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    • 1. 发明授权
    • Pigment dispersions with polymeric dispersants having pending chromophore groups
    • 具有悬浮发色团的聚合物分散剂的颜料分散体
    • US08759441B2
    • 2014-06-24
    • US11995330
    • 2006-06-23
    • Johan LoccufierWojciech JaunkyGeert DerooverLambertus Groenendaal
    • Johan LoccufierWojciech JaunkyGeert DerooverLambertus Groenendaal
    • C08L67/00C08L67/02C08L73/00C08L77/00C08L81/00C08G18/06C09D11/10
    • C09B69/106C09B67/0033C09B67/0036C09B67/0051C09B67/0063C09B67/009C09B69/10C09B69/109C09D11/101C09D11/326
    • A pigment dispersion includes a color pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group, wherein the at least one pending chromophore group is a derivative from a color pigment selected from the group consisting of monoazo pigments, disazo pigments, β-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindolinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacridone pigments, diketopyrrolo-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminum pigment lakes, dioxazine pigments, triarylcarbonium pigments, and quinophthalone pigments; the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; the polymeric dispersant has a polymeric backbone with a polymerization degree between 5 and 1,000; and at most 30 % of the monomer units of the polymeric backbone have a pending chromophore group. The pigment dispersion can be advantageously used in inkjet inks. Also disclosed is a method for preparing the pigment dispersion including the step of preparing the polymeric dispersant by copolymerizing a monomer already containing the pending chromophore group.
    • 颜料分散体包括着色颜料和聚合物分散剂,其具有通过连接基团与聚合物分散剂的聚合物主链共价结合的至少一个待处理的发色团,其中所述至少一个未完成的发色团是来自选自以下的颜色颜料的衍生物: 由单偶氮颜料,双偶氮颜料,萘酚颜料,萘酚AS颜料,偶氮颜料湖,苯并咪唑酮颜料,双偶氮缩合颜料,金属络合颜料,异吲哚啉酮颜料,异吲哚啉颜料,酞菁颜料,喹吖啶酮颜料,二酮吡咯并 - 吡咯 颜料,硫靛颜料,蒽醌颜料,蒽嘧啶颜料,阴丹酮颜料,黄烷酮酮颜料,吡喃酮颜料,蒽醌颜料,异卤蒽酮颜料,铝颜料湖,二恶嗪颜料,三芳基碳鎓颜料和喹酞酮颜料; 至少一个未决发色团组是作为聚合物主链上的侧基而不是聚合物主链本身中的基团发生或仅作为聚合物主链的端基发生的发色团。 连接基团由聚合物主链和芳族基团的第一个原子之间的所有原子组成,待处理的发色团通过该原子连接到聚合物主链上; 聚合物分散剂具有聚合度为5至1,000的聚合物主链; 并且至多30%的聚合物主链的单体单元具有未决的发色团组。 颜料分散体可以有利地用于喷墨油墨中。 还公开了一种制备颜料分散体的方法,其包括通过使已经含有未完成发色团的单体共聚制备聚合物分散剂的步骤。
    • 4. 发明授权
    • Pigment dispersions with polymeric dispersants having pending chromophore groups
    • 具有悬浮发色团的聚合物分散剂的颜料分散体
    • US07582150B2
    • 2009-09-01
    • US11995322
    • 2006-06-23
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • C09D11/02C08K5/23
    • C09B67/009C09B67/0046C09B67/0051C09B69/106C09D11/326C09D17/003
    • A pigment dispersion comprising a color pigment represented by formula (I) wherein, R1 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH, —COOCH3 and R2, R4 and R5 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH and —COOCH3; R3 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH, —COOCH3, —SO2NH—C6H5, —CONH—C6H5, —CONH—C6H5—CONH2 and —CONH2; R6 and R7 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH and —COOCH3, or R6 and R7 represent the necessary atoms to form an imidazolone ring; and a polymeric dispersant having via a linking group covalently linked to its polymeric backbone at least one pending chromophore group which has a molecular weight smaller than 95% of the molecular weight of said color pigment. The pigment dispersion can be advantageously used in inkjet inks.
