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11. 发明授权

US5185422A Polyisocyanate suspensions in isocyanate reactive compounds and their use 失效
标题翻译：异氰酸酯反应性化合物中的聚异氰酸酯悬浮体及其用途
公开(公告)号：US5185422A
公开(公告)日：1993-02-09
申请号：US862854
申请日：1992-04-03
申请人： Werner Drouve , Peter Hohlein , Wolfhart Wieczorrek
发明人： Werner Drouve , Peter Hohlein , Wolfhart Wieczorrek
IPC分类号： B60R13/06 , C08G18/48 , C08G18/70 , C08G18/78 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04 , C09J175/00 , C09J175/04 , C09K3/10
CPC分类号： C08G18/4891 , C08G18/707 , C08G18/7825 , C08G18/798 , C08G18/8038 , C08G2190/00 , Y10S528/903
摘要： Suspensions of solid polyisocyanates inactivated on the surface of adduct formation in organic, isocyanate reactive compounds as continuous phase, which suspensions are stable in storage at room temperature and heat curable and optionally contain auxiliary agents and additives, the continuous phase containing at least 10% by weight of ether group- and ester group-containing polyhydroxyl compounds having an (average) hydroxyl functionality of from 0.5 to 3 and an (average) hydroxyl number of from 15 to 150 constituting esterification products of (i) polyether polyols having an (average) hydroxyl functionality of from 3 to 8 and an (average) hydroxyl number of from 200 to 1000 with (ii) from 40 to 90 equivalents percent of inorganic monocarboxylic acids and the use of these suspensions for the production of coatings, adhesives or sealing compounds, in particular as underseal and doorseal compounds for motor vehicles.
摘要翻译：固体多异氰酸酯的悬浮液在有机异氰酸酯反应性化合物的连接相上在加合物形成的表面上失活，该悬浮液在室温下储存稳定并且可热固化并且任选地含有助剂和添加剂，连续相含有至少10％（平均）羟基官能度为0.5〜3，（平均）羟基数为15〜150的含醚基和酯基的多羟基化合物的重量构成（i）具有（平均）羟基官能度的聚醚多元醇的酯化产物，羟基官能度为3至8，（平均）羟基数为200至1000，（ii）40至90当量无机一元羧酸，以及这些悬浮液用于生产涂料，粘合剂或密封剂的用途，特别是用于机动车辆的下侧和门锁化合物。

12. 发明授权

US4410663A Storable, saponification-resistant aqueous lacquer binders 失效
标题翻译：可储存，可皂化的水性漆粘合剂
公开(公告)号：US4410663A
公开(公告)日：1983-10-18
申请号：US377625
申请日：1982-05-13
申请人： Peter Hohlein , Jochen Schoeps
发明人： Peter Hohlein , Jochen Schoeps
IPC分类号： C08L33/06 , C08L33/04 , C08L61/20 , C09D125/14 , C09D133/04 , C09D161/20 , C08L61/28
CPC分类号： C09D125/14 , C08L61/20
摘要： This invention relates to lacquer binders which can be diluted with water, consisting of a mixture of:A. 50-94% by weight, preferably 55-80% by weight of a copolymer consisting of copolymerized units ofa. 30-65% by weight of an aromatic vinyl or isopropenyl compound having 8-14 C-atoms or of a methacrylic acid alkyl ester having 1-4 C-atoms in the alcohol component or mixtures thereof,b. 10-30% by weight of at least one acrylic acid alkyl ester having 1-8 C-atoms in the alcohol component,c. 1-20% by weight of maleic acid, fumaric acid, itaconic acid or semiesters thereof having 1-8 C-atoms in the alcohol component, or (meth)acrylic acid or mixtures of the aforesaid monomers,d. 0-20% by weight of at least one hydroxyalkyl ester of (meth)acrylic acid having 2-4 C-atoms in the alkyl group or glycidyl (meth)acrylate or mixtures of the aforesaid monomers,e. 10-30% by weight of N-methylol(meth)acrylic acid amide or N-methoxymethyl (meth)acrylic acid amide, preferably N-methoxymethyl(meth)acrylic acid amide, andf. 2-40% by weight of a reaction product of an allyl glycidyl ether and aliphatic, cycloaliphatic, araliphatic or aromatic monocarboxylic acid having 2-30 C-atoms or mixtures thereof, preferably saturated aliphatic branched chain monocarboxylic acids having 5-20 C-atoms, in particular .alpha.-ethyl-hexanoic acid isononanoic acid; andB. 6-50% by weight, preferably 20 to 55% by weight of an aminoplast resin; andC. 0-30% by weight, based on the copolymer, of a lactam, 30-100% of the number of carboxyl groups of component A.c. incorporated in the copolymer being neutralised by ammonia or mono- or polyamines.
摘要翻译：本发明涉及可用水稀释的漆粘合剂，其由以下混合物组成：A.50-94重量％，优选55-80重量％的由共聚单元组成的共聚物。 b）在醇组分或其混合物中含有30-65重量％的具有8-14个碳原子的芳族乙烯基或异丙烯基化合物或具有1-4个C原子的甲基丙烯酸烷基酯。 10-30重量％的至少一种在醇组分中具有1-8个C原子的丙烯酸烷基酯，c。 1-20重量％的在醇组分中具有1-8个碳原子的马来酸，富马酸，衣康酸或其半酯或（甲基）丙烯酸或上述单体的混合物，d。 0-20重量％的至少一种在烷基中具有2-4个C原子的（甲基）丙烯酸的羟烷基酯或（甲基）丙烯酸缩水甘油酯或上述单体的混合物， 10-30重量％的N-羟甲基（甲基）丙烯酸酰胺或N-甲氧基甲基（甲基）丙烯酸酰胺，优选N-甲氧基甲基（甲基）丙烯酸酰胺，和f。 2-40重量％的烯丙基缩水甘油醚与具有2-30个碳原子的脂族，脂环族，芳脂族或芳族一元羧酸或其混合物的反应产物，优选具有5-20个C原子的饱和脂肪族支链单羧酸，特别是α-乙基 - 己酸异壬酸; 和B. 6-50重量％，优选20至55重量％的氨基塑料树脂; 和基于共聚物的0-30重量％的内酰胺，30-100重量份的组分A.c.的羧基数。掺入共聚物中被氨或单胺或多胺中和。

