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    • 27. 发明授权
    • Water-dispersed coating composition comprising an acrylic graft polymer
containing carboxyl groups, hydroxyl and/or amide groups
    • 包含含有羧基,羟基和/或酰胺基团的丙烯酸接枝聚合物的水分散涂料组合物
    • US4329266A
    • 1982-05-11
    • US186557
    • 1980-09-12
    • Yukio SuzukiNaozumi IwasawaTadashi Watanabe
    • Yukio SuzukiNaozumi IwasawaTadashi Watanabe
    • C08F290/12C09D151/00C08L61/28
    • C08F290/126C09D151/003
    • A water-dispersed coating composition comprising (1) a dispersion of a water-dispersible form of an acrylic graft polymer containing carboxyl groups and hydroxyl and/or amide groups in an aqueous medium containing 60 to 90% by weight of water, and (2) an amino resin. The water-dispersible form of this polymer is obtained by neutralizing at least 50% of the carboxyl groups of the polymer with a basic substance. Prior to neutralization, the polymer has an acid value of 15 to 40 and a glass transition temperature of -10.degree. C. to 70.degree. C., and is produced by polymerizing (A) an acrylic copolymer and (B) a mixture of an alpha,beta-ethylenically unsaturated carboxylic acid and another copolymerizable unsaturated monomer. The copolymer (A) and the mixture (B) is selected so that either one of them has hydroxyl and/or amide groups and the difference between the acid value of the copolymer (A) and that of the mixture (B) is from 25 to 200. The present invention also provides a water-dispersed coating composition comprising a dispersion of a water-dispersible form of a self-curable acrylic graft polymer without an amino resin.
    • 一种水分散涂料组合物,其包含(1)含水分散体形式的含羧基和羟基和/或酰胺基的丙烯酸接枝聚合物在含有60-90%重量水的水性介质中的分散体,和(2) )氨基树脂。 该聚合物的水分散形式通过用碱性物质中和聚合物的至少50%的羧基而获得。 在中和之前,聚合物的酸值为15至40,玻璃化转变温度为-10℃至70℃,并通过聚合(A)丙烯酸共聚物和(B)将 α,β-烯属不饱和羧酸和另一种可共聚的不饱和单体。 选择共聚物(A)和混合物(B),使得它们中的任一个具有羟基和/或酰胺基,并且共聚物(A)和混合物(B)的酸值之间的差异为25 本发明还提供一种水分散涂料组合物,其包含不具有氨基树脂的可分散自由基的丙烯酸接枝聚合物的分散体。