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    • 23. 发明申请
    • Positive-type resist composition for liquid immersion lithography and method for forming resist pattern
    • 用于液浸光刻的正型抗蚀剂组合物和形成抗蚀剂图案的方法
    • US20070190448A1
    • 2007-08-16
    • US10591718
    • 2005-03-07
    • Keita IshidukaKotaro Endo
    • Keita IshidukaKotaro Endo
    • G03C1/00
    • G03F7/0046C08F220/18C08F220/28G03F7/0397G03F7/2041
    • The present invention relates to a positive-type resist composition for liquid immersion lithography and a method of forming a resist pattern, in particular, a positive-type resist composition for liquid immersion lithography that exhibits superior liquid immersion resistance to water; and a method for forming a resist pattern by thereof. The positive-type resist composition for liquid immersion lithography according to the present invention includes a resin component (A) increasing alkali-solubility by acid action; and an acid generator generating acid by exposure; in which, the resin component (A) contains at least one acrylic ester constitutional unit (a1), and one (meth)acrylic ester constitutional unit (a2) having acid dissociable, dissolution inhibiting group, and the constitutional unit (a1) consists of a cyclic group bonded to the acrylic ester of the constitutional unit (a1), and a fluoro organic group bonded to the cyclic group.
    • 本发明涉及一种用于液浸光刻的正型抗蚀剂组合物和形成抗蚀剂图案的方法,特别涉及一种耐水浸性优良的用于液浸光刻的正型抗蚀剂组合物, 以及通过其形成抗蚀剂图案的方法。 根据本发明的液浸光刻用正型抗蚀剂组合物包括通过酸作用提高碱溶性的树脂组分(A) 和通过暴露产生酸的酸发生剂; 其中,树脂成分(A)含有至少一种丙烯酸酯结构单元(a1)和具有酸解离性,溶解抑制基团的一个(甲基)丙烯酸酯结构单元(a2),结构单元(a1)由 与结构单元(a1)的丙烯酸酯键合的环状基团和与该环状基团键合的氟有机基团。
    • 25. 发明申请
    • Photoresist composition and method for forming resist pattern using the same
    • 光刻胶组合物及其形成方法
    • US20060166130A1
    • 2006-07-27
    • US10547427
    • 2004-03-24
    • Toshiyuki OgataKotaro EndoHiromitsu TsujiMasaaki Yoshida
    • Toshiyuki OgataKotaro EndoHiromitsu TsujiMasaaki Yoshida
    • G03C1/76
    • G03F7/0046G03F7/0395Y10S430/108
    • A photoresist composition containing a polymer (A) containing an alkali-soluble constituent unit (a1) containing an alicyclic group having both a fluorine atom or a fluorinated alkyl group (i) and an alcoholic hydroxyl group (ii), whose alkali-solubility is changeable by an action of an acid; an acid generator (B) which generates an acid by light irradiation; and a dissolution inhibitor (C) having a fluorine atom(s) and/or a nitrogen-containing compound (D) selected from a tertiary amine (d1) having a polar group, a tertiary alkylamine (d2) having 7 or more and 15 or less of carbon atoms or an ammonium salt (d3). The composition has a resist property capable of accomplishing line and space (1:1) of 90 nm or less in good shape as a pattern processing accuracy of a semiconductor integrated circuit by lithography.
    • 1.一种光致抗蚀剂组合物,其含有含有具有氟原子或氟代烷基(i)和醇羟基(ii)的脂环族基团的碱溶性结构单元(a1)的聚合物(A),其碱溶性为 可以通过酸的作用而变化; 通过光照射产生酸的酸产生剂(B); 和具有氟原子的溶解抑制剂(C)和/或选自具有极性基团的叔胺(d1),具有7以上的叔烷基胺(d2)和15以上的含氮化合物(D) 或更少的碳原子或铵盐(d3)。 该组合物具有能够通过光刻作为半导体集成电路的图案处理精度而实现90nm或更小的线和空间(1:1)的良好形状的抗蚀剂性质。
    • 26. 发明授权
    • Method and system for controlling access to logical unit of a storage device shared by computers
    • 用于控制计算机共享的存储设备的逻辑单元访问的方法和系统
    • US08566948B2
    • 2013-10-22
    • US11725472
    • 2007-03-20
    • Kotaro Endo
    • Kotaro Endo
    • G06F21/10
    • G06F21/80
    • An acquisition unit of a user terminal acquires an initiator ID including a user ID and a computer ID. The initiator ID is transmitted by a transmitter unit, and then, received by a transmitter/receiver unit of a storage device. A LUDB stores information determining a LU corresponding to each user ID of several users. A masking unit refers to the LUDB to determine the LU corresponding to the user ID. If the received initiator ID differs from an initiator ID stored in a table corresponding to the determined LU, an access control unit refuses access to the LU by the user terminal.
