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31. 发明授权

US6040443A Process for the production of benzoxazinones 失效
标题翻译：生产苯并恶嗪酮的方法
公开(公告)号：US6040443A
公开(公告)日：2000-03-21
申请号：US119300
申请日：1998-07-20
申请人： Georges Metzger , Dieter Reinehr , Serge Hauger
发明人： Georges Metzger , Dieter Reinehr , Serge Hauger
IPC分类号： C07D265/22 , C07D265/02
CPC分类号： C07D265/22
摘要： There is described a process for the production of a 1,3-benzoxazin-4-one having the formula: ##STR1## in which R.sub.1 and R.sub.2, independently, are hydrogen, cyano, halogen, nitro, C.sub.1 -C.sub.20 alkyl, O--C.sub.1 -C.sub.20 alkyl, phenyl, NH--CO--C.sub.1 -C.sub.20 alkyl, N(R.sub.3).sub.2, SO.sub.2 N(R.sub.3).sub.2, COOR.sub.3 or CON(R.sub.3).sub.2 in which R.sub.3 is hydrogen, cyano, halogen, nitro, C.sub.1 -C.sub.20 alkyl, O--C.sub.1 -C.sub.20 alkyl, phenyl or NH--CO--C.sub.1 -C.sub.20 alkyl, comprising reacting, at elevated temperature, 1 molar equivalent of an o-hydroxybenzamide of formula: ##STR2## in which R.sub.1 has its previous significance, with 2 to 6 molar equivalents of a benzoyl chloride of formula: ##STR3## in which R.sub.2 has its previous significance. The 1,3-benzoxazin-4-ones having the formula (1) so obtained are important intermediates for the production of triazine compounds having excellent absorption spectrum characteristics and good resistance to exposure to UV light.
摘要翻译：描述了制备具有下式的1,3-苯并恶嗪-4-酮的方法：其中R 1和R 2独立地是氢，氰基，卤素，硝基，C 1 -C 20烷基，O-C 1 -C 20烷基，苯基，NH-CO-C 1 -C 20烷基，N（R 3）2，SO 2 N（R 3）2，COOR 3或CON（R 3）2，其中R 3是氢，氰基，卤素，硝基，C 1 -C 20烷基，O-C 1 -C 20烷基苯基或NH-CO-C 1 -C 20烷基，其包括在升高的温度下，将1摩尔当量的具有其先前意义的式的邻羟基苯甲酰胺与2至6摩尔当量的下式的苯甲酰氯反应：其中R2具有以前的意义。具有式（1）的1,3-苯并恶嗪-4-酮是制备具有优异的吸收光谱特性和良好的耐紫外线性的三嗪化合物的重要中间体。

32. 发明授权

US5733341A Inhibition of dye migration in a wash liquor 失效
标题翻译：在洗液中抑制染料迁移
公开(公告)号：US5733341A
公开(公告)日：1998-03-31
申请号：US572417
申请日：1995-12-14
申请人： Claude Eckhardt , Dieter Reinehr , Georges Metzger
发明人： Claude Eckhardt , Dieter Reinehr , Georges Metzger
IPC分类号： C07D213/38 , C07D213/53 , C07D255/04 , C07D257/10 , C07D487/22 , C07F13/00 , C11D3/00 , C11D3/16 , C11D3/28 , C11D3/32 , C11D3/34 , C11D3/37 , C11D3/39 , C11D3/30 , C11D3/395 , C11D7/10 , D06L3/02
CPC分类号： C07D213/53 , C07D213/38 , C07D255/04 , C07D257/10 , C07F13/005 , C11D3/0021 , C11D3/168 , C11D3/28 , C11D3/32 , C11D3/349
摘要： A process is described for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150, preferably from 1.5 to 75, especially from 7.5 to 40 mg, per liter of wash liquor, of one or more compounds having the formula (1), (2), (3), (4), (5), (6), (7), (8), (9), (10), (11), (12), (13) or (14) as defined in the specification. The compounds of formula (1), (2), (3), (4), (5), (6), (8), (9) (10), (11), (12), (13) or (14) are new compounds. The compounds used do not exhaust at all on to cotton, polyamide or polyester fibers, so that the compounds cannot lead to fiber discoloration problems.
摘要翻译：描述了一种用于抑制洗涤液中迁移染料的再吸收的方法，包括将含有过氧化物的洗涤剂的洗涤液从0.5至150，优选1.5至75，特别是7.5至40mg，一种或多种具有式（1），（2），（3），（4），（5），（6），（7），（8），（9） 10），（11），（12），（13）或（14）。式（1），（2），（3），（4），（5），（6），（8），（9）（10），（11），（12）或（14）是新化合物。所使用的化合物根本不排放到棉，聚酰胺或聚酯纤维上，使得化合物不会导致纤维变色问题。

