权

US07018786B2 Toning agents for use in thermographic recording materials 失效
标题翻译：用于热敏记录材料的调色剂
公开(公告)号：US07018786B2
公开(公告)日：2006-03-28
申请号：US10737495
申请日：2003-12-16
申请人： Ingrid Geuens , Johan Loccufier , Vera Drieghe
发明人： Ingrid Geuens , Johan Loccufier , Vera Drieghe
IPC分类号： C03C1/35 , C03C1/494 , C03C1/498 , C03C5/29
CPC分类号： G03C1/4989 , G03C1/49845 , Y10S430/165 , Y10S430/166
摘要： A black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one toning agent, wherein the at least one toning agent is represented by formula (I): wherein R1 is a hydrogen atom or an alkyl, an alkenyl, an alkynyl, a cycloalkyl, an alkaryl, an aryl, a heterocyclic or a heteroaryl group all of which may be optionally substituted; with the proviso that R1 may not be a hydrogen atom if both R2 and R3 are both hydrogen atoms; R2 and R3 are independently a hydrogen or a halogen atom or an amino, amide, ester, carboxy, carbonate, alkyl, alkenyl, alkynyl, cycloalkyl, alkaryl, aryl, heterocyclic or heteroaryl group all of which may be optionally substituted; R2 and R3 may together represent the atoms necessary to complete a heteroaromatic ring with no more than one nitrogen atom, an alicyclic or a heterocyclic group which all may be optionally substituted; and X is a carbonyl group, or is —N—R4, where R4 is an alkyl group.
摘要翻译：一种包含支持体和热敏元件的黑色和白色单片热成像记录材料，所述热敏元件含有基本上不光敏的有机银盐，与其热加工关系的有机还原剂，粘合剂和至少一种调色剂，其中所述至少一种调色剂由式（I）表示：其中R 1是氢原子或烷基，烯基，炔基，环烷基，烷芳基，芳基，杂环或全部可以任选被取代的杂芳基; 条件是如果R 2和R 3两个都是氢原子，R 1可以不是氢原子; R 2和R 3独立地是氢或卤素原子或氨基，酰胺，酯，羧基，碳酸酯，烷基，烯基，炔基，环烷基，烷芳基，芳基，杂环或杂芳基，其全部可以任选被取代; R 2和R 3可以一起表示完成具有不超过一个氮原子的杂芳环所必需的原子，所有可以任选取代的脂环族或杂环基 ; 并且X是羰基，或者是-N-R 4，其中R 4是烷基。

2. 发明授权

US07045487B2 Toning agents for use in substantially light-insensitive recording materials 失效
公开(公告)号：US07045487B2
公开(公告)日：2006-05-16
申请号：US10739241
申请日：2003-12-18
申请人： Ingrid Geuens , Johan Loccufier , Vera Drieghe
发明人： Ingrid Geuens , Johan Loccufier , Vera Drieghe
IPC分类号： B41M5/30
CPC分类号： G03C1/4989 , G03C1/49845 , G03C2200/40
摘要： A black and white monosheet substantially light-insensitive thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one toning agent, wherein the at least one toning agent is selected from compounds represented by formula (I): wherein R1 is an alkyl group optionally substituted with a hydroxy, carboxy, carboxy ester, acyl or carbonato group; X is S, O or N—R6; R6 is an optionally substituted alkyl group; R2, R3, R4 and R5 independently represent a hydrogen atom, a halogen atom or an alkyl, an alkoxy, a thio-alkoxy, a nitro, a cyano, a carboxy, a carboxy ester, an acyl, an aldehyde, an acylamido, a sulphonamido, an acylamino, a carbonato, a hydroxy or an aryl group or at least one of R2 and R3, R3 and R4 and R4 and R5 independently represent the atoms necessary to form a carbocyclic or heterocyclic group or at least one of R1 and R5 and R2 and R6 independently represent the atoms necessary to form a heterocyclic ring; and compounds represented by formula (II): wherein R7 is an optionally substituted alkyl group; Y is S, O or N—R10; R10 is an optionally substituted alkyl group; R8 and R9 independently represent a hydrogen atom, a halogen atom or an alkyl, an alkoxy, a thio-alkoxy, a nitro, a cyano, a carboxy, a carboxy ester, an acyl, an aldehyde, an acylamido, a sulphonamido, an acylamino, a carbonato, a hydroxy or an aryl group or R8 and R9 represent the atoms necessary to form a heterocyclic or a non-aromatic carbocyclic ring or at least one of R8 and R10 and R9 and R7 independently represent the atoms necessary to form a heterocyclic ring; and both R8 and R9 cannot both be an alkyl group.

