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    • 41. 发明授权
    • Manufacturing method of a semiconductor device with a silicide layer
    • 具有硅化物层的半导体器件的制造方法
    • US5950098A
    • 1999-09-07
    • US911979
    • 1997-08-15
    • Hidekazu OdaTakashi Kuroi
    • Hidekazu OdaTakashi Kuroi
    • H01L29/78H01L21/265H01L21/28H01L21/285H01L21/336H01L29/45H01L29/49H01L21/425
    • H01L29/66575H01L21/28052H01L21/28518H01L29/456H01L29/4933
    • To form a silicide layer excellent in flatness, uniform in film thickness, and less in junction leak, by destroying the natural oxide film which adversely affects a formation of silicide layer of cobalt or nickel. A cobalt layer (7) is formed in a film thickness of 20 nm or less on an electrode layer (4A) of a gate electrode (4) and on source/drain diffusion layers (1, 2), and a nitrogen (8) is injected by the ion implantation at a density of about 1E15/cm.sup.3 with an injection energy of 10 keV or more. At this time, the nitrogens (8) destroy the natural oxide film existing in the interface of the cobalt layer (7) and electrode layer (4A), and in the interface of the cobalt layer (7) and the source/drain diffusion layers (1, 2), and distribute deeply into the electrode layer (4A) and the source/drain diffusion layers (1, 2). Later, by a silicide forming reaction of cobalt, a silicide layer (6) is formed. Since the natural oxide film does not exist, the silicide forming reaction proceeds uniformly. Instead of the nitrogen (8), fluorine or silicon may be also used.
    • 通过破坏对钴或镍的硅化物层的形成有不利影响的自然氧化膜,形成平坦度优异,膜厚均匀,并且漏点较少的硅化物层。 在栅电极(4)的电极层(4A)和源/漏扩散层(1,2)上形成厚度为20nm以下的钴层(7),氮(8) 通过离子注入以约1E15 / cm3的密度注入,注入能量为10keV以上。 此时,氮(8)破坏存在于钴层(7)和电极层(4A)的界面中的自然氧化膜,并且在钴层(7)和源极/漏极扩散层 (1,2),并且深深地分布到电极层(4A)和源极/漏极扩散层(1,2)中。 然后,通过钴的硅化物形成反应,形成硅化物层(6)。 由于天然氧化物膜不存在,所以硅化物形成反应均匀地进行。 代替氮(8),也可以使用氟或硅。
    • 44. 发明授权
    • Method of manufacturing semiconductor device
    • 制造半导体器件的方法
    • US06667221B2
    • 2003-12-23
    • US10212274
    • 2002-08-06
    • Masashi KitazawaTomohiro YamashitaTakashi Kuroi
    • Masashi KitazawaTomohiro YamashitaTakashi Kuroi
    • H01L2176
    • H01L23/544H01L21/3081H01L21/76229H01L2223/5442H01L2223/54426H01L2223/54453H01L2924/0002Y10S438/975H01L2924/00
    • A technique for preventing a decrease in alignment accuracy during a photolithography process is provided. A substrate (1) is prepared, in the surface (80) of which trenches (7) for use as alignment marks and trenches (17, 27) each forming an element isolation structure are formed and on the surface (80) of which a polysilicon film (3) is formed, avoiding the trenches (7, 17, 27). The trenches (7, 17, 27) are filled with an insulation film (30). The insulation film (30) is then selectively etched to partially remove the insulation film (30) in the trenches (7) and to leave the insulation film (30) on side and bottom surfaces (81, 82) of the trenches (7). Using the insulation film (30) in the trenches (7) as a protective film, the polysilicon film (3) is selectively etched. The use of the insulation film (30) in the trenches (7) as a protective film prevents the substrate (1) from being etched and thereby prevents the shape of the trenches (7) from being changed. This results in prevention of a decrease in alignment accuracy during a photolithography process.