13. 发明授权

US5387642A Aqueous binder composition and a process for its preparation 失效
标题翻译：水性粘合剂组合物及其制备方法
公开(公告)号：US5387642A
公开(公告)日：1995-02-07
申请号：US7219
申请日：1993-01-22
申请人： Harald Blum , Werner Kubitza , Peter Hohlein
发明人： Harald Blum , Werner Kubitza , Peter Hohlein
IPC分类号： C08G18/08 , C08G18/10 , C08G18/12 , C08G18/66 , C08J3/20 , C08K3/20 , C08L51/00 , C08L67/00
CPC分类号： C08G18/6659 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G2190/00
摘要： This invention relates to an aqueous binder composition containingA) an aqueous solution or dispersion of an organic polyol component which can be diluted with water and contains at least one polyester resin containing urethane, carboxylate and hydroxyl groups andB) a polyisocyanate component which has a viscosity of 50 to 10,000 mPa.s at 23.degree. C. and contains at least one organic polyisocyanate which is present as an emulsion in component A),wherein the NCO/OH equivalent ratio, based on the isocyanate groups of component B) and the hydroxyl groups of the polyol component present in A), is 0.5:1 to 5:1.The invention also relates to a process for the preparation of these coating compositions by emulsifying a polyisocyanate component having a viscosity of 50 to 10,000 mPa.s at 23.degree. C. and containing at least one organic polyisocyanate in an aqueous solution or dispersion of a polyester resin containing urethane, carboxylate and hydroxyl groups in an sufficient to provide an an NCO/OH equivalent ratio, based on the isocyanate groups of the polyisocyanate component and the hydroxyl groups of the polyester resin, of 0.5:1 to 5:1.
摘要翻译：本发明涉及一种水性粘合剂组合物，其含有A）有机多元醇组分的水溶液或分散体，其可以用水稀释并含有至少一种含有氨基甲酸酯，羧酸酯和羟基的聚酯树脂，和B）多异氰酸酯组分，其具有粘度在23℃为50至10,000mPa.s，并且含有至少一种有机多异氰酸酯，其作为组分A）中的乳液存在，其中基于组分B）的异氰酸酯基和NCO / OH当量比存在于A）中的多元醇组分的羟基为0.5:1至5:1。本发明还涉及一种制备这些涂料组合物的方法，该方法是在23℃下将粘度为50至10,000mPa.s的多异氰酸酯组分乳化并在聚酯的水溶液或分散体中含有至少一种有机多异氰酸酯含有聚氨酯，羧酸酯和羟基的树脂，其量足以提供基于多异氰酸酯组分的异氰酸酯基团和聚酯树脂的羟基的NCO / OH当量比为0.5:1至5:1。

