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11. 发明授权

US07179945B2 High-selective production method of di(aminomethyl)-substituted aromatic compound 有权
标题翻译：二（氨基甲基）取代芳族化合物的高选择性生产方法
公开(公告)号：US07179945B2
公开(公告)日：2007-02-20
申请号：US10781884
申请日：2004-02-20
申请人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yoshiaki Yamamoto
发明人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yoshiaki Yamamoto
IPC分类号： C07C211/00
CPC分类号： C07C253/30 , C07C209/48 , C07C211/27 , C07C211/30 , C07C255/58
摘要： A di(aminomethyl)-substituted aromatic compound is produced by a two-stage hydrogenation. In the first stage, an aromatic dinitrile is hydrogenated into a cyano(aminomethyl)-substituted aromatic compound in the presence of a Pd-containing catalyst. The resultant cyano(aminomethyl)-substituted aromatic compound is then hydrogenated in the second stage into the target di(aminomethyl)-substituted aromatic compound in the presence of a Ni- and/or Co-containing catalyst. By the above method, the di(aminomethyl)-substituted aromatic compound is produced in a high selectivity and a sufficiently high yield without reducing the catalyst life.
摘要翻译：二（氨基甲基）取代的芳族化合物是通过两阶段氢化制备的。在第一阶段中，在含Pd催化剂的存在下，将芳族二腈氢化为氰基（氨基甲基）取代的芳族化合物。然后将所得的氰基（氨基甲基）取代的芳香族化合物在Ni-和/或含Co催化剂存在下，在第二阶段中氢化成目标二（氨基甲基） - 取代的芳族化合物。通过上述方法，在不降低催化剂寿命的情况下以高选择性和足够高的产率制备二（氨基甲基）取代的芳族化合物。

12. 发明授权

US07161021B2 Process for producing a polynitrile compound 有权
标题翻译：腈化合物的制备方法
公开(公告)号：US07161021B2
公开(公告)日：2007-01-09
申请号：US10313022
申请日：2002-12-06
申请人： Kenichi Nakamura , Shuji Ebata , Fumio Tanaka , Takuji Shitara
发明人： Kenichi Nakamura , Shuji Ebata , Fumio Tanaka , Takuji Shitara
IPC分类号： C07C253/18 , C07C255/04
CPC分类号： C07C253/28 , C07C255/51
摘要： In a process for producing a polynitrile compound comprising introducing a polysubstituted organic compound (POC) which is a carbon ring or heterocyclic compounds having a plurality of organic substituents into a reactor with ammonia and a gas containing oxygen and ammoxidizing POC in the presence of a catalyst, at least a portion of the unreacted POC and a mononitrile compound of an intermediate product in the reaction gas discharged from the reactor is separated, recovered and recycled to the reactor so that the flow rate of the mononitrile compound at the outlet of the reactor is 2 to 16% by mole of the total flow rate of POC and the mononitrile compound supplied to the reactor.Burning reaction of the side reaction is suppressed and the loss of POC can be decreased without adverse effects on productivity and the polynitrile compound can be obtained at a high yield.
摘要翻译：在制备多腈化合物的方法中，包括在催化剂存在下，将具有多个有机取代基的多取代有机化合物（POC）或具有多个有机取代基的杂环化合物引入反应器中，所述反应器具有氨和含氧气和氨氧化POC的气体，将从反应器排出的反应气体中的至少一部分未反应的POC和中间产物的单腈化合物分离，回收并再循环至反应器，使得反应器出口处的单腈化合物的流速为相对于供给到反应器的POC和单腈化合物的总流量为2〜16摩尔％。抑制副反应的燃烧反应，可以降低POC的损失，而不会对生产率产生不利影响，并且可以以高产率获得腈化合物。