    • 一种颜料分散体,其包含由式(I)表示的着色颜料,其中R 1选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3,-COOH ,-COOCH 3和R 2,R 4和R 5独立地选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3,-COOH和-COOCH 3; R 3选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3,-COOH,-COOCH 3,-SO 2 NH-C 6 H 5,-CONH-C 6 H 5 - CONH-C6H5-CONH2和-CONH2; R6和R7独立地选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF3,-COOH和-COOCH3,或R6和R7表示必需的原子 形成咪唑啉酮环; 以及聚合物分散剂,其通过共价连接至其聚合物主链的至少一个分子量小于所述彩色颜料分子量的95%的待发色团。 颜料分散体可以有利地用于喷墨油墨中。
    • 5. 发明授权
    • Pigment dispersion with polymeric dispersants having pending chromophore groups
    • 具有悬浮发色团的聚合物分散剂的颜料分散体
    • US07582151B2
    • 2009-09-01
    • US11995323
    • 2006-06-23
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • C09D11/02C08K5/23
    • C09B69/106C09B67/0046C09B67/0063C09B67/009C09B69/10C09D11/326
    • A pigment dispersion includes a color pigment represented by formula (I): wherein X1 to X4 are independently selected from the group consisting of hydrogen and a halogen atom; R1 to R10 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, and an ethoxy group; and a polymeric dispersant, having via a linking group covalently linked to its polymeric backbone, at least one pending chromophore group which has a molecular weight smaller than 90% of the molecular weight of the color pigment; wherein the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; and the at least one pending chromophore group is represented by formula (II): wherein, one of L1, L2 or L3 is the linking group and is selected from the group consisting of an aliphatic group, a substituted aliphatic group, an unsaturated aliphatic group, and a substituted unsaturated aliphatic group; L1, L2, and/or L3, if not representing the linking group, are independently selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkoxy group, a carboxylic acid group, an ester group, an acyl group, a nitro group, and a halogen; AR1 and AR2-represent an aromatic group; and n represents the integer 0 or 1. The pigment dispersion can be advantageously used in inkjet inks. Also disclosed are methods for preparing the inkjet ink.
    • 颜料分散体包括由式(I)表示的着色颜料:其中X1至X4独立地选自氢和卤素原子; R 1至R 10独立地选自氢,卤素原子,甲基,乙基,甲氧基和乙氧基; 和通过与其聚合物骨架共价连接的连接基团的聚合物分散剂,至少一种分子量小于彩色颜料分子量的90%的待发色团; 其中所述至少一个未完成的发色团组是作为所述聚合物主链上的侧基而不是所述聚合物主链本身中的基团或仅作为所述聚合物主链的端基发生的发色团。 并且所述至少一个未决发色团由式(II)表示:其中,L1,L2或L3中的一个为连接基团,并且选自脂族基团,取代的脂族基团,不饱和脂族基团 和取代的不饱和脂族基团; 如果不代表连接基团,则L1,L2和/或L3独立地选自氢,烷基,烯基,烷氧基,羧酸基,酯基,酰基 ,硝基和卤素; AR1和AR2代表芳族基团; 并且n表示整数0或1.颜料分散体可有利地用于喷墨油墨中。 还公开了制备喷墨油墨的方法。
    • 6. 发明申请
    • Pigment Dispersion with Polymeric Dispersants Having Pending Chromophore Groups
    • 具有悬垂发色团的聚合物分散剂的颜料分散体
    • US20080242776A1
    • 2008-10-02
    • US11995323
    • 2006-06-23
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • C09B67/00
    • C09B69/106C09B67/0046C09B67/0063C09B67/009C09B69/10C09D11/326
    • A pigment dispersion includes a color pigment represented by formula (I): wherein X1 to X4 are independently selected from the group consisting of hydrogen and a halogen atom; R1 to R10 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, and an ethoxy group; and a polymeric dispersant, having via a linking group covalently linked to its polymeric backbone, at least one pending chromophore group which has a molecular weight smaller than 90% of the molecular weight of the color pigment; wherein the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; and the at least one pending chromophore group is represented by formula (II): wherein one of L1, L2, or L3 is the linking group and is selected from the group consisting of an aliphatic group, a substituted aliphatic group, an unsaturated aliphatic group, and a substituted unsaturated aliphatic group; L1, L2, and/or L3, if not representing the linking group, are independently selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkoxy group, a carboxylic acid group, an ester group, an acyl group, a nitro group, and a halogen; AR1 and AR2 represent an aromatic group; and n represents the integer 0 or 1. The pigment dispersion can be advantageously used in inkjet inks. Also disclosed are methods for preparing the inkjet ink.