14. 发明授权

US4798859A Polyhydroxyl compounds containing ester and ether groups as reactive diluents 失效
标题翻译：含有酯和醚基团的多羟基化合物作为反应性稀释剂
公开(公告)号：US4798859A
公开(公告)日：1989-01-17
申请号：US95928
申请日：1987-09-14
申请人： Peter Hohlein , Eberhard Kreiss , Franz Mory , Bernd Riberi
发明人： Peter Hohlein , Eberhard Kreiss , Franz Mory , Bernd Riberi
IPC分类号： C08F299/04 , C08F283/01 , C08L67/06 , C09D167/00 , C09D167/02 , C09D167/08 , C08L67/02 , C08L67/08
CPC分类号： C09D167/00
摘要： An improved lacquer system composition based on alkyl resins and/or oil-free polyesters contains as a reactive diluent the esterification product of(A) polyols containing an average on average at least 3 hydroxyl groups per molecule and, per hydroxyl group, an average of 0.5 to 15, but in total no more than an average of 20 ether groups per molecule and(B) 0.05 to 1.0 equivalent, based on hydroxyl groups of A, of C.sub.2 -C.sub.30 monocarboxylic acids,with the proviso that the esterification products of A and B have an acid number of at most 5, a hydroxyl number of from 5 to 800 and, on average, from 0.1 to 5 hydroxyl groups per molecule.
摘要翻译：基于烷基树脂和/或无油聚酯的改进的漆系统组合物含有作为反应性稀释剂的（A）多元醇的酯化产物，其每分子平均含有至少3个羟基，每个羟基平均为 0.5〜15，但总共不超过每个分子20个醚基团，（B）基于A的C 2 -C 30单羧酸的羟基为0.05-1.0当量，条件是A的酯化产物 B的酸值最多为5，羟值为5〜800，平均每个分子为0.1〜5个羟基。

15. 发明授权

US4684691A Process for the production of siccativated aqueous lacquers with polybutadiene/maleic acid anhydride adducts as bonding agent 失效
标题翻译：用聚丁二烯/马来酸酐加合物作为粘合剂生产酸洗水性漆的方法
公开(公告)号：US4684691A
公开(公告)日：1987-08-04
申请号：US757800
申请日：1985-07-22
申请人： Hans G. Stahl , Peter Hohlein , Hans-Joachim Traenckner , Lothar Fleiter , Jurgen Schwindt
发明人： Hans G. Stahl , Peter Hohlein , Hans-Joachim Traenckner , Lothar Fleiter , Jurgen Schwindt
IPC分类号： C08F279/00 , C08C19/28 , C08F279/02 , C09D7/80 , C09D151/00 , C09D151/04 , C09F9/00 , C08L51/00
CPC分类号： C08F279/02 , C08C19/28 , C09D151/04
摘要： Aqueous lacquers, which contain grafted polybutadiene/maleic acid semi-esters or semi-amides as bonding agent, can be siccativated while the siccative is firstly dispersed in the aqueous phase and the bonding agent is dispersed in this dispersion.
摘要翻译：含有接枝聚丁二烯/马来酸半酯或半酰胺作为粘合剂的水性漆可以在首先分散在水相中并将粘合剂分散在该分散体中的同时被干燥。

16. 发明授权

US4304695A Air-drying, fatty acid-modified lacquer binders, based on fumaric or maleic acid bis-glycidyl ester copolymers 失效
标题翻译：基于富马酸或马来酸双缩水甘油酯共聚物的空气干燥脂肪酸改性漆粘合剂
公开(公告)号：US4304695A
公开(公告)日：1981-12-08
申请号：US181043
申请日：1980-08-25
申请人： Peter Hohlein , Hans-Joachim Traenckner , Lothar Fleiter , Ludwig Bottenbruch
发明人： Peter Hohlein , Hans-Joachim Traenckner , Lothar Fleiter , Ludwig Bottenbruch
IPC分类号： C08F8/00 , C08F8/14 , C09D155/04 , C09D163/00 , C08F220/32
CPC分类号： C09D155/04 , C08F8/14 , C08F2810/30
摘要： A binder composition which has a number average molecular weight of from 1000 to 20,000 and which comprises, in copolymerized form, from 5 to 55% by weight of fumaric acid and/or maleic acid bis-glycidyl ester and from 95 to 45% by weight of one or more vinyl and/or vinylidene monomers, esterified to an acid number of from 3 to 30 mg KOH/g with from 18 to 72% by weight, based on copolymer plus fatty acid, of a fatty acid and subsequently reacted with 0 to 3% by weight, based on copolymer plus fatty acid plus dicarboxylic acid anhydride, of a dicarboxylic acid anhydride.
摘要翻译：数均分子量为1000〜20,000的粘合剂组合物，其共聚形式为5〜55重量％的富马酸和/或马来酸双缩水甘油酯，95〜45重量％的一种或多种乙烯基和/或亚乙烯基单体，酯化为酸值为3至30mg KOH / g，基于共聚物加脂肪酸的18至72重量％的脂肪酸，随后与0 至3重量％，基于共聚物加脂肪酸加二羧酸酐的二羧酸酐。