13. 发明授权

US06541632B2 Process for producing heterocyclic nitriles 有权
标题翻译：制备杂环腈的方法
公开(公告)号：US06541632B2
公开(公告)日：2003-04-01
申请号：US10173619
申请日：2002-06-19
申请人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
发明人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
IPC分类号： C07D24124
CPC分类号： C07C253/28 , C07D213/85 , C07C255/51
摘要： A carbocyclic or heterocyclic compound, ammonia and an oxygen-containing gas are subjected to fluid catalytic reaction in vapor phase in the presence of a catalyst containing alkali metal to produce an aromatic or heterocyclic nitrile. The use of the catalyst containing a specific amount of alkali metal enables the stable production of the aromatic or heterocyclic nitrile in high yields with little change with time even when water is present in the reaction system. The use of the catalyst containing the alkali metal also enables the recycle and reuse of unreacted ammonia which is usually accompanied by water, thereby reducing production costs.
摘要翻译：在含有碱金属的催化剂存在下，将碳环或杂环化合物，氨和含氧气体在气相中进行流化催化反应以产生芳族或杂环腈。使用含有特定量的碱金属的催化剂能够以高产率稳定地生产芳族或杂环腈，即使在反应体系中存在水时也几乎不改变。使用含有碱金属的催化剂也能够再循环和再利用通常伴有水的未反应的氨，从而降低生产成本。

14. 发明授权

US4987256A Process for production of .alpha.-hydroxycarboxylic acid amide 失效
标题翻译： α-羟基羧酸酰胺的制备方法
公开(公告)号：US4987256A
公开(公告)日：1991-01-22
申请号：US550150
申请日：1990-07-09
申请人： Shuji Ebata , Hiroyuki Hirayama , Takako Uchiyama
发明人： Shuji Ebata , Hiroyuki Hirayama , Takako Uchiyama
IPC分类号： B01J23/34 , C07B61/00 , C07C231/06 , C07C235/06
CPC分类号： C07C231/065
摘要： Process for production of .alpha.-hydroxycarboxylic acid amide of the general formula (A), comprising hydrating cyanhydrin of the general formula (B) by the use of a modified manganese dioxide catalyst containing one or more of zirconium, vanadium, and tin, and an alkali metal element. ##STR1## wherein all the symbols are as defined in the appended claims.

15. 发明授权

US4386017A Preparation of improved catalyst composition 失效
标题翻译：改进的催化剂组合物的制备
公开(公告)号：US4386017A
公开(公告)日：1983-05-31
申请号：US205594
申请日：1980-11-10
申请人： Tadasi Nakamura , Minoru Osugi , Yoriko Obata , Shuji Ebata
发明人： Tadasi Nakamura , Minoru Osugi , Yoriko Obata , Shuji Ebata
IPC分类号： C07C29/15 , B01J23/80 , C07B61/00 , C07C27/00 , C07C29/154 , C07C31/04 , C07C67/00 , B01J23/08 , B01J21/02 , B01J27/24
CPC分类号： B01J23/80 , C07C29/154 , Y02P20/52
摘要： A process for preparing a catalyst composition comprising copper oxide, zinc oxide and aluminum oxide as essential ingredients and optionally containing boron oxide, which comprises(a) a step of precipitating from an aqueous solution of a water-soluble copper salt optionally containing a water-soluble boron compound the copper component, together with the boron component if it is present, using an alkaline substance selected from alkali carbonates and alkali bicarbonates as a precipitant;(b) a step of blowing carbon dioxide gas into an aqueous dispersion of a zinc compound selected from zinc oxide and zinc hydroxide optionally containing a water-soluble boron compound to convert the zinc compound to basic zinc carbonate and simultaneously precipitate the boron component if it is present; and(c) a step of calcining a mixture of the solid products obtained in steps (a) and (b) in the presence of an alumina precursor compound.The resulting catalyst is useful for synthesizing methanol from a gaseous mixture of carbon monoxide and/or carbon dioxide and hydrogen.
摘要翻译：一种制备包含氧化铜，氧化锌和氧化铝作为必要成分并任选地含有氧化硼的催化剂组合物的方法，其包括（a）从任选含有水溶性铜盐的水溶性铜盐的水溶液中沉淀出的步骤，使用选自碱金属碳酸盐和碱金属碳酸氢盐的碱性物质作为沉淀剂，将铜组分与硼组分一起存在; （b）将任选含有水溶性硼化合物的锌化合物的锌化合物的水分散体吹入二氧化碳气体的步骤，将锌化合物转化为碱式碳酸锌，同时使硼成分沉淀存在; 和（c）在氧化铝前体化合物的存在下煅烧步骤（a）和（b）中获得的固体产物的混合物的步骤。所得催化剂可用于从一氧化碳和/或二氧化碳和氢气的气体混合物合成甲醇。

