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    • 4. 发明授权
    • Thermoplastic elastomeric block copolymers
    • 热塑性弹性体嵌段共聚物
    • US06197889B1
    • 2001-03-06
    • US08981051
    • 1997-12-11
    • Konrad KnollHermann GausepohlNorbert NiessnerPaul NaegeleWolfgang Fischer
    • Konrad KnollHermann GausepohlNorbert NiessnerPaul NaegeleWolfgang Fischer
    • C08F29300
    • C08F297/04
    • Elastomeric block copolymers comprising at least one hard block A composed of styrene monomers and at least one elastomeric block (B/A) composed of styrene monomers and dienes, the glass transition temperature Tg of the block A being more than 25° C. and that of block (B/A) being less than 25° C. and the phase volume ratio of block A to block (B/A) being chosen so that the proportion of the hard phase in the total block copolymer is from 1 to 40% by volume and the amount by weight of the diene is less than 50% by weight, and the relative proportion of 1,2 linkages of the polydiene, based on the sum of 1,2- and 1,4-cis/trans linkages, being below 15%, are prepared by anionic polymerization by means of a lithium alkyl in a nonpolar solvent in the presence of a soluble potassium salt and are used for the production of shaped articles.
    • 弹性体嵌段共聚物包含至少一个由苯乙烯单体组成的硬嵌段A和至少一个由苯乙烯单体和二烯构成的弹性嵌段(B / A),嵌段A的玻璃化转变温度Tg高于25℃, (B / A)小于25℃,并且选择块A与嵌段(B / A)的相体积比,使得总嵌段共聚物中硬相的比例为1〜40% 并且二烯的重量百分比小于50重量%,并且基于1,2-和1,4-顺/反键的总和的聚二烯的1,2-键的相对比例, 低于15%,通过在非极性溶剂中在可溶性钾盐的存在下通过烷基锂进行阴离子聚合制备,并用于生产成型制品。