17. 发明授权

US4291135A Binders for coating compositions 失效
标题翻译：涂料组合物粘合剂
公开(公告)号：US4291135A
公开(公告)日：1981-09-22
申请号：US152567
申请日：1980-05-22
申请人： Peter Hohlein , Michael Sonntag
发明人： Peter Hohlein , Michael Sonntag
IPC分类号： C08L33/00 , C08G59/00 , C08G59/32 , C08G63/181 , C08G63/46 , C08G81/00 , C08G81/02 , C08L33/02 , C08L33/04 , C08L63/00 , C08L67/00 , C08L83/00 , C08L83/04 , C09D133/14 , C09D167/00 , C09D187/00 , C09D201/02 , B05D3/02 , B32B15/08 , B32B27/00
CPC分类号： C09D133/14 , C08G63/181 , C08G63/46 , C09D167/00 , C08L67/00 , C08L83/04 , Y10T428/31681 , Y10T428/31699
摘要： Reaction products of alkyd resins and/or oil-free polyesters, (meth) acrylic acid copolymers and polysiloxans are excellent binders for high quality lacquers particularly for surface lacquers used in the motor car industry.
摘要翻译：醇酸树脂和/或无油聚酯，（甲基）丙烯酸共聚物和聚硅氧烷的反应产物是用于高品质漆的优异粘合剂，特别是用于汽车工业中的表面漆。

18. 发明授权

US4985506A Oxidatively cross-linkable, water dilutable binders, a process for their preparation and their use 失效
标题翻译：可氧化交联的水可稀释粘合剂，其制备方法及其用途
公开(公告)号：US4985506A
公开(公告)日：1991-01-15
申请号：US371262
申请日：1989-06-26
申请人： Harald Blum , Peter Hohlein , Michael Sonntag , Wolfgang Wellner
发明人： Harald Blum , Peter Hohlein , Michael Sonntag , Wolfgang Wellner
IPC分类号： C08F8/14 , C08F8/44 , C08F20/02 , C08F22/06 , C08F222/00 , C08G81/02 , C09D133/00 , C09D133/04 , C09D135/00 , C09J133/00 , C09J133/04 , C09J135/00 , C09K3/10
CPC分类号： C08F8/14 , C08F8/44 , C08F2810/20 , C08F2810/30
摘要： Oxidatively cross-linkable, water dilutable binders suitable for lacquers, coating compositions and sealing compounds are modified co-polymers of olefinically unsaturated compounds, having a molecular weight of 6000 to 160,000 and having for each 100 grams of solids content, a total of from60 to 250 milliequivalents of chemically incorporated carboxyl groups, of which from 10 to 100% are neutralized thereby rendering the product dilutable in water andfrom 15 to 50% by weight of chemically incorporated moieties corresponding to the formula--O--RwhereinR represents an olefinically monounsaturated or polyunsaturated aliphatic hydrocarbon having a molecular weight above 166 and containing from 12 to 22 carbon atoms, are prepared by:(a) preparing a co-polymer having a molecular weight from 5000 to 80,000, determined by gel permeation chromatography, and having intramolecular carboxylic acid anhydride units corresponding to the formula ##STR1## and an anhydride equivalent weight of from 240 to 1960 by a radically initiated co-polymerization of olefinically unsaturated dicarboxylic acid anhydrides with other olefinically unsaturated monomers,(b) reacting at least 50% of the acid anhydride units present in the co-polymer from (a) with an unsaturated monohydric alcohol corresponding to the formulaR--OH with anhydride ring opening ester formation, and(c) converting the free carboxyl groups in the reaction product of (b) to an extent of 10 to 100% into carboxylate groups by neutralization of the carboxys with a base.
摘要翻译：适用于漆，水溶性组合物和密封化合物的可氧化交联的水可稀释粘合剂是烯属不饱和化合物的改性共聚物，其分子量为6000至160,000，并且对于每100克固体含量，总共为60 至250毫当量的化学引入的羧基，其中10至100％被中和，使产物在水中可稀释，和15至50重量％的化学引入部分对应于式-OR，其中R表示烯属单不饱和或分子量大于166且含有12至22个碳原子的多不饱和脂族烃通过以下方法制备：（a）通过凝胶渗透色谱法测定分子量为5000至80,000，并具有分子内羧酸的共聚物对应于式“IMAGE”的酸酐单元和2当量的酸酐当量通过烯属不饱和二羧酸酐与其它烯属不饱和单体的自由引发共聚，（b）使来自（a）的共聚物中存在的至少50％的酸酐单元与不饱和一元醇对应于具有酸酐开环酯形成的式R-OH，和（c）通过用碱中和羧基将羧酸酯基团将（b）的反应产物中的游离羧基转化成羧酸酯基团。