3. 发明授权

US08973830B2 PET-C based security laminates and documents 有权
标题翻译： PET-C型安全层压板和文件
公开(公告)号：US08973830B2
公开(公告)日：2015-03-10
申请号：US13637837
申请日：2011-03-28
申请人： Ingrid Geuens , Bart Waumans , Vera Drieghe
发明人： Ingrid Geuens , Bart Waumans , Vera Drieghe
IPC分类号： G06K19/02 , B29C55/02 , B32B37/14 , B42D25/00 , B29C55/14 , B32B37/24 , B32B38/00 , B42D25/47
CPC分类号： B42D25/45 , B29C55/026 , B29C55/14 , B32B27/08 , B32B37/144 , B32B2037/243 , B32B2038/0028 , B32B2255/10 , B32B2255/26 , B32B2309/02 , B32B2309/105 , B32B2367/00 , B32B2425/00 , B42D25/00 , B42D25/21 , B42D25/23 , B42D25/24 , B42D25/305 , B42D25/47 , B42D2033/30 , B42D2033/46
摘要： A method of preparing a security laminate including the steps of: a) providing a polyethylene terephthalate substrate (1); b) stretching the polyethylene terephthalate substrate in either a longitudinal or a transversal direction; c) coating and drying a first coating composition (2) on the stretched polyethylene terephthalate substrate; d) stretching the coated polyethylene terephthalate substrate in the longitudinal or transversal direction not selected in step b) in order to obtain a coated biaxially stretched polyethylene terephthalate substrate having a layer of the first coating composition with a dry thickness between 50 nm and 400 nm; e) coating and drying a second coating composition (3) on top of the dry layer on the biaxially stretched substrate, wherein the first coating composition contains a copolymer selected from the group consisting of a hydroxyl—functional, partially-hydrolyzed vinyl chloride/vinyl acetate copolymer and a polyester-urethane copolymer; and wherein the second coating composition contains a hydroxyl—functional, partially-hydrolyzed vinyl chloride/vinyl acetate copolymer. Security laminates and security documents containing them are also disclosed.
摘要翻译：一种制备安全层压板的方法，包括以下步骤：a）提供聚对苯二甲酸乙二醇酯基材（1）; b）在纵向或横向上拉伸聚对苯二甲酸乙二醇酯基材; c）在拉伸的聚对苯二甲酸乙二醇酯基材上涂覆和干燥第一涂料组合物（2） d）在步骤b）中未选择的纵向或横向上拉伸涂覆的聚对苯二甲酸乙二醇酯基材，以获得具有干厚度为50nm至400nm的第一涂料组合物层的涂布双轴拉伸聚对苯二甲酸乙二醇酯基材; e）在第二涂料组合物（3）上涂覆并干燥在双轴拉伸基材上的干层顶部，其中第一涂料组合物含有选自羟基官能的部分水解的氯乙烯/乙烯基乙酸酯共聚物和聚酯 - 氨基甲酸酯共聚物; 并且其中所述第二涂料组合物含有羟基官能的部分水解的氯乙烯/乙酸乙烯酯共聚物。还披露了包含它们的安全层压板和安全文件。