    • 用户终端的获取单元获取包括用户ID和计算机ID的发起者ID。 发起者ID由发送单元发送,然后由存储装置的收发单元接收。 LUDB存储确定与几个用户的每个用户ID相对应的LU的信息。 掩蔽单元是指LUDB来确定与用户ID相对应的LU。 如果接收到的发起者ID与存储在与所确定的LU相对应的表中的发起者ID不同,则访问控制单元拒绝用户终端访问LU。
    • 28. 发明授权
    • Material for forming resist protection films and method for resist pattern formation with the same
    • 用于形成抗蚀剂保护膜的材料及其抗蚀剂图案形成方法
    • US08278025B2
    • 2012-10-02
    • US11722797
    • 2005-12-22
    • Keita IshidukaKotaro Endo
    • Keita IshidukaKotaro Endo
    • G03F7/004G03F7/30
    • G03F7/11C08F220/18C08F220/24G03F7/0046G03F7/2041
    • The formation of high-resolution resist patterns by liquid immersion lithography with various fluids is enabled by protecting a resist film from deterioration (such as bridging) during the immersion exposure in a fluid (such as water) and the fluid from deterioration and improving the stability of a resist film in the storage after exposure without increase in the number of treatment steps. A material for forming resist protection films which comprises an alkali-soluble polymer for forming a protective overcoat for a resist film, characterized in that the contact angle of the polymer to water is 90° or above. The polymer is preferably an acrylic polymer which comprises as the essential components constituent units derived from (meth) acrylic acid and constituent units derived from a specific acrylic ester.
    • 通过在各种流体中通过液浸光刻形成高分辨率抗蚀剂图案可以通过在液体(例如水)浸没暴露期间保护抗蚀剂膜免于劣化(例如桥接),并且使流体变质并提高稳定性 的抗蚀剂膜在曝光后的储存中,而不增加处理步骤的数量。 一种用于形成抗蚀剂保护膜的材料,其包含用于形成抗蚀剂膜的保护性外涂层的碱溶性聚合物,其特征在于,聚合物与水的接触角为90°或更高。 聚合物优选为丙烯酸类聚合物,其包含作为主要组分的构成单元,其衍生自(甲基)丙烯酸和由特定丙烯酸酯衍生的构成单元。
    • 29. 发明授权
    • Material for formation of resist protection film and method of forming resist pattern therewith
    • 用于形成抗蚀剂保护膜的材料及其形成抗蚀剂图案的方法
    • US07879529B2
    • 2011-02-01
    • US11658900
    • 2005-07-29
    • Kotaro EndoMasaaki YoshidaKeita Ishizuka
    • Kotaro EndoMasaaki YoshidaKeita Ishizuka
    • G03F7/11G03F7/26C07D265/00C07D285/00
    • G03F7/2041G03F7/11
    • In the liquid immersion lithography process, by simultaneously preventing deterioration of a resist film and deterioration of an immersion liquid employed during liquid immersion lithography which uses various immersion liquids, including water, resistance to post exposure delay of the resist film can be improved without increasing the number of processes, thereby making it possible to form a high resolution resist pattern using liquid immersion lithography. Furthermore, it is possible to apply a high refractive index liquid immersion medium, used in combination with the high refractive index liquid immersion medium, thus making it possible to further improve pattern accuracy. Using a composition comprising an acrylic resin component having characteristics which have substantially no compatibility with a liquid in which a resist film is immersed, particularly water, and are also soluble in alkaline, a protective film is formed on the surface of a resist film used.
    • 在液浸光刻工艺中,通过同时防止抗蚀剂膜的劣化以及使用包括水在内的各种浸渍液体的液浸光刻中所使用的浸渍液的劣化,可以提高抗蚀剂膜的后曝光延迟性,而不会增加 处理次数,从而可以使用液浸光刻法形成高分辨率抗蚀剂图案。 此外,可以应用与高折射率浸液介质组合使用的高折射率液浸介质,从而可以进一步提高图案精度。 使用包含与浸渍有抗蚀剂膜的液体基本上不相容的特性的丙烯酸树脂组分的组合物,特别是水,并且也可溶于碱性,在所用的抗蚀剂膜的表面上形成保护膜。