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11. 发明授权

US06248924B1 Process for reacting an organic compound in the presence of a supported ruthenium catalyst 失效
标题翻译：在负载型钌催化剂存在下使有机化合物反应的方法
公开(公告)号：US06248924B1
公开(公告)日：2001-06-19
申请号：US08877820
申请日：1997-06-16
申请人： Thomas Rühl , Boris Breitscheidel , Jochem Henkelmann , Andreas Henne , Rolf Lebkücher , Konrad Knoll , Paul Naegele , Hermann Gausepohl , Sabine Weiguny , Norbert Niessner
发明人： Thomas Rühl , Boris Breitscheidel , Jochem Henkelmann , Andreas Henne , Rolf Lebkücher , Konrad Knoll , Paul Naegele , Hermann Gausepohl , Sabine Weiguny , Norbert Niessner
IPC分类号： C07C2920
CPC分类号： B01J23/462 , B01J23/44 , B01J35/0053 , B01J35/10 , B01J35/1019 , B01J35/108 , C08F8/04
摘要： A process for the reaction of an organic compound in the presence of a catalyst comprising, as active metal, ruthenium alone or together with at least one Group Ib, VIIb, or VIIIb metal in an amount of from 0.01 to 30 wt %, based on the total weight of the catalyst, applied to a support, wherein from 10 to 50% of the pore volume of the support comprises macropores having a pore diameter in the range of from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support comprises mesopores having a pore diameter in the range of from 2 to 50 nm, the sum of said pore volumes being 100%, and said catalyst as such.
摘要翻译：一种有机化合物在催化剂存在下反应的方法，所述催化剂包含作为活性金属的钌单独或与至少一种量为0.01至30重量％的Ib族，VIIb或Ⅷb族金属，基于施加到载体上的催化剂的总重量，其中载体的孔体积的10至50％包含孔径在50nm至10,000nm的孔径和50至90％的孔隙中的大孔载体的体积包含孔径在2至50nm范围内的孔隙，所述孔体积的总和为100％，所述催化剂本身。

12. 发明授权

US6031053A Thermoplastic elastomer 失效
标题翻译：热塑性弹性体
公开(公告)号：US6031053A
公开(公告)日：2000-02-29
申请号：US750705
申请日：1996-12-17
申请人： Konrad Knoll , Hermann Gausepohl , Norbert Niessner , Dietmar Bender , Paul Naegele
发明人： Konrad Knoll , Hermann Gausepohl , Norbert Niessner , Dietmar Bender , Paul Naegele
IPC分类号： C08F297/04 , C08J5/18
CPC分类号： C08J5/18 , C08F297/04 , C08J2353/02
摘要： An elastomeric block copolymer comprising at least one block A having polymerized units of a vinylaromatic monomer and forming a rigid phase and at least one elastomeric block B/A having polymerized units of both vinylaromatic monomers and of a diene and forming a flexible phase, and glass transition temperature Tg of the block A being above 25.degree. C. and that of the block B/A being below 25.degree. C. and the phase volume ratio of block A to block B/A being chosen so that the amount of the rigid phase in the total block copolymer is 1 to 40% by volume and the amount of the diene is less than 50% by weight.
摘要翻译： PCT No.PCT / EP95 / 02207 Sec。 371日期1996年12月17日第 102（e）日期1996年12月17日PCT提交1995年6月8日PCT公布。第WO95 / 35335号公报日期1995年12月28日一种弹性体嵌段共聚物，其包含至少一个具有乙烯基芳族单体的聚合单元并形成刚性相的嵌段A和至少一个具有乙烯基芳族单体和二烯的聚合单元的弹性嵌段B / A，块A的柔性相和玻璃化转变温度Tg高于25℃，块B / A的玻璃化转变温度Tg低于25℃，并且选择块A与嵌段B / A的相体积比，使得总嵌段共聚物中的刚性相的量为1〜40体积％，二烯的量小于50重量％。