33. 发明授权

US5241109A Asymmetrical oxalic acid diarylamide 失效
标题翻译：不对称氧化二乙酰胺
公开(公告)号：US5241109A
公开(公告)日：1993-08-31
申请号：US858913
申请日：1992-03-27
申请人： Jurgen Kaschig , Gerhard Reinert , Georges Metzger
发明人： Jurgen Kaschig , Gerhard Reinert , Georges Metzger
IPC分类号： D06P1/645 , C07C309/11 , C07C309/51 , D06M13/02 , D06M13/322 , D06M13/402 , D06M101/00 , D06M101/12 , D06M101/16 , D06M101/30 , D06M101/34 , D06P1/649 , D06P3/24 , D06P5/00 , D06P5/06
CPC分类号： C07C309/11 , C07C309/51 , D06P1/6495
摘要： There is disclosed a water-soluble, asymmetrical oxalic acid diarylamide of general formula ##STR1## wherein the substituents R.sub.1 are each independently of the other unsubstituted or hydroxy- or alkoxy-substituted C.sub.1 -C.sub.5 alkyl, unsubstituted or C.sub.1 -C.sub.5 alkyl-substituted benzyl,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.12 alkyl or phenyl-C.sub.1 -C.sub.5 alkyl,R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.12 alkyl, phenyl-C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy,A is a direct bond or a divalent radical of formula --O--Q--, whereinQ is unsubstituted or hydroxy-substituted C.sub.1 -C.sub.6 alkylene,M is hydrogen or alkali metal, andr is 2, 1 or 0.The novel water-soluble compound having fiber affinity is suitable for the photochemical and thermal stabilisation of polyamide fiber materials and the dyeings produced thereon.
摘要翻译：公开了通式为（1）的水溶性不对称草酸二芳基酰胺，其中取代基R 1各自独立地为其它未取代的或羟基或烷氧基取代的C 1 -C 5烷基，未取代的或C 1 -C 5烷基取代的苄基，R 2是氢，卤素，C 1 -C 12烷基或苯基-C 1 -C 5烷基，R 3是氢，卤素，C 1 -C 12烷基，苯基-C 1 -C 5烷基或C 1 -C 5烷氧基，A是直接键或式 - OQ-，其中Q为未取代的或羟基取代的C 1 -C 6亚烷基，M为氢或碱金属，r为2或1。具有纤维亲和性的新型水溶性化合物适用于聚酰胺的光化学和热稳定性纤维材料和其上产生的染色。

34. 发明授权

US06468958B2 Biphenyl-substituted triazines 有权
标题翻译：联苯取代三嗪
公开(公告)号：US06468958B2
公开(公告)日：2002-10-22
申请号：US09848013
申请日：2001-05-03
申请人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
发明人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
IPC分类号： C07D25124
CPC分类号： C07D405/04 , A61K8/4966 , A61Q17/04 , C07D251/10 , C07D251/24 , C08K5/3435 , C08K5/3475 , C08K5/3492
摘要： Biphenyl-substituted triazines of the formulae which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
摘要翻译：用于高热稳定性的配方的联苯取代三嗪作为有机聚合物的稳定剂用作抗光，氧和热引起的损伤，作为纺织纤维材料的光稳定剂和用作人体皮肤的防晒剂。