4. 发明申请

US20130008965A1 PET-C BASED SECURITY LAMINATES AND DOCUMENTS 有权
标题翻译：基于PET-C的安全层压板和文件
公开(公告)号：US20130008965A1
公开(公告)日：2013-01-10
申请号：US13637837
申请日：2011-03-28
申请人： Ingrid Geuens , Bart Waumans , Vera Drieghe
发明人： Ingrid Geuens , Bart Waumans , Vera Drieghe
IPC分类号： G06K19/02 , B42D15/00 , G06K19/077 , B05D3/12
CPC分类号： B42D25/45 , B29C55/026 , B29C55/14 , B32B27/08 , B32B37/144 , B32B2037/243 , B32B2038/0028 , B32B2255/10 , B32B2255/26 , B32B2309/02 , B32B2309/105 , B32B2367/00 , B32B2425/00 , B42D25/00 , B42D25/21 , B42D25/23 , B42D25/24 , B42D25/305 , B42D25/47 , B42D2033/30 , B42D2033/46
摘要： A method of preparing a security laminate including the steps of: a) providing a polyethylene terephthalate substrate (1); b) stretching the polyethylene terephthalate substrate in either a longitudinal or a transversal direction; c) coating and drying a first coating composition (2) on the stretched polyethylene terephthalate substrate; d) stretching the coated polyethylene terephthalate substrate in the longitudinal or transversal direction not selected in step b) in order to obtain a coated biaxially stretched polyethylene terephthalate substrate having a layer of the first coating composition with a dry thickness between 50 nm and 400 nm; e) coating and drying a second coating composition (3) on top of the dry layer on the biaxially stretched substrate, wherein the first coating composition contains a copolymer selected from the group consisting of a hydroxyl—functional, partially-hydrolyzed vinyl chloride/vinyl acetate copolymer and a polyester-urethane copolymer; and wherein the second coating composition contains a hydroxyl—functional, partially-hydrolyzed vinyl chloride/vinyl acetate copolymer. Security laminates and security documents containing them are also disclosed.
摘要翻译：一种制备安全层压板的方法，包括以下步骤：a）提供聚对苯二甲酸乙二醇酯基材（1）; b）在纵向或横向上拉伸聚对苯二甲酸乙二醇酯基材; c）在拉伸的聚对苯二甲酸乙二醇酯基材上涂覆和干燥第一涂料组合物（2） d）在步骤b）中未选择的纵向或横向上拉伸涂覆的聚对苯二甲酸乙二醇酯基材，以获得具有干厚度为50nm至400nm的第一涂料组合物层的涂布双轴拉伸聚对苯二甲酸乙二醇酯基材; e）在第二涂料组合物（3）上涂覆并干燥在双轴拉伸基材上的干层顶部，其中第一涂料组合物含有选自羟基官能的部分水解的氯乙烯/乙烯基乙酸酯共聚物和聚酯 - 氨基甲酸酯共聚物; 并且其中所述第二涂料组合物含有羟基官能的部分水解的氯乙烯/乙酸乙烯酯共聚物。还披露了包含它们的安全层压板和安全文件。

5. 发明授权

US09434863B2 PET-C based security laminates and documents 有权
标题翻译： PET-C型安全层压板和文件
公开(公告)号：US09434863B2
公开(公告)日：2016-09-06
申请号：US14238810
申请日：2012-09-03
申请人： Vera Drieghe , Peter Cantraine , Bart Waumans , Walther Wouters , Ingrid Geuens
发明人： Vera Drieghe , Peter Cantraine , Bart Waumans , Walther Wouters , Ingrid Geuens
IPC分类号： C09J7/02 , B42D25/00 , C08J7/04 , B29C55/10
CPC分类号： B42D25/47 , B29C55/10 , B42D25/00 , B42D2033/04 , B42D2033/20 , B42D2033/30 , B42D2033/46 , C08J7/042 , C08J2367/02 , C09J7/29 , Y10T428/264 , Y10T428/265 , Y10T428/2848
摘要： A security laminate (1) including in order a transparent oriented polyester support (2), a subbing layer (3) and an adhesive layer (4) which is coated on top of the subbing layer, wherein the binder of the adhesive layer is based on a mixture of a first and a second polymer in a weight ratio from 50/50 to 90/10, wherein the first polymer is a copolymer comprising vinyl acetate and at least 85 wt % of vinyl chloride based on the total weight of the first polymer; wherein the second polymer is a copolymer of styrene, butadiene and methylmethacrylate or a copolymer of vinyl butyral, vinyl acetate and vinyl alcohol; and wherein the binder of the subbing layer is based on a polyester-urethane copolymer.
摘要翻译：一种安全层压板（1），其包括以透明取向的聚酯载体（2），底层（3）和粘合剂层（4）为基础，所述粘合层涂覆在所述底层的顶部，其中所述粘合剂层的粘合剂基于在第一和第二聚合物的重量比为50/50至90/10的混合物中，其中第一聚合物是包含乙酸乙烯酯和至少85重量％的氯乙烯的共聚物，基于第一和第二聚合物的总重量聚合物; 其中所述第二聚合物是苯乙烯，丁二烯和甲基丙烯酸甲酯的共聚物或乙烯醇缩丁醛，乙酸乙烯酯和乙烯醇的共聚物; 并且其中所述底层的粘合剂基于聚酯 - 氨基甲酸酯共聚物。