13. 发明授权

US5880166A Expandable styrene polymers 失效
标题翻译：可发性苯乙烯聚合物
公开(公告)号：US5880166A
公开(公告)日：1999-03-09
申请号：US58899
申请日：1998-04-13
申请人： Guiscard Gluck , Klaus Hahn , Rolf Henn , Karl-Heinz Wassmer , Hermann Gausepohl , Konrad Knoll , Karl-Heinz Batscheider
发明人： Guiscard Gluck , Klaus Hahn , Rolf Henn , Karl-Heinz Wassmer , Hermann Gausepohl , Konrad Knoll , Karl-Heinz Batscheider
IPC分类号： C08J9/14 , C08F287/00 , C08J9/16 , C08L25/06 , C08L51/04 , C08L53/02
CPC分类号： C08J9/16 , C08L25/06 , C08L51/04 , C08L53/02 , C08J2351/04
摘要： Expandable, rubber-modified styrene polymers for elastic polystyrene foams comprisea) a continuous phase comprising polystyrene or a styrene copolymer containing at most 50% of copolymerized comonomers andb) from 5 to 30% by weight of a butadiene-styrene block copolymer dispersed therein,and also a low-boiling blowing agent. The rubber particles have a compact lamellar structure without polystyrene inclusions. The expandable styrene polymers are prepared by polymerization of styrene in the presence of the block copolymer and impregnation with the blowing agent.
摘要翻译：用于弹性聚苯乙烯泡沫的可膨胀的橡胶改性的苯乙烯聚合物包括a）包含聚苯乙烯或含有至多50％的共聚单体的苯乙烯共聚物的连续相，和b）分散在其中的5-30重量％的丁二烯 - 苯乙烯嵌段共聚物，还有低沸点发泡剂。橡胶颗粒具有紧密的层状结构而没有聚苯乙烯夹杂物。可发性苯乙烯聚合物通过在嵌段共聚物存在下苯乙烯的聚合和用发泡剂浸渍来制备。

14. 发明授权

US5700876A Thermoplastic molding material 失效
标题翻译：热塑性成型材料
公开(公告)号：US5700876A
公开(公告)日：1997-12-23
申请号：US527496
申请日：1995-09-13
申请人： Konrad Knoll , Hermann Gausepohl
发明人： Konrad Knoll , Hermann Gausepohl
IPC分类号： C08F4/48 , C08F285/00 , C08F287/00 , C08F297/04 , C08F297/02
CPC分类号： C08F287/00 , C08F297/04
摘要： In a process for preparing a thermoplastic molding material comprising from 80 to 50% by weight of a hard matrix of an anionically polymerized aromatic vinyl compound and from 20 to 50% by weight of a soft phase uniformly distributed in the hard matrix, the percentages being based in each case on the sum of the hard matrix and soft phase, a rubber-elastic block copolymer based on an aromatic vinyl compound and on an alkadiene in a weight ratio of 5:95 to 55:45 is anionically polymerized in a first stage, if desired the living chain ends are capped and the aromatic vinyl compound is polymerized in the presence of the block copolymer with renewed addition of an anionic initiator and while stirring, and the living chain ends are finally (re)closed.
摘要翻译：在制备热塑性成型材料的方法中，其包含80至50重量％的阴离子聚合的芳族乙烯基化合物的硬质基质和均匀分布在硬质基质中的20至50重量％的软相，百分比为在每种情况下基于硬质基质和软相的总和，基于芳族乙烯基化合物和重量比为5:95至55:45的链二烯的橡胶弹性嵌段共聚物在第一阶段中阴离子聚合如果需要，活性链末端被封端，并且在嵌段共聚物存在下聚合芳香族乙烯基化合物，同时重新加入阴离子引发剂并在搅拌的同时终止活性末端的封闭。

15. 发明授权

US06916885B2 Method for breaking a chain during anionic polymerisation 失效
标题翻译：在阴离子聚合过程中断链的方法
公开(公告)号：US06916885B2
公开(公告)日：2005-07-12
申请号：US10399228
申请日：2001-10-26
申请人： Konrad Knoll , Hermann Gausepohl , Josef Richard Wünsch , Paul Naegele , Jürgen Koch
发明人： Konrad Knoll , Hermann Gausepohl , Josef Richard Wünsch , Paul Naegele , Jürgen Koch
IPC分类号： C08F2/38 , C08F12/00 , C08F12/08
CPC分类号： C08F12/08 , C08F2/42
摘要： A process for the preparation of linear polymers or block copolymers of styrene by anionic polymerization comprises carrying out the chain termination with an n-alkyl glycidyl ether or a dialkyl ketone.
摘要翻译：通过阴离子聚合制备苯乙烯的线性聚合物或嵌段共聚物的方法包括用正烷基缩水甘油醚或二烷基酮进行链终止。