35. 发明授权

US06365737B1 Process for the preparation of stilbene compounds 失效
标题翻译：二苯乙烯化合物的制备方法
公开(公告)号：US06365737B1
公开(公告)日：2002-04-02
申请号：US09622472
申请日：2000-08-17
申请人： Georges Metzger , Fabienne Cuesta , Peter Rohringer , Dieter Reinehr , René Schlatter
发明人： Georges Metzger , Fabienne Cuesta , Peter Rohringer , Dieter Reinehr , René Schlatter
IPC分类号： C07D25168
CPC分类号： C11D3/42 , C07D251/68 , D06L4/621 , D06M2200/25 , D21H21/30
摘要： A process for the preparation of a 4,4′-bis-(triazinylamino)-stilbene-2,2′-disulphonic acid compound of formula (1) is disclosed, characterized in that (a) in a first reaction step cyanurchloride is reacted with the disodium salt of 4,4′-diaminostilbene-2,2′-disulfonic acid to give the intermediate of formula (2); (b) in a second reaction step the compound of formula (2) is reacted with a compound of formula R1—H and/or R2—H to give the compound of formula (3); (c) in a third step the compound of formula (3) is reacted with the compound of the formula R3H, and reaction step (a) and/or (c) are carried out in a medium consisting of a mixture of water and a polyglycol to give the compound of formula (1), wherein R1, R2 and R3, independently, are phenylamino; phenylamino substitued by C1-C3alkyl, halogen, cyano, COOR or COR; CONH—R; SO2NH—R; NH—COR; mono- or disulphonated phenylamino; morpholino; piperidino; pyrrolidino; —NH2; —NH(C1-C4alkyl); —N(C1-C4alkyl)2; —NH(C2-C4hydroxyalkyl); —N(C2-C4hydroxyalkyl)2; —N(C1-C4alkyl)(C2-C4hydroxyalkyl); NHC2-C4 alkylsulphonic acid; —OC1-C4alkyl; an aminoacid or aminoacid amide residue from which a hydrogen atom on the amino group has been removed; R1 and R2 may further independently represent hydrogen; C1-C4alkyl; phenyl; naphthyl; phenyl or naphthyl substituted by C1-C4alkyl, C1-C4alkoxy, halogen, C2-C5alkanoyl-amino, nitro, sulpho or C1-C4alkylated amino; R is hydrogen; or C1-C3alkyl; and M is H, Na, Li, K, Ca, Mg, ammonium, or ammonium that is mono-, di-, tri- or tetrasubstituted by C1-C4alkyl, C2-C4hydroxyalkyl or a mixture thereof.
摘要翻译：公开了制备式（1）的4,4'-双 - （三嗪基氨基） - 茋-2,2'-二磺酸化合物的方法，其特征在于（a）在第一反应步骤中，氰化氢反应与4,4'-二氨基芪-2,2'-二磺酸的二钠盐得到式（2）的中间体; （b）在第二反应步骤中，将式（2）化合物与式R 1 -H和/或R 2 -H的化合物反应，得到式（3）化合物; （c）在第三步中，式（3）化合物与式R3H的化合物反应，反应步骤（a）和/或（c）在由水和得到式（1）化合物，其中R 1，R 2和R 3独立地是苯基氨基; 由C 1 -C 3烷基，卤素，氰基，COOR或COR取代的苯基氨基; CONH-R; SO2NH-R; NH-COR; 单或二磺基苯基氨基; 吗啉代哌啶子吡咯烷 -NH2; -NH（C 1 -C 4烷基）; -N（C 1 -C 4烷基）2; -NH（C 2 -C 4羟烷基）; -N（C 2 -C 4羟烷基）2; -N（C 1 -C 4烷基）（C 2 -C 4羟烷基）; NHC2-C4烷基磺酸; -OC1-C4烷基; 已除去氨基上的氢原子的氨基酸或氨基酸酰胺残基; R 1和R 2可以进一步独立地表示氢; C 1 -C 4烷基; 苯基; 萘基; 被C 1 -C 4烷基，C 1 -C 4烷氧基，卤素，C 2 -C 5烷酰基 - 氨基，硝基，磺基或C 1 -C 4烷基化氨基取代的苯基或萘基; R是氢; 或C 1 -C 3烷基; 并且M是被C 1 -C 4烷基，C 2 -C 4羟烷基或其混合物单，二，三或四取代的H，Na，Li，K，Ca，Mg，铵或铵。

36. 发明授权

US06255483B1 Biphenyl-substituted triazines 有权
标题翻译：联苯取代三嗪
公开(公告)号：US06255483B1
公开(公告)日：2001-07-03
申请号：US09383163
申请日：1999-08-25
申请人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
发明人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
IPC分类号： C07D25124
CPC分类号： C07D405/04 , A61K8/4966 , A61Q17/04 , C07D251/10 , C07D251/24 , C08K5/3435 , C08K5/3475 , C08K5/3492
摘要： Biphenyl-substituted triazines of the formulae which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
摘要翻译：用于高热稳定性的配方的联苯取代三嗪作为有机聚合物的稳定剂用作抗光，氧和热引起的损伤，作为纺织纤维材料的光稳定剂和用作人体皮肤的防晒剂。