16. 发明授权

US06429330B1 Process for producing carbocyclic nitriles 有权
标题翻译：制备碳环腈的方法
公开(公告)号：US06429330B1
公开(公告)日：2002-08-06
申请号：US09613632
申请日：2000-07-11
申请人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
发明人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
IPC分类号： C07C25328
CPC分类号： C07C253/28 , C07D213/85 , C07C255/51
摘要： A carbocyclic or heterocyclic compound, ammonia and an oxygen-containing gas are subjected to fluid catalytic reaction in vapor phase in the presence of a catalyst containing alkali metal to produce an aromatic or heterocyclic nitrile. The use of the catalyst containing a specific amount of alkali metal enables the stable production of the aromatic or heterocyclic nitrile in high yields with little change with time even when water is present in the reaction system. The use of the catalyst containing the alkali metal also enables the recycle and reuse of unreacted ammonia which is usually accompanied by water, thereby reducing production costs.
摘要翻译：在含有碱金属的催化剂存在下，将碳环或杂环化合物，氨和含氧气体在气相中进行流化催化反应以产生芳族或杂环腈。使用含有特定量的碱金属的催化剂能够以高产率稳定地生产芳族或杂环腈，即使在反应体系中存在水时也几乎不改变。使用含有碱金属的催化剂也能够再循环和再利用通常伴有水的未反应的氨，从而降低生产成本。

17. 发明授权

US06284893B1 Process for producing nitrile compounds 有权
公开(公告)号：US06284893B1
公开(公告)日：2001-09-04
申请号：US09742359
申请日：2000-12-22
申请人： Takuji Shitara , Takashi Okawa , Shuji Ebata , Fumisada Kosuge
发明人： Takuji Shitara , Takashi Okawa , Shuji Ebata , Fumisada Kosuge
IPC分类号： C07C25328
摘要： There is disclosed a process for producing a nitrile compounds by ammoxidation of a carbocyclic or heterocyclic compound having organic substituent(s) by reacting the compound with ammonia and an oxygen-containing gas, wherein unreacted ammonia is recovered from the reaction product gas and recycled to the reaction system.

18. 发明授权

US4547482A Catalyst composition suited for synthesis of methanol 失效
标题翻译：适用于合成甲醇的催化剂组合物
公开(公告)号：US4547482A
公开(公告)日：1985-10-15
申请号：US515933
申请日：1983-07-20
申请人： Minoru Osugi , Tadasi Nakamura , Shuji Ebata
发明人： Minoru Osugi , Tadasi Nakamura , Shuji Ebata
IPC分类号： C07C29/15 , B01J27/16 , B01J27/18 , C07B61/00 , C07C27/00 , C07C29/153 , C07C29/154 , C07C31/04 , C07C67/00 , B01J23/80
CPC分类号： B01J27/1817 , C07C29/153 , Y02P20/52
摘要： A catalyst composition comprising copper oxide, zinc oxide and an oxyacid of phosphorus or its salt; and a method for producing methanol by reacting carbon monoxide and/or carbon dioxide with hydrogen in the vapor phase in the presence of a catalyst, wherein the catalyst is the aforesaid catalyst composition which has been activated by reduction with a hydrogen-containing gas.
摘要翻译：包含氧化铜，氧化锌和磷或其盐的含氧酸的催化剂组合物; 以及在催化剂存在下，使气相中的一氧化碳和/或二氧化碳与氢气反应生成甲醇的方法，其中催化剂是通过用含氢气体还原而活化的上述催化剂组合物。