    • 提供了一种在光刻工艺中防止对准精度降低的技术。 在表面(80)中制备基板(1),其中形成用作对准标记的沟槽(7)和形成元件隔离结构的沟槽(17,27),并且其表面(80) 形成多晶硅膜(3),避免了沟槽(7,17,27)。 沟槽(7,17,27)填充绝缘膜(30)。 然后选择性地蚀刻绝缘膜(30)以部分去除沟槽(7)中的绝缘膜(30)并且在沟槽(7)的侧面和底面(81,82)上留下绝缘膜(30) 。 使用沟槽(7)中的绝缘膜(30)作为保护膜,选择性地蚀刻多晶硅膜(3)。 使用作为保护膜的沟槽(7)中的绝缘膜(30)可防止基板(1)被蚀刻,从而防止沟槽(7)的形状发生变化。 这导致防止在光刻工艺期间对准精度降低。
    • 48. 发明授权
    • Method of manufacturing semiconductor device
    • 制造半导体器件的方法
    • US06383884B1
    • 2002-05-07
    • US09496057
    • 2000-02-02
    • Katsuomi ShiozawaTakashi KuroiYasuyoshi ItohKatsuyuki Horita
    • Katsuomi ShiozawaTakashi KuroiYasuyoshi ItohKatsuyuki Horita
    • H01L21336
    • H01L29/66545H01L21/28247H01L29/66537
    • A semiconductor device includes a silicon substrate (1), a pair of isolating insulation films (9), a channel region (2), a pair of source/drain regions (3), a pair of silicon oxide films (4) formed on an upper surface of the silicon substrate (1) so as to overlie the source/drain regions (3), and a gate structure (8) formed in a first recess defined by the upper surface of the silicon substrate (1) over the channel region (2) and side surfaces of the pair of silicon oxide films (4). The gate structure (8) includes a gate oxide film (5) formed on the upper surface of the silicon substrate (1), a pair of silicon oxide films (6) formed on lower part of the side surfaces of the pair of silicon oxide films (4), and a metal film (7) filling a second recess surrounded by upper part of the side surfaces of the silicon oxide films (4), the silicon oxide films (6) and the gate oxide film (5). A method of manufacturing the semiconductor device is provided which attains reduction in gate length without the decrease in driving capability to accomplish the increase in operating speed.
    • 半导体器件包括硅衬底(1),一对隔离绝缘膜(9),沟道区(2),一对源/漏区(3),一对氧化硅膜(4),形成在 硅衬底(1)的上表面覆盖在源极/漏极区(3)上,并且栅极结构(8)形成在由硅衬底(1)的上表面限定的第一凹部中,沟道 区域(2)和一对氧化硅膜(4)的侧表面。 栅极结构(8)包括形成在硅衬底(1)的上表面上的栅氧化膜(5),一对氧化硅膜(6),形成在该一对氧化硅的侧表面的下部 以及填充由氧化硅膜(4)的侧面的上部,氧化硅膜(6)和栅极氧化膜(5)所包围的第二凹部的金属膜(7)。 提供了一种制造半导体器件的方法,其在不降低驱动能力的情况下实现栅极长度的减小以实现操作速度的提高。
    • 50. 发明授权
    • Method of forming a trench type element isolation in semiconductor substrate
    • 在半导体衬底中形成沟槽型元件隔离的方法
    • US06268263B1
    • 2001-07-31
    • US09196134
    • 1998-11-20
    • Maiko SakaiTakashi KuroiKatsuyuki Horita
    • Maiko SakaiTakashi KuroiKatsuyuki Horita
    • H01L2176
    • H01L21/31053H01L21/76224Y10S438/97
    • A trench (21) is formed in a silicon substrate (1) on which an underlying oxide film (2) and a silicon nitride film (3) are formed. Then, a silicon oxide (11) is deposited by an HDP-CVD method to fill the trench (21) with the oxide. Further, a resist (41) including a second resist portion (42), and a resist (43) are formed. The silicon oxide film (11) that is not covered with the resists (41) and (43), is removed by dry etching. Etch selectivity of the silicon oxide film (11) to the stopper film (3) is not less than a value (2(c−a)/d) obtained by dividing twice a value (c−a) which is obtained by subtracting an alignment margin (a) from the maximum film thickness (c) of the silicon oxide film (11), by the film thickness (d) of the stopper film (3). The resists (41) and (43) are then removed, and the residual silicon oxide film (11B, 11DC, 11DE, 11FE) is polished and removed by the CMP method. This forms a trench type element isolation with no depression at its edge portion.
    • 在其上形成有下面的氧化膜(2)和氮化硅膜(3)的硅衬底(1)中形成沟槽(21)。 然后,通过HDP-CVD法沉积氧化硅(11)以用氧化物填充沟槽(21)。 此外,形成包括第二抗蚀剂部分(42)和抗蚀剂(43)的抗蚀剂(41)。 通过干蚀刻除去未被抗蚀剂(41)和(43)覆盖的氧化硅膜(11)。 氧化硅膜(11)对阻挡膜(3)的蚀刻选择性不小于通过将通过减去取向余量(a)获得的值(ca)的两倍所获得的值(2(ca)/ d) )从氧化硅膜(11)的最大膜厚度(c)到阻挡膜(3)的膜厚度(d)。 然后除去抗蚀剂(41)和(43),并通过CMP方法研磨和除去残留氧化硅膜(11B,11DC,11DE,11FE)。 这形成了在其边缘部分没有凹陷的沟槽型元件隔离。