37. 发明授权

US06193960B1 Triazine derivatives 失效
标题翻译：三嗪衍生物
公开(公告)号：US06193960B1
公开(公告)日：2001-02-27
申请号：US09544852
申请日：2000-04-06
申请人： Georges Metzger , Dieter Reinehr , Helmut Luther
发明人： Georges Metzger , Dieter Reinehr , Helmut Luther
IPC分类号： A61K742
CPC分类号： C07D251/52 , A61K8/4966 , A61K8/4993 , A61Q17/04 , C07D251/48 , C07D251/50 , C07D251/70
摘要： The present invention relates to novel s-triazine compounds, processes for their preparation and the use of these novel compounds as UV filters in sunscreen compositions. The novel compounds are those of the formula The triazine compounds of the formula (1) according to the invention are distinguished by a high UV absorption and are particularly suitable as UV filters, i.e. for protecting ultra-violet-sensitive organic materials, in particular the skin and the hair of man and animals, from the harmful action of UV radiation.
摘要翻译：本发明涉及新型的三嗪化合物，它们的制备方法以及这些新化合物作为防晒组合物中的紫外线过滤剂的用途。新化合物是下式的那些：根据本发明的式（1）的三嗪化合物是其特征在于高的紫外线吸收，并且特别适用于紫外线过滤器，即用于保护紫外线有害的紫外线辐射有害作用的紫外线敏感有机材料，特别是人和动物的皮肤和头发。

38. 发明授权

US6096919A Process for the preparation of sulphonated distyryl-biphenyl compounds 失效
标题翻译：制备磺化二苯乙烯基 - 联苯化合物的方法
公开(公告)号：US6096919A
公开(公告)日：2000-08-01
申请号：US309232
申请日：1999-05-10
申请人： Dieter Reinehr , Georges Metzger , Fabienne Cuesta , Denis Planchenault , Eric Signoret
发明人： Dieter Reinehr , Georges Metzger , Fabienne Cuesta , Denis Planchenault , Eric Signoret
IPC分类号： C11D3/395 , C07C303/06 , C07C303/08 , C07C303/22 , C07C303/32 , C07C309/32 , C07C309/39 , C07C309/42 , C07C309/46 , C07C309/48 , C07C309/49 , C11D3/42 , C11D7/54 , D06L3/12 , D21H21/30 , C07C247/00
CPC分类号： C07C309/46 , C07C303/06 , C07C303/22 , C07C303/32 , C11D3/42 , D06L3/1214 , D21H21/30
摘要： A process for the preparation of sulphonated distyryl-biphenyl compounds of formula: ##STR1## in which R.sub.1 represents hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy or halogen, R.sub.1A represents hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy or halogen and M represents hydrogen, an alkaline- or alkaline earth-metal, or ammonium, characterised by reacting a compound of formula: ##STR2## in which R.sub.2 represents C.sub.1 -C.sub.5 alkyl, with a compound of formula: ##STR3## whereby R.sub.3 represents phenyl, optionally substituted by C.sub.1 -C.sub.4 alkoxy, halogen or SO.sub.3 M, or C.sub.1 -C.sub.12 alkyl, R.sub.4 represents C.sub.2 -C.sub.6 alkylene, and M, R.sub.1 and R.sub.1A are defined as above, in an alcoholic or dipolar aprotic solvent and in the presence of a strong base. Novel compounds of formulae (3) and (4) and a process for their preparation.
摘要翻译：制备下式的磺化二苯乙烯基联苯化合物的方法：其中R 1表示氢，C 1 -C 5烷基，C 1 -C 5烷氧基或卤素，R 1A表示氢，C 1 -C 5烷基，C 1 -C 5烷氧基或卤素，M表示氢，碱土金属或碱土金属或铵，其特征在于使下式化合物（其中R 2表示C 1 -C 5烷基）与下式化合物反应：其中R 3表示苯基，任选被C 1 -C 4烷氧基，卤素或 SO 3 M或C 1 -C 12烷基，R 4表示C 2 -C 6亚烷基，并且M，R 1和R 1A如上定义，在醇或偶极非质子溶剂中并在强碱存在下。式（3）和（4）的新型化合物及其制备方法。