16. 发明授权

US06369160B1 Polymer mixtures comprised of styrene polymers 有权
标题翻译：由苯乙烯聚合物组成的聚合物混合物
公开(公告)号：US06369160B1
公开(公告)日：2002-04-09
申请号：US09623179
申请日：2000-08-29
申请人： Konrad Knoll , Norbert Niessner , Josef Wünsch , Hermann Gausepohl
发明人： Konrad Knoll , Norbert Niessner , Josef Wünsch , Hermann Gausepohl
IPC分类号： C08L5302
CPC分类号： C08J5/18 , C08J2325/06 , C08J2353/02 , C08L25/06 , C08L53/02 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2666/24 , C08L2666/04
摘要： Polymer mixtures comprise P1) from 1 to 85% by weight of an elastomeric block copolymer which has been built up from hard blocks S made from vinylaromatic monomers and from random soft blocks B/S made up from dienes and from vinylaromatic monomers, and which contains at least the block structure S-B/S-S, where the diene content is less than 50 percent by weight and the proportion of the soft phase formed from the blocks B/S is at least 60 percent by weight, based in each case on the entire block copolymer, P2) from 5 to 89% by weight of a block copolymer differing from P1) and made from vinylaromatic monomers and from dienes, P3) from 10 to 94% by weight of glass-clear or impact-modified polystyrene or mixtures thereof, and P4) from 0 to 84% by weight of other additives, where the total of components P1) to P4) is 100%.
摘要翻译：聚合物混合物包含1至85重量％的弹性体嵌段共聚物，其由由乙烯基芳族单体制成的硬块S和由二烯和乙烯基芳族单体组成的无规软嵌段B / S构成，并且其包含至少块结构SB / SS，其中二烯含量小于50重量％，并且由块B / S形成的软相的比例为至少60重量％，基于每种情况下在整个嵌段共聚物，P2）5至89重量％的不同于P1的嵌段共聚物，并由乙烯基芳族单体和二烯制成P3）10至94重量％的玻璃透明或冲击改性的聚苯乙烯或其混合物，和P 4 ）0〜84重量％的其他添加剂，其中组分P1）至P4的总量）为100％。

17. 发明授权

US6162866A Thermoplastic molding compositions based on star polymers with thermoplastic elastomers and polyarylene ethers 失效
标题翻译：基于具有热塑性弹性体和聚亚芳基醚的星形聚合物的热塑性模塑组合物
公开(公告)号：US6162866A
公开(公告)日：2000-12-19
申请号：US372809
申请日：1999-08-12
申请人： Josef Wunsch , Konrad Knoll , Hermann Gausepohl
发明人： Josef Wunsch , Konrad Knoll , Hermann Gausepohl
IPC分类号： C08F293/00 , C08K5/00 , C08L53/00 , C08L51/00
CPC分类号： C08L53/00
摘要： Thermoplastic molding compositions comprise:______________________________________ A) from 20 to 96% by weight of star polymers obtainable by polymerizing vinylaromatic monomers with a branched monomer building block which contains at least two vinylaromatic functions, B) from 3 to 50% by weight of copolymers comprising vinylaromatic monomers, 1,1-diphenylethylene and, if desired, dienes, C) from 1 to 15% by weight of polyarylene ethers, D) from 0 to 5% by weight of nucleating agents, E) from 0 to 5% by weight of antioxidants, F) from 0 to 5% by weight of stabilizers, and G) from 0 to 50% by weight of fibrous or particulate fillers. ______________________________________
摘要翻译：热塑性成型组合物包含：A）20至96重量％的星形聚合物，可通过将乙烯基芳族单体与含有至少两个乙烯基芳族官能团的支链单体结构单元聚合而获得，B）3至50％共聚物的重量包括 - 乙烯基芳族单体，1,1-二苯基乙烯，以及如果需要的话，二烯，-C）1至15重量％的聚亚芳基醚， - D）0-5重量％的成核剂， - E）0至5重量％的抗氧化剂， - F）0至5重量％的稳定剂， - 和 - G）0至50重量％的纤维或颗粒填料。 -