19. 发明授权

US07468342B2 Catalysts and process for producing aromatic amines 有权
标题翻译：催化剂和生产芳香胺的方法
公开(公告)号：US07468342B2
公开(公告)日：2008-12-23
申请号：US10139214
申请日：2002-05-07
申请人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yasushi Hiramatsu
发明人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yasushi Hiramatsu
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： B01J21/066 , B01J21/06 , B01J23/70 , B01J23/755 , B01J23/868 , B01J37/0009 , B01J37/03 , C07C209/48 , C07C211/27
摘要： As catalysts for producing aromatic amines by hydrogenating aromatic nitrites, there are disclosed (1) the catalyst comprising a metal catalyst component comprising Ni and/or Co and a specific amount of zirconia as a carrier component, which is prepared by drying, calcining and forming a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; and (2) the catalyst comprising the metal catalyst component and the carrier component, which is prepared by filtering a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; forming the precipitate without drying to obtain a formed product; and subjecting the formed product to drying and then calcining. These catalysts are free from breaking owing to rapid generation of methane and evaporation of liquid ammonia by hydrogenolysis of high boiling by-products of the hydrogenation when reactivated after deactivation of the catalyst, which allows the long-term use of the catalysts.
摘要翻译：作为用于通过氢化芳族亚硝酸盐生产芳族胺的催化剂，公开了（1）催化剂，其包含由Ni和/或Co组成的金属催化剂组分和特定量的氧化锆作为载体组分，其通过干燥，煅烧和形成通过将含有金属催化剂组分和载体组分的可溶性盐的水溶液加入到碱性水溶液中而产生的沉淀物; 和（2）包含金属催化剂组分和载体组分的催化剂，其通过将含有金属催化剂组分和载体组分的可溶性盐的水溶液过滤到碱水溶液中制备的沉淀物; 在不干燥的状态下形成沉淀物，得到成形品; 对成形体进行干燥，然后煅烧。由于催化剂失活后再活化时氢化的高沸点副产物的氢解，液体氨的迅速产生和液氨的蒸发，这些催化剂不会破裂，这允许长期使用催化剂。

20. 发明授权

US07307181B2 Process for producing a nitrile compound 有权
标题翻译：腈化合物的制造方法
公开(公告)号：US07307181B2
公开(公告)日：2007-12-11
申请号：US10865824
申请日：2004-06-14
申请人： Kenichi Nakamura , Shuji Ebata , Fumio Tanaka , Takuji Shitara
发明人： Kenichi Nakamura , Shuji Ebata , Fumio Tanaka , Takuji Shitara
IPC分类号： C07C253/24
CPC分类号： C07C253/28 , C07C255/51
摘要： In a process for producing a nitrile compound comprising introducing a carbon ring or heterocyclic compound having organic substituents, ammonia and the air into a reactor and reacting the introduced compounds in the presence of a catalyst, during the reaction, a residual gas obtained after the formed nitrile compound is separated from a reaction gas discharged from the reactor is recycled to the reactor in an amount of 10 to 60% by volume based on the amount of the fresh raw material gas supplied to the reactor and the ratio of the amount by mole of molecular oxygen to the amount by mole of the organic substituent in the carbon ring or heterocyclic compound having organic substituents supplied to the reactor (O2/organic substituent) is kept within 1.5 to 7. The reaction is achieved under an advantageous condition and the nitrile compound can be produced industrially advantageously at a higher yield.
摘要翻译：在制备腈化合物的方法中，包括将具有有机取代基的碳环或杂环化合物，氨和空气引入反应器中并在催化剂存在下使引入的化合物反应，在反应过程中获得的残余气体将从反应器排出的反应气体中分离的腈化合物以供给反应器的新鲜原料气体的量为基准，以10〜60体积％的量循环至反应器，具有提供给反应器（O 2 2 /有机取代基）的有机取代基的碳环或杂环化合物中的有机取代基的分子氧保持在1.5〜7范围内。在有利条件下，腈化合物可以在工业上有利地以更高的产率生产。

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