19. 发明授权

US4677181A Polyhydroxyl compounds containing ether and ester groups and their use in the production of polyurethane plastics 失效
标题翻译：含有醚和酯基的多羟基化合物及其在生产聚氨酯塑料中的应用
公开(公告)号：US4677181A
公开(公告)日：1987-06-30
申请号：US888541
申请日：1986-07-21
申请人： Peter Hohlein , Alois Fehlbier , Hermann Gruber
发明人： Peter Hohlein , Alois Fehlbier , Hermann Gruber
IPC分类号： C08G18/00 , C08G18/48 , C08G65/26 , C08G65/332 , C08G65/34 , C08G18/32
CPC分类号： C08G65/2606 , C08G18/4887 , C08G18/4891 , C08G65/3322
摘要： The present invention is directed to polyhydroxyl compounds containing both ether and ester groups, having an average hydroxyl functionality of 2 to 6 and an average hydroxyl number of about 100 to 600, based on the esterification product of (i) polyether polyols having an average hydroxyl functionality of 3 to 8 and an average hydroxyl number of about 200 to 1000 with (ii) about 5 to 70 equivalent %, based on the hydroxyl group of component (i) and the carboxyl group of component (ii), of organic monocarboxylic acids. The present invention is also directed to the use of the polyhydroxyl compounds as synthesis components in the production of polyurethane plastics materials by the isocyanate-polyaddition process, particularly their use as the polyol component in two-component polyurethane coating agents and/or polyurethane casting systems which are solvent-free or have a low solvent content.
摘要翻译：本发明涉及包含醚和酯基的多羟基化合物，其平均羟基官能度为2-6，平均羟值为约100-600，基于（i）具有平均羟基的聚醚多元醇的酯化产物官能度为3至8，平均羟值为约200至1000，（ii）约5至70当量％，基于组分（i）的羟基和组分（ii）的羧基，有机单羧酸。本发明还涉及多异羟基化合物作为合成成分在聚氨酯塑料材料生产中的用途，通过异氰酸酯加成方法，特别是它们在双组分聚氨酯涂料和/或聚氨酯浇注体系中作为多元醇组分的用途它们是无溶剂的或具有低溶剂含量。

20. 发明授权

US4442145A Process for coating substrates with polyisocyanates and polyhydroxy polyacrylates 失效
标题翻译：用多异氰酸酯和多羟基聚丙烯酸酯涂覆基材的方法
公开(公告)号：US4442145A
公开(公告)日：1984-04-10
申请号：US393224
申请日：1982-06-28
申请人： Joachim Probst , Bernd Riberi , Gunter Kolb, deceased , Peter Hohlein
发明人： Joachim Probst , Bernd Riberi , Gunter Kolb, deceased , Peter Hohlein
IPC分类号： C08G18/00 , B05D7/24 , C08G18/62 , B05D3/02
CPC分类号： C08G18/6229
摘要： The invention relates to a process for the production of coatings using a coating composition containing as binder optionally blocked lacquer-grade polyisocyanates in combination with polyhydroxy polyacrylate resins based on copolymers of certain hydroxy alkyl(meth)acrylates, methyl methacrylate, 2-ethylhexyl acrylate and, optionally, (meth)acrylic acid, wherein the molecular weight is in the range from about 30,000 to 80,000, the content of low molecular weight constituents having molecular weights of at most about 3000 amounts to between 3 and 15% by weight, the molecular heterogeneity factor amounts to between about 1.0 and 10.0, and the parameter for the chemical heterogeneity of the copolymer is between 0 and about 0.06.
摘要翻译：本发明涉及一种使用涂料组合物制备涂料的方法，所述涂料组合物含有作为粘合剂的任选封闭的漆级多异氰酸酯与多羟基聚丙烯酸酯树脂的组合，所述聚羟基聚异氰酸酯基于某些羟基烷基（甲基）丙烯酸酯，甲基丙烯酸甲酯，丙烯酸2-乙基己酯和，任选地，（甲基）丙烯酸，其中分子量在约30,000至80,000的范围内，分子量至多约3000的低分子量组分的含量为3至15重量％，分子量异质因子在约1.0和10.0之间，共聚物的化学异质性参数在0和约0.06之间。

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