    • 颜料分散体包括由式(I)表示的着色颜料:其中X1至X4独立地选自氢和卤素原子; R 1至R 10独立地选自氢,卤素原子,甲基,乙基,甲氧基和乙氧基; 和通过与其聚合物骨架共价连接的连接基团的聚合物分散剂,至少一种分子量小于彩色颜料分子量的90%的待发色团; 其中所述至少一个未完成的发色团组是作为所述聚合物主链上的侧基而不是所述聚合物主链本身中的基团或仅作为所述聚合物主链的端基发生的发色团。 并且所述至少一个未决发色团组由式(II)表示:其中,L 1,L 2或L 3中的一个为连接基团,并且选自脂族基团,取代的脂族基团,不饱和脂族基团 和取代的不饱和脂族基团; 如果不代表连接基团,则L1,L2和/或L3独立地选自氢,烷基,烯基,烷氧基,羧酸基,酯基,酰基 ,硝基和卤素; AR1和AR2代表芳族基团; 并且n表示整数0或1.颜料分散体可有利地用于喷墨油墨中。 还公开了制备喷墨油墨的方法。
    • 8. 发明申请
    • Pigment Dispersions with Polymeric Dispersants Having Pending Chromophore Groups
    • 具有悬垂发色团的聚合物分散剂的颜料分散体
    • US20080227894A1
    • 2008-09-18
    • US11995330
    • 2006-06-23
    • Johan LoccufierWojciech JaunkyGeert DerooverLambertus Groenendaal
    • Johan LoccufierWojciech JaunkyGeert DerooverLambertus Groenendaal
    • C08K5/3445C08K5/23C08K5/13
    • C09B69/106C09B67/0033C09B67/0036C09B67/0051C09B67/0063C09B67/009C09B69/10C09B69/109C09D11/101C09D11/326
    • A pigment dispersion comprising a colour pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group wherein the at least one pending chromophore group is a derivative from a colour pigment selected from the group consisting of monoazo pigments, disazo pigments, β-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindolinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacridone pigments, diketopyrrolo-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminium pigment lakes, dioxazine pigments, triarylcarbonium pigments and quinophthalone pigments; the at least one pending chromophore group is a chromophore group occurring as a side group on the polymeric backbone and not a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; the polymeric dispersant has a polymeric backbone with a polymerization degree between 5 and 1000; and at most 30% of the monomer units of the polymeric backbone have a pending chromophore group. The pigment dispersion can be advantageously used in inkjet inks.Also disclosed is a method for preparing the pigment dispersion comprising the step of preparing the polymeric dispersant by copolymerizing a monomer already containing the pending chromophore group.
