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    • 23. 发明专利
    • THIN FILM THERMOELECTRIC CONVERSION ELEMENT
    • JPS62177985A
    • 1987-08-04
    • JP1795586
    • 1986-01-31
    • HITACHI LTD
    • MIYAZAKI KUNIOFUKADA SHINICHISUZUKI HITOSHI
    • H01L35/08H01L35/32
    • PURPOSE:To enable a thin film thermoelectric conversion element to be available in a high temperature range by laminating a plurality of element substrates in which P-type and N-type thermoelectric substances are electrically connected at an end to become a high temperature side, and connecting in series the P-type and the N-type films of the respective substrates. CONSTITUTION:After an Ni 2 is metallized by a depositing method on the end face of a glass substrate 1 at a high temperature side, an Fe-Si-Mn film 3 of a P-type thermal substance is first formed on the side of the glass by a sputtering method. Further, an Fe-Si-Co film 4 of an N-type thermoelectric substance is sputtered to the other side face of the glass substrate 1 to form an element substrate 5. The substrates 5 are laminated through an inorganic adhesive 6. At this time, since P-type and N-type films between the adjacent substrates are electrically connected in series, conductive paste 7 is buried in the part of the layer 6 at the low temperature side. Further, a Cu plate 8 is bonded through an inorganic adhesive 9, and electrodes 10 are led from the ends of the P-type and N-type thermoelectric film.
    • 26. 发明专利
    • INTER-LAYER CONNECTION OF SEMICONDUCTOR INTEGRATED CIRCUIT WIRING
    • JPH1041388A
    • 1998-02-13
    • JP19729496
    • 1996-07-26
    • HITACHI LTD
    • FUKADA SHINICHIKOBAYASHI NOBUYOSHI
    • H01L21/28H01L21/768
    • PROBLEM TO BE SOLVED: To lower the required film thickness of a wiring layer for filling up connection holes to lower required pressure for the fill up in a high pressure fill up technique, by forming this wiring layer in a three-layer structure composed of a lower wiring metal layer, high m.p. metal layer, and upper wiring metal layer thicker than the lower wiring layer in an order from a substrate. SOLUTION: A wiring layer for filling up connection holes 7 has a three layer structure composed of a lower wiring metal layer 8, high m.p. metal layer 9 formed by the directional sputtering, and upper wiring metal layer 10 thicker than the lower wiring layer in an order from a substrate. The holes 7 are covered with only the upper wiring layer 10 and filled up with the metal of this layer 10 with holding a high temp. and high pressure in this condition. After forming the holes 7 through a layer insulation film 6, e.g. an Al-Cu alloy- made lower wiring metal layer 8, TnN-made high m.p. metal liner layer 9 and AlCu alloy-made upper wiring metal layer 10 are formed and holes 7 are filled up with the Al alloy at 450 deg.C, 500atm.
    • 30. 发明专利
    • LAMINATED WIRINGS FOR LSI AND FORMATION THEREOF
    • JPH0536692A
    • 1993-02-12
    • JP19149691
    • 1991-07-31
    • HITACHI LTD
    • KUDO KAZUEFUKADA SHINICHISUWA MOTOHIRO
    • H01L21/3213H01L21/3205H01L23/52
    • PURPOSE:To improve throwing power of an interlayer insulating film to wirings and to eliminate corrosion of a main wiring during processing by so forming a shape of a section perpendicular to a current direction of an uppermost layer of laminated wirings made of three or more layers in a curved shape that a protrusion side is disposed at an upper side. CONSTITUTION:A thermal oxide SiO2 film 5, a barrier layer 2, a main wiring 1 and an uppermost layer 3 are formed on an Si substrate 1. The wiring 1 is formed of Cu or a Cu alloy film, and the layers 2, 3 are formed of TiN films. The layer 3 is formed thicker than the layer 2. After the layer 3 is etched with resist as a mask, the resist is removed by a plasma asher. Further, with the layer 3 as a mask the wiring 1, the layer 2 are dry etched. In this case, the shape of the layer 3 is formed in a shape in which a protrusion is disposed at an upper side. Then, an interlayer insulating film 6 is formed several thousands Angstrom on the wiring by a plasma CVD method without removing the TiN of the layer 3. Thus, the shape of the main wiring is not altered, and throwing power of the insulating film is improved.