18. 发明授权

US5877242A .alpha.tocopherol-stabilized styrene/butadiene block copolymers 失效
标题翻译： α-生育酚稳定的苯乙烯/丁二烯嵌段共聚物
公开(公告)号：US5877242A
公开(公告)日：1999-03-02
申请号：US750670
申请日：1997-08-14
申请人： Norbert Niessner , Wolfgang Loth , Konrad Knoll , Norbert Guntherberg , Paul Naegele , Hubert Trauth , Jurgen Pohrt
发明人： Norbert Niessner , Wolfgang Loth , Konrad Knoll , Norbert Guntherberg , Paul Naegele , Hubert Trauth , Jurgen Pohrt
IPC分类号： C08K5/49 , C08K5/1545 , C08K5/50 , C08K5/524 , C08L53/02 , C08K5/34
CPC分类号： C08L53/02 , C08K5/1545 , C08K5/524
摘要： A molding material comprises styrene/butadiene block copolymers obtainable by anionic polymerization and from 0.01 to 1% by weight, based on the polymer, of .alpha.-tocopherol.
摘要翻译： PCT No.PCT / EP95 / 02212 Sec。 371日期1997年8月14日 102（e）日期1997年8月14日PCT归档1995年6月8日PCT公布。 WO95 / 34600 PCT出版物日期1995年12月21日一种成型材料包括通过阴离子聚合可获得的苯乙烯/丁二烯嵌段共聚物和基于聚合物的0.01至1重量％的α-生育酚。

19. 发明授权

US06521712B1 Glass-clear impact-modified polystyrene based on styrene-butadiene block copolymers 有权
标题翻译：基于苯乙烯 - 丁二烯嵌段共聚物的透明抗冲改性聚苯乙烯
公开(公告)号：US06521712B1
公开(公告)日：2003-02-18
申请号：US09471288
申请日：1999-12-23
申请人： Konrad Knoll , Herrmann Gausepohl , Wolfgang Fischer , Josef Wünsch , Paul Naegele , Jürgen Koch
发明人： Konrad Knoll , Herrmann Gausepohl , Wolfgang Fischer , Josef Wünsch , Paul Naegele , Jürgen Koch
IPC分类号： C08F29300
CPC分类号： C08F293/00 , C08F293/005 , C08F297/04 , C08L25/06 , C08L51/003 , C08L53/02 , C08L2666/24 , C08L2666/02
摘要： Block copolymers comprise at least two hard blocks S1 and S2 made from vinyl aromatic monomers and, between these, at least ore random soft block B/S made from vinyl aromatic monomers and from dienes, where the proportion of the hard blocks is above 40% by weight, based on the total block copolymer, wherein the 1,2-vinyl content in the soft block B/S is less than 20%.
摘要翻译：嵌段共聚物包含由乙烯基芳族单体制成的至少两个硬嵌段S1和S2，并且在这些之间，至少是由乙烯基芳族单体制成的矿石随机软嵌段B / S和二烯，其中硬嵌段的比例高于40％，基于总嵌段共聚物，其中软嵌段B / S中的1,2-乙烯基含量小于20％。

20. 发明授权

US08536279B2 Phase-separating block or graft copolymers comprising incompatible hard blocks and moulding compositions having a high stiffness 有权
标题翻译：包含不相容的硬块和具有高刚度的模塑组合物的相分离嵌段或接枝共聚物
公开(公告)号：US08536279B2
公开(公告)日：2013-09-17
申请号：US13141870
申请日：2009-12-14
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
IPC分类号： C08L53/02 , C08F279/00
CPC分类号： C08L25/10 , C08F257/02 , C08F279/02 , C08F297/04 , C08F297/044 , C08L25/06 , C08L51/003 , C08L51/06 , C08L53/02 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.
摘要翻译：包含重量平均摩尔质量Mw至少为100 000g / mol的嵌段共聚物或接枝共聚物，其包含a）至少一种由95至100重量％的乙烯基芳族单体和0至5重量％的二烯，和b）至少一种由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的共聚物嵌段（S / B）A，玻璃化转变温度TgA为5 至30℃，其中基于嵌段共聚物或接枝共聚物，所有嵌段S的总重量的比例为50至70重量％，以及它们的混合物及其用途。

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