6. 发明申请

US20140193638A1 PET-C Based Security Laminates and Documents 有权
标题翻译： PET-C型安全层压板和文件
公开(公告)号：US20140193638A1
公开(公告)日：2014-07-10
申请号：US14238810
申请日：2012-09-03
申请人： Vera Drieghe , Peter Cantraine , Bart Waumans , Walther Wouters , Ingrid Geuens
发明人： Vera Drieghe , Peter Cantraine , Bart Waumans , Walther Wouters , Ingrid Geuens
IPC分类号： C09J7/02
CPC分类号： B42D25/47 , B29C55/10 , B42D25/00 , B42D2033/04 , B42D2033/20 , B42D2033/30 , B42D2033/46 , C08J7/042 , C08J2367/02 , C09J7/29 , Y10T428/264 , Y10T428/265 , Y10T428/2848
摘要： A security laminate (1) including in order a transparent oriented polyester support (2), a subbing layer (3) and an adhesive layer (4) which is coated on top of the subbing layer, wherein the binder of the adhesive layer is based on a mixture of a first and a second polymer in a weight ratio from 50/50 to 90/10, wherein the first polymer is a copolymer comprising vinyl acetate and at least 85 wt % of vinyl chloride based on the total weight of the first polymer; wherein the second polymer is a copolymer of styrene, butadiene and methylmethacrylate or a copolymer of vinyl butyral, vinyl acetate and vinyl alcohol; and wherein the binder of the subbing layer is based on a polyester-urethane copolymer.
摘要翻译：一种安全层压板（1），其包括以透明取向的聚酯载体（2），底层（3）和粘合剂层（4）为基础，所述粘合层涂覆在所述底层的顶部，其中所述粘合剂层的粘合剂为基础在第一和第二聚合物的重量比为50/50至90/10的混合物中，其中第一聚合物是包含乙酸乙烯酯和至少85重量％的氯乙烯的共聚物，基于第一和第二聚合物的总重量聚合物; 其中所述第二聚合物是苯乙烯，丁二烯和甲基丙烯酸甲酯的共聚物或乙烯醇缩丁醛，乙酸乙烯酯和乙烯醇的共聚物; 并且其中所述底层的粘合剂基于聚酯 - 氨基甲酸酯共聚物。

7. 发明授权

US07175977B2 Stabilizers for use in thermographic recording materials 失效
标题翻译：稳定剂用于热成像记录材料
公开(公告)号：US07175977B2
公开(公告)日：2007-02-13
申请号：US11000407
申请日：2004-11-30
申请人： Ingrid Geuens , Johan Loccufier
发明人： Ingrid Geuens , Johan Loccufier
IPC分类号： B41M5/20 , G03C1/34
CPC分类号： G03C1/4989 , G03C1/49845 , G03C2200/40
摘要： A black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one five-membered heterocyclic ring compound selected from the group consisting of optionally substituted, optionally annelated 1-thia-2,3-diazole compounds; optionally substituted, optionally annelated 1-thia-2,5-diazole compounds; optionally substituted 1-thia-2,4-diazole compounds; optionally substituted 1-thia-3,4-diazole compounds; optionally substituted thiatriazole compounds; optionally substituted, optionally annelated 1-seleno-2,3-diazole compounds; optionally substituted, optionally annelated 1-seleno-2,5-diazole compounds; optionally substituted 1-seleno-2,4-diazole compounds; optionally substituted 1-seleno-3,4-diazole compounds; and optionally substituted selenotriazole compounds, with the proviso that the at least one compound is not substituted with or contain a mercapto, a —SO2CBr3, a —S-alkylene-COOH or a N-acyl-hydrazine group.
摘要翻译：一种包含支持体和热敏元件的黑色和白色单片热成像记录材料，所述热敏元件含有基本上不光敏的有机银盐，与其热加工关系的有机还原剂，粘合剂和至少一种五元杂环选自任选取代的，任选被取代的1-硫杂-2,3-二唑化合物的环化合物; 任选取代的，任选被取代的1-硫杂-2,5-二唑化合物; 任选取代的1-硫杂-2,4-二唑化合物; 任选取代的1-硫杂-3,4-二唑化合物; 任选取代的噻唑三唑化合物; 任选取代的，任选被取代的1-硒代-2,3-二唑化合物; 任选取代的，任选被取代的1-硒基-2,5-二唑化合物; 任选取代的1-硒基-2,4-二唑化合物; 任选取代的1-硒基-3,4-二唑化合物; 和任选取代的硒代三唑化合物，条件是至少一种化合物未被巯基，-SO 2 C 3 -C 3亚烷基，-S-亚烷基 -COOH或N-酰基 - 肼基。