    • 一种颜料分散体,其包含着色颜料和聚合物分散剂,其具有通过连接基团与聚合物分散剂的聚合物主链共价结合的至少一个未决发色团,其中所述至少一个未决发色团基团是选自以下的颜色颜料的衍生物: 由双偶氮颜料,双偶氮颜料,β-萘酚颜料,萘酚AS颜料,偶氮颜料湖,苯并咪唑酮颜料,双偶氮缩合颜料,金属络合物颜料,异吲哚啉酮颜料,异吲哚啉颜料,酞菁颜料,喹吖啶酮颜料,二酮吡咯并 - 吡咯颜料, 硫靛颜料,蒽醌颜料,蒽嘧啶颜料,阴丹酮颜料,黄烷酮酮颜料,吡喃酮颜料,蒽醌颜料,异卤蒽酮颜料,铝颜料湖,二恶嗪颜料,三芳基碳鎓颜料和喹酞酮颜料; 至少一个未决发色团组是作为聚合物主链上的侧基而不是聚合物主链本身中的基团发生或仅作为聚合物主链的端基发生的发色团。 连接基团由聚合物主链和芳族基团的第一个原子之间的所有原子组成,待处理的发色团通过该原子连接到聚合物主链上; 聚合物分散剂具有聚合度在5和1000之间的聚合物主链; 并且至多30%的聚合物主链的单体单元具有未决的发色团组。 颜料分散体可以有利地用于喷墨油墨中。 还公开了一种制备颜料分散体的方法,其包括通过共聚已经含有待发色团的单体来制备聚合物分散剂的步骤。
    • 9. 发明申请
    • Pigment Dispersions with Polymeric Dispersants Having Pending Chromophore Groups
    • US20080214705A1
    • 2008-09-04
    • US11995321
    • 2006-06-23
    • Geert DerooverJohan LoccufierLambertus GroenendaalWojciech Jaunky
    • Geert DerooverJohan LoccufierLambertus GroenendaalWojciech Jaunky
    • C08K5/23C08K5/13C08K5/34C08K5/3415
    • C09B69/106C09B67/0046C09B67/0051C09B67/0063C09B67/009C09B69/10C09D11/326C09D11/40
    • A pigment dispersion includes a color pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking groupwherein the color pigment is selected from the group consisting of monoazo pigments, disazo pigments, β-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindolinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacridone pigments, diketopyrrolo-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminium pigment lakes, dioxazine pigments, triarylcarbonium pigments and quinophthalone pigments; the at least one pending chromophore group has a molecular weight which is smaller than 85% of the molecular weight of the color pigment; the at least one pending chromophore group occurs as a side group on the polymeric backbone and not as a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; and the at least one pending chromophore group has a similarity coefficient SIM of at least 0.75, with the similarity coefficient defined by: SIM = t · C M + P - C wherein, M represents the number of atoms in the at least one pending chromophore group; P represents the number of atoms in the color pigment; C represents the largest number of atoms in common between the at least one pending chromophore group and the color pigment as one continuous structure; and t is an integer representing the number of times that the largest number of atoms in common C fits into the organic color pigment, without using atoms of the color pigment twice. A method for preparing the pigment dispersion wherein the polymeric dispersant is prepared by copolymerizing a monomer already containing the pending chromophore group is also disclosed.
    • 10. 发明申请
    • Pigment Dispersions with Polymeric Dispersants Having Pending Chromophore Groups
    • 具有悬垂发色团的聚合物分散剂的颜料分散体
    • US20080207806A1
    • 2008-08-28
    • US11995322
    • 2006-06-23
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • C09B67/20C09D11/02
    • C09B67/009C09B67/0046C09B67/0051C09B69/106C09D11/326C09D17/003
    • A pigment dispersion comprising a colour pigment represented by formula (I) wherein, R1 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH, —COOCH3 and R2, R4 and R5 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH and —COOCH3; R3 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH, —COOCH3, —SO2NH—C6H5, —CONH—C6H5, —CONH—C6H5—CONH2 and —CONH2; R6 and R7 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH and —COOCH3, or R6 and R7 represent the necessary atoms to form an imidazolone ring; and a polymeric dispersant having via a linking group covalently linked to its polymeric backbone at least one pending chromophore group which has a molecular weight smaller than 95% of the molecular weight of said colour pigment. The pigment dispersion can be advantageously used in inkjet inks.
    • 一种颜料分散体,其包含由式(I)表示的着色颜料,其中R 1选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3,-COOH,-COOCH 3,R 2,R 4和R 5独立地选自氢,卤素原子,甲基,乙基,甲氧基 ,乙氧基,-CF 3,-COOH和-COOCH 3; R 3选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3 - ,-COOH,-COOCH 3 -SO 2,NH-C 6 H 5,-CONH-C 6 H, -CONH-C 6 H 5 -CONH 2和-CONH 2 N 2 - , - ; R 6和R 7独立地选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3 - ,-COOH和-COOCH 3, 或者R 6和R 7代表形成咪唑啉酮环的必要原子; 以及聚合物分散剂,其通过共价连接至其聚合物主链的至少一个分子量小于所述彩色颜料分子量的95%的待发色团。 颜料分散体可以有利地用于喷墨油墨中。