39. 发明授权

US6015504A Method for increasing the SPF rating of textile fibers by treatment with triazinyldiamino stilbene compounds 失效
标题翻译：通过用三嗪基二氨基二苯乙烯化合物处理提高纺织纤维的SPF等级的方法
公开(公告)号：US6015504A
公开(公告)日：2000-01-18
申请号：US13657
申请日：1998-01-26
申请人： Dieter Reinehr , Claude Eckhardt , Robert Hochberg , Werner Kaufmann , Georges Metzger
发明人： Dieter Reinehr , Claude Eckhardt , Robert Hochberg , Werner Kaufmann , Georges Metzger
IPC分类号： D06L1/00 , C07D251/48 , C07D251/50 , C07D251/68 , C07D251/70 , C09K3/00 , C11D1/02 , C11D1/66 , C11D1/83 , C11D3/00 , C11D3/28 , C11D3/39 , C11D3/42 , C12S11/00 , D06L3/11 , D06L3/12 , D06L3/16 , D06M13/02 , D06M13/322 , D06M13/325 , D06M13/328 , D06M13/332 , D06M13/345 , D06M13/35 , D06M13/355 , D06M13/358 , D06M13/364 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/10 , D06M101/16 , D06M101/18 , D21H19/10 , D06M13/262 , D06P1/62
CPC分类号： C11D3/28 , C07D251/48 , C07D251/50 , C07D251/68 , C11D3/42 , D06L3/1207 , D06L3/1214 , D06L3/1228 , D06L3/125 , D06L3/16 , D06M13/358 , C11D3/39 , C11D3/3905 , D06M2101/06 , D06M2101/12 , D06M2101/34 , D06M2200/25
摘要： The present invention relates to new compounds which are useful as ultraviolet absorbing agents (UVAs) and as fluorescent whitening agents (FWAs), and to a method of improving the sun protection factor (SPF) of textile fiber material, especially cotton, polyamide and wool, treated with the new compounds and with certain known compounds.
摘要翻译：本发明涉及可用作紫外线吸收剂（UVA）和荧光增白剂（FWA）的新化合物，以及改善纺织纤维材料，特别是棉花，聚酰胺和羊毛的防晒因子（SPF）的方法用新化合物和某些已知化合物处理。

40. 发明授权

US5945396A Compounds 失效
标题翻译：化合物
公开(公告)号：US5945396A
公开(公告)日：1999-08-31
申请号：US996895
申请日：1997-12-23
申请人： Claude Eckhardt , Georges Metzger , Dieter Reinehr , Hanspeter Sauter , Mario Dubini
发明人： Claude Eckhardt , Georges Metzger , Dieter Reinehr , Hanspeter Sauter , Mario Dubini
IPC分类号： C07D251/68 , C07D251/50 , C07D251/54 , C09K3/00 , C11D1/62 , C11D3/42 , D06L3/12 , D06M13/07 , D06M13/355 , D06M13/358 , D06M11/00 , C07D251/38
CPC分类号： C07D251/50 , C07D251/54 , C11D1/62 , C11D3/42 , D06L3/1214 , D06L3/1257 , D06M13/07 , D06M13/355 , D06M13/358 , D06M2200/25 , D06M2200/50
摘要： The present invention provides a compound having the formula: ##STR1## in which each R.sub.d is the same or different and each is --NH--Z--N(R.sub.a)(R.sub.b) or --N--�Z--N(R.sub.a)(R.sub.b)!.sub.2 in which Z is C.sub.2 -C.sub.14 alkylene or optionally substituted arylene, R.sub.a and R.sub.b are the same or different and each is C.sub.1 -C.sub.12 alkyl, or R.sub.a and R.sub.b, together with the nitrogen atom to which they are each attached, form a morpholino, piperidino or piperazino ring; each R.sub.c is the same or different and is NH.sub.2, NH(C.sub.1 -C.sub.4 alkyl), N(C.sub.1 -C.sub.4 alkyl).sub.2, N(CH.sub.2 CH.sub.2 OH).sub.2, O--C.sub.1 -C.sub.4 alkyl, ##STR2## alkali metal atom, ammonium or a cation formed from an amine; or a quaternized form thereof. The present invention also relates to a composition for the treatment of textiles, in particular to a composition containing the new ultra-violet absorbing agents; and to a method for the improvement of both the sun protection factor (UPF) and the whiteness of textile fiber material, comprising treating the material with the composition according to the present invention.
摘要翻译：本发明提供具有下式的化合物：其中每个R d相同或不同，各自为-NH-ZN（Ra）（Rb）或-N- [ZN（Ra）（Rb）] 2，其中Z为 C 2 -C 14亚烷基或任选取代的亚芳基，R a和R b相同或不同，各自为C 1 -C 12烷基，或者R a和R b与它们各自连接的氮原子一起形成吗啉代，哌啶子基或哌嗪基环; 每个Rc相同或不同，是NH 2，NH（C 1 -C 4烷基），N（C 1 -C 4烷基）2，N（CH 2 CH 2 OH）2，O-C 1 -C 4烷基，碱金属原子，铵或由胺形成的阳离子 ; 或其季铵化形式。本发明还涉及用于处理纺织品的组合物，特别涉及含有新的紫外线吸收剂的组合物; 以及用于改善防晒因子（UPF）和纺织纤维材料的白度的方法，包括用根据本发明的组合物处理该材料。

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