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    • 22. 发明授权
    • Method for thermal spray coating and rare earth oxide powder used therefor
    • 热喷涂法和稀土氧化物粉末的使用方法
    • US06733843B2
    • 2004-05-11
    • US10423903
    • 2003-04-28
    • Toshihiko TsukataniYasushi TakaiTakao Maeda
    • Toshihiko TsukataniYasushi TakaiTakao Maeda
    • C23C410
    • C23C4/11Y10T428/25Y10T428/26Y10T428/2982
    • The invention discloses an efficient method for the formation of a highly corrosion- or etching-resistant thermal spray coating layer of a rare earth oxide or rare earth-based composite oxide by a process of plasma thermal spray method by using a unique thermal spray powder consisting of granules of the oxide. The thermal spray granules are characterized by a specified average particle diameter of 5 to 80 &mgr;m with a specified dispersion index of 0.1 to 0.7 and a specified BET specific surface area of 1 to 5 m2/g as well as a very low content of impurity iron not exceeding 5 ppm by weight as oxide. The flame spat powder used here is characterized by several other granulometric parameters including globular particle configuration, particle diameter D90, bulk density and cumulative pore volume.
    • 本发明公开了一种通过使用独特的热喷涂粉末等离子体热喷涂方法形成稀土氧化物或稀土类复合氧化物的高耐腐蚀或耐蚀刻热喷涂层的有效方法, 的氧化物颗粒。 热喷雾颗粒的特征在于指定的平均粒径为5-80μm,指定的分散指数为0.1-0.7,指定的BET比表面积为1-5m 2 / g,并且含量非常低 的杂质铁作为氧化物不超过5ppm。 这里使用的火焰喷雾粉的特征在于几种其他粒度参数,包括球状颗粒构型,粒径D90,体积密度和累积孔体积。
    • 27. 发明授权
    • Corrosion-resistant composite oxide material
    • 耐腐蚀复合氧化物材料
    • US06326076B1
    • 2001-12-04
    • US09468304
    • 1999-12-21
    • Yasushi Takai
    • Yasushi Takai
    • B32B326
    • Disclosed is a corrosion-resistant material capable of withstanding attack of a halogen-containing corrosive gas such as sulfur hexafluoride or a plasma thereof. The corrosion-resistant material is characterized in that at least the surface layer thereof is formed from a sintered body of a composite oxide having a crystalline structure of garnet and having a composition expressed by the formula Ln3Al5O12, in which Ln is a rare earth element or a combination of rare earth elements selected from the group consisting of dysprosium, holmium, erbium, thulium, ytterbium and lutetium, the material having a surface roughness Ra not exceeding 1 &mgr;m and the sintered body having a porosity not exceeding 3%.
    • 公开了能够耐受含卤素腐蚀性气体如六氟化硫或其等离子体的侵蚀的耐腐蚀材料。 耐腐蚀材料的特征在于,至少其表面层由具有石榴石晶体结构且具有由式Ln3Al5O12表示的组成的复合氧化物的烧结体形成,其中Ln是稀土元素或 选自镝,钬,铒,ium,镱和镥的稀土元素的组合,其表面粗糙度Ra不超过1μm,烧结体的孔隙率不超过3%。