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    • 14. 发明授权
    • Functional molecular device
    • 功能分子装置
    • US07679080B2
    • 2010-03-16
    • US11571135
    • 2005-06-23
    • Eriko MatsuiNobuyuki MatsuzawaAkio YasudaOliver Harnack
    • Eriko MatsuiNobuyuki MatsuzawaAkio YasudaOliver Harnack
    • H01L51/30
    • B82Y30/00B82Y10/00H01L27/283H01L51/005H01L51/0067H01L51/0512H01L51/0583H01L51/0595Y10S977/731Y10S977/791Y10S977/94Y10S977/943
    • A functional molecular device displaying its functions under the action of an electrical field is provided. A Louis base molecule, exhibiting positive dielectric constant anisotropy or exhibiting dipole moment along the long-axis direction of the Louis base molecule, is arrayed in the form of a pendant on an electrically conductive linear or film-shaped principal-axis molecule of a conjugated system, via a metal ion capable of acting as a Louis acid. The resulting structure is changed in conformation on application of an electrical field to exhibit its function. The electrically conductive linear or film-shaped principal-axis molecule and the Louis base molecule form a complex with the metal ion. On application of the electrical field, the Louis base molecule performs a swinging movement or a seesaw movement to switch the electrical conductivity of the principal-axis molecule. This molecule exhibits electrical characteristics which may be reversed depending on whether or not the molecule has been subjected to electrical field processing. A molecular device having a function equivalent to one of CMOS may be produced from one and the same material.
    • 提供了在电场作用下显示其功能的功能分子装置。 在路易斯碱分子的长轴方向显示出正介电常数各向异性或显示偶极矩的路易斯碱基分子以共轭的导电线性或膜状主轴分子的侧基的形式排列 系统,通过能够作为路易斯酸的金属离子。 所产生的结构在施加电场以表现其功能的结构上改变。 导电线性或膜状主轴分子和路易斯碱分子与金属离子形成络合物。 在施加电场时,路易斯碱分子进行摆动运动或跷跷板运动以切换主轴分子的导电性。 该分子表现出电特性,其可以根据分子是否经受电场加工而反转。 具有与CMOS之一相当的功能的分子器件可以由同一材料制造。
    • 16. 发明授权
    • Metal complexes of heterocyclic aromatic compounds
    • 杂环芳族化合物的金属络合物
    • US07038025B2
    • 2006-05-02
    • US10468982
    • 2002-12-18
    • Eriko MatsuiYuriko KainoToshiyuki KunikiyoYoshifumi MoriTatsushiro Hirata
    • Eriko MatsuiYuriko KainoToshiyuki KunikiyoYoshifumi MoriTatsushiro Hirata
    • C09B45/00C07D207/00
    • C07D207/32C07D207/323
    • A novel metal complex of a heterocyclic aromatic compound which shows a low activation energy, is stabilized structurally, is capable of modulation of the structure thereof, and capable of preferably functioning as a molecular device in technological fields. The metal complex of a heterocyclic aromatic compound comprises a transition metal (for example, silver ion) as a central atom, and basic ligands comprised of a 5-membered heterocyclic aromatic compound (for example, pyrrole rings), in which the position of the central atom can be changed by an internal factor such as transfer of an electric charge or by an external factor such as application of an electric field, a change in acidity of the surrounding environment, etc., whereby the number of atoms (or the number of electrons) relating to the coordination ability can be modulated, and, upon polymerization, the conformation can be modulated depending on the position of the central atom.
    • 显示低活化能的杂环芳族化合物的新型金属络合物在结构上是稳定的,能够调节其结构,并且能够优选在技术领域中用作分子装置。 杂环芳族化合物的金属络合物包含作为中心原子的过渡金属(例如银离子)和由5元杂环芳族化合物(例如吡咯环)构成的碱性配体,其中, 中心原子可以通过诸如电荷的转移或诸如施加电场的外部因素,周围环境的酸度变化等内部因素而改变,由此原子数(或数) 的电子)可以调节,并且在聚合时,可以根据中心原子的位置来调节构象。
    • 20. 发明授权
    • Metal complex of heterocyclic aromatic compound
    • 杂环芳族化合物的金属络合物
    • US07598358B2
    • 2009-10-06
    • US11368793
    • 2006-03-06
    • Eriko MatsuiYuriko KainoToshiyuki KunikiyoTatsushiro HirataYoshifumi Mori
    • Eriko MatsuiYuriko KainoToshiyuki KunikiyoTatsushiro HirataYoshifumi Mori
    • C09B45/00
    • C07D207/32C07D207/323
    • A novel metal complex of a heterocyclic aromatic compound which shows a low activation energy, is stabilized structurally, is capable of modulation of the structure thereof, and capable of preferably functioning as a molecular device in technological fields. The metal complex of a heterocyclic aromatic compound comprises a transition metal (for example, silver ion) as a central atom, and basic ligands comprised of a 5-membered heterocyclic aromatic compound (for example, pyrrole rings), in which the position of the central atom can be changed by an internal factor such as transfer of an electric charge or by an external factor such as application of an electric field, a change in acidity of the surrounding environment, etc., whereby the number of atoms (or the number of electrons) relating to the coordination ability can be modulated, and, upon polymerization, the conformation can be modulated depending on the position of the central atom.
    • 显示低活化能的杂环芳族化合物的新型金属络合物在结构上是稳定的,能够调节其结构,并且能够优选在技术领域中用作分子装置。 杂环芳族化合物的金属络合物包含作为中心原子的过渡金属(例如银离子)和由5元杂环芳族化合物(例如吡咯环)构成的碱性配体,其中, 中心原子可以通过诸如电荷的转移或诸如施加电场的外部因素,周围环境的酸度变化等内部因素而改变,由此原子数(或数) 的电子)可以调节,并且在聚合时,可以根据中心原子的位置来调节构象。