8. 发明授权

US06908731B2 Stabilizers for use in substantially light-insensitive thermographic recording materials 有权
标题翻译：用于基本上不透光的温度记录材料的稳定剂
公开(公告)号：US06908731B2
公开(公告)日：2005-06-21
申请号：US10712189
申请日：2003-11-13
申请人： Ingrid Geuens , Carlo Uyttendaele , Ivan Hoogmartens , Johan Loccufier
发明人： Ingrid Geuens , Carlo Uyttendaele , Ivan Hoogmartens , Johan Loccufier
IPC分类号： B41M5/30 , B41M5/32 , G03C1/498 , G03C1/34 , G03C1/494
CPC分类号： G03C1/4989 , G03C1/49845 , G03C2200/40 , Y10S430/165 , Y10S430/166
摘要： A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one stabilizer selected from the group consisting of 1-phenyl-5-mercaptotetrazole compounds in which the phenyl group is substituted with a substituent containing an optionally substituted aryl group; and
摘要翻译：一种基本上不透光的黑色和白色单片热成像记录材料，包括支撑体和热敏元件，该热敏元件含有基本上不光敏的有机银盐，与其热加工关系的有机还原剂，粘合剂和至少一种选自1-苯基-5-巯基四唑化合物的稳定剂，其中苯基被含有任选取代的芳基的取代基取代; 和

9. 发明授权

US07294605B2 Thermographic recording materials containing a mesionic, 1,2,4-triazolium-3-thiolate compound 失效
标题翻译：含有中间体1,2,4-三唑鎓-3-硫醇盐化合物的热成像记录材料
公开(公告)号：US07294605B2
公开(公告)日：2007-11-13
申请号：US11007487
申请日：2004-12-08
申请人： Johan Loccufier , Ingrid Geuens
发明人： Johan Loccufier , Ingrid Geuens
IPC分类号： B41M5/30
CPC分类号： G03C1/49845 , G03C1/49881 , G03C1/4989
摘要： A substantially light-insensitive black and white monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one mesionic 1,2,4-triazolium-3-thiolate compound.
摘要翻译：一种基本上不透光的黑色和白色单片热成像记录材料，包括支撑体和热敏元件，该热敏元件含有基本上不光敏的有机银盐，与其热加工关系的有机还原剂，粘合剂和至少一种中间体1,2,4-三唑鎓-3-硫醇化合物。

10. 发明授权

US6037114A Thermographic recording material with improved image density and/or image gradation upon thermal development 有权
标题翻译：热成像记录材料，具有改善的图像密度和/或图像等级
公开(公告)号：US6037114A
公开(公告)日：2000-03-14
申请号：US199924
申请日：1998-11-25
申请人： Ivan Hoogmartens , Ingrid Geuens , Johan Loccufier
发明人： Ivan Hoogmartens , Ingrid Geuens , Johan Loccufier
IPC分类号： G03C1/498
CPC分类号： G03C1/49845 , G03C1/4989
摘要： A recording material exclusive of a thermal bleachable dye comprising a support and a thermosensitive element comprising an organic silver salt, an organic reducing agent therefor in thermal working relationship therewith and a binder, wherein the recording material further contains non-halide-ion-containing arylonium compound exclusive of compounds according to formula (I): ##STR1## wherein L.sub.a is a valence bond or a divalent or trivalent linking group, L.sub.2 is an alkylene group, each of R.sub.a and R.sub.b is a hydrogen atom or monovalent substituent group, M.sub.1 is an onium ion, R.sub.a and R.sub.b may form a ring taken together and D is an electron donative group of atoms, with the proviso that where D is a hydrazino group which is not a part of a semicarbazido group, no oxo group is substituted to the carbon atom which is directly attached to a nitrogen atom of the hydrazine; and a recording process therefor.
摘要翻译：不含热可漂白染料的记录材料，其包含载体和包含有机银盐的热敏元件，与其热加工关系的有机还原剂和粘合剂，其中所述记录材料还含有非卤化物离子的芳基不包括根据式（I）的化合物的化合物：其中La是价键或二价或三价连接基团，L2是亚烷基，Ra和Rb各自为氢原子或一价取代基，M1为鎓离子，R a和R b可以形成一个环，D是原子的给电子基团，条件是其中D是不是一个氨基脲基的一部分的肼基，没有氧代基被碳原子取代直接连接到肼的氮原子上; 及其记录过程。

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